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Inte.national Journal of Organic Che.istry 2024年第1期14卷 20-31页

作者： dmitry e. pugachev Ge.rgy V. Zatonsky Tatyana S. Kostryukova Anna G. Shubina Nikolay V. Vasilie. De.artme.t of Biological Microanalysis FGUP State Research Institute of Biological Engineering Moscow Russia De.artme.t of The.re.ical and Applie. Che.istry State University of Education Mytishchi Russia

Ne. re.ge.ts for immunofluore.ce.ce.analysis of carbazole.se.ie. containing fluorinate. β-dicarbonyl fragme.ts and carboxylic substitue.t groups se.arate. by space.s of diffe.e.t le.gths from the.light-gathe.ing carbazole.scaffold have.be.n de.e.ope.. The.marke.s in comple. with e.3+ ions posse.s stability in the.aque.us phase. inte.se.and prolonge. lumine.ce.ce.(τ 550 - 570 μs) with characte.istic e.ission maxima in the.re.ion of 615 nm and e.citation wave.e.gths in the.re.ion of 380 - 390 nm, which distinguishe. the. from most of the.analogs use.. In the.study of marke. conjugation with stre.tavidin, a re.ge.t containing 4 - 5 e.ropium labe.ing comple.e. base. on space.-containing carbazole.te.rake.one.was obtaine.. The.marke.-dope. silicate.nanoparticle. e.hibit inte.se.and long-live. lumine.ce.ce.in the.characte.istic re.ion.

关键词： Fluore.ce.ce.Immunoassay Fluorinate. β-Dike.one. Carbazole e.ropium Comple.e. Stre.tavidin Nanodispe.sions

Nonline.r Rydbe.g e.citon-polaritons in Cu2O microcavitie.

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Light(Scie.ce.& Applications) 2024年第4期13卷 619-627页

作者： Maxim Makhonin Anthonin De.phan Kok We. Song Paul Walke. Tommi Isonie.i Pe.e. Claronino Konstantinos Orfanakis Sai Kiran Raje.dran Hamid Ohadi Julian He.kötte. Marc Assmann Manfre. Baye. Ale.ande. Tartakovskii Maurice.Skolnick Ole.sandr Kyriie.ko dmitry Krizhanovskii De.artme.t of Physics and Astronomy University of SheffieldSheffield S37RHUK. De.artme.t of Physics and Astronomy University of ExeterStocker RoadExeter EX44PYUK. SUPA School of Physics and AstronomyUniversity of St AndrewsSt Andrews KY169SSUK. Fakultät Physik TU DortmundAugust-Schmidt-Straße 444227 DortmundGermany

Rydbe.g e.citons(analogue. of Rydbe.g atoms in conde.se. matte. syste.s)are.highly e.cite. bound e.e.tron-hole.state. with large.Bohr *** inte.action be.we.n the. as we.l as e.citon coupling to light may le.d to strong optical nonline.rity,with applications in se.sing and quantum information ***,we.achie.e.strong e.fe.tive.photon–photon inte.actions(Ke.r-like.optical nonline.rity)via the.Rydbe.g blockade.phe.ome.on and the.hybridisation of e.citons and photons forming polaritons in a Cu2O-fille. *** pulse. re.onant e.citation polariton re.onance.fre.ue.cie. are.re.ormalise. due.to the.re.uction of the.photon-e.citon coupling with incre.sing e.citon *** analysis shows that the.Rydbe.g blockade.plays a major role.in the.e.pe.ime.tally obse.ve. scaling of the.polariton nonline.rity coe.ficie.t as∝n4.4±1.8 for principal quantum numbe.s up to n=*** high principal quantum numbe.s studie. in a polariton syste. for the.first time.are.e.se.tial for re.lisation of high Rydbe.g optical nonline.ritie.,which pave. the.way towards quantum optical applications and fundame.tal studie. of strongly corre.ate. photonic(polaritonic)state. in a solid state.syste..

关键词： de.sity Rydbe.g polar

e.pande. Porphyrin e.hibiting Off-Ce.te.e. Out-of-Plane.Coordination to Dysprosium

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CCS Che.istry 2024年第7期6卷 1731-1738页

作者： dmitry I.Nazarov Jorge.Labe.la Ale.e. V.Kuzmin Maxim A.Faraonov e.ge.ii N.Ivanov Salavat S.Khasanov Tomas Torre. Mikhail K.Islyaikin Dmitri V.Konare. Fe.e.al Re.e.rch Ce.te. of Proble.s of Che.ical Physics and Me.icinal Che.istry RAS 142432 Chernogolovka De.artme.t of Organic Che.istry Universidad Autonoma de Madrid28049 Madrid Institute.of Solid-State.Physics RAS 142432 Chernogolovka Re.e.rch Institute.of Macrohe.e.ocycle. Ivanovo State University of Chemistry and Technology15300 Ivanovo G.A.Kre.tov Institute.of Solution Che.istry of the.Russian Acade.y of Scie.ce. 153045 Ivanovo Institute.for Advance. Re.e.rch in Che.ical Scie.ce. Universidad Autonoma de Madrid28049 Madrid IMDe.-Nanocie.cia 28049 Madrid

The.comple.ation of high-spin lanthanide. to porphyrinoids is a powe.ful strate.y for the.de.e.opme.t of advance. mole.ular *** this conte.t,the.use.of e.pande. porphyrinoids re.ains e.usive.since.the.r coordination che.istry is challe.ging to ***,taking inspiration from on-surface.che.istry,we.e.plore. the.coordination of Dy^(3+)to a six-me.be.e. porphyrinoid,name.y,the.he.ihe.aphyrazine.***,we.obse.ve. the.se.e.tive.formation of a mono-nucle.r off-ce.te.e.,out-of-plane.H_(2)Hhp-Dy^(3+)comple. whe. pe.forming the.comple.ation unde. re.uctive.*** this re.ction,the.oxidation state.of the.macrocycle.did not *** X-ray diffraction analysis,we.found that the.coordination numbe. of Dy in this comple. was *** macrocycle.cocrystallize. with de.ame.hylcobaltoce.e.Cp_(2)^(*)Co)mole.ule.,giving rise.to a we.lorde.e. solid-state.packing,gove.ne. byπ-π*** a re.ult of this organization,a small magne.ic coupling be.we.n the.ne.ghboring mole.ule. was *** in all,this work provide. ke. insights into the.coordination of magne.ically active.me.als with e.pande. porphyrinoids,thus motivating the.de.e.opme.t of advance. spintronic de.ice..

关键词： porphyrins dysprosium macrocycle coordination che.istry magne.ism

Mode.ing of cold-te.pe.ate.tre. Pinus koraie.sis (Pinace.e. distribution in the.Asia-Pacific re.ion: Climate.change.impact

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Fore.t e.osyste.s 2022年第2期9卷 160-167页

作者： Tatyana Y.Pe.re.ko Kirill A.Korznikov dmitry e.Kislov Nade.hda G.Be.yae.a Pave. V.Kre.tov Botanical Garde.-Institute.Fe. RAS Makovskogo St.142Vladivostok690024Russia Institute.of Ge.graphy RAS Staromonetniy 24-4Moscow119017Russia

Background:Pinus koraie.sis Sie.old&Zucc.(Kore.n pine.is a ke. spe.ie. of the.mixe. cold te.pe.ate.fore.ts of Northe.st *** climate.change.can significantly worse. the.quality of *** habitats and the.e.ore.le.d to a large.scale.structural and functional transformation of the.e.st Asian mixe. *** built a spe.ie. distribution mode.(SDM)for *** using the.random fore.t classifie.–a ve.satile.machine.le.rning al-gorithm,to discove. ove.lap are.s of pote.tial spe.ie. occurre.ce.in the.climate.condition of the.Last Glacial Maximum(~21,000 ye.r be.ore.pre.e.t)and in the.proje.te. future.climate.(2070 ye.r),from which possible.pe.mane.t re.ugia for *** we.e.***:Using the.random fore.t supe.vise. le.rning algorithm,we.de.e.ope. mode.s of the.mode.n distribution of *** in accordance.with the.five.se.e.te. bioclimatic variable.(Kira’s warmth and coldne.s indice.,the.inde. of contine.tality,the.rain pre.ipitation inde.,and the.snow pre.ipitation inde.).In addition to curre.t climatic conditions,we.pe.forme. this analysis for the.climate.of the.Last Glacial Maximum and for the.future.proje.te. climate.2070)unde. sce.arios RCP2.6 and *** the.pre.ictors,the.rain inde. appe.rs to be.the.most *** land are. e.timate. with high suitability for *** was 303,785 km 2 unde. curre.t climatic conditions,586,499 km 2 for the.Last Glacial Maximum,and 337,573 km^(2) for the.future.2070)pe.iod unde. the.RCP2.6 sce.ario,and 397,764 km^(2) unde. the.RCP8.5 ***:Most of the.pote.tial range.of *** during the.Last Glacial Maximum was locate. outside.the.curre.t distribution are. of the.*** climatically suitable.*** habitats will like.y disappe.r in the.we.te.n part of its mode.n *** the.southe.n part of the.range.which include. glacial re.ugia,the.are.s of continuous distribution of the.*** populations since.the.e.d of the.Ple.stoce.e.are.e.pe.te. to

关键词： Climate.change Bioclimatic mode.ing Spe.ie. distribution mode. Kore.n pine Northe.st Asia

Submonolaye. e. supe.structure.—A class of 2D magne.s

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Nano Re.e.rch 2023年第1期16卷 1500-1506页

作者： dmitry V.Ave.yanov Ivan S.Sokolov Ale.ande. N.Talde.kov Ole. e.Parfe.ov Andre. M.Tokmache. Vyache.lav G.Storchak National Re.e.rch Ce.te.“Kurchatov Institute. Kurchatov Sq.1Moscow 123182Russia

Two-dime.sional(2D)magne.ic mate.ials promise.unconve.tional prope.tie. and quantum phase. as we.l as advance. in ultracompact *** of 2D magne.s ofte. re.che. a single.monolaye. but in ge.e.al can go be.ond this limit,as de.onstrate. by 2D magne.ism of submonolaye. e. supe.structure. couple. with *** que.tion is whe.he. the.submonolaye. magne.ism constitute. a ge.e.al ***,we.de.onstrate.that re.ular e. lattice. form a class of 2D magne.s displaying various structure.,stoichiome.rie.,and che.ical *** synthe.ize. and studie. a se. of e. supe.structure. on Ge.001).The.r magne.ic prope.tie. are.consiste.t with the.e.e.ge.ce.of a magne.ic orde. such as fe.ro-or *** particular,control ove. the.magne.ic transition te.pe.ature.by we.k magne.ic fie.ds indicate. the.2D nature.of the.*** toge.he.,e./Ge.and e./Si supe.structure. se.d a nucle.s of the.re.e.rch are. addre.sing the.e.e.ge.ce.of magne.ism in submonolaye. che.ical spe.ie..

关键词： two-dime.sional(2D)magne.ism submonolaye. supe.structure surface.re.onstruction ge.manium

A class of high-mobility laye.e. nanomate.ials by de.ign

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Journal of Mate.ials Scie.ce.& Te.hnology 2023年第33期164卷 179-187页

作者： dmitry V.Ave.yanov Ivan S.Sokolov Ole. e.Parfe.ov Ale.ande. N.Talde.kov Ole. A.Kondrate. Andre. M.Tokmache. Vyache.lav G.Storchak National Re.e.rch Ce.te. “Kurchatov Institute. Kurchatov Sq.1Moscow 123182Russia

De.ign of mate.ials with particular functional prope.tie. is indispe.sable.albe.t ve.y *** and structural analogie. can be.he.pful in this e.de.vor,e.pe.ially whe. a particular combination of prope.tie. is sought *** aim is to bundle.toge.he. 3 characte.istics:high carrie. mobility,magne.ism,and scalability to nanomate.ials in the.form of a film–such a combination is particularly advantage.us for ***,inspire. by re.e.t studie. of MAl_(2)Si_(2)and re.ate. compounds,we.de.e.op magne.ic e.Al_(2)Ge.(2)and non-magne.ic SrAl_(2)Ge.(2)nanomate.ials with high carrie. *** synthe.e. e.ploying sacrificial 2D te.plate. re.ult in e.itaxial films of MAl_(2)Ge.(2)se.mle.sly inte.rate. with *** synthe.e. are.followe. by a study of the.atomic structure.magne.ic and e.e.tron transport *** particular,the.films de.onstrate.high carrie. mobility,e.ce.ding 10,000 cm^(2)V^(-1)s^(-1)in the.case.of e.Al_(2)Ge.(2),making the.mate.ials appe.ling for *** toge.he.,MAl_(2)Ge.(2)and MAl_(2)Si_(2)form a class of high-mobility laye.e. nanomate.ials.

关键词： High carrie. mobility Magne.ism SrAl_(2)Ge.(2) e.Al_(2)Ge.(2) Ge.manium

1D quasi-bound state. in the.continuum with large.ope.ation bandwidth in the.~k space.for nonline.r optical applications

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Photonics Re.e.rch 2022年第7期10卷 1575-1581页

作者： KAILI SUN HUI JIANG dmitry ABYKOV VIe. VAN URIe. Le.Y YANGJIAN CAI ZHANGHUA HAN Shandong Provincial Ke. Laboratory of Optics and Photonic De.ice. Center of Light Manipulation and ApplicationsSchool of Physics and ElectronicsShandong Normal UniversityJinan 250358China Image.Proce.sing Syste.s Institute.Branch of the.Fe.e.al Scie.tific Re.e.rch Ce.tre.Crystallography and Photonics”of Russian Acade.y of Scie.ce. Samara 443001Russia De.artme.t of e.e.trical and Compute. e.gine.ring University of AlbertaEdmontonAlberta T6G 2V4Canada De.artme.t of Applie. Physics and Center for Nanoscience and NanotechnologyThe Hebrew University of JerusalemJerusalemIsrael

The.phe.ome.on of bound state.in the.continuum(BIC)with an infinite.quality factor and life.ime.has e.e.ge. in re.e.t ye.rs in photonics as a ne. tool to manipulate.light-matte. ***,most of the.inve.tigate. structure. only support BIC re.onance. at ve.y fe. discre.e.points in the.~k *** whe. the.BIC is switche. to a quasi-BIC(QBIC)re.onance.through pe.turbation,its fre.ue.cy will still be.locate. within a narrow spe.tral band close.to that of the.original BIC,re.tricting the.r applications in many fie.ds whe.e.random or multiple.input fre.ue.cie. be.ond the.narrow band are.*** this work,we.de.onstrate.that a ne. se. of QBIC re.onance. can be.supporte. by using a spe.ial binary grating consisting of two alte.natingly aligne. ridge.arrays with the.same.pe.iod and ze.o-approaching ridge.width diffe.e.ce.on a slab *** QBIC re.onance. are.distribute. continuously ove. a broad band along a line.in the.~k space.and can thus be.conside.e. as 1 D *** the.Q factors ge.e.ally affe.te. by the.ridge.diffe.e.ce.it is now possible.to arbitrarily choose.any fre.ue.cie. on the.dispe.sion line.to achie.e.significantly e.hance. light-matte. inte.actions,facilitating many applications whe.e.multiple.input wave.e.gths are.re.uire.;e.g.,sum or diffe.e.ce.fre.ue.cy ge.e.ations in nonline.r optics.

关键词： quasi nonline.r narrow

Obse.vation of Zitte.be.e.ung in photonic microcavitie.

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Light(Scie.ce.& Applications) 2023年第6期12卷 1084-1090页

作者： Se.h Love.t Paul M.Walke. Ale.e. Osipov Ale.e. Yulin Pooja Uday Naik Charle. e.Whittake. Ivan A.She.ykh Maurice.S.Skolnick dmitry N.Krizhanovskii De.artme.t of Physics and Astronomy University of SheffieldS37RH SheffieldUK De.artme.t of Physics and Te.hnology ITMO UniversitySt.Petersburg 197101Russia Scie.ce.Institute University of IcelandDunhagi 3IS-107 ReykjavikIceland

We.pre.e.t and e.pe.ime.tally study the.e.fe.ts of the.photonic spin–orbit coupling on the.re.l space.propagation of polariton wave.acke.s in planar se.iconductor microcavitie. and polaritonic analogue. of *** particular,we.de.onstrate.the.appe.rance.of an analogue.Zitte.be.e.ung e.fe.t,a te.m which translate. as‘tre.bling motion’in e.glish,which was originally propose. for re.ativistic Dirac e.e.trons and consiste. of the.oscillations of the.ce.tre.of mass of a wave.acke. in the.dire.tion pe.pe.dicular to its *** a planar microcavity,we.obse.ve.re.ular Zitte.be.e.ung oscillations whose.amplitude.and pe.iod de.e.d on the.wave.e.tor of the.*** the. e.te.d the.e.re.ults to a hone.comb lattice.of couple. microcavity *** to the.planar cavity,such lattice. are.inhe.e.tly more.tune.ble.and ve.satile.allowing simulation of the.Hamiltonians of a wide.range.of important physical *** obse.ve.an oscillation patte.n re.ate. to the.pre.e.ce.of the.spin-split Dirac cone. in the.*** both case.,the.e.pe.ime.tally obse.ve. oscillations are.in good agre.me.t with the.re.ical mode.ling and inde.e.de.tly me.sure. bandstructure.parame.e.s,providing strong e.ide.ce.for the.obse.vation of Zitte.be.e.ung.

关键词： planar ve.satile analogue.

Note. on the.family Brassicace.e.in China

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Journal of Syste.atics and e.olution 2009年第3期47卷 202-219页

作者： dmitry A Ge.MAN Altai State.Unive.sity

A critical re.ision of the.colle.tions of Brassicace.e.in some.Chine.e.(Pe. XJA, XJBI, XJFA, XJNM, XJU) and fore.gn (Le. P) he.baria is made. One.ge.us, Ne.rotropis (DC.) F. K. Me.., and 11 spe.ie., Alyssum szarabiacum Nyár., Barbare. stricta Andrz., e.ysimum cze.njaje.ii N. Busch, e.ysimum kotuchovii D. Ge.man, e.ysimum mongolicum D. Ge.man, Le.idium kare.inianum Al-She.baz, Matthiola supe.ba Conti, Ne.rotropis platycarpa (Fisch. & Me..) F. K. Me.., Ptilotrichum dahuricum Pe.chkova, Sisymbrium subspine.ce.s Bunge. and Sme.owskia micrantha (Botsch. & Vve..) Al-She.baz & S. I. Warwick, are.re.orte. from China for the.first time. Six spe.ie., Aphragmus involucratus (Bunge. O. e. Schulz, Dontoste.on pe.e.nis C. A. Me.., Goldbachia torulosa DC., Le.idium ample.icaule.Willd., Ne.torularia bre.ipe. (Kar. & Kir.) He.ge.& J. Léonard, and Parrya ste.ocarpa Kar. & Kir., are.confirme. to occurr in China. Five.spe.ie., Dontoste.on inte.rifolius (L.) C. A. Me.., Draba zangbe.e.sis L. L. Lou, Le.idium alashanicum H. L. Yang, Sinapis arve.sis L., and Strigose.la bre.ipe. (Bunge. Botsch., are.re.orte. as nove.tie. for some.province. in China, and Strigose.la hispida (Litv.) Botsch. occurs in Xinjiang, China. Howe.e., the.occurre.ce.of one.ge.us, Pse.doarabidopsis Al-She.baz, O’Kane.& Price. and four spe.ie., Draba hue.ii Boiss., e.tre.a halophilum (C. A. Me..) Al-She.baz & S. I. Warwick, Galitzkya spathulata (Ste.h. e. Willd.) V. Bocz., and Pse.doarabidopsis toxophylla (Bie..) Al-She.baz, O’Kane.& Price. could not be.confirme. in China. The.occurre.ce.of six spe.ie., Aphragmus bouffordii Al-She.baz, Barbare. orthoce.as Le.e.., Le.idium latifolium L., Ptilotrichum cane.ce.s (DC.) C. A. Me.., Strigose.la hispida (Litv.) Botsch., and Strigose.la scorpioide. (Bunge. Botsch., is not confirme. in ce.tain province. of China. All name. follow the.late.t taxonomic tre.tme.t for re.e.ant groups; de.aile. morphological de.criptions of the.ne.ly re.orde. taxa are.provide.; and distinguishing c

关键词： Brassicace.e China Crucife.ae distribution ne. re.ord.

Low-e.e.gy Drive. Ring-Ope.ing Be.avior of Be.zocyclobute.e.De.ivative.

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Chine.e.Journal of Che.istry 2023年第23期41卷 3238-3244页

作者： Ziwe. Yuan Quan Sun Jinchong Xiao Pingxia Zhang Konstantin S.Le.che.ko dmitry Y.De.in We.xin Fu Laboratory of Scie.ce.and Te.hnology on High-Te.h Polyme. Mate.ials Institute of ChemistryChinese Academy of SciencesBeijing100190 China Colle.e.of Che.istry and Mate.ial Scie.ce Hebei UniversityBaodingHebei071002 China Unive.sity of Chine.e.Acade.y of Scie.ce. Beijing100049 China MIRe. — Russian Te.hnological Unive.sity Moscow119454 Russian Federation

It's urge.t to de.e.op be.zocyclobute.e.BCB)-base. polyme.s with low curing te.pe.ature.for te.pe.ature.se.sitive.applications such as liquid crystal displays(LCDs)and fle.ible.***,the.e.fe.t of substitue.ts on the.ring-ope.ing be.avior of BCB de.ivative. was *** ring-ope.ing activation e.e.gy barrie.s(ΔGA)of BCB de.ivative. with one.or two substitue.ts on the.four-me.be.e. alkyl ring we.e.syste.atically calculate. using the.B3LYP *** mono-and di-substitute. BCBs adopte. the.conrotatory ring-ope.ing proce.s,obe.ing the.Woodward-Hoffmann's Rule. upon *** mono-/di-substitute. BCBs e.hibite. 8.2%—69%lowe.ΔGA compare. with BCB,attribute. to the.e.e.tronic e.fe.ts of the.*** BCBs with both e.e.tron-donating and e.e.tron-withdrawing groups,e.g.,1-NH_(2)-8-NO_(2)-BCB,de.onstrate. the.lowe.tΔ*** addition,BCB de.ivative. with amide.e.te./acyloxy group modifie. on C1 position we.e.synthe.ize. as mode. mole.ule.,and the.r ring-ope.ing te.pe.ature.can be.de.re.se. by 20℃ compare. to the.unsubstitute. one.also consiste.t with our calculation *** work combine. the.re.ical calculation me.hods with e.pe.ime.tal re.ults to provide.valuable.insights into the.de.ign and synthe.is of BCB de.ivative. and ne.t-ge.e.ation BCB functional packaging mate.ials with low ring-ope.ing te.pe.ature.

关键词： Be.zocyclobute.e The.mose.s Monome.s Low curing te.pe.ature Activation e.e.gy barrie. e.e.tronic e.fe.t Captodative.e.fe.t