检索结果-南通市图书馆

Enhanced thermoelectric performance enabled by compositing ZrO_(2)in n-type SiGe alloy with low thermal conductivity

引用

Rare Metals 2024年第3期43卷 1167-1176页

作者： Meng-Fei Wang Hua-Jun Lai Ji-Sheng Liang Jun-Liang Chen Wang-yang Ding Qi Zhou Ying Peng cheng-yan liu Lei Miao Guangxi Key Laboratory for Relativity Astrophysics State Key Laboratory of Featured Metal Materials and Life-Cycle Safety for Composite StructuresSchool of Physical Science and TechnologyGuangxi UniversityNanning530004China Guangxi Academy of Sciences Nanning530007China Key Laboratory of Information Material Engineering Research Center of Electronic Information Materials and DevicesGuilin University of Electronic TechnologyMinistry of EducationGuilin541004China Guangxi Key Laboratory of Precision Navigation Technology and Application School of Information and CommunicationGuilin University of Electronic TechnologyGuilin541004China

SiGe-based thermoelectric(TE)materials have gained increasing interests due to their low maintenance costs,environmental friendliness and long ***,the intrinsically high thermal conductivity of Si-based materials also results in poor TE *** this investigation,a zirconia(ZrO_(2))composite strategy was applied to an n-type SiGe alloy,tremendously elevating its TE *** mechanical alloying and spark plasma sintering(SPS)processes,the ZrO_(2)induced the formation of nanopores in the SiGe matrix via phosphorus ***,such increase in porosity enhanced the phonon scattering and dramatically suppressed lattice thermal conductivity,from 2.83 to 1.59 W·m^(-1)·K^(-1)at 873 ***,reduced phosphorus doping led to an increase in Seebeck coefficients and a relatively minor decrease in electrical conductivity,The power factor didn't deteriorate significantly,either,as its maximum of~3.43 mW·m^(-1-)K^(-2)was achieved at 873 K with(Si_(0.8)Ge_(0.2))_(0.097)P_(0.03)(ZrO_(2))_(0.003).In short,a peak figure of merit(ZT)of~1.27 at 873 K and an average ZT~0.7 from 323 to 873 K were *** study demonstrates that the electrical and thermal transportation of SiGe material can be synergistically tuned by compositing ZrO_(2),illustrating a novel strategy to optimize the TE properties of bulk materials.

关键词： Thermoelectric SiGe alloy ZrO2 composting P element adsorption nanopores

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

A Linear Perturbed Palais-Smale Condition for Lower Semicontinuous Functions on Banach Spaces

引用

Acta Mathematica Sinica,English Series 2008年第11期24卷 1853-1860页

作者： Li Xing cheng Xiao yan liu Mai Fang ZUO Department of Mathematics Xiamen University Xiamen 361005 P. R. China

This paper introduces a notion of linear perturbed Palais-Smale condition for real-valued functions on Banach spaces. In terms of strongly exposed points, it presents a characterization which guarantees linear perturbed Palais-Smale condition holds for lower semicontinuous functions with bounded effective domains defined on a Banach space with the Radon-Nikody＇m property; and gives an example showing that linear perturbed P-S condition is strictly weaker than the P-S condition.

关键词： Palais-Smale condition variational question perturbed optimization Radon-Nikody'm property Banach space

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Effects of N-1 substituent on the phototoxicity of fluoroquinolone antibiotics: comparison of pefloxacin and difloxacin

引用

Nuclear Science and Techniques 2020年第7期31卷 34-45页

作者： Jian-Feng Zhao yan-cheng liu Yu-Lie Xu Wen-Feng Wang Shanghai Institute of Applied Physics Chinese Academy of SciencesShanghai 201800China University of Chinese Academy of Science Beijing 100049China

The photophysics and photochemistry of pefloxacin(PEF),a 1-ethyl-substituted fluoroquinolone(FQ)antibiotic,were studied using transient,steady-state experimental methods and computational *** fundamental photoproperties of PEF and its phototoxicity toward lysozyme,a single-chain protein,were compared with those of a 1-fluorophenyl-substituted FQ antibiotic,difloxacin(DIF).The results showed that the phototoxicity was significantly decreased by the insertion of the bulky1-fluorophenyl substituent(the phototoxicity of DIF was approximately one-quarter of that observed for PEF).This trend was attributed to the lowest lying singlet state with sizeable oscillator strength(f C 0.1)being shifted from319 nm in PEF to 266 nm in DIF upon the insertion of the bulky substituent at the 1-position,as investigated by using computational *** addition,95%of the solar UV irradiation that reaches the earth’s surface has wavelength[315 ***,reducing the most effective excitation wavelength by optimizing the substituent at the1-position may be a promising strategy to alleviate the phototoxicity of FQ *** findings may be applied to other FQ antibiotics because a large number of phototoxicity studies on FQ antibiotics with different substituents at the 1-position can prove these finding’s ***,an FQ antibiotic bearing a chlorine and bulky substituent at the 8-and 1-positions,respectively,exhibits no phototoxicity is the most recent example reported to *** the best of our knowledge,this is the first transient and steady-state study of the effect of the N-1 substituent on the photochemistry and phototoxicity of FQ *** findings will be beneficial to the development of novel FQ antibiotics without phototoxicity.

关键词： substituent transient photochemistry

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Model-driven path planning for robotic plasma cutting of branch pipe with single Y-groove based on pipe-rotating scheme

引用

Advances in Manufacturing 2024年第1期12卷 94-107页

作者： yan liu Qiu Tang Xin-cheng Tian School of Control Science and Engineering Shandong UniversityJinan250061People’s Republic of China Engineering Research Center of Intelligent Unmanned System Ministry of EducationJinan250061People’s Republic of China School of Mechanical and Electronic Engineering Shandong Jianzhu UniversityJinan250101People’s Republic of China

The automatic cutting of intersecting pipes is a challenging task in *** improved automation and accuracy,this paper proposes a model-driven path planning approach for the robotic plasma cutting of a branch pipe with a single ***,it summarizes the intersection forms and introduces a dual-pipe intersection *** on this model,the moving three-plane structure(a description unit of the geometric characteristics of the intersecting curve)is constructed,and a geometric model of the branch pipe with a single Y-groove is ***,a novel mathematical model for plasma radius and taper compensation is ***,the compensation model and groove model are integrated by establishing movable ***,to prevent collisions between the plasma torch and workpiece,the torch height is planned and a branch pipe-rotating scheme is *** the established models and moving frames,the planned path description of cutting robot is provided in this novel *** accuracy of the proposed method is verified by simulations and robotic cutting experiments.

关键词： Automatic groove cutting of intersecting pipes Model-driven robot path planning Plasma beam radius and taper compensation

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Ytterbium modified birnessite MnO_(2) for improving deep oxidation of toluene

引用

Journal of Rare Earths 2024年第4期42卷 668-675页

作者： Linjiang Sun yan cheng Yujie liu Can Yi Faculty of Geosciences and Environmental Engineering Southwest Jiaotong UniversityChengdu611756China

A series of rare earth metals modified birnessite manganese dioxides(RE-Mn)was synthesized by hydrothermal method and their catalytic degradation of toluene was ***-Mn shows the best toluene oxidation activity with the conversion of T50%and T99%at 196 and 226℃,*** physiochemical characterizations identified that the high catalytic performance and excellent stability of Yb-Mn are mainly associated with its higher molar ratios of Mn^(4+)/Mn^(3+),more lattice oxygen(Olatt),and better mobility of surface adsorbed oxygen(O_(ads)).Moreover,it is confirmed that introduction of Yb into birnessite MnO_(2) facilitates the production of acetic acid at lower *** results can aid the design of high-efficiency manganese oxide catalysts for the catalytic combustion of VOCs.

关键词： Manganese oxide Rare earth metal doping Toluene Catalytic combustion

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Geometry and formation mechanism of tension gashes and their implication on the hydrocarbon accumulation in the deep-seated strata of sedimentary basin:A case from Shunnan area of Tarim Basin

引用

Petroleum Science 2024年第1期21卷 87-99页

作者： yan-Nan Du Kong-You Wu Yin liu yan-Ying Li Zi-cheng Cao You-Wei Cui Jun liu Key Laboratory of Deep Oil and Gas School of GeosciencesChina University of Petroleum(East China)Qingdao 266580ShandongChina Exploration and Development Research Institute SINOPEC Northwest Oilfield BranchUrumqi 830011XinjiangChina The Fifth Gas Production Plant Changqing OilfieldPetroChinaXi'an 710018ShaanxiChina

With the theoretical and technological developments related to cratonic strike-slip faults,the Shuntuoguole Low Uplift in the Tarim Basin has attracted considerable attention *** by multi-stage tectonic movements,the strike-slip faults have controlled the distribution of hydrocarbon resources owing to the special fault characteristics and fault-related *** contrast,the kinematics and formation mechanism of strike-slip faults in buried sedimentary basins are difficult to investigate,limiting the discussion of these faults and hydrocarbon *** this study,we identified the characteristics of massive sigmoidal tension gashes(STGs)that formed in the Shunnan area of the Tarim ***-resolution three-dimensional seismic data and attribute analyses were used to investigate their geometric and kinematic ***,the stress state of each point of the STGs was calculated using seismic curvature ***,the formation mechanism of the STGs and their roles in controlling hydrocarbon migration and accumulation were *** results suggest that:(1)the STGs developed in the Shunnan area have a wide distribution,with a tensile fault arranged in an enéchelon pattern,showing an S-shaped *** STGs formed in multiple stages,and differential rotation occurred along the direction of strike-slip stress during formation.(2)Near the principal displacement zone of the strike-slip faults,the stress value of the STGs was higher,gradually decreasing at both *** shallow layer deformation was greater than the deep layer deformation.(3)STGs are critical for connecting source rocks,migrating oil and gas,sealing horizontally,and developing efficient *** study not only provides seismic evidence for the formation and evolution of super large STGs,but also provides certain guidance for oil and gas exploration in this area.

关键词： Tarim Basin Sigmoidal tension gashes Seismic attributes Shear stress calculation Formation mechanism Reservoir control

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Defects in the grain interiors of 3 mol%yttria-stabilized tetragonal zirconia polycrystal ceramics with 0.25 wt%alumina

引用

Journal of Advanced Ceramics 2024年第4期13卷 469-477页

作者： yan Xiong Lian Luo Yao cheng Zhi liu Qi liu Weimin Wang Wei Ji School of Materials&Chemical Engineering Hubei Province Key Laboratory of Green Materials for Light IndustryHubei University of TechnologyWuhan 430068China Fujian Institute of Research on the Structure of Mater Chinese Academy of SciencesFuzhou 350002China Jiangxi Provincial Engineering Research Center for Multifunction Zirconia Materials Jiangxi Size Materials Co.Ltd.Jiujiang 332500China State Key Laboratory of Advance Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China

The presence of high-density defects is rarely observed in bulk 3 mol%yttria-stabilized tetragonal zirconia polycrystal(3Y-TZP)ceramics obtained through conventional pressureless *** the present work,fine-grained dense 147 nm 3Y-TZP ceramics were prepared by pressureless sintering of commercial 0.25 wt%alumina-doped zirconia powders at 1300℃.A novel discovery was reported in which large amounts of defects were present in the grain interiors of the *** phenomenon was further examined using three types of powder samples,and the reasons for defect formation were investigated by microstructural characterization using high-resolution transmission electron microscopy(HRTEM)analysis and Rietveld *** results confirmed the essential dependence of the defect formation on the alumina *** authors attributed the defect formation to the significant difference in ionic radii of the solvent and solute during the dissolution of alumina into the zirconia *** sintering kinetics were proposed to be enhanced by the presence of substantial defects,which consequently favored the low-temperature sintering of the alumina-doped zirconia ceramics.

关键词： 3 mol%yttria-stabilized tetragonal zirconia polycrystal(3Y-TzP)ceramics alumina addition microstructure defect

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

BaCe_(0.8)Fe_(0.1)Ni_(0.1)O_(3−δ)-impregnated Ni-GDC by phase-inversion as an anode of solid oxide fuel cells with on-cell dry methane reforming

引用

Journal of Advanced Ceramics 2024年第6期13卷 834-841页

作者： yanya liu Jun Luo cheng Li Bo liu Dong yan Jian Li Lichao Jia School of Materials Science and Engineering State Key Laboratory of Materials Processing and Die&Mould TechnologyHuazhong University of Science and TechnologyWuhan 430074China

BaCe_(0.8)Fe_(0.1)Ni_(0.1)O_(3−δ)(BCFN)in a perovskite structure is impregnated consecutively by BCFN solution and BCFN suspension into a phase-inversion prepared NiO–Gd_(0.1)Ce_(0.9)O_(2−δ)(GDC)scaffold as an anode for solid oxide fuel cells(SOFCs)with on-cell dry reforming of methane(DRM).The whole pore surface of the scaffold is covered by small BCFN particles formed by BCFN solution impregnation;the large pores near the scaffold surface are filled by BCFN aerogels with a high specific surface area produced by BCFN suspension impregnation,which act as a catalytic layer for on-cell *** reduction,the anode consists of a Ni–GDC scaffold and BCFN particles with exsolved FeNi3 *** BCFN-impregnated Ni–GDC anode has higher electrical conductivity,electrochemical activity,and resistance to carbon deposition,with which the cell shows maximum power densities between 1.44 and 0.92 W·cm^(−2) when using H_(2) and between 1.09 and 0.50 W·cm^(−2) when using CO_(2)–CH_(4) at temperatures ranging from 750 to 600℃.A stable performance at 400 mA·cm^(−2) and 700℃is achieved using 45%CO_(2)–45%CH_(4)–10%N_(2) for more than 400 h without carbon deposition,benefiting from the impregnated BCFN aerogel with a high specific surface area and water adsorbability.

关键词： aerogel solid oxide fuel cells(SOFCs) phase-inversion dry reforming of methane(DRM) carbon resistance

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Insights into Formation and Li-Storage Mechanisms of Hierarchical Accordion-Shape Orthorhombic CuNb_(2)O_(6) toward Lithium-Ion Capacitors as an Anode-Active Material

引用

Energy & Environmental Materials 2024年第2期7卷 287-298页

作者： Chao cheng Yunsheng yan Minyu Jia yang liu Linrui Hou Changzhou Yuan School of Material Science and Engineering University of JinanJinan 250022China

The orthorhombic CuNb_(2)O_(6)(O-CNO)is established as a competitive anode for lithium-ion capacitors(LICs)owing to its attractive compositional/structural ***,the high-temperature synthesis(>900℃)and controversial charge-storage mechanism always limit its ***,we develop a low-temperature strategy to fabricate a nano-blocks-constructed hierarchical accordional O-CNO framework by employing multilayered Nb_(2)CT_(x)as the niobium *** intrinsic stress-induced formation/transformation mechanism of the monoclinic CuNb_(2)O_(6)to O-CNO is tentatively put ***,the integrated phase conversion and solid solution lithium-storage mechanism is reasonably unveiled with comprehensive in(ex)situ *** to its unique structural merits and lithium-storage process,the resulted O-CNO anode is endowed with a large capacity of 150.3 mAh g^(-1)at 2.0 A g^(-1),along with long-duration cycling ***,the constructed O-CNO-based LICs exhibit a high energy(138.9 Wh kg^(-1))and power(4.0 kW kg^(-1))densities with a modest cycling stability(15.8%capacity degradation after 3000 consecutive cycles).More meaningfully,the in-depth insights into the formation and charge-storage process here can promote the extensive development of binary metal Nb-based oxides for advanced LICs.

关键词： high-rate anodes lithium-ion capacitors lithium-storage mechanisms orthorhombic CuNb_(2)O_(6) phase transform

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Unusual photocarrier and coherent phonon dynamics behaviors of layered PdSe_(2)unveiled by ultrafast spectroscopy of the edge surface

引用

Science China(Physics,Mechanics & Astronomy) 2024年第8期67卷 143-152页

作者： Tiantian Yun Changfu Huo Jinluo cheng Zhi-Bo liu Xiao-Qing yan Key Laboratory of Weak-Light Nonlinear Photonics Ministry of EducationSchool of PhysicsNankai UniversityTianjin 300071China Collaborative Innovation Center of Extreme Optics Shanxi UniversityTaiyuan 030006China GPL Photonics Laboratory Key Laboratory of Luminescence Science and TechnologyChinese Academy of Sciences&State Key Laboratory of Luminescence Science and ApplicationsChangchun Institute of OpticsFine Mechanics and PhysicsChinese Academy of SciencesChangchun 130033China

Layered materials exhibit different electronic and phonon properties along in-plane and out-of-plane directions;existing studies focus on their in-plane behaviors,and the influence of such anisotropies on the dynamics of photocarriers and phonons is ***,we fabricate layered PdSe_(2)crystals with flat edge surfaces and compare the time-resolved ultrafast spectroscopies on their basal and edge *** differences in the transient reflection spectroscopies reveal the inconsistent photocarrier and phonon dynamics behaviors on the two surfaces:the slow hot carrier relaxation process is accelerated and the thermoelasticity-induced longitudinal coherent acoustic phonon oscillation completely vanishes on the edge surface,as compared with the basal *** analysis reveals that the inconsistent hot carrier dynamics originate from the anisotropic properties of low-energy phonons in PdSe_(2),and the absence of phonon oscillation on the edge surface results from the wavevector-limited sensitivity of acoustic B_(1u)***,polarization-dependent spectroscopies indicate the diverse optical anisotropies beyond the in-plane of PdSe_(2).This work provides a new method to explore unique physical properties and modulate the optical anisotropy of layered materials.

关键词： PdSe_(2) ultrafast spectroscopy edge surface carrier dynamics coherent phonon oscillation anisotropy

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：