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Materials Sciences and Applications 2018年第1期9卷 41-54页

作者： Namory Meite Léon Koffi Konan drissa bamba Bi Irié Hervé Goure-Doubi Samuel Oyetola Laboratory of Materials Chemistry Felix Houphouet Boigny University Cocody-Abidjan Ivory Coast Laboratory of Water Chemistry Training School of Abidjan (ENS) Abidjan Ivory Coast Laboratory of Biological Sciences Péléforo Gon Coulibaly University of Korhogo Korhogo Ivory Coast

The structural and thermomechanical properties of starch-based plastic films reinforced with kaolin and metakaolin have been studied by various techniques (X-ray diffraction, IR-TF spectroscopy, scanning electron microscopy, tensile tests, and thermal resistance). The results obtained showed that kaolin, an inert material, prevents the starch from losing its granular structure and to solubilize during the heating, generating plastic films of low Young’s modulus (7 MPa). On the other hand, metakaolin, an amorphous and dehydroxylated material obtained after heating of kaolin at 700°C for 1 hour, substantially improves the thermomechanical properties of the plastic films. The Young’s modulus increases from 19 MPa to 25 MPa while the thermal resistance increases from 90°C to 120°C. This was attributed to good dispersion of the metakaolin in the polymer matrix after the loss of the granular structure of the starch during heating.

关键词： Cassava Starch Plastic Films Kaolin Metakaolin Stress at Break Young’s Modulus

Combining Experimental and Quantum Chemical Study of 2-(5-Nitro-1,3-Dihydro Benzimidazol-2-Ylidene)-3-Oxo-3-(2-Oxo-2H-Chromen-3-yl) Propanenitrile as Copper Corrosion Inhibitor in Nitric Acid Solution

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Open Journal of Physical Chemistry 2022年第4期12卷 47-70页

作者： Mougo André Tigori Aboudramane Koné bamba Souleymane Doumadé Zon drissa Sissouma Paulin Marius Niamien Laboratoire des Sciences et Technologies de l’Environnement UFR Environnement Université Jean Lorougnon Guédé Daloa C&#244 te d’Ivoire UFR des Sciences Biologiques Université Péléforo Gon Coulibaly Korhogo C&#244 te d’Ivoire Laboratoire de Constitution et de Réaction de la Matière UFR SSMT Université Félix Houphou&#235 t-Boigny Abidjan C&#244 te d’Ivoire

Due to acidic solutions aggressiveness, corrosion inhibitors use is considered to be one the most practical methods to delay metals dissolution in the said solutions. In this study benzimidazolyl derivative namely 2-cyanochalcones 2-(5-nitro-1,3-dihydrobenzimidazol-2-ylidene)-3-oxo-3-(2-oxo-2H-chromen-3-yl) propanenitrile which was synthesized was then applied as a corrosion inhibitor for copper in 1 M HNO3 solution. The inhibition action of this molecule was evaluated by gravimetric and density functional theory (DFT) methods. It was found experimentally that this compound has a better inhibition performance and its adsorption on copper surface follows Langmuir adsorption isotherm. This adsorption evolves with temperature and inhibitor concentration, it is endothermic and occurs spontaneously with an increase in disorder. Corrosion kinetic parameters analysis supported by Adejo-Ekwenchi model revealed the existence of both physisorption and chemisorption. DFT calculations related that compound adsorption on copper surface is due to its electron donating and accepting capacity. The reactive regions specifying the electrophilic and nucleophilic attack sites were analyzed using Fukui and dual descriptor functions. Experimental results obtained were compared with the theoretical findings.

关键词： 2-Cyanochalcones2-(5-Nitro-1 3-Dihydrobenzimidazol-2-Ylidene)-3-Oxo-3-(2-Oxo-2H-Chromen-3-Yl) Propanenitrile Copper HNO3 Solution Gravimetric Density Functional Theory

Assessment of Wastewater Management and Health Impacts in African Secondary Cities: Case of Dimbokro (Côte D’Ivoire)

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Journal of Geoscience and Environment Protection 2016年第8期4卷 15-25页

作者： Sandotin Lassina Coulibaly drissa Sangaré Sylvain Kouakou Akpo Seydou Coulibaly Habib Ben bamba Lacina Coulibaly Unité de recherche en Biotechnologie et Ingénierie de l’Environnement Université Nangui Abrogoua Abidjan C&#244te D’Ivoire Service Hydraulique et Assainissement TERRABO Ingénieur Conseil Abidjan C&#244te D’Ivoire

The majority of population growth in developing countries will occur in secondary cities where there is limited access to clean water and sanitation. Wastewater management priorities in these cities will be different from those in larger cities and developed countries. For this reason, it is important to assess wastewater management in these cities of sub-Saharan Africa. This study assessed clean water supply, wastewater and faecal sludge management and associated health risks in Dimbokro, C?te D’Ivoire. The study was performed in March 2015 in 12 neighborhoods with a total of 703 households. In these neighborhoods, the questions were addressed and discussed with household head. The study revealed that the households of the city were structured on three topology habitats: residential (5%), economic (42%) and evolutive or yards housing (53%). For water supply, 99.4% of the households used water from SODECI, the local public water supply network, while the remaining 0.6% of surveyed household obtained water from wells. Domestic wastewater, used for doing laundry, dishwashing and showering, was disposed of in the following ways: directly into the street (33%), septic tank (23%), backyards (18%), storm drain (16%), sewer network (6%), pit latrine (3%) or into soakaway (2%). In addition, untreated wastewater was sometimes discharged into the N’Ziriver by certain households. 52% of households surveyed emptied latrines manually and 48 % used mechanic drain services. The most frequent diseases occurring in the households were Malaria (63%), Diarrhoea (13%) and Typhoid fever (9%) in the households of the city. In the light of this study, the municipal authorities of Dimbokro should provide the city with wastewater systems that drain to a central outlet system where the waste-water can be easily treated before final disposal for reuse in agriculture.

关键词： Diseases Households Faecal Sludge N’Zi River Secondary Cities Wastewater

Pulmonary Hypoplasia: A Rare Cause of Chronic Cough in TB Endemic Area

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Open Journal of Respiratory Diseases 2019年第1期9卷 18-25页

作者： Ouattara Khadidia Kanoute Tenin Baya Bocar Soumaré Dianguina Kamian Youssouf Mama Sidibé Youssouf Fofana Aminata Traoré Mohamed Maba Guindo Ibrahim Sidibe Fatoumata Dakouo Aimé Paul Sanogo Fatoumata Bintou bamba Salimata Coulibaly Lamine Yossi Oumar Kone drissa Samba Toloba Yacouba Department of Pneumology University Teaching Hospital of Point G Bamako Mali Department of ENT Secondary Hospital “Luxembourg” Bamako Mali Department of ENT Nianakoro Fomba Hospital Ségou Mali Department of Radiology Hospital of Mali Bamako Mali

Pulmonary hypoplasia is a rare disease characterized by a defect of lung development more often unilateral. The diagnosis requires several exams to eliminate other causes of pulmonary retraction. We report two cases at the department of pneumophtisiology of the University Teaching Hospital of Point G. The first case is a young adult who was complaining of a chronic cough. Etiological investigation required several exams including spirometry and Computed tomographic scan (CT scan). After elimination of all suspected causes of pulmonary opacity, the diagnosis of pulmonary hypoplasia was retained. The second case is a 2-year-old girl who was born with congenital cardiopathy whose respiratory complications were increasing during her childhood and respiratory explorations discovered pulmonary agenesis. Pulmonary hypoplasia is rare in our medical practice, but attention must be drawn to a retractile pulmonary opacity in young age after elimination of all infectious causes in TB endemic area.

关键词： A Chronic Cough Pulmonary Hypoplasia Bamako

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