检索结果-南通市图书馆

Journal of Rare Earths 2024年第4期42卷 775-782页

作者： Glaydson S.dos Reis diana pinto Sabrina F.Lütke Eder C.Lima Luis F.O.Silva Irineu A.S.De Brum Guilherme L.Dotto Department of Forest Biomaterials and Technology Biomass Technology Centre Swedish University of Agricultural SciencesUmeaE13Swedn Universidad De La Costa Calle 58#55-66080002BarranquillaAtlanticoColombia Research Group on Adsorptive and Catalytic Process Engineering(ENGEPAC) Federal University of Santa MariaAv.Roraima100079705900Santa MariaRSBrazil Institute of Chemistry Federal University of Rio Grande do Sul90040060Porto AlegreBrazil

Chitin powder and chitin-aerogel were prepared from shrimp wastes and used to uptake Y^(3+)from aqueous solutions and concentrate this rare earth element from phosphogypsum(PG).Chitin aerogel displays a specific surface area of 945 m^(2)/g,while chitin powder is 3.6 m^(2)/g,which largely influences its adsorption *** the adsorption in synthetic solutions,the effect of pH on Y^(3+)removal is strong for chitin powder *** contrast,no big pH influence was detected for chitin *** interactions and chelation can highlight the proposed mechanism of Y^(3+)on chitin adsorbents for the powder and ***,in addition to these interactions,pore filling/pore diffusion is the main mechanism of Y^(3+)removal in the chitin *** aerogel is efficient in concentrating 8 times the Y^(3+)from PG,a very complex *** complex chitin aerogel-Y^(3+)can be a secondary source of rare earth elements for other applications.

关键词： Rare earths Sustainable material Chitin powder Chitin porous aerogel Yttrium adsorption and recovery

Deposition of nanoparticles on school eyeglasses in urban and rural areas:A methodology for a more real assessment of the possible impacts

在线全文

学校读者我要写书评

暂无评论

Geoscience Frontiers 2022年第1期13卷 498-505页

作者： Kátia Martinello James C.Hower Guilherme L.Dotto Claudete G.Ramos Carlos E.Schnorr diana pinto Instituto Inanís Rua Felizardo FurtadoPorto AlegreBrazil University of Kentucky Department of Earth&Environmental SciencesLexingtonKY 40506USA University of Kentucky Center for Applied Energy Research2540 Research Park DriveLexingtonKY 40511USA Chemical Engineering Department Federal University of Santa Maria97105-900 Santa MariaBrazil Department of Civil and Environmental Universidad de la CostaCUCCalle 58#55–66BarranquillaAtlánticoColombia

Because incomplete confirmation is available concerning the influential role of atmosphere contamination on conjunctivitis,myopia,asthma,and allergic rhinitis in Brazil,the focus of the present work is to explore the possible relations among atmosphere contamination and eye *** that a case study on eye diseases,by way of questionnaires supplemented by the investigation of nanoparticles(NPs)on eyeglasses,the study examines the mechanisms in which NPs and ultra-fine particles are deposited on the glasses of children up to 10 years of age in urban and rural *** important connection between atmosphere contaminants and individual protection equipment justifies improving indoor school properties in order could protect children’s eyes,particularly in high-pollution/high-particulate areas.

关键词： Indoor air pollution Nanoparticles Eyes health Allergic reaction Schools

Geochemical study of submicron particulate matter(PM1)in a metropolitan area

在线全文

学校读者我要写书评

暂无评论

Geoscience Frontiers 2022年第1期13卷 417-429页

作者： Ismael L.Schneider Elba C.Teixeira Guilherme L.Dotto diana pinto Cheng-Xue Yang Luis F.O.Silva Postgraduate Program in Remote Sensing and Meteorology Universidade Federal do Rio Grande do SulAv.Bento Gonçalves9500 Porto AlegreRSBrazil Department of Civil and Environmental Universidad de la CostaCUCCalle 58#55-66BarranquillaAtlanticoColombia Research Department Fundação Estadual de Proteção Ambiental Henrique Luís RoesslerAv.Borges de Medeiros261Porto AlegreRSBrazil Chemical Engineering Department Federal University of Santa Maria97105-900 Santa MariaBrazil School of Earth Sciences and Resources China University of Geosciences BeijingBeijing 100083PR China Departamento de Ingeniería Civil y Arquitectura Universidad de LimaAvenida Javier Prado Este 4600–Santiago de Surco 1503Perú

Air pollution has become a major problem in urban areas due to increasing industrialization and *** this study ambient concentrations of PM1 and metal concentrations as well as source contributions were identified and quantified by using Positive Matrix Factorization(PMF)in receptor modeling in the Metropolitan Area of Porto Alegre,*** PM1 samples were collected on PTFE filters from December 2012 to December 2014 in two sampling *** ion and trace element concentrations were *** average concentrations were 12.8 and 15.2μg/m^(3) for Canoas and Sapucaia do Sul sites,*** ion contributions of PM1 were secondary pollutants such as sulfate and *** elements,especially Cu,Pb,Zn,Cd,and Ni also made important contributions which are directly associated with anthropogenic *** results show significantly higher levels in winter than in *** of the PM1 and the analyzed PM species and elements originated from anthropogenic sources,especially road traffic,combustion processes and industrial activities,which are grouped in 7 major contributing sources.A back-trajectory analysis showed that the long-range transport of pollutants was not relevant in relation to the contribution to PM1 and metal *** work highlights the importance of urban planning to reduce human health exposure to traffic and industrial emissions,combined with awareness-raising actions for citizens concerning the impact of indoor sources.

关键词： PM1 Trace elements Source apportionment PMF Back trajectory

Artisanal ceramic factories using wood combustion:A nanoparticles and human health study

在线全文

学校读者我要写书评

暂无评论

Geoscience Frontiers 2022年第1期13卷 488-497页

作者： Kátia Martinello James C.Hower diana pinto Carlos E.Schnorr Guilherme L.Dotto Marcos Leandro Silva Oliveira Claudete G.Ramos Instituto Inanís Rua Felizardo FurtadoPorto AlegreBrazil Department of Civil and Environmental Universidad de la CostaCUCCalle 58#55–66BarranquillaAtlánticoColombia University of Kentucky Department of Earth&Environmental SciencesLexingtonKY 40506USA University of Kentucky Center for Applied Energy Research2540 Research Park DriveLexingtonKY 40511USA Centro de Estudos em Estresse Oxidativo-Departamento de Bioquímica-Instituto de Ciências Básicas da Saúde-Universidade Federal do Rio Grande do Sul(UFRGS) Porto AlegreRSBrazil Chemical Engineering Department Federal University of Santa MariaUFSMRoraima Avenue1000Santa MariaRS97105-900Brazil Departamento de Ingeniería Civil y Arquitectura Universidad de LimaAvenida Javier Prado Este 4600–Santiago de Surco 1503Peru

The ceramics industry,resulting from developments of modern compounds,is a segment of great influence in worldwide *** ceramic factories based on wood combustion have significant risks for the creation and discharge of atmosphere nanoparticles(NPs)and ultra-fine particles(UFPs).At present,there is insufficient recognition on the influence of engineered-NPs on the atmosphere and *** improvements are indispensable to diminish contact with *** present study demonstrates the main NPs and UFPS present in an area of intense artisanal wood-combustion ceramic *** matter was sampled for morphological,chemical,and geochemical studies by sophisticated electron microbeam microscopy,X-Ray Diffraction,and Raman *** NPs configuration(10 nm)were produced around the studied artisanal ceramic *** study presents an indication of the recent information on population and work-related contact to NPs in the artisanal ceramic factories and their influence on health.

关键词： Ceramic manufacturing Nanoparticles Advanced characterization Multiple impacts

Adsorption of rare earth elements onto diatomite M45:Experimental investigations and modeling with statistical physics theory

在线全文

学校读者我要写书评

暂无评论

Journal of Rare Earths 2023年第11期41卷 1805-1811,I0006页

作者： Fatma Dhaouadi Guilherme L.Dotto Julien Vieillard diana pinto Luis F.O.Silva Éder C.Lima Mu Naushad Fatma Aouaini Samia Nasr Adrián Bonilla-Petriciolet Abdelmottaleb Ben Lamine Laboratory of Quantum and Statistical Physics LR18ES18Faculty of Sciences of MonastirMonastir UniversityMonastirTunisia Research Group on Adsorptive and Catalytic Process Engineering(ENGEPAC) Federal University of Santa MariaAv.Roraima1000-797105–900Santa MariaRSBrazil NormandieUniversité UNIROUENINSA RouenCNRSCOBRA(UMR 6014)27000EvreuxFrance Universidad De La Costa Calle 58#55-66080002BarranquillaAtlánticoColombia Advanced Materials Research Chair Department of ChemistryCollege of ScienceKing Saud UniversityRiyadh11451Saudi Arabia Department of Chemistry College of ScienceBuilding#5King Saud UniversityRiyadhSaudi Arabia Department of Physics College of SciencePrincess Nourah Bint Abdulrahman UniversityP.O.Box 84428Riyadh11671Saudi Arabia Research Center for Advanced Materials Science(RCAMS) King Khalid UniversityAbha61413P.O.Box 9004Saudi Arabia Chemistry Department Faculty of ScienceKing Khalid UniversityP.O.Box 9004Abha61413Saudi Arabia Instituto Tecnológico de Aguascalientes 20256AguascalientesMexico

The separation of rare earth elements using diatomite M45 from aqueous solutions was *** experimental isotherms for the adsorption of trivalent lanthanum,cerium,and neodymium cations on this adsorbent were quantified under strongly acidic conditions(pH 2)at 298-328 *** adsorption equilibria of these earth elements were analyzed using two statistical physics models(homogeneous and heterogeneous monolayer models).The results show that the adsorption of these ions implies a multiionic mechanism,which is ***-containing functional groups are responsible for the adsorption of these rare-earth elements on the diatomite surface.A heterogeneous statistical physics model confirms that two Si-based functional groups participate in the separation of these *** calculated adsorption capacities at saturation follow the order:neodymium>cerium>*** interaction energies range from 28600 to 40100 J/mol,indicating physical adsorption on diatomite *** study demonstrates that diatomite M45 is a promising separation medium that can be used for the recovery of REEs dissolved in aqueous solutions via adsorption.

关键词： Lanthanum Cerium Neodymium Adsorption Diatomite M45 Statistical physics model

Particulate matter geochemistry of a highly industrialized region in the Caribbean:Basis for future toxicological studies

在线全文

学校读者我要写书评

暂无评论

Geoscience Frontiers 2022年第1期13卷 376-387页

作者： Luis F.O.Silva Ismael L.Schneider Paulo Artaxo Yuleisy Núñez-Blanco diana pinto Érico M.M.Flores Leandro Gómez-Plata Omar Ramírez Guilherme L.Dotto Department of Civil and Environmental Universidad de la CostaCUCCalle 58#55–66BarranquillaAtlánticoColombia Department of Applied Physics Institute of PhysicsUniversity of São PauloBrazil Department of Chemistry Universidade Federal de Santa MariaRSBrazil Universidad Militar Nueva Granada(UMNG) Faculty of EngineeringEnvironmental EngineeringKm 2 Cajicá-ZipaquiráColombia Chemical Engineering Department Federal University of Santa Maria-UFSM1000Roraima Avenue97105-900 Santa MariaRSBrazil

Air pollution has become an important issue,especially in Caribbean urban areas,and,particulate matter(PM)emitted by different natural and anthropogenic sources causes environmental and health *** this work,we studied the concentrations of PM_(10) and PM_(2.5) sources in an industrial and port urban area in the Caribbean region of *** samples were collected within 48-h periods between April and October 2018 by using a Partisol 2000 i-D *** geochemical characterization was performed by X-ray fluorescence(XRF)***,ionic species and black carbon(BC)were quantified by ion chromatography and reflectance spectroscopy,*** the Positive Matrix Factorization(PMF)receptor model,the contributions of PM sources were *** average concentration of PM_(10) was 46.6±16.2μg/m^(3),with high concentrations of Cl and *** PM_(2.5),the average concentration was 12.0±3.2μg/m^(3),and the most abundant components were BC,S,and *** receptor model identified five sources for PM_(10) and PM_(2.5).For both fractions,the contributions of marine sea spray,re-suspended soil,and vehicular traffic were *** addition,PM_(2.5) included two mixed sources were found to be fuel oil combustion with fertilizer industry emissions,and secondary aerosol sources with building construction ***,PM_(10) was found to also include building construction emissions with re-suspended soil,and metallurgical industry *** obtained geochemical atmospheric results are important for the implementation of strategies for the continuous improvement of the air quality of the Caribbean region.

关键词： Urban air pollution Particulate matter Geochemical composition Aerosol source apportionment Receptor models PMF

An analysis of vehicular exhaust derived nanoparticles and historical Belgium fortress building interfaces

在线全文

学校读者我要写书评

暂无评论

Geoscience Frontiers 2020年第6期11卷 2053-2060页

作者： Luis F.O.Silva diana pinto Alcindo Neckel Marcos L.S.Oliveira Department of Civil and Environmental Engineering.Universidad de La Costa CUCCalle 58#55-66BarranquillaAtlanticoColombia Faculdade Meridional IMED 304-Passo FundoRS 99070-220Brazil University of Antwerp Prinsstraat 132000AntwerpBelgium

Air pollution monitoring is one of the most important features in contamination risk *** is because many of the compounds contained within air pollution present a serious risk both for the preservation of open air cultural heritage and for human *** particle formation is a major contributor to urban pollution,but how it occurs in cities is often *** more and more people enjoy an increased quality of life through outdoor activity,managing outdoor air quality is *** study presents the application of a low-cost system for monitoring the current level of road traffic passengers’exposure to particulate air *** global rise in tourism also leads to apprehension about its probable destructive influence on various aspects of global *** of the major risks encountered by tourists,stemming from modes of transport,are nanoparticles(NPs)(<100 nm)and ultra-fine particles(UFPs)(100-1000 nm)consisting of potentially hazardous elements(PHEs).This study examines Steen Castle,a medieval fortress located in Antwerp,*** NPs with PHEs,were found in the air sampled in this *** self-made passive sampler(LSPS)described in this study,consisting of retainers specially designed for advanced microscopic analysis,is used for the first time as a simple way to characterize the surrounding atmospheric contamination caused by NPs and UFPs,without the need of other commonly employed more expensive particulate focused active samplers such as cascade *** study aims to assess the result of the utilization of a low-cost,LSPS,to determine outdoor NPs and UFPs in a Belgian urban(Steen Castle)and rural area(Fort van Schoten).This work is the first to detail the usefulness of LSPS for the evaluation of Belgium’s outdoor air for NPs and UFPs,which contain PHEs.

关键词： Atmospheric contamination Historic construction Carbonaceous particles Source investigation Vehicular traffic effects

Nanomineralogy of evaporative precipitation of efflorescent compounds from coal mine drainage

在线全文

学校读者我要写书评

暂无评论

Geoscience Frontiers 2021年第6期12卷 404-410页

作者： Luis F.O.Silva diana pinto Guilherme L.Dotto James C.Hower Department of Civil and Environmental.Universidad de La Costa CUCCalle 58#55–66BarranquillaAtlanticoColombia Universidade Federal de Santa Maria–UFSM 1000Roraima Avenue97105–900Santa MariaRSBrazil University of Kentucky Department of Earth&Environmental SciencesLexingtonKY40506USA University of Kentucky Center for Applied Energy Research2540 Research Park DriveLexingtonKY40511USA

Efflorescent nanophases(NPs) are found as a transitory accumulation of potentially hazardous elements(PHEs),particularly in tropical climates. The central objective of this study was to investigate the distribution of PHEs with NPs through the evaporative formation structures(EFS) of enormously PHEs-rich coal-mine drainages(CMD). The EFS were studied in natural coal mine drainage for five months in order to determine their geochemical and ecological structures and to assess their position in the reduction of PHEs in nature. The largest coal-fired power plant in South America, located in south Brazil, is used as an example of such a problem. In this work, a novel methodology for the analysis of PHEs in CMD precipitates is proposed for this affected coal *** analytical method, combining X-Ray Diffraction(XRD) and advanced electron microscopies, shows the importance of nanomineralogy in understanding different circumstances of coal contamination. Several ultrafinenanoparticles(UNPs) were identified in the sampled soils and river sediments together with the PHEs. A decrease in PHEs was identified in association with UNPs. However, further investigations are required with regard to the mobility of PHEs in water, atmosphere, soils, and sediments. The EPS was thoroughly studied, acquiring suitable understanding with investigational facts for Ca and Fe-sulphates, pickeringite, and several amorphous phases.

关键词： Coal mine drainage Evaporative precipitation Sediments Water and soil pollution

Integrated CO_(2)capture and reduction catalysis:Role ofγ-Al_(2)O_(3)support,unique state of potassium and synergy with copper

在线全文

学校读者我要写书评

暂无评论

Journal of Environmental Sciences 2024年第6期140卷 113-122页

作者： Donato pinto Stefano Minorello Zhouping Zhou Atsushi Urakawa Catalysis Engineering Department of Chemical EngineeringDelft University of TechnologyDelft2629HZNetherlands

Carbon dioxide capture and reduction(CCR)process emerges as an efficient catalytic strategy for CO_(2)capture and conversion to valuable chemicals.K-promoted Cu/Al_(2)O_(3)catalysts exhibited promising CO_(2)capture efficiency and highly selective conversion to syngas(CO+H_(2)).The dynamic nature of the Cu-K system at reaction conditions complicates the identification of the catalytically active phase and surface *** present work aims at more precise understanding of the roles of the potassium and copper and the contribution of the metal oxide ***γ-Al_(2)O_(3)guarantees high dispersion and destabilisation of the potassium phase,potassium and copper act synergistically to remove CO_(2)from diluted streams and promote fast regeneration of the active phase for CO_(2)capture releasing CO while passing H_(2).A temperature of 350℃is found necessary to activate H_(2)dissociation and generate the active sites for CO_(2)*** effects of synthesis parameters on the CCR activity are also described by combination of ex-situ characterisation of the materials and catalytic testing.

关键词： Carbon dioxide Carbon capture and utilisation CO_(2)capture and reduction Solid CO_(2)sorbents Heterogeneous catalysis Potassium Copper catalysts Aluminium oxide

The Role of the Spatial Network in Urban Disaster Risk Variations:Reimagining the Notion of Spatial Vulnerability at the Urban Scale

在线全文

学校读者我要写书评

暂无评论

International Journal of Disaster Risk Science 2024年第3期15卷 303-316页

作者： Monia Del pinto Ksenia Chmutina Falli Palaiologou Lee Bosher School of Architecture Building and Civil Engineering Loughborough University School of Business University of Leicester

The notion of “spatial vulnerability” is present in most disaster studies with a strong geographical connotation and accordingly is adopted at all scales, including the urban. While enabling mapping and visualizing risk patterns at macroscales, this geocentric foundation fails to capture disaster risk dynamics associated with the urban spatial network—an element that plays a significant role in the everyday and emergency functioning of cities, enabling users' movement and interaction. Yet,urban vulnerability assessment overlooks this aspect and thus leaves urban disaster risk mechanisms partially *** study investigated the role of the network of urban public open spaces(UPOS) in the creation and progression of urban disaster risk in earthquake-prone settlements. Through a multimethod approach that integrates quantitative and qualitative methods and explores spatial configuration, planning policies, and practices of use of UPOS in everyday and emergency scenarios, our study demonstrated that UPOS configuration plays an active role in urban disaster risk. Urban public open spaces impact risk by influencing the exposure of pedestrians and their capacity for self-protection. The study further reconceptualized spatial vulnerability at the urban scale, as the fraction of vulnerability associated to the spatial network, highlighting the interplay of planning policies and spatial practices in its production and progression. Our findings make the notion of spatial vulnerability less ambiguous at the urban scale, by viewing the variable as an imbalance in capacities and exposure that generates spatially unsafe conditions. This refined conceptualization of spatial vulnerability becomes a lens for a more granular approach to urban disaster risk reduction and city planning by identifying and integrating sociospatial considerations.

关键词： Central Italy Earthquakes Pedestrian evacuation Space syntax Spatial vulnerability Urban disaster risk