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Chinese Journal of Aeronautics 2025年第1期38卷 115-130页

作者： yang LIU Ningsong QU Hansong LI Zhaoyang zhang School of Mechanical Engineering Jiangsu UniversityZhenjiang 212013China National Key Laboratory of Science and Technology on Helicopter Transmission Nanjing University of Aeronautics and AstronauticsNanjing 210016China

Large size titanium alloy parts are widely used in ***,they are difficult to manufacture using mechanical cutting technology because of severe tool *** jet machining is a promising technology to achieve high efficiency,because it has high machining flexibility and no machining tool ***,reports on the macro electrochemical jet machining of large size titanium alloy parts are very scarce,because it is difficult to achieve effective constraint of the flow field in macro electrochemical jet *** addition,titanium alloy is very sensitive to fluctuation of the flow field,and a turbulent flow field would lead to serious stray *** paper reports a series of investigations of the electrochemical jet machining of titanium alloy *** on the flow analysis and experiments,the machining flow field was effectively ***6 titanium alloy part with a perimeter of one meter was *** machined surface was smooth with no obvious machining *** machining process was particularly stable with no obvious spark *** research provides a reference for the application of electrochemical jet machining technology to achieve large allowance material removal in the machining of large titanium alloy parts.

关键词： Electrochemical jet machining Titanium alloys Large size parts Flow simulation Turbulent flow

Unraveling the impacts of intermolecular interaction on morphology evolution for highly efficient organic solar cells and modules

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Science China Chemistry 2025年第1期68卷 264-272页

作者： Xueqing Ma Yingying cheng Yuqiang Liu Xinming Zheng Guangliu Ran Hongxiang Li Xinyue Cui Andong zhang Wenkai zhang Pei cheng Wenchao Huang Zhishan Bo Beijing Key Laboratory of Energy Conversion and Storage Materials College of ChemistryBeijing Normal UniversityBeijing 100875China College of Textiles and Clothing State Key Laboratory of Bio-fibers and Eco-textilesQingdao UniversityQingdao 266071China Key State Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and EngineeringWuhan University of TechnologyWuhan 430070China Department of Physics and Applied Optics Beijing Area Major Laboratory Center for Advanced Quantum StudiesBeijing Normal UniversityBeijing 100875China State Key Laboratory of Polymer Materials Engineering College of Polymer Science and EngineeringSichuan UniversityChengdu 610065China

Understanding the effect of intermolecular interaction on the growth dynamic of active layers is critical for advancing organic solar cells(OSCs).However,the diverse structure of donors and acceptors makes the research *** with customizable structures and properties could simplify this ***,we meticulously tailor two additives of 3,4-ethylenedioxythiophene(EDOT)and 2,5-dibromo-3,4-ethylenedioxythiophene(DBEDOT),possessing distinct intermolecular interaction features to elaborate the inherent *** is found that varied interaction strengths can alter film formation *** enhanced intermolecular interaction between the DBEDOT and non-fullerene acceptor BTP-e C9-4F results in pre-aggregation and longer crystallization duration of BTP-e C9-4F,facilitating the formation of films with compact molecular packing and decent phase ***,exciton dissociation and charge transport become more ***,devices processed with DBEDOT exhibit a remarkable power conversion efficiency of 19.35%in small-area OSCs and 14.11%in bladecoated 5 cm×5 cm organic solar ***,OSCs can maintain 80%of their initial efficiency after continuous annealing at 85℃for over 2,100 h.

关键词： organic solar cell non-fullerene acceptor film growth molecular packing intermolecular interaction

Study on the off situ reconstruction of the core neutron field based on dual-task hybrid network architecture

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Nuclear Science and Techniques 2025年第1期36卷 175-191页

作者： Pei Cao Hui Ding cheng-Long Cao Zi-Hui yang Guo-Min Sun School of Artificial Intelligence and Big Data Hefei UniversityHefei 230001China College of Electronic Engineering National University of Defense TechnologyHefei 230001China Institute of Nuclear Energy Safety Technology HFIPSChinese Academy of SciencesHefei 230027China

The off situ accurate reconstruction of the core neutron field is an important step in realizing real-time reactor *** existing off situ reconstruction method of the neutron field is only applicable to cases wherein a single region changes at a specified location of the ***,when the neutron field changes are complex,the accurate identification of the individual changed regions becomes challenging,which seriously affects the accuracy and stability of the neutron field ***,this study proposed a dual-task hybrid network architecture(DTHNet)for off situ reconstruction of the core neutron field,which trained the outermost assembly reconstruction task and the core reconstruction task jointly such that the former could assist the latter in the reconstruction of the core neutron field under core complex ***,to exploit the characteristics of the ex-core detection signals,this study designed a global-local feature upsampling module that efficiently distributed the ex-core detection signals to each reconstruction unit to improve the accuracy and stability of *** experiments were performed on the simulation datasets of the CLEAR-I reactor to verify the accuracy and stability of the proposed *** results showed that when the location uncertainty of a single region did not exceed nine and the number of multiple changed regions did not exceed ***,the reconstructed ARD was within 2%,RD_(max)was maintained within 17.5%,and the number of RD≥10%was maintained within ***,when the noise interference of the ex-core detection signals was within±2%,although the average number of RD≥10%increased to 16,the average ARD was still within in 2%,and the average RD_(max)was within 22%.Collectively,these results show that,theoretically,the DTHNet can accurately and stably reconstruct most of the neutron field under certain complex core changes.

关键词： Real-time reactor monitoring Core neutron field reconstruction Dual-task hybrid network architecture Global-local feature upsampling module

水轮机转轮结构与过机幼鱼受压强损伤相关性研究

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水力发电学报 2017年第10期36卷 110-120页

作者：王煜李成张洋三峡大学水利与环境学院湖北宜昌443002 贵州省水利水电勘测设计研究院贵阳550002

大坝阻隔了洄游性鱼类的洄游通道,鱼类通过水轮机下行或误入水轮机流道将遭受水轮机流道复杂水动力特性及水轮机结构的影响,导致过机鱼体的损伤甚至死亡。为有效保护鱼类资源,本文在对大型轴流式水轮机进行全流道三维数值模拟的基础上,... 详细信息

大坝阻隔了洄游性鱼类的洄游通道,鱼类通过水轮机下行或误入水轮机流道将遭受水轮机流道复杂水动力特性及水轮机结构的影响,导致过机鱼体的损伤甚至死亡。为有效保护鱼类资源,本文在对大型轴流式水轮机进行全流道三维数值模拟的基础上,以鱼类受压强和压强梯度损伤阈值作为评价指标,对水轮机流道转轮叶片数目及转轮泄水锥尺寸进行降低幼鱼损伤概率的优化研究。研究结果表明,在满足水轮机出力要求的前提下,大型轴流式水轮机转轮叶片数目增多将增大下行幼鱼受压力及压力梯度损伤的概率,转轮泄水锥相对高度的减小将增加幼鱼受压力及压力梯度损伤的概率。该研究成果可为减小鱼体损伤的环境友好型水轮机优化设计提供参考。

关键词：水力机械 CFD数值模拟压强损伤优化研究

Enhanced rate capability and cycle stability of Ti2C MXene for sodium storage through an aniline molecules welding strategy

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Tungsten 2025年第1期7卷 161-171页

作者： Hao Chen Ya-Qin Wang Dong-Ting zhang Bei Zhao Min-Peng Li Chen-yang Li Tian-Peng Xu Mao-cheng Liu State Key Laboratory of Advanced Processing and Recycling of Non-Ferrous Metals Lanzhou University of Technology School of Materials Science and Engineering Lanzhou University of Technology School of Computer and Communication Technology Lanzhou University of Technology

MXenes obtained significant attention in the field of energy storage devices due to their characteristic layered structure,modifiable surface functional groups,large electrochemically active surface,and regulable interlayer ***,the self-restacking and sluggish ions diffusion kinetics performance of MXenes during the alkali metal ions insertion/extraction process severely impedes their cycle stability and rate *** paper proposes an aniline molecule welding strategy for welding p-phenylenediamine（PPDA） into the interlayers of Ti2C through a dehydration condensation *** welded PPDA molecules can contribute pillar effect to the layered structure of *** pillar effect effectively maintains the structural stability during the sodium ions insertion/extraction process and effectively expands the interlayer spacing of Ti2C from 1.16 to 1.38 nm,thereby enhancing ions diffusion kinetics performance and improving the long-term cycle *** Ti2C-PPDA demonstrates outstanding Na+storage capability,exhibiting a specific capacity of 100.2 mAh·g-1at a current density of 0.1 A·g-1over 960 cycles and delivering a remarkable rate capability 81.2 mAh·g-1at a current density of 5 A·*** study demonstrates that expanding interlayer spacing is a promising strategy to enhance the Na+storage capacity and improve long-term cycling stability,which provides significant guidance for the design of two-dimensional Na+storage materials with high-rate capability and cycle stability.

关键词： Diffusion kinetics Expanding interlayer spacing Rate capability Sodium ions storage Ti2C

A sensitive fluorescent sensor-based on the photoinduced electron transfer mechanism for cefixime

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A sensitive fluorescent sensor-based on the photoinduced ele...

Constructing diverse switchable circularly polarized luminescence via a single azobenzene polymer film

中国化学会第六届全国热分析动力学与热动力学学术会议

作者： cheng-zhang yang cheng Xu Yong-Chang Liu 胡艳军 Hubei Key Laboratory of Pollutant Analysis & Reuse Technology Department of ChemistryHubei Normal University 湖北师范大学化学化工学院

Cefixime is a third generation orally administered cephalosporin that is frequently used as a broad spectrum antibiotic against various gram-negative and gram-positive bacteria. In this study, a simple and sensitive fluorescent sensor for the determination the Cefixime was established based on the CdTe:Zn quantum dots(QDs). The fluorescence of CdTe:Zn QDs can be effectively quenched by Cefixime in virtue of the surface binding of Cefixime on CdTe:Zn QDs and the subsequent photoinduced electron transfer process from CdTe:Zn QDs to Cefixime, in particular, the high sensitivity of QDs PL emission to Cefixime at the micromole per liter level, which render the Cefixime-CdTe:Zn QDs system into fluorescence "OFF" status. Furthermore, the FTIR of characteristics bands of C-O, N–H, O–H groups of Cefixime endow evidence for the interaction of Cefixime with CdTe:ZnQDs. The relative thermodynamic behaviour of the affinity of CdTe:ZnQDs for Cefixime reveals the potential molecular binding mechanism.

关键词： Fluorescent sensor CdTe:Zn2+QDs Cefixime photoinduced electron transfer

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Chinese Chemical Letters 2025年第1期36卷 299-305页

作者： Xiang Wang Qingping Song Zixiang He Gong zhang Tengfei Miao Xiaoxiao cheng Wei zhang State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials Department of Polymer Science and EngineeringCollege of ChemistryChemical Engineering and Materials ScienceSoochow UniversitySuzhou 215123China School of Chemical and Environmental Engineering Anhui Polytechnic UniversityWuhu 241000China Jiangsu Key Laboratory for Chemistry of Low-Dimensional Materials School of Chemistry and Chemical EngineeringHuaiyin Normal UniversityHuaian 223300China

Recently circularly polarized luminescence(CPL)materials have attracted significant *** reversible dynamic property to these materials has been a key focus in cutting-edge fields,such as in high-level information ***,we provided a novel and general strategy involving handednessselective filtration and ground-state chiral self-recovery(CSR)in double film system to address this *** on this strategy,we achieved CPL switch through the reversible modulation of ground-state chirality including absorption and scattering circular dichroism(CD)signals over the full UV-visible wavelength range(365-700 nm)in a single azobenzene polymer(PAzo)*** importantly,by flexibly changing the type of fluorescent films,it is convenient to achieve general excited-state CSR,that is reversible switching of full-color including ideal white(CIE coordinate(0.33,0.33)),as well as room-temperature phosphorescent *** these CPL signals without almost any intensity decay after three cycles of onand-off *** results indicated that the trans-cis isomerization and ordered rearrangement of azobenzene units in PAzo film were the fundamental reasons for realizing CPL ***,based on this system we achieved dynamic visual encryption and decryption process including multiple decryption *** study provides an effective method for constructing a universally applicable chiroptical switch in excited state.

关键词： Circularly polarized luminescence Azobenzene polymer Multiple CPL Chiral switch Information encryption

C-C motif chemokine ligand 2/C-C motif chemokine receptor 2 pathway as a therapeutic target and regulatory mechanism for spinal cord injury

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Neural Regeneration Research 2025年第8期20卷 2231-2244页

作者： Xiangzi Wang Xiaofei Niu Yingkai Wang yang Liu cheng yang Xuyi Chen Zhongquan Qi School of Medicine Guangxi UniversityNanningGuangxi Zhuang Autonomous RegionChina Graduate School of Tianjin University of Traditional Chinese Medicine TianjinChina Characteristic Medical Center of People’s Armed Police Forces TianjinChina Fujian Maternity and Child Health Hospital FuzhouFujian ProvinceChina

Spinal cord injury involves non-reversible damage to the central nervous system that is characterized by limited regenerative capacity and secondary inflammatory *** expression of the C-C motif chemokine ligand 2/C-C motif chemokine receptor 2 axis exhibits significant differences before and after *** studies have revealed that the C-C motif chemokine ligand 2/C-C motif chemokine receptor 2 axis is closely associated with secondary inflammatory responses and the recruitment of immune cells following spinal cord injury,suggesting that this axis is a novel target and regulatory control point for *** review comprehensively examines the therapeutic strategies targeting the C-C motif chemokine ligand 2/C-C motif chemokine receptor 2 axis,along with the regenerative and repair mechanisms linking the axis to spinal cord ***,we summarize the upstream and downstream inflammatory signaling pathways associated with spinal cord injury and the C-C motif chemokine ligand 2/C-C motif chemokine receptor 2 *** review primarily elaborates on therapeutic strategies that target the C-C motif chemokine ligand 2/C-C motif chemokine receptor 2 axis and the latest progress of research on antagonistic drugs,along with the approaches used to exploit new therapeutic targets within the C-C motif chemokine ligand 2/C-C motif chemokine receptor 2 axis and the development of targeted ***,there are presently no clinical studies relating to spinal cord injury that are focusing on the C-C motif chemokine ligand 2/C-C motif chemokine receptor 2 *** review aims to provide new ideas and therapeutic strategies for the future treatment of spinal cord injury.

关键词： apoptosis C-C motif chemokine ligand 2/C-C motif chemokine receptor 2 pathway C-C motif chemokine receptor 2 antagonists chemokine ligand 2 chemokine receptor 2 inflammation macrophage microglia spinal cord injury therapeutic method

Investigations of inelastic cross sections of H_(2)O molecule by He^(2+) and C^(6+) projectiles with energy range around the Bragg peak

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Nuclear Science and Techniques 2025年第2期36卷 141-154页

作者： Guo-Zhuang Li cheng-Ye Sun Rui cheng Yan-Shi zhang Liang-Wen Chen Sheng zhang Xin-Xia Li Lei yang School of Nuclear Science and Technology University of South ChinaHengyang 421001China Advanced Energy Science and Technology Guangdong Laboratory Huizhou 516000China Institute of Modern Physics Chinese Academy of SciencesLanzhou 730000China Interdisciplinary Center for Fundamental and Frontier Sciences Nanjing University of Science and TechnologyJiangyin 214443China Center for Basic Teaching and Experiment Nanjing University of Science and TechnologyJiangyin 214443China School of Nuclear Science and Technology University of Chinese Academy of SciencesBeijing 100049China

Inelastic collisions are the dominant cause of energy loss in *** the energy range around the Bragg peak,single ionization(SI)and single-electron capture(SC)are the primary inelastic collisions that lead to energy *** study employs the classical trajectory Monte Carlo method to study the SI and SC processes of H_(2)O molecules using He^(2+) and C^(6+) projectiles in the energy range of 10 keV/u to 10 MeV/*** total cross sections,single differential cross sections,impact parameter dependence of SI and SC,and fragmentation cross sections were *** illustrate that the cross section for SI is the highest when the projectile energy is close to the Bragg peak *** the projectile energy is below the Bragg peak energy,the ionized electrons in the forward direction dominate,and the removal of electrons can be associated with large impact *** the projectile energy increases,the emission angle of the electrons gradually transitions from small angles(60°~120°)to large angles(60°~120°),and the removal of electrons is associated with small impact *** energy distributions of the ionized electron are similar when the projectile energy is equal to,below or above the Bragg peak *** fragmentation cross sections after SI and SC in the energy range around the Bragg peak were also estimated.

关键词： Classical trajectory Monte Carlo Heavy ion-water molecule collision Inelastic cross sections

Increased contribution of microbial necromass to soil organic carbon in solar farms on the Tibetan Plateau

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Journal of Mountain Science 2025年第1期22卷 184-197页

作者： zhang Xiyu ZHOU Jun CHEN yang FAN Jianrong Institute of Mountain Hazards and Environment Chinese Academy of SciencesChengdu 610299China

Solar farms have been rapidly expanding on the Qinghai-Tibetan ***,the effects of photovoltaic arrays on the contribution of microbial necromass carbon(MNC)to soil organic carbon(SOC),along with the underlying mechanisms,remain *** address this,we collected soil samples from the top 20 cm in under-panel,inter-panel and control plots at five solar farms constructed between 2012 and 2014 in the dry Yarlung Tsangpo and Lhasa River valleys on the Qinghai-Tibetan *** determined SOC,fungal and bacterial necromass and relevant soil *** found that the concentration of MNC in the under-panel plots(3.93±0.79 mg g-1)was significantly higher compared to the control plots(2.28±0.79 mg g-1)across all five solar *** proportion of MNC to SOC in the under-panel plots(34.7±2.4%)was also significantly higher than that in the control plots(27.5±1.4%).Specifically,the contribution of fungal necromass to SOC in the under-panel plots(26.4±2.2%)was significantly larger than that in the control plots(19.7±1.6%),while the increase in the bacterial necromass proportion was *** least squares structural equation modeling(PLS-SEM)indicated a significant and positive effect of increased soil moisture in the under-panel plots on the proportion of fungal necromass to *** results highlight that beyond their economic benefits,solar farms in the arid regions on the Qinghai-Tibetan Plateau can enhance soil C sequestration by improving soil moisture and promoting microbial necromass accumulation.

关键词： Photovoltaic power station Fungal necromass Bacterial necromass Microbial residues Yarlung Tsangpo Arid river valley