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Transactions of Nonferrous Metals Society of China 2024年第7期34卷 2367-2380页

作者： Vesna S.CVETKOVIĆ Nebojša d.NIKOLIĆ Tanja S.BARUdŽija Silvana B.dIMITRIJEVIĆ Jovan N.JOVIĆEVIĆ department of Electrochemistry Institute of ChemistryTechnology and MetallurgyUniversity of BelgradeNjegoševa 1211000 BelgradeSerbia Institute for Nuclear Sciences Vinča University of BelgradeP.O.Box 52211001 BelgradeSerbia Mining and Metallurgy Institute Zeleni bulevar 3519210 BorSerbia

以氯化胆碱和乙二醇混合液为低共熔溶剂,不使用其他添加剂,电化学沉积无枝晶Zn/Au合金。在不同的Zn(Ⅱ)浓度下,采用恒电位电沉积法在相对较低的Zn电沉积过电位下进行电沉积。通过循环伏安法(CV)和计时安培法(CA)揭示Zn电沉积的电化学机... 详细信息

以氯化胆碱和乙二醇混合液为低共熔溶剂,不使用其他添加剂,电化学沉积无枝晶Zn/Au合金。在不同的Zn(Ⅱ)浓度下,采用恒电位电沉积法在相对较低的Zn电沉积过电位下进行电沉积。通过循环伏安法(CV)和计时安培法(CA)揭示Zn电沉积的电化学机理。采用扫描电子显微镜和X射线衍射分析(XRd)对沉积层的形貌和结构进行表征,并用能谱仪对沉积层进行元素分析。CV结果表明,Zn的电沉积始于Zn欠电位沉积区,并一直持续到Zn过电位沉积(OPd)区。随着Zn(Ⅱ)浓度的增加,Zn/Zn(Ⅱ)电偶的沉积电位向更高的正值偏移。CA分析表明,在Zn的OPd区开始三维渐进形核,随后形成三维生长。形貌分析表明,电沉积始于致密Zn岛的形成,随后形成无枝晶Zn/Au合金。XRd分析表明,其物相为金属Zn、立方AuZn3和Au Zn金属间化合物。

关键词：锌电沉积低共熔溶剂锌金合金形貌结构

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Bioremediation perspective of historically contaminated sediment with polycyclic aromatic hydrocarbons

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International Journal of Sediment Research 2021年第4期36卷 479-488页

作者： Sne?ana Maleti? Jelena Beljin d.agana tamind.ija Marko Grgi? Jelena Molnar Jazi? Marijana Kragulj Isakovski Sr■an Ron?cevi? department of Chemistry Biochemistry and Environmental Protection Faculty of Sciences University of Novi Sad

The purpose of the current study is to compare the influence of different aerobic conditions(biostimulation(BS), bioaugmentation(BA), and a combination of biostimulation and bioaugmentation(BB))on polycyclic aromatic hydrocarbons(PAH) degradation and compare the degraded amount with single step XAd-4 extraction as a new tool for bioavailability assessment for chronically contaminated sediment samples obtained from territory of Autonomous Province Vojvodina of Serbia(S1, S2, and S3). A great number of papers dealing with biodegradation of PAHs in spiked sediment or soil have been published,but to the authors' knowledge, a limited number of papers studied aged, historically polluted sediment and a sum of chosen U.S. Environmental Protection Agency(USEPA) PAHs. A significant reduction(up to67%) in PAH concentration was observed, while the percentage of reduction varied depending on the sediment sample and treatment used. BS treatment successfully stimulated growth of indigenous bacteria. Further, PAH-degrading strain Sphingomonas paucimobilis F8 inoculated in BA and BB treatment survived for up to 7 weeks after it was suppressed by unfavorable conditions or native *** amounts generally showed good correlation with results obtained from XAd-4 *** obtained in the current study represent a good start for standardizing a XAd-4 extraction technique as a simplified, easier, and lower cost method for bioavailability assessment.

关键词： Contaminated sediment Bioavailability PAH Biodegradation

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The first cavefish in the dinaric Karst?Cave colonization made possible by phenotypic plasticity in Telestes karsticus

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Zoological Research 2023年第4期44卷 821-833页

作者： MateoČupić Zoran Marčić Marko Lukić Romana Gračan Helena Bilandžija division of Molecular Biology Ruđer BoškovićInstituteZagreb 10000Croatia department of Biology Faculty of ScienceZagreb 10000Croatia Croatian Biospeleological Society Zagreb 10000Croatia

Cave animals are an excellent model system for studying adaptive *** present,however,little is known about the mechanisms that enable surface colonizers to survive in the challenging environment of *** possibility is that these species have the necessary genetic background to respond with plastic changes to the pressures of underground *** gain insight into this process,we conducted a comparative study with the fish species Telestes karsticus,which occurs in a hydrological system consisting of an interconnected stream and a *** showed that *** resided year-round and spawned in Sušik cave,making it the first known cavefish in the dinaric *** and surface populations differed in morphological and physiological characteristics,as well as in patterns of gene expression without any evidence of genetic *** test whether observed trait differences were plastic or genetic,we placed adult fish from both populations under light/dark or constant dark *** laboratory conditions erased all morphometric differences between the two morphs,suggesting phenotypic plasticity is driving the divergence of shape and size in wild *** pigmentation and increased fat deposition exhibited by cave individuals were also observed in surface fish kept in the dark in the *** study also revealed that specialized cave traits were not solely attributed to developmental plasticity,but also arose from adult responses,including ***,we conclude that *** can adapt to cave conditions,with phenotypic plasticity playing an important role in the process of cave colonization.

关键词： Maladaptive and adaptive phenotypic plasticity Troglobionts and stygobionts Endemic leuciscid fish Acclimatization European cavefish Cave adaptations Gene expression differences

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Celiac disease in patients with type 1 diabetes:a condition with distinct changes in intestinal immunity?

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Cellular & Molecular Immunology 2011年第2期8卷 150-156页

作者： Raivo Uibo Marina Panarina Kaupo Teesalu ija Talja Epp Sepp Meeme Utt Marika Mikelsaar Kaire Heilman Oivi Uibo Tamara Vorobjova department of Immunology University of TartuTartuEstonia department of Microbiology University of TartuTartuEstonia Children’s Clinic of Tartu University Hospital TartuEstonia department of Pediatrics University of TartuTartuEstonia

Two common chronic childhood diseases-celiac disease(Cd)and type 1 diabetes(T1d)-result from complex pathological mechanisms where genetic susceptibility,environmental exposure,alterations in intestinal permeability and immune responses play central *** this study,we investigated whether these characteristics were universal for Cd independently of T1d *** this purpose,we studied 36 children with normal small-bowel mucosa and 26 children with active Cd,including 12 patients with *** samples from the small-bowel mucosa,we detected the lowest expression of tight junction protein 1(TJP1)mRNA in Cd patients with T1d,indicating an increase in intestinal ***,these samples displayed the highest expression of forkhead box P3(FoxP3)mRNA,a marker for regulatory T cells,as compared with other patient *** the same time,serum levels of IgA antibodies specific for the Cd-related antigens deamidated gliadin and tissue transglutaminase(tTG)were the highest in Cd patients with *** contrast,no significant differences were found in IgA or IgG antibodies specific for bovine beta-lactoglobulin or Bifidobacterium adolescentis dSM 20083-derived *** were also no differences in the transamidating activity of serum autoantibodies between patients and control *** results show that patients with T1d and newly detected Cd exhibit severely altered intestinal permeability,strong local immune activation and increased immunoregulatory mechanisms in the small *** study is required to determine whether these extreme changes in this Cd subgroup are due to some specific environmental factors(virus infections),unknown genetic effects or autoimmune reactions to antigenic targets in intracellular tight junctions.

关键词： autoimmunity celiac disease immunoregulation intestinal mucosa type 1 diabetes

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