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Green Chemical Engineering 2024年第2期5卷 236-244页

作者： Chi ma Lihong Zhao Zhengxin mao Hao Su Qingfen Liu CAS Key Laboratory of Green Process and Engineering Institute of Process EngineeringChinese Academy of SciencesBeijing100190China School of Chemical Engineering University of Chinese Academy of SciencesBeijing100049China

Industrial pharmaceutical wastewater usually contains butyl acetate(BA)with a concentration of 1 wt%-7 wt%,and the traditional method for BA recovery is distillation with high energy *** method is developed to recover BA with low concentration for the high efficiency and low energy *** polar polyacrylate resins with macroporous structure of 233.1 nm and average particle size of about 526.5μm are successfully synthesized by suspension polymerization and used for the BA adsorption and *** maximum adsorption capacity reaches 171.1 mg g^(-1)with relative standard deviation(RSd)value of 0.2%,which is more than twice the results in the *** BA desorption rate is 97.0%at 100℃with RSd value of 0.4%,and the resins are beneficial to the reuse in the adsorption-desorption *** adsorption thermodynamics and kinetics are investigated,and the BA adsorption is a spontaneous and endothermic process with the increase of disorder *** process is mainly contributed by physical absorption and agree well with Freundlich model and pseudo-first-order adsorption kinetic *** adsorption method avoids boiling a large amount of wastewater and hopefully provides a novel alternative technology for the BA recovery.

关键词： Butyl acetate recovery Resin adsorption desorption Thermodynamics Kinetics

Promoted Non-enzymatic Glucose Sensor Based on Synergistic Effect of Hydrothermal Synthesized Ni(OH)_(2)-Graphene Nanocomposite

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Chemical Research in Chinese Universities 2024年第5期40卷 914-921页

作者： CAI Yuqing CUI Qingyan ZHANG Huanrong ma Xinlei XUE Mianqi School of Chemistry and Life Resources Renmin University of ChinaBeijing100872P.R.China Technical Institute of Physics and Chemistry Chinese Academy of ScienceBeijing100190P.R.China

Although glucose electrochemical sensors based on enzymes play a dominant role in market,their stability remains a problem due to the inherent nature of ***,glucose sensors that are independent on enzymes have attracted more attention for the development of stable detection *** we present an enzyme-free glucose sensor based on Ni(OH)_(2)and reduced graphene oxide(rGO).The as-fabricated sensor still exhibits excellent electrocatalytic activity for detecting glucose under enzyme independent *** enhanced catalytic performance may due to synergistic effect as follows:(i)the interaction between the Ni2+andπelectron of graphene induces the formation of theβ-phase Ni(OH)_(2)with higher catalytic activity;(ii)the frozen dry process works as a secondary filtration,getting rid of poorly formed Ni(OH)_(2)particles with low catalytic activity;(iii)the rGO network with good conductivity provides a good electronic pathway for promoting electron transfer to reduce the response *** on the synergistic effect,the sensor exhibits a wide linear detection range from 0.2µmol/L to 1.0µmol/L and a low detection limit(0.1µmol/L,S/N=3).The excellent detection performance,as well as the easy and low-cost preparation method,suggests the promising applicability of the sensor in the glucose detection market.

关键词： Glucose sensing Non-enzyme sensor Graphene 2d material Ni(OH)_(2)nanosheet

dimensional reduction enhances photocatalytic carbon dioxide reduction performance of metal-organic frameworks

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Nano Research 2024年第5期17卷 3653-3659页

作者： Kaiyue ma Jixin Li Jinlu Liu Chunguang Li Zhan Shi Shouhua Feng State Key Laboratory of Inorganic Synthesis and Preparative Chemistry College of ChemistryJilin UniversityChangchun 130012China

Metal-organic frameworks(MOFs)have shown significant potential as *** has been widely assumed that all catalytic active sites within MOFs are functional in photocatalytic reactions but for a three-dimensional MOF,whether the internal catalytic active sites can effectively absorb light and actively contribute to photocatalytic reactions remains to be *** this context,we synthesized a two-dimensional nanosheet MOF(2d-MOF)and a three-dimensional bulk MOF(3d-MOF)composed of Zr^(6) clusters and tetracarboxylic porphyrin(TCPP)by the approach described in the ***(bpy)(CO)^(3)Cl(bpy=2,2’-bipyridine),which has remarkable CO_(2) photoreduction ability,was introduced to the two MOFs to create two new photocatalysts 2d-MOF-Re and 3d-MOF-Re,*** CO_(2) reduction experiments show that based on the equal number of catalytic active sites,the CO turnover number(TON)of 2d-MOF-Re reaches 27.8 in 6 h,which is 50 times that of *** result shows that certain catalytic active sites inside the bulk MOF are inactive due to the inability to absorb *** study illuminates the potential of the dimensional reduction approach in the design of photocatalysts to exploit the capabilities fully.

关键词： photocatalysis CO_(2)reduction metal-organic frameworks(MOFs) nanosheets light absorption

Overcoming the Na-ion conductivity bottleneck for the cost-competitive chloride solid electrolytes

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Journal of Energy Chemistry 2024年第8期95卷 1-8,I0001页

作者： Lv Hu Hui Li Fang Chen Yating Liu Jinzhu Wang Cheng ma Hefei National Research Center for Physical Sciences at the Microscale CAS Key Laboratory of Materials for Energy ConversionDepartment of Materials Science and EngineeringUniversity of Science and Technology of ChinaHefei 230026AnhuiChina National Synchrotron Radiation Laboratory Hefei 230026AnhuiChina

Chloride solid electrolytes possess multiple advantages for the construction of safe,energy-dense allsolid-state sodium batteries,but presently the chlorides with sufficiently high cost-competitiveness for commercialization almost all exhibit low Na-ion conductivities of around 10^(-5)S cm^(-1)or ***,we report a chloride solid electrolyte,Na_(2.7)ZFCl_(5.3)O_(0.7),which reaches a Na-ion conductivity of 2.29×10^(-4)S cm^(-1)at 25℃without involving overly expensive raw materials such as rare-earth chlorides or Na_(2)*** addition to the efficient ion transport,Na_(2.7)ZrCl_(5.3)O_(0.7)also shows an excellent deformability surpassing that of the widely studied Na_(3)PS_(4),Na_(3)SbS_(4),and Na_(2)ZrCl_(6)solid *** combination of these advantages allows the all-solid-state cell based on Na_(2.7)ZrCl_(5.3)O_(0.7)and NaCrO_(2)to realize stable room-temperature cycling at a much higher specific current than those based on other non-viscoelastic chloride solid electrolytes in literature(120 ma g^(-1)vs.12-55 ma g^(-1));after 100 cycles at such a high rate,the Na_(2.7)ZFCl_(5.3)O_(0.7)-based cell can still deliver a discharge capacity of 80 mah g^(-1)at25℃.

关键词： All-solid-state sodium batteries Ionic conductivities Solid electrolytes Chlorides High voltage stability

A prompt-based approach to adversarial example generation and robustness enhancement

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Frontiers of Computer Science 2024年第4期18卷 85-96页

作者： Yuting YANG Pei HUANG Juan CAO Jintao LI Yun LIN Feifei ma Key Lab of Intelligent Information Processing of Chinese Academy of Sciences(CAS) Institute of Computing TechnologyCASBeijing 100190China School of Computer Science and Technology University of Chinese Academy of SciencesBeijing 100049China department of Computer Science Stanford UniversityCA 94305USA School of Computing National University of SingaporeSingapore 119077Singapore Laboratory of Parallel Software and Computational Science Institute of SoftwareChinese Academy of SciencesBeijing 100190China

Recent years have seen the wide application of natural language processing(NLP)models in crucial areas such as finance,medical treatment,and news media,raising concerns about the model robustness and *** find that prompt paradigm can probe special robust defects of pre-trained language *** prompt texts are first constructed for inputs and a pre-trained language model can generate adversarial examples for victim models via *** results show that prompt paradigm can efficiently generate more diverse adversarial examples besides synonym ***,we propose a novel robust training approach based on prompt paradigm which incorporates prompt texts as the alternatives to adversarial examples and enhances robustness under a lightweight minimax-style optimization *** on three real-world tasks and two deep neural models show that our approach can significantly improve the robustness of models to resist adversarial attacks.

关键词： robustness adversarial example prompt learning pre-trained language model

NMR-based analysis of the effect of moisture migration on sandstone pore structure under alternating wetting and drying conditions

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International Journal of Mining Science and Technology 2024年第8期34卷 1135-1150页

作者： Huasu Wang Jing Bi Yu Zhao Chaolin Wang Jiabao ma College of Civil Engineering Guizhou UniversityGuiyang 550025China

The wetting-drying(W-d)cycle is a type of water–rock *** pore structure of rock,such as shape,size,distribution and pore throat,affects fluid storage and *** theory and experimental research on the evolution characteristics of pore damage during the wet-dry erosion process are highly important for determining W-d *** mass and velocity of liquid migration are related to the pore size,porosity,fluid properties,*** data show that the water absorption quality and velocity in rocks decrease with the number of wet-dry *** the same test time,the mass and velocity of the SI water absorption method are smaller than those of the FI *** these two conditions,the amount and rate of water absorption represent the degree of water–rock *** the pore evolution during the wet-dry cycling,an equation describing the motion of liquid in porous media was derived based on the imbibition-type separation *** experimental data are in excellent agreement with the calculated values of the *** characteristics can affect the area and degree of rock deterioration as well as the development rate of pores and *** on the interaction between permeability and pores,quantitative analysis of the weakening process(local damage)of rocks under W-d cycles can provide good reference indicators for evaluating the stability of geotechnical engineering.

关键词： W-d cycle Capillary absorption Pore characteristic Fractal theory dynamic damage model

direct enantioselective reduction of C=C bond of β-polyfluoro-alkylated enones via asymmetric photoredox catalysis

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Science China Chemistry 2024年第6期67卷 2016-2021页

作者： Linghong Zhang Jin ma Xu Ban Xiaowei Zhao Yanli Yin Zhiyong Jiang Key Laboratory of Natural Medicine and Immuno-Engineering of Henan Province Henan UniversityKaifeng475004China School of Chemistry and Chemical Engineering Henan Normal UniversityPingyuan LaboratoryXinxiang453007China College of Advanced Interdisciplinary Science and Technology Henan University of TechnologyZhengzhou450001China

direct enantioselective reduction of the C=C bond ofβ-polyfluoro-alkylated enones is an important but long-pending subject in asymmetric ***,we report on the viability of visible light-driven cooperative photoredox and chiral hydrogenbonding catalysis to effectively address this challenge,as a variety of products are obtained in high yields(up to 85%)with good to excellent enantioselectivities(up to 98%ee).The formation of thermodynamically favorable enol intermediates after double single-electron reduction represents the center of the ***,the utility of the current method is validated by the convenient regio-specific and-diverse synthesis of various deuterated derivatives for these products using inexpensive d_(2)O as the deuterium source.

关键词： photoredox catalysis Br?nsted acids asymmetric reduction enantioselective protonation azaarenes

An improved GNSS ambiguity best integer equivariant estimation method with Laplacian distribution for urban low-cost RTK positioning

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Satellite Navigation 2024年第1期5卷 109-124页

作者： Ying Liu Wanke Liu Xiaohong Zhang Yantao Liang Xianlu Tao Liye ma School of Geodesy and Geomatics Hubei Luojia LaboratoryWuhan University129 Luoyu RoadWuhan430079HubeiChina Chinese Antarctic Center of Surveying and mapping Wuhan University129 Luoyu RoadWuhan430079HubeiChina School of Instrument Science and Engineering Southeast UniversityNanjingJiangsuChina The 54 Research Institute of China Electronics Technology Group CorporationShijiazhuang050081HebeiChina State Key Laboratory of Satellite Navigation System and Equipment Technology Shijiazhuang050081HebeiChina

The integer least squares(ILS)estimation is commonly used for carrier phase ambiguity resolution(AR).More recently,the best integer equivariant(BIE)estimation has also attracted an attention for complex application scenarios,which exhibits higher reliability by a weighted fusion of integer ***,traditional BIE estimation with gaussian distribution(GBIE)faces challenges in fully utilizing the advantages of BIE for urban low-cost positioning,mainly due to the presence of outliers and unmodeled *** this end,an improved BIE estimation method with Laplacian distribution(LBIE)is proposed,and several key issues are discussed,including the weight function of LBIE,determination of the candidates included based on the OIA test,and derivation of the variance of LBIE solutions for reliability *** results show that the proposed LBIE method has the positioning accuracy similar to the BIE using multivariate t-distribution(TBIE),and significantly outperforms the ILS-PAR and GBIE *** an urban expressway test with a Huawei mate40 smartphone,the LBIE method has positioning errors of less than 0.5 m in three directions and obtains over 50%improvements compared to the ILS-PAR and GBIE *** an urban canyon test with a low-cost receiver STA8100 produced by STMicroelectronics,the positioning accuracy of LBIE in three directions is 0.112 m,0.107 m,and 0.252 m,respectively,with improvements of 17.6%,27.2%,and 26.1%compared to GBIE,and 23.3%,28.2%,and 30.6%compared to ***,its computational time increases by 30–40%compared to ILS-PAR and is approximately half of that using TBIE.

关键词： Ambiguity resolution Best integer equivariant estimation Laplacian distribution Urban environments Low-cost GNSS receivers Real-time kinematic

Highβ-sitosterol-d-glucoside content in sweet potato varieties and its anti-breast cancer potential through multiple metastasis-associated signals

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Food Science and Human Wellness 2024年第5期13卷 2779-2789页

作者： Jinyin Zhang Lu Huang Xiang Tang Miao Pan Xiaoli Ye Xuegang Li Hang ma School of Pharmaceutical Sciences Southwest UniversityChongqing 400716China School of Life Sciences Southwest UniversityChongqing 400715China

β-Sitosterol-d-glucoside(β-SdG)is a phytosterol compound whose antitumor activity has been confirmed by previous ***,its suppression on breast cancer remains *** that purpose,we isolatedβ-SdG from sweet potato and investigated the breast-cancer-inhibiting mechanism using proteomic *** sweet potato species S6 with highβ-SdG content were chosen form 36 species andβ-SdG was isolated by ***,an in situ animal model of breast cancer was established,andβ-SdG significantly reduced the tumor volume of MCF-7 xenograft *** analysis of tumor tissues revealed that 127 of these proteins were upregulated and 80 were *** ontology and network analysis showed that regulatory proteins were mainly associated with epithelial-mesenchymal transition(EMT),myogenesis,cholesterol homeostasis,oxidative phosphorylation and reactive oxygen pathways,while Vimentin,NdUF,VdAC1,PPP2CA and SNx9 were the most significant 5 node degree ***,in vitro and in vivo results showed that the protein expression of PPP2CA and Vimentin,which are markers of EMT,were involved in breast cancer cell metastasis and could be reversed byβ-*** work highlightsβ-SdG as a bioactive compound in sweet potato and the potential therapeutic effect ofβ-SdG for the treatment of breast cancer by inhibiting metastasis.

关键词： β-Sitosterol-d-glucoside(β-SdG) Sweet potato Breast cancer Proteomic Metastasis

Special Unipotent Representations of Simple Linear Lie Groups of Type A

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Acta mathematica Sinica,English Series 2024年第3期40卷 707-716页

作者： dan BARBASCH Jia Jun ma Bin Yong SUN Chen Bo ZHU department of mathematics Cornell UniversityIthacaNY 14853USA School of mathematical Sciences Xiamen UniversityXiamen 361005P.R.China department of mathematics Xiamen University Malaysia CampusSepangSelangor Darul Ehsan43900Malaysia Institute for Advanced Study in mathematics&New Cornerstone Science Laboratory Zhejiang UniversityHangzhou 310058P.R.China department of mathematics National University of Singapore10 Lower Kent Ridge RoadSingapore 119076

Let G be a special linear group over the real,the complex or the quaternion,or a special unitary *** this note,we determine all special unipotent representations of G in the sense of Arthur and Barbasch-Vogan,and show... 详细信息

关键词： Special unipotent representations unitary representations coherent continuation Weyl group representations