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Nutrient exchange and release experiment and its simulation study in lake water-sediment interface

Journal of Environmental Sciences 2006年第3期18卷 591-595页

作者： XUE lian-qing HAO Zhen-chun State Key Laboratory of Hydrology-Water Resources and Hydraulic Engineering College of Water Resources and Environment Hohai UniversityNanjing 210098 China

The sediment distributed and insolated under lake was collected for experiments. The nutrient layer distribution conditions of sampled sediment and its physical and chemical characteristics were analyzed to simulate and assess the influence degree to lake water quality. Based on the dynamic water exchanging experiments the nutrient release process in sediment and influence mechanism to substance exchanging on water-sediment interface was studied, and the correlation between the changing content of total phosphors and total nitrogen in sediment and covered water were analyzed for setting up a simulation model. At the same time the influence degree is explained in detail. The experimental results indicated that even if clean water without nutrient contents was used for water exchangement so as to decrease pollution or prevent eutrophication, however owing to the vertical nutrient distribution in lake sediment, it will lead to the increasing release amount greatly especially when the organic nutrient contained in sediment turns into inorganic status because of isolation. Besides the release process of total phosphate （TP） and total nitrogen （TN） were modeled and each nutrient＇s exchanging equation at interface caused by covered water nutrient concentration changing was set up. According to the simulating prediction, TP and TN content of cover water will also sustain a steady higher level in a long period. The nutrient release amount of sediment is not only affected by the covered water concentration but also connects with accumulative time. The experiments provide the fundamental theoretical and practical basis for taking ecological restoration project. And research is helpful to prevent or restore lake eutrophication.

关键词： phosphate and nitrogen release water-sediment interface experiments simulation model

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High-energy-density lithium manganese iron phosphate for lithium-ion batteries: Progresses, challenges, and prospects

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Journal of Energy Chemistry 2025年第1期100卷 1-17页

作者： Bokun Zhang Xiaoyun wang Shuai wang Yan Li Libo Chen Handong Jiao Zhijing Yu Jiguo Tu State Key Laboratory of Advanced Metallurgy University of Science and Technology Beijing Research Institute for Intelligent Wearable Systems The Hong Kong Polytechnic University Institute of Advanced Structure Technology Beijing Institute of Technology

The soaring demand for smart portable electronics and electric vehicles is propelling the advancements in high-energy–density lithium-ion *** manganese iron phosphate (LiMnxFe1-xPO4) has garnered significant attention as a promising positive electrode material for lithium-ion batteries due to its advantages of low cost,high safety,long cycle life,high voltage,good high-temperature performance,and high energy *** LiMnxFe1-xPO4has made significant breakthroughs in the past few decades,there are still facing great challenges in poor electronic conductivity and Li-ion diffusion,manganese dissolution affecting battery cycling performance,as well as low tap *** review systematically summarizes the reaction mechanisms,various synthesis methods,and electrochemical properties of LiMnxFe1-xPO4to analyze reaction processes accurately and guide material ***,the main challenges currently faced are concluded,and the corresponding various modification strategies are discussed to enhance the reaction kinetics and electrochemical performance of LiMnxFe1-xPO4,including multi-scale particle regulation,heteroatom doping,surface coating,as well as microscopic morphology ***,in view of the current research challenges faced by intrinsic reaction processes,kinetics,and energy storage applications,the promising research directions are *** importantly,it is expected to provide key insights into the development of high-performance and stable LiMnxFe1-xPO4materials,to achieve practical energy storage requirements.

关键词： Lithium manganese iron phosphate High energy density Lithium-ion batteries Reaction mechanism Tap density

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Flexible molecules dedicate to release strain of inverted inorganic perovskite solar cell

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Journal of Energy Chemistry 2025年第1期100卷 87-93页

作者： Hongrui Sun Sanlong wang Pengyang wang Yali Liu Shanshan Qi Biao Shi Ying Zhao Xiaodan Zhang Institute of Photoelectronic Thin Film Devices and Technology Renewable Energy Conversion and Storage Center State Key Laboratory of Photovoltaic Materials and CellsNankai University Key Laboratory of Photoelectronic Thin Film Devices and Technology of Tianjin Haihe Laboratory of Sustainable Chemical Transformations Engineering Research Center of Thin Film Photoelectronic Technology of Ministry of Education Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)

The tensile strain in inorganic perovskite films induced by thermal annealing is one of the primary factors contributing to the inefficiency and instability of inorganic perovskite solar cells （IPSCs）,which reduces the defect formation ***,a flexible molecule 5-maleimidovaleric acid （5-MVA） was introduced as a strain buffer to release the residual strain of *** anhydride and carboxyl groups in 5-MVA interact strongly with the uncoordinated Pb2+through Lewis acid-base reaction,thus tightly“pull”the perovskite *** in-between soft carbon chain increased the structural flexibility of CsPbI2.85Br0.15perovskite materials,which effectively relieved the intrinsic internal strain of CsPbI2.85Br0.15,resisted the corrosion of external strain,and also reduced the formation of defects such as VIand *** addition,the introduction of 5-MVA improved crystal quality,passivated residual defects,and narrowed energy level ***,power conversion efficiency （PCE） of NiOxbased inverted IPSCs increased from 19.25% to 20.82% with the open-circuit voltage enhanced from 1.164 V to 1.230 *** release of strain also improved the stability of CsPbI2.85Br0.15perovskite films and devices.

关键词： Inverted inorganic perovskite solar cells Flexible molecules Strain release Crystallization Energy barrier High PCE

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Hemichorea in patients with temporal lobe infarcts: Two case reports

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World Journal of Clinical Cases 2024年第4期12卷 806-813页

作者： Xu-Dong wang Xing Li chun-lian Pan Department of Neurology Puren Hospital Affiliated to Wuhan University of Science and TechnologyWuhan 430081Hubei ProvinceChina School of Medicine Wuhan University of Science and TechnologyWuhan 430065Hubei ProvinceChina

BACKGROUND Hemichorea and other hyperkinetic movement disorders are uncommon present-ations of stroke and are usually secondary to deep infarctions affecting the basal ganglia and ***,temporal ischemic lesions causing hemichorea are *** report the cases of two patients with acute ischemic temporal lobe infarct strokes that presented as *** SUMMARY Patient 1:An 82-year-old woman presented with a 1-mo history of involuntary movement of the left extremity,which was consistent with *** diffusion-weighted imaging(DWI)revealed an acute ischemic stroke that predominantly affected the right temporal cortex,and magnetic resonance angiography of the head showed significant stenosis of the right middle cerebral artery(MCA).Treatment with 2.5 mg of olanzapine per day was *** she was discharged from the hospital,her symptoms appeared to have improved compared with those previously ***-seven days after the first admission,she was readmitted due to acute ischemic *** tomogra-phy perfusion showed marked hypoperfusion in the right MCA *** emergency transfemoral cerebral angiogram was performed and showed severe stenosis in the M1 segment of the right *** percutaneous transluminal angioplasty was successfully performed,abnormal movements or other neuro-logic problems did not *** 2:A 76-year-old man was admitted to our hospital for a 7-d history of right-upper-sided involuntary *** showed an acute patchy ischemic stroke in the left temporal lobe without basal ganglia *** diffusion tensor imaging confirmed fewer white matter fiber tracts on the left side than on the opposite *** with 2.5 mg of olanzapine per day improved his condition,and he was *** When acute hemichorea suddenly appears,temporal cortical ischemic stroke should be considered a possible *** addition,hemichorea may be a sign of impending cerebral infarcti

关键词： Acute ischemic stroke Temporal ischemic stroke Movement disorders Cortical hemichorea Case report

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Phytochrome B Is Involved in Mediating Red Light-Induced Stomatal Opening in Arabidopsis thaliana

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Molecular Plant 2010年第1期3卷 246-259页

作者： Fang-Fang wang Hong-Li lian chun-Ying Kang Hong-Quan Yang National Key Laboratory of Plant Molecular Genetics Institute of Plant Physiology and Ecology Shanghai Institutes for Biological Sciences Chinese Academyof Sciences 300 Fenglin Road Shanghai 200032 China School of Agricultural and Biological Sciences Shanghai Jiaotong University 800 Dongchuan Road Shanghai 200240 China

The stomatal pores of higher plants enable gaseous exchange into and out of leaves for photosynthesis and evaporation. Stomatal opening is induced by both blue and red lights. It is shown that blue light-induced stomatal opening is mediated by the blue light receptor phototropins （PHOT1 and PHOT2） and cryptochromes （CRY1 and CRY2）. However, whether phytochrome B （phyB） is involved in red light regulation of stomatal opening remains largely unclear. Here, we report a positive role for Arabidopsis （Arabidopsis thaliana） phyB in the regulation of red light-induced stomatal opening. The phyB mutant stomata displayed a reduced red light response, whereas stomata of the phyB-overexpressing plants displayed a hypersensitive response to red light. In addition, stomata of the cry1 cry2 phyB, photl phot2 phyB, and cry1 phyA phyB triple mutant plants showed more reduced light response than those of the single or double mutant plants under white light, implying that phyB acts in concert with phyA, CRY, and PHOT in light regulation of stomatal opening. Stomata of phyB cop1 mutant opened less wide than those of the cop1 mutant, and stomata of the pif3 pif4 mutant opened wider than those of the wild-type, indicating that COP1, together with the PIFs （phytochrome interacting factors）, may act downstream of PHYB in regulating stomatal opening. Furthermore, quantitative RT-PCR analysis showed that the expression of MYB60 was reduced in the cry1 cry2 and phyA phyB mutants under blue and red lights, respectively, but induced in the CRY1- and phyB-overexpressing plants. These results demonstrate that phyB and CRY might regulate stomatal opening, at least in part, by regulating MYB60 expression.

关键词： Arabidopsis phyB stomatal opening red light.

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Validation of an improved two-fluid model with particle rotation for gas-solid fluidized bed

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Particuology 2023年第10期81卷 149-161页

作者： lian wang Xihua Chu School of Civil Engineering Wuhan UniversityWuhan430072HubeiChina

Gas-solid fluidized beds are widely applied in chemical and process *** is of significance to establish a reasonable and effective mathematical model to explore the hydrodynamics of gas-particle system for industrial *** a less computationally demanding alternative to the discrete descriptions,two-fluid model considering kinetic theory of granular flow is often adopted to describe the fluidized behaviors of particles,but it cannot characterize the rotation of particles and its influence on the fluidized *** this study,to address the rotation effect of the fluidized particles,a two-fluid model combining the classical fluid and micropolar fluid is established,namely *** the CMTFM,classical fluid is used to describe the motion of gas phase,while micropolar fluid is adopted to describe the motion of particle phase,and the rotation of particles and its influence on the hydrodynamics of the gas-particle system are characterized by the degree of freedom of microrotation and the improved drag force based on micropolar *** the calculation of the gas-solid bubbling fluidized bed,we investigated the influence of the microstructure parameters,particle-particle collision restitution coefficient and inlet velocity,and the results are compared to those from TFM model and *** the analysis,it manifests that pressure drop and expansion height of the fluidized bed under the consideration of the microrotation effect are closer to the experiments,which demonstrates the feasibility and advantage of the classical-micropolar two-fluid model.

关键词： Gas-solid fluidized bed Two-fluid model Micropolar fluid Microstructure parameter Fluidized behaviors

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Time-Domain Nonlinear Wave-Current Interaction with A Steep Wave Riser Considering Internal Flow Effect

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China Ocean Engineering 2021年第3期35卷 410-421页

作者： TANG lian-yang CHENG Yong JI chun-yan School of naval architecture and ocean engineering Jiangsu University of Science and TechnologyZhenjiang 212003China Nippon Kaiji Kyokai(China)Co. LtdShanghai 200336China

The nonlinear dynamic response induced by the wave-current interaction on a deepwater steep wave riser(SWR)is numerically investigated based on a three-dimensional(3 D)time-domain finite element method(FEM).The governing equation considering internal flow is established in the global coordinate *** whole SWR consists of three segments:the decline segment,buoyancy segment and hang-off segment,in which the buoyancy segment is wrapped by several buoyancy modules in the middle section,leading to the arch bend and sag bend.A Newmark-β iterative scheme is adopted for the accurate analysis to solve the governing equation and update the dynamic response at each time *** proposed method is verified through the published results for the dynamic response of steel catenary riser(SCR)and static configuration of steel lazy wave riser(SLWR).Simulations are executed to study the influence of wave height,current velocity/direction,internal flow density/velocity and top-end pressure on the tension,configuration and bending moment of the *** results indicate that the influence of the current on the configuration and mechanical behavior of the SWR is greater than that of the wave,especially in the middle *** increasing current velocity,the suspending height of the middle section drops,meanwhile,its bending moment decreases accordingly,but the tension increases *** a fixed external load,the increasing internal flow density induces the amplification of the tension at the hang-off segment and the mitigation at the decline segment,while the opposite trend occurs at the bending moment.

关键词： steep wave riser(SWR) nonlinear dynamic response wave-current interaction time-domain finite element method(FEM)

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Wideband Circularly Polarized Substrate-Integrated Waveguide Aperture-Coupled Metasurface Antenna Array for Millimeter-Wave Applications

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Chinese Journal of Electronics 2024年第6期33卷 1468-1477页

作者： Jiwei lian chun GENG Xue LU Dazhi DING School of Microelectronics(School of Integrated Circuits) Nanjing University of Science and Technology State Key Laboratory of Millimeter Waves Southeast University Qian Xuesen College Nanjing University of Science and Technology

A wideband circularly polarized(CP) aperture-coupled metasurface antenna operating at millimeterwave frequency spectrum in substrate-integrated waveguide(SIW) technology is proposed. The proposed metasurface antenna is composed of two substrates. The first substrate contains an end-shorted SIW section with a slot *** introduced metasurface is printed on the top of the second substrate. The metasurface is comprised of 3 × 3 unit cells, each of which contains two interconnected patches and two parasitic patches. The working mechanism of the proposed metasurface antenna is illustrated in details. The proposed metasurface antenna has wide impedance bandwidth and axial ratio(AR) bandwidth, which are 66.7% and 40%, respectively. Using the proposed metasurface antenna, a 4 × 4 CP metasurface antenna array with an impedance bandwidth of 24%, an AR bandwidth of 30%, and a peak gain of 18.7 dBic in simulation is developed in this paper for millimeter-wave applications.

关键词： Antenna measurements Parametric study Millimeter wave technology Metasurfaces Aperture antennas Impedance Broadband antennas Substrates Wideband Antenna arrays

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Nonlinear Analysis of Bidirectional Vortex-Induced Vibration of A Deepwater Steep Wave Riser Subjected to Oblique Currents

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China Ocean Engineering 2021年第6期35卷 852-865页

作者： CHENG Yong TANG lian-yang JI chun-yan School of Naval Architecture and Ocean Engineering Jiangsu University of Science and TechnologyZhenjiang 212003China Nippon Kaiji Kyokai(China)Co. LtdShanghai 200336China

An improved three-dimensional(3D)time-domain couple model is established in this paper to simulate the bidirectional vortex-induced vibration(VIV)of a deepwater steep wave riser(SWR)subjected to oblique *** this model,the nonlinear motion equations of the riser are established in the global coordinate system based on the slender rod theory with the finite element *** der Pol equations are used to describe the lift forces induced by the x-and y-direction current components,*** coupled equations at each time step are solved by a Newmark-βiterative scheme for the SWR *** present model is verified by comparison with the published experimental results for a top-tension ***,a series of simulations are executed to determine the influences of the oblique angle/velocity of the current,different top-end positions and the length of the buoyancy segment on the VIV displacement,oscillating frequency as well as hydrodynamic coefficients of the *** results demonstrate that there exists a coupled resonant VIV corresponding to x-direction and y-direction,***,the effective frequency is almost identical between the vibrations at the hang-off segment along x and y *** addition of the buoyancy modules in the middle of the SWR has a beneficial impact on the lift force of three segments and simultaneously limits the VIV response,especially at the decline segment and the hang-off ***,the incident current direction significantly affects the motion trajectory of the SWR which mainly includes the fusiform and rectangle shapes.

关键词： steep wave riser(SWR) bidirectional vortex-induced vibration wake oscillator model time-domain finite element method(TDFEM)

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Magnesium hydroxide whisker modified via in situ copolymerization of n-butyl acrylate and maleic anhydride

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Rare Metals 2017年第12期36卷 997-1002页

作者： Yu-Zhi Jiang Yu-lian wang chun-Yan wang Li-Mei Bai Xin Li Yan-Bo Li Collogy of Materials Science and Engineering Shenyang Ligong University Shenyang 110159 China Kailong Lanfeng New Material Technology Co. LtdZhenjiang 212132 China College of Mining Engineering Hebei United UniversityTangshan 063009 China School of Materials Science and Engineering Central South University Changsha 410083 China

Magnesium hydroxide(MH) whiskers were modified via in situ polymerization of n-butyl acrylate and maleic anhydride. Sodium dodecyl sulfonate was used as emulsifier. The modifying effect was evaluated by using contact angle and activation index. The thermal stability,functional groups, structure, morphology, phase composition and surface element valence of MH whiskers were characterized by thermogravimetry-differential scanning calorimetry(TG-DSC), Fourier transform infrared spectroscopy(FTIR), X-ray diffraction(XRD), scanning electron microscopy(SEM) and X-ray photoelectron spectroscopy(XPS). Results reveal that the contact angle and activation index of modified MH whiskers are 105°and 76.5%, the thermal stability shows little change, and the decomposition temperature ranges between 38 and419 ℃. The copolymer of n-butyl acrylate and maleic anhydride absorbed on the surface of MH whiskers leads to the increased diameter and makes the surface of whiskers be rougher. Furthermore, the absorption of element C on the surface of MH whiskers increases, and the diffraction intensity of C 1 s spectra increases; thus, the compatibility of whiskers in the organic phase can be improved significantly. Lastly, the surface molecular model of MH whiskers modified via in situ copolymerization of n-butyl acrylate and maleic anhydride is established.

关键词： Magnesium hydroxide whiskers n-Butyl acrylate Maleic anhydride In situ copolymerization Surface molecular model

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