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N-叔丁基-N'-氟代苯甲酰基-取代吡啶甲酰肼衍生物的合成与杀虫活性研究

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有机化学 2016年第5期36卷 1051-1059页

作者：胡崇波刘建华杜晓华浙江工业大学催化加氢中心浙江省绿色农药清洁生产技术研究重点实验室浙江省绿色农药协同创新中心杭州310014

为改进双酰肼类杀虫剂的性能,将氟代苯基和吡啶环同时引入双酰肼的基本结构中,设计合成了20个新型的N-叔丁基-N'-氟代苯甲酰基-取代吡啶甲酰肼衍生物,经~1H NMR、^(13)C NMR、IR和HRMS确证了分子结构.生物活性测试表明,在浓度为500 mg/L... 详细信息

为改进双酰肼类杀虫剂的性能,将氟代苯基和吡啶环同时引入双酰肼的基本结构中,设计合成了20个新型的N-叔丁基-N'-氟代苯甲酰基-取代吡啶甲酰肼衍生物,经~1H NMR、^(13)C NMR、IR和HRMS确证了分子结构.生物活性测试表明,在浓度为500 mg/L时,大部分化合物对粘虫(Mythimna separata)的致死率都达到80%以上.其中N-叔丁基-N'-(2,6-二氟苯甲酰基)-2-氯烟酰肼(6bb)和N-叔丁基-N'-(2,6-二氟苯甲酰基)-2,5-二氯烟酰肼(6gb)在浓度为10 mg/L时对粘虫的致死率分别为100%和80%.化合物6bb对东方粘虫的半致死浓度(LC_(50)值)为8.77 mg/L,对东方粘虫的毒力约为虫酰肼的0.51倍,对小菜蛾(Plutella xylostella)的毒力为虫酰肼的1.5倍.

关键词：双酰肼吡啶甲酰肼合成杀虫活性

原位衍生化技术在液相色谱和液相色谱-质谱联用分析中的应用

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色谱 2018年第7期36卷 579-587页

作者：杜苑琪肖小华李攻科中山大学化学学院广东广州510275

衍生化是将待分析物转化为更适合的物质形式以便于分析的有效手段。原位衍生化技术作为一种常用的柱前衍生化方法,可以在样品基质中同时完成分析物的萃取和衍生化,具有高效、灵敏和选择性好的优点。原位衍生化结合其他前处理技术广泛用... 详细信息

衍生化是将待分析物转化为更适合的物质形式以便于分析的有效手段。原位衍生化技术作为一种常用的柱前衍生化方法,可以在样品基质中同时完成分析物的萃取和衍生化,具有高效、灵敏和选择性好的优点。原位衍生化结合其他前处理技术广泛用于胺类、醛酮类、醇类、酚类、羧酸和巯基化合物的分析中,在生物、药物、食品、环境、化妆品分析等领域有广泛的应用。该文概述了原位衍生化的反应类型和代表性衍生试剂,综述了原位衍生化技术在液相色谱和液相色谱-质谱联用分析中的应用,并展望其发展趋势。

关键词：原位衍生化液相色谱液相色谱-质谱综述

Mechanical parameter evolutions and deterioration constitutive model for ductile-brittle failure of surrounding rock in high-stress underground engineering

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Underground Space 2024年第2期15卷 131-152页

作者： Zhi Zheng Ronghua Li Qiang Zhang xiaohua Huang Wei Wang Shuling Huang State Key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite Structures Key Laboratory of Disaster Prevention and Structural Safety of Ministry of EducationCollege of Civil Engineering and ArchitectureGuangxi UniversityNanning 530004China Key Laboratory of Ministry of Education on Safe Mining of Deep Metal Mines Northeastern UniversityShenyang 110819China State Key Laboratory of Simulation and Regulation of Water Cycle in River Basin China Institute of Water Resources and Hydropower ResearchBeijing 100038China Key Laboratory of Ministry of Education for Geomechanics and Embankment Engineering Hohai UniversityNanjing 210098China Key Laboratory of Geotechnical Mechanics and Engineering of Ministry of Water Resources Yangtze River Scientific Research InstituteWuhan 430010China

The deep surrounding rock is usually in the true triaxial stress state,and previous constitutive models based on the understanding of uniaxial and conventional triaxial test results have difficulty characterizing the degradation and fracture process of rock ductile–brittle failure under true triaxial stress ***,this study conducted a series of true triaxial tests to obtain the understanding of the ductile–brittle behaviour of rock,and then combined the test results and the Mogi–Coulomb strength criterion,and proposed calculation methods for the elastic modulus E,cohesion c and internal friction angle u and the evolution functions of E,c and u of rock under true triaxial *** the decreasing of the minimum principal stress r3 or increasing of the intermediate principal stress r2,the marble post-peak stress drop rate gradually increases,the ductility gradually weakens,and the brittleness significantly *** calculation method and evolution function of rock E,c and u under true triaxial stress were proposed.E decreased at first and then tended to remain stable with the increasing of equivalent plastic strain increment dep.c and u slowly increased at first and then rapidly *** a method of parameter degradation rate to realize post-peak stress drop rate to reflect the ductile–brittle characteristics,a new three-dimensional ductile–brittle deterioration mechanical model(3DBDM)was *** proposed model can accurately characterize the influence of r2 and r3 on mechanical parameters,the ductile–brittle behaviour of rock under true triaxial stresses,and the asymmetric failure characteristics of surrounding rock after excavation of deep underground *** proposed model can be reduced to elastic–perfectly plastic,elastic–brittle,cohesion weakening friction strengthening(CWFS),Mohr–Coulomb,and Drucker–Prager models.

关键词： True triaxial stress Post-peak characteristics 3D deterioration model Elastic modulus evolution Cohesion and friction angle evolution

WRKY11 up-regulated dirigent expression to enhance lignin/lignans accumulation in Lilium regale Wilson during response to Fusarium wilt

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Journal of Integrative Agriculture 2024年第8期23卷 2703-2722页

作者： Jie Deng Zi’e Wang Wenyun Li xiaohua Chen Diqiu Liu Faculty of Life Science and Technology Kunming University of Science and TechnologyKunming 650500China

Lilium are highly economically valuable ornamental plants that are susceptible to Fusarium wilt caused by Fusarium *** regale Wilson,a wild lily native to China,is highly resistant to *** this study,a WRKY transcription factor,WRKY11,was isolated from ***,and its function during the interaction between *** and *** was *** ectopic expression of LrWRKY11 in tobacco increased the resistance to F oxysporum,moreover,the transcriptome sequencing and UHPLC-MS/MS analysis indicated that the methyl salicylate and methyl jasmonate levels rose in LrWRKY11 transgenic tobacco,meanwhile,the expression of lignin/lignans biosynthesis-related genes including a dirigent(DiR)was *** lignin/lignans contents in LrWRKY11-transgenic tobacco also significantly increased compared with the wild-type *** addition,the resistance of *** scales in which LrWRKY11 expression was silenced by RNAi evidently decreased,and additionally,the expression of lignin/lignans biosynthesis-related genes including LrDIR1 was significantly ***,LrDIR1 and its promoter(PLrDIR1)sequence containing the W-box element were isolated from *** interaction assay indicated that LrWRKY11 specifically bound to the W-box element in PLrDIR1 and activated LrDIR1 ***,β-glucuronidase activity in the transgenic tobacco co-expressing LrWRKY11/PLrDIR1-β-glucuronidase was higher than that in transgenic tobacco expressing PLrDIR1-β-glucuronidase ***,the ectopic expression of LrDIR1 in tobacco enhanced the resistance to *** and increased the lignin/lignans *** brief,this study revealed that LrWRKY11 positively regulated *** resistance to *** through interaction with salicylic acid/jasmonic acid signaling pathways and modulating LrDIR1 expression to accumulate lignin/lignans.

关键词： Lilium regale Fusarium oxysporum WRKY transcription factor dirigent

Distributed Platooning Control of Automated Vehicles Subject to Replay Attacks Based on Proportional Integral Observers

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IEEE/CAA Journal of Automatica Sinica 2024年第9期11卷 1954-1966页

作者： Meiling Xie Derui Ding xiaohua Ge Qing-Long Han Hongli Dong Yan Song Department of Control Science and Engineering University of Shanghai for Science and TechnologyShanghai 200093China School of Science Computing and Engineering TechnologiesSwinburne University of TechnologyMelbourne VIC 3122Australia Artificial Intelligence Energy Research Institute Northeast Petroleum UniversityDaqing 163318the Heilongjiang Provincial Key Laboratory of Networking and Intelligent ControlNortheast Petroleum UniversityDaqing 163318 Sanya Offshore Oil&Gas Research Institute Northeast Petroleum UniversitySanya 572024China

Secure platooning control plays an important role in enhancing the cooperative driving safety of automated vehicles subject to various security *** paper focuses on the distributed secure control issue of automated vehicles affected by replay attacks.A proportional-integral-observer(PIO)with predetermined forgetting parameters is first constructed to acquire the dynamical information of ***,a time-varying parameter and two positive scalars are employed to describe the temporal behavior of replay *** light of such a scheme and the common properties of Laplace matrices,the closed-loop system with PIO-based controllers is transformed into a switched and time-delayed ***,some sufficient conditions are derived to achieve the desired platooning performance by the view of the Lyapunov stability *** controller gains are analytically determined by resorting to the solution of certain matrix inequalities only dependent on maximum and minimum eigenvalues of communication ***,a simulation example is provided to illustrate the effectiveness of the proposed control strategy.

关键词： Automated vehicles platooning control proportional-integral-observers(PIOs) replay attacks time-delays

Accumulated-state-error-based event-triggered sampling scheme and its application to H∞ control of sampled-data systems

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Science China(Information Sciences) 2024年第6期67卷 328-341页

作者： Xian-Ming ZHANG Qing-Long HAN Bao-Lin ZHANG xiaohua GE Dawei ZHANG School of Science Computingand Engineering TechnologiesSwinburne University of Technology College of Automation and Electronic Engineering Qingdao University of Science & Technology School of Mathematics Shandong University

This paper is concerned with event-triggered H∞control of sampled-data systems. Its novelties lie in three aspects:（i） A novel accumulated-state-error-based event-triggered scheme is introduced by comparing the integral of the state error from tk to t with the system state sampled at tk. This condition works well due to the fact that the so-called Zeno behaviour does not occur.（ii） A novel Lyapunov functional is constructed to establish a criterion to ensure some certain H∞performance of the closed-loop system. This Lyapunov functional is dependent on the integral of the state error involved in the event-triggered scheme.（iii） Under the event-triggered sampling scheme, suitable state-feedback controllers can be designed rather than be given a priori. Moreover, a self-triggered implementation of the proposed event-triggered sampling scheme is presented as well. Finally, a batch reactor model and an inverted pendulum system are given to demonstrate the effectiveness of the proposed method.

关键词： event-triggered sampling self-triggered implementation $H_\infty$ control looped-functional

Regioselective and asymmetric allylic alkylation of vinyl epoxides for the construction of allylic alcohols via synergistic catalysis

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Science China Chemistry 2024年第2期67卷 542-550页

作者： Min Chen Longqing Yang Yuzhen Li Yinhe Qu Guihua Pan Xiaoming Feng xiaohua Liu Key Laboratory of Green Chemistry&Technology Ministry of EducationCollege of ChemistrySichuan UniversityChengdu610064China

A highly efficient asymmetric allylic alkylation of cyclic and acyclic carbon nucleophiles with vinyl epoxides has been developed,which exhibits good functional group compatibility,high atomic and step *** protocol utilizes a strategy of synergistic catalysis with a chiral N,N'-dioxide/Ni~Ⅱ complex and an achiral Pd~0 catalyst,generating a series of multisubstituted allylic alcohols with a quaternary carbon stereocenter in high yield and excellent regio-,Z/E-and enantioselectivity under mild *** transformations of the product demonstrate the potential utility of this protocol in the synthesis of allyl alcohol derivatives and natural product *** studies revealed that the N,N′-dioxide/metal complexes play an important role in controlling the Z/E-and *** density functional theory(DFT) calculations further demonstrated that multiple C–H···π interactions between the aromatic rings of the two substrates and the amide moiety in the ligand stabilized the dominant transition state.

关键词： asymmetric allylic alkylation synergistic catalysis vinyl epoxides allyl alcohol multiple weak interactions

A hybrid contact approach for modeling soil-structure interaction using the material point method

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第5期16卷 1864-1882页

作者： Qinyang Sang Yonglin Xiong Rongyue Zheng xiaohua Bao Guanlin Ye Feng Zhang Key Laboratory of Impact and Safety Engineering Ministry of EducationSchool of Mechanical Engineering and MechanicsNingbo UniversityNingbo315211China Institute of Geotechnical Engineering Ningbo UniversityNingbo315211China College of Civil and Transportation Engineering Shenzhen UniversityShenzhen518060China Department of Civil Engineering Shanghai Jiao Tong UniversityShanghai200240China Department of Civil Engineering Nagoya Institute of TechnologyShowa-kuGokiso-choNagoya466-8555Japan

The grid-based multi-velocity field technique has become increasingly popular for simulating the Material Point Method(MPM)in contact ***,this traditional technique has some shortcomings,such as(1)early contact and contact penetration can occur when the contact conditions are unsuitable,and(2)the method is not available for contact problems involving rigid-nonrigid materials,which can cause numerical *** study presents a new hybrid contact approach for the MPM to address these limitations to simulate the soil and structure *** approach combines the advantages of point-point and point-segment contacts to implement contact detection,satisfying the impenetrability condition and smoothing the corner contact *** proposed approach is first validated through a disk test on an inclined ***,several typical cases,such as granular collapse,bearing capacity,and deformation of a flexible retaining wall,are simulated to demonstrate the robustness of the proposed approach compared with FEM or analytical ***,the proposed method is used to simulate the impact of sand flow on a deformable *** results show that the proposed contact approach can well describe the phenomenon of soil-structure interaction problems.

关键词： Material point method Soil-structure interaction Numerical simulation Contact algorithm

Towards carbon neutrality of calcium carbide-based acetylene production with sustainable biomass resources

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Green Energy & Environment 2024年第6期9卷 1068-1078页

作者： Peng Jiang Guanhan Zhao Hao Zhang Tuo Ji Liwen Mu xiaohua Lu Jiahua Zhu State Key Laboratory of Materials-oriented Chemical Engineering College of Chemical EngineeringNanjing Tech UniversityNanjing211816China

Acetylene is produced from the reaction between calcium carbide(CaC_(2))and water,while the production of CaC_(2) generates significant amount of carbon dioxide not only because it is an energy-intensive process but also the raw material for CaC_(2) synthesis is from ***,a comprehensive biomass-to-acetylene process was constructed that integrated several units including biomass pyrolysis,oxygen-thermal CaC_(2) fabrication and calcium *** comparison,a coal-to-acetylene process was also established by using coal as *** carbon efficiency,energy efficiency and environmental impacts of the bio-based calcium carbide acetylene(BCCA)and coal-based calcium carbide acetylene(CCCA)processes were systematically ***,the environmental impacts were further evaluated by applying thermal integration at system level and energy substitution in CaC_(2) *** though the BCCA process showed lower carbon efficiency and energy efficiency than that of the CCCA process,life cycle assessment demonstrated the BCCA(1.873 kgCO_(2eq) kg-prod^(-1))a lower carbon footprint process which is 0.366 kgCO_(2eq) kg-prod^(-1) lower compared to the CCCA *** sustainable energy(biomass power)substitution in CaC_(2) furnace,an even lower GWP value of 1.377 kgCO_(2eq) kg-prod^(-1) can be achieved in BCCA *** work performed a systematic analysis on integrating biomass into industrial acetylene production,and revealed the positive role of biomass as raw material(carbon)and energy supplier.

关键词： Biomass pyrolysis CO_(2)mitigation Calcium carbide Acetylene Calcium loop