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Aligned Ion Conduction Pathway of Polyrotaxane‑Based Electrolyte with Dispersed Hydrophobic Chains for Solid‑State Lithium–Oxygen Batteries

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Nano-Micro Letters 2025年第2期17卷 169-186页

作者： Bitgaram kim Myeong‑Chang Sung Gwang‑Hee Lee Byoungjoon Hwang Sojung Seo Ji‑Hun Seo dong‑Wan kim Department of Materials Science and Engineering Korea University145 Anam‑RoSeongbuk‑GuSeoul 02841Republic of Korea School of Civil Environmental and Architectural EngineeringKorea University145 Anam‑RoSeongbuk‑GuSeoul 02841Republic of Korea Materials Science and Chemical Engineering Center Institute for Advanced Engineering(IAE)Yongin 17180Republic of Korea

A critical challenge hindering the practical application of lithium–oxygen batteries(LOBs)is the inevitable problems associated with liquid electrolytes,such as evaporation and safety *** study addresses these problems by proposing a modified polyrotaxane(mPR)-based solid polymer electrolyte(SPE)design that simultaneously mitigates solvent-related problems and improves ***-SPE exhibits high ion conductivity(2.8×10^(−3)S cm^(−1)at 25℃)through aligned ion conduction pathways and provides electrode protection ability through hydrophobic chain *** this mPR-SPE into solid-state LOBs resulted in stable potentials over 300 *** situ Raman spectroscopy reveals the presence of an LiO_(2)intermediate alongside Li_(2)O_(2)during oxygen *** situ X-ray diffraction confirm the ability of the SPE to hinder the permeation of oxygen and moisture,as demonstrated by the air permeability *** present study suggests that maintaining a low residual solvent while achieving high ionic conductivity is crucial for restricting the sub-reactions of solid-state LOBs.

关键词： Solid polymer electrolyte Lithium-oxygen batteries Polyrotaxane ion conductivity Hydrophobic chain

INTERDECADAL CHANGE OF KOREA LANDFALLING TROPICAL CYCLONE FREQUENCY AND ITS POSSIBLE ASSOCIATION WITH PDO

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Tropical Cyclone Research and Review 2016年第3期5卷 58-71页

作者： Jae-Won Choi Yumi Cha hae-dong kim State Key Laboratory of Numerical Modeling for Atmospheric Sciences and Geophysical Fluid Dynamics,Institute of Atmospheric Physics,Chinese Academy of Sciences National Institute of Meteorological Sciences Department of Global Environment,Keimyung University State Key Laboratory of Numerical Modeling for Atmospheric Sciences and Geophysical Fluid Dynamics Institute of Atmospheric PhysicsChinese Academy of Sciences National Institute of Meteorological Sciences Department of Global Environment Keimyung University

The present study verified that Korea landfalling tropical cyclone(TC) frequency was rapidly increased since 1981 through the statistical change-point analysis. The increase was due to the formation of anomalous southerlies around Korea from the low latitude ultimately because anomalous cyclone was strengthened in East Asia continent due to the movement of western North Pacific subtropical high(WNPSH) to the east whereas anomalous anticyclone was strengthened in the western North Pacific. The anomalous southerlies played a role in steering flow that moved TCs generated in the subtropical western North Pacific to Korea. In order to determine the cause of strengthening of anomalous cyclone in East Asia continent, a snow depth during the preceding spring(March-May) was analyzed. The analysis result showed that most regions in East Asia had lower snow depth than that before 1981. Thus, anomalous cyclone can be developed in the region during summer due to heating in East Asia continent, which was started from the preceding spring, thereby forming a steering flow of anomalous southerlies that can move TCs into Korea. Furthermore, a correlation analysis between Pacific Decadal Oscillation(PDO) and Korea landfalling TC frequency verified that negative correlation was somewhat stronger after 1981.

关键词： Korea tropical cyclone statistical change-point analysis snow depth Pacific Decadal Oscillation

A Flexible Smart Healthcare Platform Conjugated with Artificial Epidermis Assembled by Three‑Dimensionally Conductive MOF Network for Gas and Pressure Sensing

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Nano-Micro Letters 2025年第2期17卷 601-620页

作者： Qingqing Zhou Qihang Ding Zixun Geng Chencheng Hu Long Yang Zitong Kan Biao dong Miae Won Hongwei Song Lin Xu Jong Seung kim State Key Laboratory of Integrated Optoelectronics College of Electronic Science and EngineeringJilin UniversityChangchun 130012People’s Republic of China Department of Chemistry Korea UniversitySeoul 02841Republic of Korea TheranoChem Incorporation Seoul 02856Republic of Korea

The rising flexible and intelligent electronics greatly facilitate the noninvasive and timely tracking of physiological information in telemedicine *** building bionic-sensitive moieties is vital for designing efficient electronic skin with advanced cognitive functionalities to pluralistically capture external ***,realistic mimesis,both in the skin’s three-dimensional interlocked hierarchical structures and synchronous encoding multistimuli information capacities,remains a challenging yet vital need for simplifying the design of flexible logic ***,we construct an artificial epidermal device by in situ growing Cu_(3)(HHTP)_(2) particles onto the hollow spherical Ti_(3)C_(2)T_(x) surface,aiming to concurrently emulate the spinous and granular layers of the skin’s *** bionic Ti_(3)C_(2)T_(x)@Cu_(3)(HHTP)_(2) exhibits independent NO_(2) and pressure response,as well as novel functionalities such as acoustic signature perception and Morse code-encrypted message ***,a wearable alarming system with a mobile application terminal is self-developed by integrating the bimodular senor into flexible printed *** system can assess risk factors related with asthmatic,such as stimulation of external NO_(2) gas,abnormal expiratory behavior and exertion degrees of fingers,achieving a recognition accuracy of 97.6%as assisted by a machine learning *** work provides a feasible routine to develop intelligent multifunctional healthcare equipment for burgeoning transformative telemedicine diagnosis.

关键词： Ti_(3)C_(2)T_(x)@Cu_(3)(HHTP)_(2)composites NO_(2)/pressure flexible sensors Health-monitoring Machine learning

The H∞ Robust Stability and Performance Conditions for Uncertain Robot Manipulators

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IEEE/CAA Journal of Automatica Sinica 2025年第1期 270-272页

作者： Geun Il Song hae Yeon Park Jung Hoon kim the Department of Electrical Engineering Pohang University of Science and Technology (POSTECH) the Department of Electrical Engineering Pohang University of Science and Technology (POSTECH) the Institute for Convergence Research and Education in Advanced Technology Yonsei University

Dear Editor,H∞This letter develops a new framework for the robust stability and performance conditions as well as the relevant controller synthesis with respect to uncertain robot *** often exist model uncertainties between the nominal model and the real robot manipulator and disturbances. Hence, dealing with their effects plays a crucial role in leading to high tracking performances, as discussed in [1]–[5].

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Dietary flavonoid intake and risk of stomach and colorectal cancer

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World Journal of Gastroenterology 2013年第7期19卷 1011-1019页

作者： hae dong Woo Jeongseon kim Molecular Epidemiology Branch Division of Cancer Epidemiology and PreventionResearch InstituteNational Cancer CenterGyeonggi-do 410-769South Korea

Stomach and colorectal cancers are common cancers and leading causes of cancer *** the alimentary tract can interact directly with dietary components,stomach and colorectal cancer may be closely related to dietary *** systematically searched published literature written in English via PubMed by searching for terms related to stomach and colorectal cancer risk and dietary flavonoids up to June 30,***-three studies out of 209 identified articles were finally selected for the *** point effect estimates and the corresponding standard errors were calculated using covariate-adjusted point effect estimates and 95%CIs from the selected *** dietary flavonoid intake was not associated with a reduced risk of colorectal or stomach cancer [odds ratio(OR)(95%CI) = 1.00(0.90-1.11) and 1.07(0.70-1.61),respectively].Among flavonoid subclasses,the intake of flavonols,flavan-3-ols,anthocyanidins,and proanthocyanidins showed a significant inverse association with colorectal cancer risk [OR(95%CI) = 0.71(0.63-0.81),0.88(0.79-0.97),0.68(0.56-0.82),and 0.72(0.61-0.85),respectively].A significant association was found only between flavonols and stomach cancer risk based on a limited number of selected studies [OR(95%CI) = 0.68(0.46-0.99)].In the summary estimates from casecontrol studies,all flavonoid subclasses except flavones and flavanones were inversely associated with colorectal cancer risk,whereas neither total flavonoids nor any subclasses of flavonoids were associated with colorectal cancer risk in the summary estimates based on the cohort *** significant association between flavonoid subclasses and cancer risk might be closely related to bias derived from the case-control *** was no clear evidence that dietary flavonoids are associated with reduced risk of stomach and colorectal cancer.

关键词： Flavonoids Flavonols Flavones Flavanones Flavan-3-ols Anthocyanidins Proanthocyanidins Cancer risk Meta-analysis

Synthesis and microstructure of zirconia nanopowders by glycothermal processing

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中国有色金属学会会刊：英文版 2009年第B09期19卷 88-91页

作者： Jun-Seop kim dong-hae LEE Sung KANG dong-Sik BAE Hoy-Yul PARK Moon-Kyeung NA School of Nano & Advanced Material Engineering College of EngineeringChangwon National University Advanced Materials and Application Research Laboratory Korea Electro Technology Research Institute

ZrO2 nanoparticles were prepared under high temperature and high pressure conditions by precipitation from metal nitrates with aqueous potassium hydroxide. The effects of synthesis parameters, such as the concentration of starting solution, pH of starting solution, reaction temperature and time, were discussed. The results show that the ZrO2 nanoparticles are obtained at 230-270 ℃. The average size and size distribution of the synthesized particles are below 10 nm and narrow, respectively. The XRD pattern shows that the synthesized particles are composed of crystalline. The synthesis of ZrO2 nanosized crystalline particles is possible under glycothermal conditions in ethylene glycol solution.

关键词：纳米氧化锆合成粉体加工微观结构结晶颗粒溶液pH值高压条件氢氧化钾

Nanostructured hafnium-doped strontium oxide film for homeotropic/homogeneous convertible liquid crystal alignment depending on the curing temperature

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International Journal of Smart and Nano Materials 2022年第4期13卷 597-611页

作者： dong Hyun kim dong Wook Lee Jin Young Oh Jonghoon Won hae-Chang Jeong Dae-Shik Seo IT Nano Electronic Device Laboratory Department of Electrical and Electronic EngineeringYonsei UniversitySeoulRepublic of Korea Department of Smart Manufacturing Engineering Changwon National UniversityChangwonGyeongnamRepublic of Korea Department of Electrical Electronic and Control Engineering Changwon National UniversityChangwonGyeongnamRepublic of Korea

A hafnium strontium oxide(HfSrO)liquid crystal(LC)alignment film was efficiently created through brush coating,and its ability to change the LC alignment direction was confirmed.A brush was applied to HfSrO sol coated on an indium-tin oxide substrate,after which the coating was solidified at var-ious curing *** was confirmed that a directional micro/nanostructure was formed above 280°C due to the shear stresses caused by the movement of the brush *** chemical changes were analyzed by using X-ray photoelectron spectroscopy and contact angle *** the curing temperature increased,the prevalence of oxygen bonds increased and the contact angle decreased,thereby increasing the surface *** anisotropic boundary of the micro-grooves and the van der Waals forces due to an increase in surface energy changed the alignment direction of LC mole-cules from vertical to horizontal,as verified through polarized optical microscopy and pretilt angle ***,the efficiency of the brush-coating method,which dramatically simplifies the LC alignment film process,was *** homeotropic/homogeneous LC alignment property of the HfSrO film produced through brush coating depending on the curing temperature provides an innovative approach for LC alignment.

关键词： Brush coating nanostructure solution process liquid crystal alignment

Exploring Artistic Embeddings in Service Design:A Keyword-Driven Approach for Artwork Search and Recommendations

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Tsinghua Science and Technology 2024年第5期29卷 1580-1592页

作者： Jie Yuan Fangru Lin hae Yoon kim College of Design Dongseo UniversityBusan 47011Republic of Korea Shandong Provincial University Laboratory for Protected Horticulture College of ArtsWeifang University of Science and TechnologyWeifang 262700China

As living standards improve,the demand for artworks has been escalating,transcending beyond the realm of mere basic human ***,amidst an extensive array of artwork choices,users often struggle to swiftly and accurately identify their preferred *** such scenarios,a recommendation system can be invaluable,assisting users in promptly pinpointing the desired artworks for better service *** the escalating demand for artwork recommendation systems,current research fails to adequately meet these ***,existing artwork recommendation methodologies tend to disregard users’implicit interests,thereby overestimating their capability to articulate their preferences in full and often neglecting the nuances of their diverse *** response to these challenges,we have developed a weighted artwork correlation graph and put forth an embedding-based keyword-driven artwork search and recommendation *** approach transforms the keywords that delineate user interests into word embedding *** allows for an effective distinction between the user’s core and peripheral ***,we employ a dynamic programming algorithm to extract artworks from the correlation graph,thereby obtaining artworks that align with the user’s explicit keywords and implicit *** have conducted an array of experiments using real-world datasets to validate our *** results attest to the superiority of our method in terms of its efficacy in searching and recommending artworks.

关键词： artwork self-attention recommendation dynamic programming implicit interest

Electrodeposited copper oxides with a suppressed interfacial amorphous phase using mixed-crystalline ITO and their enhanced photoelectrochemical performances

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Journal of Energy Chemistry 2023年第7期82卷 277-286,I0007页

作者： Ji Hoon Choi hae-Jun Seok dongchul Sung dong Su kim Hak Hyeon Lee Suklyun Hong Han-Ki kim Hyung Koun Cho School of Advanced Materials Science and Engineering Sungkyunkwan University2066Seobu-roJangan-guSuwon-siGyeonggi-do 16419Republic of Korea Department of Physics Graphene Research Instituteand GRI-TPC International Research CenterSejong UniversitySeoul 05006Republic of Korea

The effectiveness of photoelectrochemical(PEC)water splitting is significantly restricted by insufficient light harvesting,rapid charge recombination,and slow water reduction *** the presence of amorphous phases in the interfaces hinders the overcome of these inherent limitations,a photoelectrode must be built ***,we artificially controlled the crystallographic orientation of indium tin oxide(ITO)to determine the orientation with the smallest lattice mismatch at the Cu_(2)O interface,thus significantly reducing the amorphous phase in the early stage of electrodeposition ***[222]/[400]mixed orientation ITO primarily exposed the{400}surface planes and accelerated charge transfer by forming an optimal interface with preferentially grown(111)oriented Cu_(2)O and minimized amorphous *** addition,the ITO surface energy was calculated using density functional theory to theoretically verify which plane is more active for growing the photoactivation *** rationally designed ITO/Cu_(2)O/Al-dope Zn O/TiO_(2)/Rh-P device,with each layer serving a specific purpose,achieved a photocurrent density of 8.23 mA cm^(-2)at 0 VRHEunder AM 1.5 G illumination,providing a standard method for effective solar-to-hydrogen conversion photocathodes.

关键词： Photoelectrochemical water splitting Cu_(2)O ITO Hydrogen Surface energy DFT