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Highly N-doped carbon with low graphitic-N content as anode material for enhanced initial Coulombic efficiency of lithium-ion batteries

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Carbon Energy 2023年第2期5卷 236-249页

作者： Yihua Tang Jingjing Chen Zhiyong Mao christina roth Dajian Wang Department of Electrochemical Process Engineering Universitat BayreuthBayreuthGermany Chair of Electrochemical Process Engineering Bavarian Center for Battery Technology(BayBatt)BayreuthGermany Tianjin Key Laboratory for Photoelectric Materials and Devices School of Materials Science and EngineeringTianjin University of TechnologyTianjinPR China

N-doped carbons as one of the most prominent anode materials to replace standard graphite exhibit outstanding Li+storage ***,N-doped carbon anodes still suffer from low N-doping levels and low initial Coulombic efficiency(ICE).In this study,high N-doped and low graphitic-N carbons(LGNCs)with enhanced ICE were synthesized by taking advantage of a denitrification strategy for graphitic carbon nitride(g-C_(3)N_(4)).In brief,more than 14.5 at%of N from g-C_(3)N_(4)(55.1 at%N)was retained by reacting graphitic-N with lithium,which was subsequently *** graphitic-N is largely responsible for the irreversible capacity,the anode's performance was significantly *** to general N-doped carbons with high graphitic-N proportion(>50%)and low N content(<15 at%),LGNCs delivered a low proportion of 10.8%-17.2% within the high N-doping content of 14.5-42.7 at%,leading to an enhanced specific capacity of 1499.9mAh g^(-1) at an ICE of 93.7% for the optimal sample of LGNC(4:1).This study provides a facile strategy to control the N content and speciation,achieving both high Li+storage capacity and high ICE,and thus promoting research and application of N-doped carbon materials.

关键词： denitrification graphitic carbon nitride graphitic-N lithium-ion batteries N-doped carbon

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Carbon‑Based Electrodes for Advanced Zinc‑Air Batteries:Oxygen‑Catalytic Site Regulation and Nanostructure Design

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Electrochemical Energy Reviews 2023年第1期6卷 532-572页

作者： Wenjie Shao Rui Yan Mi Zhou Lang Ma christina roth Tian Ma Sujiao Cao Chong Cheng Bo Yin Shuang Li College of Polymer Science and Engineering State Key Laboratory of Polymer Materials EngineeringSichuan UniversityChengdu 610065SichuanChina College of Biomass Science and Engineering Sichuan UniversityChengdu 610065SichuanChina Department of Ultrasound West China HospitalSichuan UniversityChengdu 610041SichuanChina Electrochemical Process Engineering Engineering SciencesUniversity of BayreuthUniversitätsstr.3095447 BayreuthGermany Med-X Center for Materials Sichuan UniversityChengdu 610065SichuanChina Functional Materials Department of ChemistryTechnische Universität BerlinHardenbergstraße 4010623 BerlinGermany

Zn-air batteries are highly attractive for direct chemical-to-electrical energy conversion and for solving the energy crisis and environmental *** efficient oxygen electrodes has been considered one of the most critical steps in the development of advanced Zn-air batteries because of the sluggish kinetics of the oxygen reduction reaction and the oxygen evolution *** recent years,nanostructured carbon-based electrodes with large surface areas,efficient oxygen-catalytic centers,and hierarchically porous matrices have provided significant opportunities to optimize the performance of the oxygen electrodes in both primary and rechargeable Zn-air *** this review,we provide a comprehensive summary of the reported nanostructured carbon-based electrodes for advanced Zn-air batteries in terms of tailoring the oxygen-catalytic sites and designing carbon *** versatile synthetic strategies,characterization methods,and in-depth understanding of the relationships between the oxygen-catalytic sites/nanostructures and the oxygen electrode performance are systematically ***,we also briefly outline recent progress in engineering flexible and high-power Zn-air ***,a thorough discussion of current primary challenges and future perspectives on the rational design of nanostructured carbon-based oxygen electrodes is given,thus providing inspiration for the future prosperity of fast-kinetic and efficient Zn-air batteries in a broad range of energy fields.

关键词： Zn-air batteries Carbon nanostructures Electrocatalysts Oxygen-catalytic catalysts ORR OER

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Detrimental role of hydrogen evolution and its temperature-dependent impact on the performance of vanadium redox flow batteries

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Journal of Energy Chemistry 2019年第5期28卷 57-62页

作者： Abdulmonem Fetyan Gumaa A. El-Nagar Iver Lauermann Maike Schnucklake Jonathan Schneider christina roth Institute for Chemistry and Biochemistry Freie Universitat BerlinTakustr.3D-14195 BerlinGermany Chemistry Department Faculty of ScienceCairo UniversityCairo 12613Egypt Helmholtz-Zentrum Berlin fur Materialien und Energie Hahn-Meitner-Platz 114109 BerlinGermany

This paper addresses the damaging role of the parasitic hydrogen evolution reaction (HER) in the negative half-cell of a vanadium redox flow battery (VRFB) on state-of-the-art carbon felt electrodes at different temperatures. It was found that increasing the temperature resulted in a better catalytic performance for both the positive and negative half-cell reactions. In addition, increasing the temperature significantly enhanced the undesired HER at the negative side. Operating the VRFB cell at higher temperature led to a decrease in the coulombic efficiency attributed to the higher hydrogen production. More pronounced hydrogen production caused an oxidation on the surface of the carb on fibers and a degradation of the electrode as indicated from scanning electron microscopy and X-ray photoelectron spectroscopy measurements. This observed degradation results in fading of the overall performance of the vanadium redox flow battery over time.

关键词： Hydrogen evolution Carbon felt Degradation Electrode Redox flow batteries

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Sol-gel derived B_(2)O_(3)-CaO borate bioactive glasses with hemostatic,antibacterial and pro-angiogenic activities

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Regenerative Biomaterials 2024年第1期3卷 108-118页

作者： Kai Zheng Faina Bider Mahshid Monavari Zhiyan Xu christina Janko Christoph Alexiou Ana M.Beltran Aldo R.Boccaccini Jiangsu Province Engineering Research Center of Stomatological Translational Medicine College of StomatologyNanjing Medical UniversityNanjing 210029China Jiangsu Key Laboratory of Oral Diseases Nanjing Medical UniversityNanjing 210029China Institute of Biomaterials University of Erlangen-Nuremberg91058 ErlangenGermany Department of Oto-Rhino-Laryngology Head and Neck SurgerySection of Experimental Oncology and Nanomedicine(SEON)Else Kroener-Fresenius-Stiftung ProfessorshipUniversitaetsklinikum Erlangen91058 ErlangenGermany Departamento de Ingenier�ıa y Ciencia de los Materiales y del Transporte Escuela Politecnica

Sol-gel borate bioactive glasses(BGs)are promising ion-releasing biomaterials for wound healing ***,we report the synthesis of a series of binary B_(2)O_(3)-CaO borate BGs(CaO ranging from 50 to 90mol%)using a sol-gel-based *** influence of CaO content in B_(2)O_(3)-CaO borate BG on morphology,structure and ion release behavior was investigated in *** dissolution(ion release)and crystallization could be observed in borate BGs when CaO content increased,while the morphology was not significantly altered by increasing CaO *** results evidenced that the ion release behavior of borate BGs could be tailored by tuning the B_(2)O_(3)/CaO molar *** also evaluated the in vitro cytotoxicity,hemostatic,antibacterial and angiogenic activities of borate *** was validated for all borate ***,borate BGs exhibited composition-dependent hemostatic,antibacterial and angiogenic ***,higher contents of Ca in borate BGs facilitated hemostatic activity,while higher contents of B_(2)O_(3) were beneficial for pro-angiogenic *** synthesized sol-gel-derived borate BGs are promising materials for developing advanced wound healing dressings,given their fast ion release behavior and favorable hemostatic,antibacterial and angiogenic activities.

关键词： borate glasses sol-gel processing glass composition wound healing

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Preparation of Long-range Ordered Nanostructures in Semicrystalline Diblock Copolymer Thin Films Using Micromolding

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Chinese Journal of Polymer Science 2014年第9期32卷 1188-1198页

作者： Peng Zhang Hai-ying Huang Yu Chen Shun Yu christina Krywka Sarathlal K.Vayalil Stephan V.roth 何天白 State Key Laboratory of Polymer Physics and Chemistry Changchun Institute of Applied Chemistry Chinese Academy of Sciences Deutsches Elektronen-Synchrotron Hamburg D-22607 Germany Institute of High Energy Physics Chinese Academy of Sciences Institute for Applied and Experimental Physics University of Kiel Kiel D-24118 Germany Institute of Materials Research Helmholtz Zentrum Geesthacht D-21502 Geesthacht Germany

Long-range ordered nanostructures are prepared in the poly（styrene）-block-poly（e-caprolactone） diblock copolymer thin films using micromolding. We evaluated the change in crystallinity based on grazing-incidence X-ray diffraction and proved that the crystallinity increased with the decrease of the mold size. This means that ordered nanostructures with atomic length scale order can be adjusted by tuning the mesoscale confinement. The inherent mechanism was the cooperation of geometric confinement, microphase structure and surface-induced ordering of PS-b-PCL in the melt, which paved the way for the subsequent crystal growth. These findings establish a route to promote the cost-effective nanofabrication by combining the mature microfabrication technique with the emerging directed self-assembly of block copolymers.

关键词： Long-range ordered nanostructure Directed self-assembly Surface-induced ordering X-ray.

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