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Delicate chemical structure regulation of nonfullerene acceptor for efficient and large thickness organic solar cells

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Science China Chemistry 2024年第5期67卷 1596-1604页

作者： Zhe Zhang Wanying Feng Yunxin Zhang Shaohui Yuan Yuyang Bai Peiran Wang Zhaoyang Yao chenxi li Tainan Duan Xiangjian Wan Bin Kan Yongsheng Chen State Key Laboratory and Institute of Elemento-Organic Chemistry Frontiers Science Center for New Organic MatterThe Centre of Nanoscale Science and Technology and Key Laboratory of Functional Polymer MaterialsRenewable Energy Conversion and Storage Center(RECAST)College of ChemistryNankai UniversityTianjin 300071China School of Materials Science and Engineering National Institute for Advanced MaterialsNankai UniversityTianjin 300350China Chongqing Institute of Green and Intelligent Technology Chongqing SchoolUniversity of Chinese Academy of Sciences(UCAS Chongqing)Chinese Academy of SciencesChongqing 400722China

Inspired by the success of CH-series acceptors, a small-molecular acceptor, CH-Tz was reported by adopting a new conjugationextended electron-deficient unit([1,2,5]thiadiazolo[3,4-b]pyrazine) on the central core. Owing to the enhanced inter-/intramolecular interactions, CH-Tz exhibited near-infrared absorption and an effective three-dimensional molecular packing network in its single crystal. When blended with polymer donor PM6, the binary device achieved a high power conversion efficiency(PCE) of 18.54%, with a notable short-circuit current density(J_(sc)) of 27.54 m A cm-2and an excellent fill factor(FF) over 80%,which can be partly ascribed to the balanced charge transport properties in the blend film. After employing D18-Cl as the third component, an enhanced PCE of 18.85% was achieved due to a more obvious fiber network. Impressively, the CH-Tz-based OSC devices show excellent thermal stability and thickness insensitivity. Record-breaking Jscof 28.92 m A cm-2was reached for PM6:D18-Cl:CH-Tz ternary device with a thickness of 560 nm. Besides, CH-Tz shows potential in fabricating multicomponent high-performance organic solar cells, where over 19% efficiency could be realized in the quaternary device. Our work advances the strong influence of electron-deficient central units on molecular photovoltaic properties and guides the design of acceptors for stable and large-thickness organic solar cells.

关键词： organic solar cells non-fullerene acceptor central unit large thickness molecular packing

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A case study of comparing two dimerized acceptor molecules built by different branch-connected and terminal-connected approaches

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Science China Chemistry 2024年第5期67卷 1687-1696页

作者： Kangqiao Ma Huazhe liang Yuxin Wang Tengfei He Tainan Duan Xiaodong Si Wendi Shi Guankui Long Xiangjian Cao Zhaoyang Yao Xiangjian Wan chenxi li Bin Kan Yongsheng Chen State Key Laboratory and Institute of Elemento-Organic Chemistry Frontiers Science Center for New Organic MatterThe Centre of Nanoscale Science and Technology and Key Laboratory of Functional Polymer MaterialsInstitute of Polymer ChemistryRenewable Energy Conversion and Storage Center(RECAST)College of ChemistryNankai UniversityTianjin 300071China School of Materials Science and Engineering National Institute for Advanced MaterialsRenewable Energy Conversion and Storage Center(RECAST)Nankai UniversityTianjin 300350China Chongqing Institute of Green and Intelligent Technology Chongqing SchoolUniversity of Chinese Academy of Sciences(UCAS Chongqing)Chinese Academy of SciencesChongqing 400015China

Dimerized small-molecule acceptors(SMAs) built by the conventional connection of terminal groups of monomers have contributed to exciting long-term stabilities of organic solar cells(OSCs). However, device efficiencies, especially fill factors(FFs), still need to be improved. This probably originates from unsymmetrical molecular structure/conformation-determined less compact/ordered molecular stackings, such as ineffective stackings of constraint terminals. Herein, an exotic dimerized SMA of BC-Th is established by bridging the branched groups(BC-type, branch coupling) of two monomers rather than conventional terminal units(TC-type, terminal coupling). Benefiting from the three-dimensional conformation and more uncurbed terminals,BC-Th exhibits multiple molecular orientations along with a larger dielectric constant and electron mobility compared with TCTh. Finally, an efficiency of 17.43% is achieved by BC-Th-based OSCs, along with the highest FF of 79.13% among all dimerized SMAs-based OSCs to date. When introducing L8-BO as the third component, overall enhanced efficiency of 18.05%and FF of 80.11% are further afforded. Contrarily, TC-Th-based OSCs exhibit much inferior PCE of 16.29% and FF of 74.81%,demonstrating the great advantages of “branch coupling” over “terminal coupling” when building dimerized SMAs.

关键词： organic solar cells dimerized acceptor molecules branch coupling morphology control stability

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Dynamic Evolutionary Game-based Modeling,Analysis and Performance Enhancement of Blockchain Channels

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IEEE/CAA Journal of Automatica Sinica 2023年第1期10卷 188-202页

作者： PeiYun Zhang MengChu Zhou chenxi li Abdullah Abusorrah IEEE the School of Computer Science Nanjing University of Information Science&TechnologyNanjing 210044China the Helen and John C.Hartmann Department of Electrical and Computer Engineering New Jersey Institute of TechnologyNewarkNJ 07102 USA the School of Computer and Information Anhui Normal UniversityWuhu 241003China the Department of Electrical and Computer Engineering Faculty of Engineeringand Center of Research Excellence in Renewable Energy and Power SystemsKing Abdulaziz UniversityJeddah 21481Saudi Arabia

The recent development of channel technology has promised to reduce the transaction verification time in blockchain operations.When transactions are transmitted through the channels created by nodes,the nodes need to cooperate with each other.If one party refuses to do so,the channel is unstable.A stable channel is thus required.Because nodes may show uncooperative behavior,they may have a negative impact on the stability of such channels.In order to address this issue,this work proposes a dynamic evolutionary game model based on node behavior.This model considers various defense strategies'cost and attack success ratio under them.Nodes can dynamically adjust their strategies according to the behavior of attackers to achieve their effective defense.The equilibrium stability of the proposed model can be achieved.The proposed model can be applied to general channel networks.It is compared with two state-of-the-art blockchain channels:lightning network and Spirit channels.The experimental results show that the proposed model can be used to improve a channel's stability and keep it in a good cooperative stable state.Thus its use enables a blockchain to enjoy higher transaction success ratio and lower transaction transmission delay than the use of its two peers.

关键词： Blockchain channel network evolutionary game malicious behavior secure computing stability analysis

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Improved Adaptive Iterated Extended Kalman Filter for GNSS/INS/UWB-Integrated Fixed-Point Positioning

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Computer Modeling in Engineering & Sciences 2023年第3期134卷 1761-1772页

作者： Qingdong Wu chenxi li Tao Shen Yuan Xu Shandong Luqiao Group Co. Ltd.Jinan250014China School of Electrical Engineering University of JinanJinan250022China Shandong Beiming Medical Technology Co. Ltd.Jinan250022China

To provide stable and accurate position information of control points in a complex coastal environment,an adaptive iterated extended Kalman filter(AIEKF)for fixed-point positioning integrating global navigation satellite system,inertial navigation system,and ultra wide band(UWB)is proposed.In thismethod,the switched global navigation satellite system(GNSS)and UWB measurement are used as the measurement of the proposed filter.For the data fusion filter,the expectation-maximization(EM)based IEKF is used as the forward filter,then,the Rauch-Tung-Striebel smoother for IEKF filter’s result smoothing.Tests illustrate that the proposed AIEKF is able to provide an accurate estimation.

关键词： Rauch-tung-striebel ultra wide band global navigation satellite system adaptive iterated extended kalman filter

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Dynamic Spectrum Control-Assisted Secure and Efficient Transmission Scheme in Heterogeneous Cellular Networks

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Engineering 2022年第10期17卷 220-231页

作者： chenxi li Lei Guan Huaqing Wu Nan Cheng Zan li Xuemin(Sherman)Shen State Key Laboratory of Integrated Services Networks Xidian UniversityXi’an 710071China Department of Electrical and Computer Engineering University of WaterlooWaterlooON N2L 3G1Canada Collaborative Innovation Center of Information Sensing and Understanding Xi’an 710071China

Heterogeneous cellular networks(HCNs)are envisioned as a promising architecture to provide seamless wireless coverage and increase network capacity.However,the densified multi-tier network architecture introduces excessive intra-and cross-tier interference and makes HCNs vulnerable to eavesdropping attacks.In this article,a dynamic spectrum control(DSC)-assisted transmission scheme is proposed for HCNs to strengthen network security and increase the network capacity.Specifically,the proposed DSC-assisted transmission scheme leverages the idea of block cryptography to generate sequence families,which represent the transmission decisions,by performing iterative and orthogonal sequence transformations.Based on the sequence families,multiple users can dynamically occupy different frequency slots for data transmission simultaneously.In addition,the collision probability of the data transmission is analyzed,which results in closed-form expressions of the reliable transmission probability and the secrecy probability.Then,the upper and lower bounds of network capacity are further derived with given requirements on the reliable and secure transmission probabilities.Simulation results demonstrate that the proposed DSC-assisted scheme can outperform the benchmark scheme in terms of security performance.Finally,the impacts of key factors in the proposed DSC-assisted scheme on the network capacity and security are evaluated and discussed.

关键词： Heterogeneous cellular networks Dynamic spectrum control Transmission security Efficient data transmission

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Accelerating net-zero carbon emissions by electrochemical reduction of carbon dioxide

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Journal of Energy Chemistry 2023年第4期79卷 398-409页

作者： Fan He Sirui Tong Zhouyang Luo Haoran Ding Ziye Cheng chenxi li Zhifu Qi Zhejiang Baima Lake Laboratory Co. LtdHangzhou 311121ZhejiangChina School of Mechanical and Aerospace Engineering Nanyang Technological UniversitySingapore 639798Singapore

Electroreduction of CO_(2)shows great potential for global CO_(2)utilization and uptake when collaborated with renewable electricity.Recent advances have been achieved in fundamental understanding and electrocatalyst development for CO_(2)electroreduction.We think this research area has progressed to the stage where significant efforts can focus on translating the obtained knowledge to the development of largescale electrolyzers,which have the potential to accelerate the transition of the current energy system into a sustainable and zero-carbon emission energy structure.In this perspective paper,we first critically evaluate the advancement of vapor-feed devices that use CO_(2)as reactants,from the point of view of industry applications.Then,by carefully comparing their performance to the state-of-the-art water electrolyzers which are well-established technology providing realistic performance targets,we looped back and discussed the remaining challenges including electrode catalysts,reaction conditions,mass transporting,membrane,device durability,operation mode,and so on.Finally,we provide perspectives on the challenges and suggest opportunities for generating fundamental knowledge and achieving technological progress toward the development of practical CO_(2)electrolyzers for the goal of building lowcarbon or/and net carbon-free economies.

关键词： CO_(2)emission Energy storage CO_(2)electroreduction CO_(2)electrolyzer Scale up

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A Low Reorganization Energy and Two-dimensional Acceptor with Four End Units for Organic Solar Cells with Low E_(loss)

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Chinese Journal of Polymer Science 2022年第8期40卷 921-927,I0008页

作者： Hongbin Chen Xiangjian Cao Xiaoyun Xu chenxi li Xiangjian Wan Zhaoyang Yao Yongsheng Chen State Key Laboratory and Institute of Elemento-Organic Chemistry The Centre of Nanoscale Science and Technology and Key Laboratory of Functional Polymer MaterialsRenewable Energy Conversion and Storage Center(RECAST)College of ChemistryNankai UniversityTianjin300071China State Key Laboratory for Modification of Chemical Fibers and Polymer Materials Center for Advanced Low-dimension MaterialsCollege of Materials Science and EngineeringDonghua UniversityShanghai201620China

A novel two-dimensional A-D-A acceptor named as CH8 with four electron-withdrawing end units has been successfully designed and synthesized.The enlarged conjugation in two directions renders CH8 exhibit an extremely low electron reorganization energy of 98 meV,which makes CH8 a potential candidate for outstanding organic semiconductor material.When blended with PM6,a considerate power conversion efficiency of 9.37%along with a high open-circuit voltage(V_(oc))0.889 V and low energy loss(E_(loss))below 0.6 eV is achieved.These results indicate that the two-dimensional A-D-A molecule with four electron-withdrawing end units is an effective molecular design strategy to achieve lower voltage loss and also possible high performance for organic photovoltaics if ideal morphology could be achieved.

关键词： Two-dimensional A-D-A acceptor Reorganization energy Energy loss(E_(loss)) Organic photovoltaics

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High-performance lithium-ion batteries based on polymer/graphene hybrid cathode material

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中国科学:化学英文版 2023年第9期66卷 2683-2689页

作者： Yang Zhao Minghan Ni Nuo Xu chenxi li Yanfeng Ma Hongtao Zhang Yongsheng Chen The Centre of Nanoscale Science and Technology and Key Laboratory of Functional Polymer Materials Institute of Polymer ChemistryCollege of ChemistryNankai UniversityTianjin 300071China State Key Laboratory of Elemento-Organic Chemistry Nankai UniversityTianjin 300071China Renewable Energy Conversion and Storage Center(RECAST) Nankai UniversityTianjin 300071China

Organic and carbon-based lithium-ion batteries possess abundant resources,nontoxicity,environmental friendliness,and high performance,and they have been widely studied in the past decades.However,it remains a challenge to construct such batteries with high capacity,high cycling stability,and high conductivity simultaneously.Here,we elaborately design and integrate organic polymer(p-FcPZ) with graphene network to create a hybrid material(p-FcPZ@G) for high-performance lithium-ion batteries(liBs).The bi-polar polymer p-FcPZ containing multiple redox-active sites endows p-FcPZ@G with both remarkable cycling stability and high capacity.The porous conductive graphene network with a large surface area facilitates rapid ions/electrons transportation,resulting in superior rate performance.Therefore,the half-cell based on p-FcPZ@G cathode exhibits simultaneously high capacity(~250 mA h g^(-1) at 50 mA g^(-1)),excellent cycling stability(retention of 99.999% per cycle for 10,000 cycles at 2,000 mA g^(-1)) and superior rate performance.Additionally,the graphene-based full cell assembled with p-FcPZ@G cathode and graphene anode also demonstrates comprehensively high electrochemical performance.

关键词： lithium-ion batteries organic electrode graphene hybrid material high performance full cells

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Transaction transmission model for blockchain channels based on non-cooperative games

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Science China(Information Sciences) 2023年第1期66卷 97-114页

作者： Peiyun ZHANG chenxi li Mengchu ZHOU Wenjun HUANG Abdullah ABUSORRAH Omaimah O.BAMASAG Engineering Research Center of Digital Forensics of Ministry of Education School of Computer and SoftwareNanjing University of Information Science and Technology School of Computer and Information Anhui Normal University Department of Electrical and Computer Engineering New Jersey Institute of Technology Center of Research Excellence in Renewable Energy and Power Systems Department of Electrical and Computer Engineering Faculty of Engineering and K.A.CARE Energy Research and Innovation CenterKing Abdulaziz University Department of Computer Science Faculty of Computing and Information Technology Center of Excellence in Smart Environment Research King Abdulaziz University

In blockchain networks, transactions can be transmitted through channels. The existing transmission methods depend on their routing information. If a node randomly chooses a channel to transmit a transaction, the transmission may be aborted due to insufficient funds(also called balance) or a low transmission rate. To increase the success rate and reduce transmission delay across all transactions, this work proposes a transaction transmission model for blockchain channels based on non-cooperative game theory.Channel balance, channel states, and transmission probability are fully considered. This work then presents an optimized channel transaction transmission algorithm. First, channel balances are analyzed and suitable channels are selected if their balance is sufficient. Second, a Nash equilibrium point is found by using an iterative sub-gradient method and its related channels are then used to transmit transactions. The proposed method is compared with two state-of-the-art approaches: Silent Whispers and Speedy Murmurs. Experimental results show that the proposed method improves transmission success rate, reduces transmission delay,and effectively decreases transmission overhead in comparison with its two competitive peers.

关键词： Blockchain channel transaction transmission channel balance channel state channel transmission probability non-cooperative game

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A 2D covalent organic framework with ultra-large interlayer distance as high-rate anode material for lithium-ion batteries

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Nano Research 2022年第11期15卷 9779-9784页

作者： Manman Wu Yang Zhao Hongtao Zhang Jie Zhu Yanfeng Ma chenxi li Yamin Zhang Yongsheng Chen The Centre of Nanoscale Science and Technology and Key Laboratory of Functional Polymer Materials Institute of Polymer ChemistryCollege of ChemistryNankai UniversityTianjin 300071China State Key Laboratory of Elemento-Organic Chemistry Nankai UniversityTianjin 300071China Renewable Energy Conversion and Storage Center(RECAST) Nankai UniversityTianjin 300071China State Key Laboratory of Applied Organic Chemistry College of Chemistry and Chemical EngineeringLanzhou UniversityLanzhou 730000China

Covalent organic frameworks(COFs)have been broadly investigated for energy storage systems.However,many COF-based anode materials suffer from low utilization of redox-active sites and sluggish ions/electrons transport caused by their densely stacked layers.Thus,it is still a great challenge to obtain COF-based anode materials with fast ions/electrons transport and thus superior rate performance.Herein,a redox-active piperazine-terephthalaldehyde(PA-TA)COF with ultra-large interlayer distance is designed and synthesized for high-rate anode material,which contains piperazine units adopting a chair-shaped conformation with the nonplanar linkages of a tetrahedral configuration.This unique structure renders PA-TA COF an ultra-large interlayer distance of 6.2Å,and further enables it to achieve outstanding rate and cycling performance.With a high specific capacity of 543 mAh·g^(−1) even after 400 cycles at 1.0 A·g^(−1),it still could afford a specific capacity of 207 mAh·g^(−1) even at a high current density of 5.0 A·g^(−1).Our study indicates that expanding the interlayer distance of COFs by rational molecular design would be of great importance to develop high-rate electrode materials for lithium-ion batteries.

关键词： lithium-ion batteries high-rate anode material covalent organic frameworks ultra-large interlayer distance

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