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Gold nanorods conjugated upconversion nanoparticles nanocomposites for simultaneous bioimaging,local temperature sensing and photothermal therapy of OML-1 oral cancer cells

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International Journal of Smart and Nano Materials 2021年第1期12卷 49-71页

作者： Duc Tu Vu Thanh Thu Vu-Le Van Nghia Nguyen Quoc Minh Le churng-ren chris wang Lai-Kwan Chau Tzyy-Schiuan Yang Michael WYChan Cheng-I Lee Chu-Chi Ting Jiunn-Yuan Lin Hung-Chih Kan Chia Chen Hsu Department of Physics and Center for Nano Bio-Detection National Chung Cheng UniversityChia-YiTaiwan Electrical and Electronics Engineering Phenikaa UniversityHanoiVietnam Faculty of Electrical and Electronics Engineering Thuyloi UniversityHanoiVietnam Institute of Materials Science VAST of VietnamHanoiVietnam Institute of Fundamental Science and Application Duy Tan UniversityDanangVietnam Department of Chemistry and Biochemistry National Chung Cheng UniversityChia-YiTaiwan Department of Biomedical Sciences National Chung Cheng UniversityChia-YiTaiwan Graduate Institute of Opto-Mechatronics National Chung Cheng UniversityChia-YiTaiwan

The major challenge in photothermal therapy(PTT)is to develop nanocomposites that simultaneously exhibit bioimaging and PTT under a single near-infrared(NIR)irradiation with high therapeutic ***,we present a multifunctional nanocomposite synthesized by linking NaYF_(4):Yb^(3+),Er^(3+)upconversion nanoparticles(UCNPs)with gold nanorods(AuNR)to exhibit fluorescence label-ing,local temperature sensing and photothermal functions simul-taneously with a single NIR laser *** AuNR-NaYF_(4):Yb^(3+),Er^(3+)nanocomposite particles displayed better photothermal prop-erties compared with pure AuNRs or a blend of AuNRs and NaYF_(4):Yb^(3+),Er^(3+)*** temperature-dependent upconversion lumi-nescence(UCL)property was used to determine local temperature at the nanocomposite particles,which is useful for selecting appro-priate irradiation dosage for *** therapeutic performance of the nanocomposites in PTT for OML-1 oral cancer cells was *** cell labeling,we successfully labeled streptavidin-linked nanocomposite particles on the surface of OML-1 oral cancer using anti-human epidermal growth factor receptor 2(anti-Her2)***,the nanocomposite particles caused exceptional destruction of cancer cells up to 70%dead cells under 976 nm laser irradiation for only one min at 0.3 W/cm^(2)which is below the maximal permissible exposure of human skin.

关键词： Upconversion luminescence gold nanorod local temperature sensing bioimaging photothermal therapy

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Anomalous thermal expansion and enhanced magnetocaloric effect in<001>-textured Mn_(x)Fe_(5-x)Si_(3) alloys

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Rare Metals 2024年第5期43卷 2263-2274页

作者： Yong Gong Xue-Fei Miao Tapas Samanta chris Taake Jun Liu Feng-Jiao Qian Yan-Yan Shao Yu-Jing Zhang Qing-Yong ren Luana Caron Feng Xu MIIT Key Laboratory of Advanced Metallic and Intermetallic Materials Technology School of Materials Science and EngineeringNanjing University of Science and TechnologyNanjing210094China Department of Physics Bielefeld University33501BielefeldGermany College of Physics Nanjing University of Aeronautics and AstronauticsNanjing210016China Institute of High Energy Physics Chinese Academy of SciencesBeijing100049China Spallation Neutron Source Science Center Dongguan523803China Guangdong-Hong Kong-Macao Joint Laboratory for Neutron Scattering Science and Technology Dongguan523803China Department of Physics Bielefeld University33501BielefeldGermany Helmholtz-Zentrum Berlin für Materialien und Energie12489BerlinGermany

The development of zero and negative therma expansion(i.e.,ZTE and NTE)materials is of crucial importance to the control of undesirable thermal expansion for high-precision *** the present work,ZTE and NTE were obtained in directionally-solidified Mn_(x)Fe_(5-x)Si_(3)alloys with a strongtexture,in striking contrast to positive thermal expansion in their isotropic counterparts Magnetometry and in-situ X-ray diffraction(XRD)measurements were performed to uncover the origin of the anomalous thermal *** measurements indicate a strong easy-plane magnetocrystalline anisotropy in the textured samples,where the magnetic moments are aligned within the ab plane of the hexagonal structure Temperature-dependent XRD on the x=1 sample reveals a ZTE character in the ab plane that is coupled to a ferromagnetic *** a result,the macroscopic ZTE(~0.22×10^(-6)K^(-1))in the x=1 sample can be attributed to the microscopic magneto volume effect within the ab plane,which is realized by the introduction of the-textured ***,the competition between antiferromagnetic and ferromagnetic exchange coupling leads to NTE in textured x=1.5 and 2 ***,textured x=1 sample displays enhanced magnetocaloric properties as compared to the conventional counterparts with randomly-oriented *** this work demonstrates a new strategy toward the exploration of anomalous thermal expansion properties as well as the enhancement of magnetocaloric properties for materials with a strong magnetocrystalline anisotropy.

关键词： MnFeySis Magnetocaloric effect Magnetic phase transition Negative thermal expansion

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Intelligent Recognition Using Ultralight Multifunctional Nano‑Layered Carbon Aerogel Sensors with Human‑Like Tactile Perception

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Nano-Micro Letters 2024年第1期16卷 172-186页

作者： Huiqi Zhao Yizheng Zhang Lei Han Weiqi Qian Jiabin wang Heting Wu Jingchen Li Yuan Dai Zhengyou Zhang chris RBowen Ya Yang CAS Center for Excellence in Nanoscience Beijing Key Laboratory of Micro‑Nano Energy and SensorBeijing Institute of Nanoenergy and NanosystemsChinese Academy of SciencesBeijing 101400People’s Republic of China Tencent Robotics X Shenzhen 518054People’s Republic of China School of Nanoscience and Technology University of Chinese Academy of SciencesBeijing 100049People’s Republic of China Department of Mechanical Engineering University of BathBath BA27AKUK Center on Nanoenergy Research School of Physical Science and TechnologyGuangxi UniversityNanning 530004People’s Republic of China

Humans can perceive our complex world through multi-sensory *** limited visual conditions,people can sense a variety of tactile signals to identify objects accurately and ***,replicating this unique capability in robots remains a significant ***,we present a new form of ultralight multifunctional tactile nano-layered carbon aerogel sensor that provides pressure,temperature,material recognition and 3D location capabilities,which is combined with multimodal supervised learning algorithms for object *** sensor exhibits human-like pressure(0.04–100 kPa)and temperature(21.5–66.2℃)detection,millisecond response times(11 ms),a pressure sensitivity of 92.22 kPa^(−1)and triboelectric durability of over 6000 *** devised algorithm has universality and can accommodate a range of application *** tactile system can identify common foods in a kitchen scene with 94.63%accuracy and explore the topographic and geomorphic features of a Mars scene with 100%*** sensing approach empowers robots with versatile tactile perception to advance future society toward heightened sensing,recognition and intelligence.

关键词： Multifunctional sensor Tactile perception Multimodal machine learning algorithms Universal tactile system Intelligent object recognition

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An alfalfa MYB-like transcriptional factor MsMYBH positively regulates alfalfa seedling drought resistance and undergoes MsWAV3-mediated degradation

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Journal of Integrative Plant Biology 2024年第4期66卷 683-699页

作者： Kun Shi Jia Liu Huan Liang Hongbin Dong Jinli Zhang Yuanhong Wei Le Zhou Shaopeng wang Jiahao Zhu Mingshu Cao chris S.Jones Dongmei Ma Zan wang College of Grassland Science and Technology China Agricultural UniversityBeijing 100193China Institute of Animal Sciences Chinese Academy of Agricultural SciencesBeijing 100193China AgResearch Grasslands Research Centre Palmerston North 4442New Zealand International Livestock Research Institute Nairobi 00100Kenya School of Ecology and Environment Ningxia UniversityYinchuan 750021China

Drought is a major threat to alfalfa(Medicago sativa L.)*** discovery of important alfalfa genes regulating drought response will facilitate breeding for drought-resistant alfalfa ***,we report a genome-wide association study of drought resistance in *** identified and functionally characterized an MYB-like transcription factor gene(MsMYBH),which increases the drought resistance in *** with the wild-types,the biomass and forage quality were enhanced in MsMYBH overexpressed *** RNA-seq,proteomics and chromatin immunoprecipitation analysis showed that MsMYBH can directly bind to the promoters of MsMCP1,MsMCP2,MsPRX1A and MsCARCAB to improve their *** outcomes of such interactions include better water balance,high photosynthetic efficiency and scavenge excess H_(2)O_(2)in response to ***,an E3 ubiquitin ligase(MsWAV3)was found to induce MsMYBH degradation under long-term drought,via the 26S proteasome ***,variable-number tandem repeats in MsMYBH promoter were characterized among a collection of germplasms,and the variation is associated with promoter ***,our findings shed light on the functions of MsMYBH and provide a pivotal gene that could be leveraged for breeding drought-resistant *** discovery also offers new insights into the mechanisms of drought resistance in alfalfa.

关键词： alfalfa drought resistance E3 ubiquitin ligase MsMYBH MsWAV3 MYB-like transcriptional factor

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Time to treat the climate and nature crisis as one indivisible global health emergency

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Stroke & Vascular Neurology 2024年第4期9卷 325-327页

作者： chris Zielinski on behalf of the authorship group listed below Centre for Global Health University of WinchesterWinchesterUK 不详

Over 200 health journals call on the United Nations(UN),political leaders and health professionals to recognise that climate change and biodiversity loss are one indivisible crisis and must be tackled together to pres... 详细信息

关键词： preserve global divisible

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Attitude control of multi-spacecraft systems on SO(3)with stochastic links failure

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Chinese Journal of Aeronautics 2024年第3期37卷 320-331页

作者： KANG Zeyu SHEN Qiang WU Shufan chris J.DAMAren MU Zhongcheng School of Aeronautics and Astronautics Shanghai Jiao Tong UniversityShanghai 200240China Institute for Aerospace Studies University of TorontoTorontoOntario M3H 5T6Canada

In this paper,for Multi-Spacecraft System(MSS)with a directed communication topology link and a static virtual leader,a controller is proposed to realize attitude consensus and attitude stabilization with stochastic links failure and actuator ***,an MSS attitude error model suitable for a directed topology link and with a static virtual leader based on SO(3)is derived,which considers that the attitude error on SO(3)cannot be defined based on algebraic ***,we design a controller to realize the MSS on SO(3)with attitude consensus and attitude stabilization under stochastic links failure and actuator ***,the simulation results of a multi-spacecraft system with stochastic links failure and a static virtual leader spacecraft are demonstrated to illustrate the efficiency of the attitude controller.

关键词： Multi-spacecraft systems Attitude consensus Attitude stabilization Stochastic links failure Super-martingale convergence

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Universal insertion of molecules in ionic compounds under pressure

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National Science Review 2024年第1期11卷 120-128页

作者： Feng Peng Yanming Ma chris J.Pickard Hanyu Liu Maosheng Miao College of Physics and Electronic Information Luoyang Normal University Department of Chemistry and Biochemistry California State University Northridge State Key Laboratory of Superhard Materials & Key Laboratory of Material Simulation Methods and Software of Ministry of Education College of Physics Jilin University International Center of Future Science Jilin University Department of Materials Science & Metallurgy University of Cambridge Advanced Institute for Materials Research Tohoku University Department of Earth Science University of California Santa Barbara

Using first-principles calculations and crystal structure search methods, we found that many covalently bonded molecules such as H2, N2, CO2, NH3, H2O and CH4may react with NaC l, a prototype ionic solid,and form stable compounds under pressure while retaining their molecular structure. These molecules,despite whether they are homonuclear or heteronuclear, polar or non-polar, small or large, do not show strong chemical interactions with surrounding Na and Cl ions. In contrast, the most stable molecule among all examples, N2, is found to transform into cyclo-N5-anions while reacting with NaC l under high pressures. It provides a new route to synthesize pentazolates, which are promising green energy materials with high energy density. Our work demonstrates a unique and universal hybridization propensity of covalently bonded molecules and solid compounds under pressure. This surprising miscibility suggests possible mixing regions between the molecular and rock layers in the interiors of large planets.

关键词： molecule-solid hybrid materials high-pressure crystal structure prediction density functional theory planet interior

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Combined peakreductionandself-consumptionusingproximalpolicy optimisation

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Energy and AI 2024年第2期16卷 24-31页

作者： Thijs Peirelinck chris Hermans Fred Spiessens Geert Deconinck ESAT KU LeuvenKasteelpark Arenberg 10 bus 24453001 LeuvenBelgium AMO Flemish Institute for Technological Research(VITO)Boeretang 2002400 Mol Belgium AMO EnergyVilleThor Park 83103600 GenkBelgium

Residential demand response programs aim to activate demand flexibility at the household *** recent years,reinforcement learning(RL)has gained significant attention for these type of applications.A major challenge of RL algorithms is data *** RL algorithms,such as proximal policy optimisation(PPO),have tried to increase data *** tionally,combining RL with transfer learning has been proposed in an effort to mitigate this *** this work,we further improve upon state-of-the-art transfer learning performance by incorporating demand response domain knowledge into the learning *** evaluate our approach on a demand response use case where peak shaving and self-consumption is incentivised by means of a capacity *** show our adapted version of PPO,combined with transfer learming,reduces cost by 14.51%compared to a regular hysteresis controller and by 6.68%compared to traditional PPO.

关键词： Demand response Reinforcement learning Electric water heater Peak shaving Transfer learning

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Experimental and analytical investigation on friction resistance force between buried coated pressurized steel pipes and soil

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Frontiers of Structural and Civil Engineering 2024年第4期18卷 615-629页

作者： Shaurav ALAM Tanvir MANZUR John MATTHEWS chris BARTLETT Erez ALLOUCHE Brent KEIL John KRAFT Department of Civil Engineering and Construction Engineering Technology Louisiana Tech UniversityRustonLA 71270USA Department of Civil Engineering Bangladesh University of Engineering and TechnologyDhaka 1000Bangladesh Georgia Tech Research Institute AtlantaGA 30332USA Stantec Inc. Edmonton T5J0K4Canada North West Pipe Company VancouverWA 98684USA

This paper presents an analytical approach for estimating frictional resistance to pipe movement at soil and external pipe surface of buried coated pressurized steel pipes relative to the internal thrust *** proposed analytical method was developed based on 36 experiments,which involved three coating types(cement mortar(CM),polyurethane type-I(PT-I),prefabricated plastic tape(PPT))on pipes’surfaces,three different soils(pea-gravel(PG),sand(S),silty-clay(SC)),and four simulated over burden depths above the pipe’s *** showed frictional resistance decreased with increasing over burden depth above the pipe’s *** degree of frictional resistance at the pipe-soil interface was found to be in the order of PG>SC>S for all coating variations and overburden *** coated pipe buried in all three types of soil produced significantly higher frictional resistance as compared to other coating *** on experimental data,the developed analytical introduced a dimensionless factor“Z”,which included effects of types of coatings,soil,and overburden depths for simplified rapid *** showed that the method provided a better prediction of frictional resistance forces,in comparison to previous analytical methods,which were barely close in predicting friction resistance for different coating variations,soil types,and overburden *** resistance force values reported herein could be considered conservative.

关键词： friction resistance force thrust force coated pressurized steel pipe soil type overburden depth

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Predictive modeling for post operative delirium in elderly

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World Journal of Gastrointestinal Oncology 2024年第9期16卷 3761-3764页

作者： chris B Lamprecht Abeer Dagra Brandon Lucke-Wold Lillian S.Wells Department of Neurosurgery University of FloridaGainevilleFL 32610United States

Delirium,a complex neurocognitive syndrome,frequently emerges following surgery,presenting diverse manifestations and considerable obstacles,especially among the *** editorial delves into the intricate phenomenon of postoperative delirium(POD),shedding light on a study that explores POD in elderly individuals undergoing abdominal malignancy *** study examines pathophysiology and predictive determinants,offering valuable insights into this challenging clinical *** the synthetic minority oversampling technique,a predictive model is developed,incorporating critical risk factors such as comorbidity index,anesthesia grade,and surgical *** is an urgent need for accurate risk factor identification to mitigate POD *** specific to elderly patients with abdominal malignancies,the findings contribute significantly to understanding delirium pathophysiology and *** research is warranted to establish standardized predictive for enhanced generalizability.

关键词： Post-operative delirium Elderly delirium Neurocognitive syndrome Neurotransmitters Abdominal malignancy Predictive model Synthetic minority oversampling technique

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