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Effect of concentration on surfactant micelle shapes——A molecular dynamics study

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Science China Chemistry 2005年第5期48卷 470-475页

作者： GAO Jian1,2. GE Wei1 & LI Jinghai1 1. Multiphase Reaction Laboratory, Institute of Process Engineering, chinese academy of Sciences, Beijing 100080, China 2. Graduate School of The chinese academy of Sciences, Beijing 100085, China Multiphase Reaction Laboratory Institute of Process Engineering Chinese Academy of Sciences Beijing China Graduate School of The chinese academy of Sciences Beijing China

Many aspects of the behavior of surfactants have not been well understood due to the coupling of many different mechanisms. Computer simulation is, therefore, attractive in the sense that it can explore the effect of different mechanisms separately. In this paper, the shapes, structures and sizes of sodium dodecylbenzenesulfonate (SDBS) micelles under different con-centrations in an oil/water mixture were studied via molecular dynamics (MD) simulations using a simplified atomistic model which basically maintains the hydrophile and lipophile properties of the surfactant molecules. Above the critical micellar concentration (cmc), surfactant molecules ag-gregate spontaneously to form a wide variety of assemblies, from spherical to rodlike, wormlike and bilayer micelles. Changes in their ratios of the principle moments of inertia (g1/g3, g2.g3) in-dicated the transition of micelle shapes at different concentrations. The aggregation number of micelle is found to have a power-law dependence on surfactant concentration.

关键词： surfactant, MD simulation, sodium dodecylbenzenesulfonate, micelle shape.

A new principle of synthetic cascade utilization of chemical energy and physical energy

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Science China(Technological Sciences) 2005年第2期48卷 163-179页

作者： JIN Hongguang1, HONG Hui1,2. WANG Baoqun1,2. HAN Wei1,2.& LIN Rumou1,2.1. Institute of Engineering Thermophysics, chinese academy of Sciences, Beijing 100080, China 2. Graduate School of the chinese academy of Sciences, Beijing 100039, China Institute of Engineering Thermophysics Chinese Academy of Sciences Graduate School of the chinese academy of Sciences

We propose a new principle of the cascade utilization of both chemical energy and physical energy in energy systems with the integration of chemical processes and thermal cycles. Particularly, a general equation of energy levels of substance, Gibbs free energy of chemical reaction and physical energy is explicitly founded. On the basis of this equation, a chemical-looping combustion and an indirect combustion are investigated. Furthermore, a mechanism of energy release, with the combination of decreasing the energy level of Gibbs free energy and upgrading the energy level of low or middle- temperature thermal energy, is clarified. The promising results obtained here establish a theoretical basis for the further investigation of multi-function systems in which energy and the environment are compatible, and create a new approach to improve the performance of traditional thermal cycles.

关键词： chemical energy, cascade utilization, exergy, energy conversion.

“Double dawn”eclipse and the rotational variation of the earth

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chinese Science Bulletin 2000年第11期45卷 988-991页

作者： ZHANG Peiyu & HAN Yanben1. Purple Mountain Observatory, chinese academy of Sciences, Nanjing 2.0008, China 2. Beijing Astronomical Observatory, chinese academy of Sciences, Beijing 100012. National Astronomical Observatory, chinese academy of Sciences, Beijing 100012. China Purple Mountain Observatory Chinese Academy of Sciences Nanjing China Beijing Astronomical Observatory Chinese Academy of Sciences Beijing National Astronomical Observatory Chinese Academy of Sciences Beijing China

A record of 'double dawn' at State Zheng in the first year of the reign of King Yi in Western Zhou Dynasty in the chronicle 'Bamboo Annals' (Zhushu Jinian) is discussed. We think that it may be a record of an annular solar eclipse happening in 899 BC. The record and the AT, which describes the secular variation of the earth’s rotation, are analyzed and discussed.

关键词： solar eclipse earth’s rotation.

Estimation on dynamic release of phosphorus from wind-induced suspended particulate matter in Lake Taihu

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Science China Earth Sciences 2004年第8期47卷 710-719页

作者： FAN Chengxin1, ZHANG Lu1,2. QIN Boqiang1, WANG Sumin1, HU Weiping1 & ZHANG Chen1 1. Taihu Lake Laboratory for Ecosystem Research, Nanjing Institute of Geography & Limnology, chinese academy of Sciences, Nanjing 2.0008, China 2. Graduate School of chinese academy of Sciences, Beijing 100039, China Taihu Lake Lab. for Ecosystem Res. Nanjing Inst. of Geography/Limnology Chinese Academy of Sciences Nanjing 210008 China Grad. Sch. of chinese Acad. of Sci. Beijing 100039 China

Through man-made disturbance experiments, the corresponding relationships be-tween suspended particulate matter (SPM) and wind speed in different lake areas were simu-lated, the physicochemical formal transformation and biological mineralizing and decaying processes of phosphorus in SPM were studied, the contribution of phosphorus transformation to phosphorus loading of the water of Lake Taihu was quantitatively estimated. The results show that about 0.44 t·a-1 loading in Lake Taihu mainly comes from phosphorus-releasing action of SPM in physicochemical transformed to soluble reactive phosphorus (SRP), and the contribution mainly from biological mineralizing and decaying was about 42..8 t·a-1, which is equal to 15.0% of the total external loading of Lake Taihu, namely 4.7—7.5 times as much as SRP loading en-tering the lake by the rivers; thus it is the important source in dynamical internal loading of the lake. The determining factors for dynamical internal loading in lakes are organic phosphorus content in suspended solid and its biological transition availability.

关键词： phosphorus release,wind wave disturbance,particulate decaying,dynamical loading,Lake Taihu.

The features of gravity field and deep structure in western part of the South Yellow Sea

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chinese Science Bulletin 2000年第8期45卷 759-764页

作者： WANG Qianshen1 & AN Yulin1. Institute of Geophysics, chinese academy of Sciences, Beijing 100101, China 2. chinese University of Geology, Beijing 100083, China Institute of Geophysics Chinesc Academy of Sciences Beijing China chinese University of Geology Beijing China

The gravity data from the sea region to the west of 12.° E of the South Yellow Sea have been processed and the feature of gravity fields analyzed. An experience relationship formula on the filter wavelength and corresponding depth has been put forward. Combined with the geological and seismic data, the deep tectonic framework and structural characters as well as possible favourable prospecting district for hydrocarbon in the South Yellow Sea have been discussed and analyzed.

关键词： western part of the South Yellow Sea gravity field deep structure.

Comparison of eastern paleo-Tethyan ophiolites and its geodynamic significance--Evidence from Dur'ngoi ophiolite

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Science China Earth Sciences 2004年第4期47卷 378-384页

作者： CHEN Liang1,2. SUN Yong1,2. PEI Xianzhi2. Feng Tao2.& Zhang Guowei2.1. Open Laboratory of Continental Dynamics, Ministry of Education, Northwest University, Xi抋n 710069, China 2. Institute of Geology and Geophysics, chinese academy of Sciences, Beijing 10002., China Open Laboratory of Continental Dynamics Ministry of Education Northwest University Xi’an China Institute of Geology and Geophysics Chinese Academy of Sciences Beijing China

Nd-Pb isotopic geochemistry of metabasalt from Dur抧goi ophiolite, Qinghai Prov-ince, NW China reveals the presence of DMM mixing with EMII components in its upper mantle source, which is comparable with present Indian MORB. Comparisons indicate that the geo-chemistry, chronology and source characteristics of Dur抧goi ophiolite coincide with Pa-leo-tethyan ophiolites from 揝anjiang?area. Together with evidences from regional geology in adjacent areas, this study proves that independent paleo-tethyan basins evolved contemporarily, the dynamics of which is attributed to the interaction of mantle plume with over-riding lithosphere.

关键词： ophiolite, Paleo-Tethys, DUPAL anomaly, Indosinian movement.

Preparation and characterization of a novel adsorbent for removing lipophilic organic from water

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Science China Chemistry 2005年第6期48卷 600-604页

作者： LIU Huijuan1, DAI Ruihua1, QU Jiuhui1 & RU Jia1,2.1. State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, chinese academy of Sciences, Beijing 100085, China 2. Graduate School of the chinese academy of Sciences, Beijing 100039, China State Key Laboratory of Environmental Aquatic Chemistry Research Center for Eco-Environmental Sciences Chinese Academy of Sciences Beijing China Graduate School of the chinese academy of Sciences Beijing China

A novel composite adsorbent containing a kind of lipid-triolein is studied. The ad-sorbent is prepared by embedding triolein into cellulose acetate (CA) sphere. The preparation method, the physical-chemical properties of the adsorbent and the removal efficiency of two or-ganochlorinated pesticides are studied. The adsorbent is stable in water and no triolein leaks into water for 465 h soaking. The adsorbent has high adsorption capacity for organochlorinated pes-ticides such as dieldrin and aldrin. The results suggest that triolein-containing adsorbent could serve as a good adsorbent for lipophilic organic pollutants. The adsorption rate for lipophilic pol-lutants is very fast and has relation with the logKow of the compounds.

关键词： triolein, cellulose acetate, adsorbent, lipophilic organic, drinking water.

Statistical distribution of nonlinear random wave height

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Science China Earth Sciences 2006年第4期49卷 443-448页

作者： HOU Yijun1, GUO Peifang1,2. SONG Guiting1,2. SONG Jinbao1, YIN Baoshu1 & ZHAO Xixi1,2.1. Institute of Oceanology, chinese academy of Sciences, Qingdao 2.6071, China 2. Graduate University of the chinese academy of Sciences, Beijing 100039, China Institute of Oceanology Chinese Academy of Sciences Qingdao China Graduate University of the chinese academy of Sciences Beijing China

A statistical model of random wave is developed using Stokes wave theory of water wave dynamics. A new nonlinear probability distribution function of wave height is presented. The results indicate that wave steepness not only could be a parameter of the distribution function of wave height but also could reflect the degree of wave height distribution deviation from the Rayleigh distribution. The new wave height distribution overcomes the problem of Rayleigh distribution that the prediction of big wave is overestimated and the general wave is underestimated. The prediction of small probability wave height value of new distribution is also smaller than that of Rayleigh distribution. Wave height data taken from East China Normal University are used to verify the new distribution. The results in- dicate that the new distribution fits the measurements much better than the Rayleigh distribution.

关键词： Random ocean wave, nonlinearity, wave height distribution.

Life Science:Innovation and prosperity—commemorating the 60th anniversary of the chinese academy of Sciences

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Science China(Life Sciences) 2010年第1期53卷 2-12页

作者： LI JiaYang chinese academy of Sciences,52.Sanlihe Road,Beijing 100864,China chinese academy of Sciences

In tandem with the birth and growth of the People’s Republic of China (PRC),the chinese academy of Sciences (CAS) passed through six decades by the year of 2.09.

关键词： commemorating the 60 Life Science anniversary of the chinese academy of Sciences th Innovation