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Electrochemical filtration for drinking water purification:A review on membrane materials,mechanisms and roles

Journal of Environmental Sciences 2024年第7期141卷 102-128页

作者： Yuying Qi donghao li Shixuan Zhang Fengxiang li Tao Hua College of Environmental Science and Engineering Nankai UniversityTianjin 300350China Key Laboratory of Pollution Process and Environmental Criteria Ministry of EducationTianjin 300350China Tianjin Engineering Center of Environmental Diagnosis and Contamination Remediation Tianjin 300350China

Electrochemical filtration can not only enrich low concentrations of pollutants but also produce reactive oxygen species to interact with toxic pollutants with the assistance of a power supply,making it an effective strategy for drinking water *** addition,the application of electrochemical filtration facilitates the reduction of pretreatment procedures and the use of chemicals,which has outstanding potential for maximizing process simplicity and reducing operating costs,enabling the production of safe drinking water in smaller *** recent years,the research on electrochemical filtration has gradually increased,but there has been a lack of attention on its application in the removal of low concentrations of pollutants from low conductivity *** this review,membrane substrates and electrocatalysts used to improve the performance of electrochemical membranes are briefly ***,the application prospects of emerging single-atom catalysts in electrochemical filtration are also ***,several electrochemical advanced oxidation processes coupled with membrane filtration are described,and the related working mechanisms and their advantages and shortcomings used in drinking water purification are ***,the roles of electrochemical filtration in drinking water purification are presented,and the main problems and future perspectives of electrochemical filtration in the removal of low concentration pollutants are discussed.

关键词： Electrochemical filtration Drinking water Conductive membrane Low concentration Electrocatalyst

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Facile synthesis of NiMn2S4 nanoflakes on nickel foam for high-performance aqueous asymmetric supercapacitors

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Science China(Technological Sciences) 2024年第2期67卷 499-508页

作者： ADIL Emin li Yali GAO Zhe DONG YunXia li donghao CHEN YongChao FU YuJun HE DeYan li JunShuai LONGi Institute of Future Technology and School of Materials&EnergyLanzhou UniversityLanzhou 730000China

Supercapacitors display promising electrochemical performance with high power density and excellent cycle ***,their low energy density limits their advancement in a broader range of *** enhance their energy density,we proposed self-assembled spinel NiMn2S4nanoflakes grown on nickel foam which we successfully prepared by a facile hydrothermal *** NiMn2S4electrode delivers a high capacitance of 2096.7 F g^(-1)at 1.0 A g^(-1),with an exceptional rate capability(~720.6 F g^(-1)at a very high current density of 100 A g^(-1))and good cycle stability(~85.1%retention of the initial capacitance after 7000 cycles with the Coulombic efficiency around 100%).The as-fabricated asymmetric supercapacitors based on NiMn2S4nanoflakes//active carbon demonstrate an energy density of 73.6 W h kg^(-1)at 800.5 W kg^(-1)and adequate cycling performance of~84.6%capacitance retention at 15 A g^(-1)after 10000 *** results reveal that the nanostructured NiMn2S4is an excellent electrode material for high-performance energy storage applications.

关键词： NiMn2S4 nanostructure high capacitance aqueous supercapacitors long cycle stability high energy density

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Eco-friendly high-throughput screening of cephalosporins impurities: Utilizing 2D-carbon microfiber fractionation system combined with quadrupole time of flight high-resolution mass spectrometer

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Journal of Pharmaceutical Analysis 2024年第5期14卷 772-774页

作者： Lei Yang Yan Wang Zhao Wang Meiyu Cui Ruolan Jin Hai-Bo Shang donghao li College of Pharmacy Yanbian UniversityYanjiJilin133002China Department of Chemistry Interdisciplinary Program of Biological Functional MoleculesCollege of Integration ScienceYanbian UniversityYanjiJilin133002China

Owing to its high sensitivity,selectivity,and accuracy,liquid chromatography coupled with mass spectrometry(LC-MS)is commonly employed to screen,confirm,and quantify impurities in drugs[1].However,LC-MS has certain drawbacks such as complicated pretreatment steps,long analysis time,large consumption of organic solvents,high maintenance costs,and,most notably,the need for high-pressure pumps and compatible hardware because of the high column backpressure[2].In this study,a two-dimensional(2D)microscale carbon fiber(CF)/active carbon fiber(ACF)system combined with a quadrupole time-of-flight high-resolution mass spectrometry(2DmCFs-QTOF-HRMS)system was developed to rapid screening impurities in the typical three generations of oral cephalosporins,i.e.,cephalexin tablets(CPXTs),cefuroxime axetil tablets(CFATs),and cefixime tablets(CFXTs)(Fig.S1).The“fuzzy chromatographic separation”sample pretreatment method separates complex samples into high-,medium-,and weak-polar fractions for successive detection of MS,achieving effective reduction of the ion suppression effect in electrospray ionization(ESI)-MS and improving the MS detection *** to high performance liquid chromatography(HPLC)-MS,this method has distinct advantages such as less organic solvent consumption(1.5 mL),shorter separation and analysis times(5 min),more information on impurities,and high reproducibility.

关键词： system carbon tablets

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河南省氮素农业面源污染风险评价与关键管控区识别

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农业机械学报 2024年第3期55卷 311-320页

作者：高林林吴用杨书涵刘雪珂李玲李栋浩河南农业大学资源与环境学院郑州450002

农业面源污染是我国水环境保护面临的重要问题,风险评价对于农业面源污染防治具有重要意义。本研究以河南省为研究区域,采用层次分析法的分级赋值方法,基于熵值法和专家打分确定各影响因子权重,构建河南省氮素农业面源污染风险多因子综... 详细信息

农业面源污染是我国水环境保护面临的重要问题,风险评价对于农业面源污染防治具有重要意义。本研究以河南省为研究区域,采用层次分析法的分级赋值方法,基于熵值法和专家打分确定各影响因子权重,构建河南省氮素农业面源污染风险多因子综合评价模型,计算河南省氮素农业面源污染风险指数并在流域尺度上进行验证,划分氮素农业面源污染的风险等级并识别关键管控区。结果表明:种植源、养殖源和生活源分别贡献河南省31.52%、38.47%和30.01%的氮素流失负荷,流失负荷呈现为西低,中、东部高的特点。河南省有39 429 km^(2)的区域存在中风险,约占河南省总面积的23.61%,有17 318 km^(2)的区域存在高风险,约占总面积的10.37%;划定距河流2 km以内的中、高风险区为一般管控区和重点管控区,面积分别为10 982 km^(2)和9 285 km^(2)。通过与同期水质自动监测数据进行相关分析,决定系数为0.82,表明模型模拟结果具有较高的精准度。综合结果表明,建立的多因子综合评价模型具有科学性和准确性,可用于氮素农业面源污染风险的识别。

关键词：氮素农业面源污染多因子综合评价风险识别管控区河南省

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某埋头弹机枪弹膛驱动螺旋槽优化设计

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北京理工大学学报 2024年第1期44卷 1-9页

作者：刘强周克栋李东昊陆野任海钺赫雷南京理工大学机械工程学院江苏南京210094 国营第二九六厂重庆400050

某埋头弹机枪采用了弹膛与枪管分离的结构,其弹膛在整个自动循环中存在两个工作位置,即供弹位与发射位.该埋头弹机枪通过枪机框上的导柱与弹膛上的螺旋槽相互作用,带动弹膛摆动,以实现弹膛在两个工作位之间的相互转换.最初在设计弹膛螺... 详细信息

某埋头弹机枪采用了弹膛与枪管分离的结构,其弹膛在整个自动循环中存在两个工作位置,即供弹位与发射位.该埋头弹机枪通过枪机框上的导柱与弹膛上的螺旋槽相互作用,带动弹膛摆动,以实现弹膛在两个工作位之间的相互转换.最初在设计弹膛螺旋槽时选用了规则的螺旋线,然后在试验中发现,枪机框导柱在进入弹膛螺旋槽时螺旋槽对其的冲击力很大,冲击不仅使得枪机框动能损失严重,而且会降低导柱寿命.现以枪机框导柱与弹膛螺旋槽之间的最大冲击力为目标函数,选用5次函数曲线为弹膛螺旋槽理论轮廓线展开线的形式,运用遗传算法对弹膛螺旋槽理论轮廓线进行优化,使得枪机框导柱与弹膛螺旋槽之间的最大冲击力降低为原来的42.27%.试验验证表明枪机框导柱与优化后的弹膛螺旋槽相互作用时速度损失由优化前的30.3%降低到25.6%.研究结果为该枪的改进提供了可靠的理论依据.

关键词：埋头弹机枪弹膛螺旋槽参数优化 5次函数曲线遗传算法

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某埋头弹机枪拨弹杠杆动力学分析及优化

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振动与冲击 2024年第8期43卷 186-192页

作者：刘强周克栋李东昊陆野赫雷任海钺南京理工大学机械工程学院南京210094 国营第二九六厂重庆400050

某埋头弹机枪使用了与传统枪弹结构完全不同的埋头弹,为了适应这种弹药,该埋头弹机枪与传统机枪在结构上也有很大的差异。其中,相较于传统机枪,该埋头弹机枪的输弹行程更为靠后,为了减小全枪长度,不得不缩短拨弹杠杆中曲线槽部分的长度... 详细信息

某埋头弹机枪使用了与传统枪弹结构完全不同的埋头弹,为了适应这种弹药,该埋头弹机枪与传统机枪在结构上也有很大的差异。其中,相较于传统机枪,该埋头弹机枪的输弹行程更为靠后,为了减小全枪长度,不得不缩短拨弹杠杆中曲线槽部分的长度。这使得枪机框上的导柱进入拨弹杠杆曲线槽时,对拨弹杠杆的冲击力很大,从而对整个输弹机构的可靠工作造成极为不利的影响,同时也会严重降低枪机框的动能,使得输弹动作难以完成。现以导柱与拨弹杠杆之间的最大冲击力为目标函数,选用5次函数曲线作为拨弹杠杆曲线槽理论轮廓线的形状,运用遗传算法对该理论轮廓线进行优化,使得导柱与拨弹杠杆之间的最大冲击力降为优化前的1/3。试验验证表明,枪机框在进入拨弹杠杆曲线槽的过程中,速度损失由原来的0.94 m/s降低到0.28 m/s,达到了优化目的,该研究结果为该枪的改进提供了可靠的理论依据。

关键词：埋头弹机枪拨弹杠杆曲线槽参数优化 5次函数曲线遗传算法

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泡沫镍上生长的具有三明治纳米结构的MnCo_(2)O_(4)@NiCoMnS_(4)用于高性能水系非对称超级电容器

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Science China Materials 2024年第3期67卷 816-823页

作者：陈勇超李亚丽董云霞李东昊沈思锦胡继东付玉军贺德衍栗军帅 LONGi Institute of Future Technology and School of Materials&EnergyLanzhou UniversityLanzhou 730000China

本文介绍了一种由水热生长的MnCo_(2)O_(4)(MCO)纳米线以及随后电沉积的NiCoMnS_(4)(NCMS)纳米片组成的高性能超级电容器电极材料,即泡沫镍上生长的MCO@NCMS.由于其多孔和互联的纳米结构以及MCO和NCMS的协同效应,在1 mA cm^(-2)处实现了... 详细信息

本文介绍了一种由水热生长的MnCo_(2)O_(4)(MCO)纳米线以及随后电沉积的NiCoMnS_(4)(NCMS)纳米片组成的高性能超级电容器电极材料,即泡沫镍上生长的MCO@NCMS.由于其多孔和互联的纳米结构以及MCO和NCMS的协同效应,在1 mA cm^(-2)处实现了12,020.8 mF cm^(-2)的高电容,并展现出良好的倍率性能以及循环稳定性.电化学测试表明,组装成的水性非对称超级电容器在0.800 mW cm^(-2)的功率密度下,达到0.611 mW h cm^(-2)的高能量密度并具有良好的循环稳定性,即在15,000次充放电循环后,容量保持率可达90%,且保持100%的库仑效率.

关键词： sandwich structure high energy density transition metal sulfides aqueous asymmetric supercapacitor transition metal oxides

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Review for chiral-at-metal complexes and metal-organic framework enantiomorphs

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Science Bulletin 2017年第19期62卷 1344-1354页

作者： Zi-Hong Yan donghao li Xue-Bo Yin College of Chemistry and Environmental Sciences Laboratory of Xinjiang Native Medicinal and Edible Plant Resources ChemistryKashgar University Key Laboratory of Natural Resource of the Changbai Mountain and Functional Molecular Ministry of EducationYanbian University State Key Laboratory of Medicinal Chemical Biology and Tianjin Key Laboratory of Biosensing and Molecular Recognition College of ChemistryNankai University

This review discusses chiral-at-metal complexes and introduces enantiomorphs from assembly *** to the diverse coordination number and activity of metal ions as chiral centers, abundant structures for chiral selectivity, catalysis, and polarized light-response are the notable advantages of the chiral-at-metal complexes. The rational design and preparation of linear multi-dentate ligands is a good choice to improve the stability of chiral complexes, such as multi-bonding structure for high stability as a self-limiting system. The bio-significance and potential application of chiral-at-metal complexes are discussed, such as the synergistic effect of catalysis and chiral selectivity of the metal center in *** could be remolded to replace the original central metal ions with highly active rare earth or precious metal ions to form artificial metalloenzyme or to remove the ‘‘redundant" part around the metal center to improve the accessibility of substrate. The polarized light-response mechanism of chiral opsin is introduced in relation to its role in animal migration. Metal-organic frameworks(MOFs) are crystalline and porous materials built from metal nodes or clusters and organic linkers and provide the possibility to prepare artificial enantiomorphs. The preparations, applications, and characterization methods of MOF enatiomorphs are therefore introduced. We hope this review inspires researchers at all levels of their career to consider the title topic in their own research in terms of its application and potential value.

关键词： ChiralityStereoisomerChiral-at-metal complexAssembly enatiomorphChiral metal-organic frameworks

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河南省农业面源污染负荷估算及控制分区

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环境污染与防治 2024年第5期46卷 750-759页

作者：杨书涵吴用高林林李玲李栋浩胡亚瑾河南农业大学资源与环境学院河南郑州450000

农业面源污染问题是造成水环境污染的重要原因之一,识别农业面源污染空间分布并进行分区控制是农业面源污染防治的前提。运用清单分析法、等标污染负荷法和聚类分析法对河南省2020年农业面源的污染源、污染物及其空间分布特征进行分析... 详细信息

农业面源污染问题是造成水环境污染的重要原因之一,识别农业面源污染空间分布并进行分区控制是农业面源污染防治的前提。运用清单分析法、等标污染负荷法和聚类分析法对河南省2020年农业面源的污染源、污染物及其空间分布特征进行分析。结果如下:1)河南省农业面源主要污染源为化肥施用和畜禽养殖,污染物COD排放量最大,南阳市排放总量最高;河南省农业面源污染呈较强的区域分异特征,化肥施用污染主要集中在周口市,畜禽养殖以南阳市为最严重;总等标污染指数最高为濮阳市。2)通过聚类分析将河南省划分3个一级面源污染控制分区:高度、中度和轻度风险区,并在此基础上细分为7个二级面源污染控制分区,并针对性地给出了河南省农业面源的防治对策,为河南省农业面源污染的分类管控提供参考依据。

关键词：农业面源污染河南省控制分区等标污染指数时空特征

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An improved method that incorporates the estimated runoff for peak discharge prediction on the Chinese Loess Plateau

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International Soil and Water Conservation Research 2023年第2期11卷 290-300页

作者： Wenhai Shi Miaomiao Wang donghao li Xianwei li Mengying Sun Key Laboratory of Subsurface Hydrology and Ecological Effects in Arid Region Chang'an UniversityMinistry of EducationChina School of Water and Environment Chang'an UniversityChina

An accurate prediction of peak discharge in watersheds is critical not only for water resource manage-ment,but also for understanding the complex relationships of hydrological *** this study,a modified peak discharge formula based on the Chemicals,Runoff,and Erosion from Agricultural Man-agement Systems(CREAMS)model was developed by introducing rainfall intensity and soil moisture *** reliability of the proposed method was tested with data from 1464 storm events in 41 watersheds and was applied to 256 storm events in five remaining typical watersheds using the opti-mized *** results indicate that the proposed method is highly accurate in terms of model efficiency,as determined by Nash-Sutcliffe efficiencies(NSEs)of 88.60%,74.04%,and 90.12%during the calibration,validation,and application cases,***,it performed better than the original and modified CREAMS ***,using the parameters derived from the initial 41 watersheds and the runoff estimated using the modified Soil Conservation Service curve number(SCS-CN)method,the proposed method was used to predict the peak discharge from the last five typical *** NSE(63.88-80.83%)and low root mean square error(RMSE)values(0.31-35.93 m^(3)s^(-1))were obtained for the five ***,the proposed peak discharge model,combined with the modified SCS-CN method,may accurately predict event-based peak discharge and runoff for general applications under various hydrological and geomorphic conditions in the Loess Plateau region.

关键词： Chemicals,Runoff,and Erosion from agricultural management systems (CREAMS) NRCS-CN Peak discharge Surface runoff Rainfall intensity

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