检索结果-南通市图书馆

Fabrication of Molecularly Imprinted Electrospun Nanofibers with Mono-amidoxime Functional Ligand for Efficient Decontamination of Toxic Organophosphates

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Chinese Journal of Polymer Science 2024年第4期42卷 446-456页

作者： Lan Wang peng Jiang Ya-Lin Niu Jun-peng cao Tian-Ying Guo Key Laboratory of Functional Polymer Materials Ministry of EducationInstitute of Polymer ChemistryCollege of Chemistry and Frontier Science Center for the Creation of New Organic SubstancesNankai UniversityTianjin300071China

There is an urgent imperative to discover practical and efficacious artificial catalysts for the expeditious decontamination of toxic organophosphates. Herein, we propose a novel molecularly imprinted approach utilizing electrospun fiber scaffolds. Specifically, an amidoxime-based functional polymer (PMAOX) has been synthesized, which contains amidoxime groups that can act as nucleophiles and ligands for the formation of catalytic active sites. This polymer was blended with polyacrylonitrile (PAN), a well-processable material, to prepare a nanofiber mat using electrospinning techniques. Then, the amidoxime side groups on fiber surface were further cross-linked after the molecular coordination of templates to complete the molecularly imprinting process. This approach can not only enhance the content of functional molecularly imprinted polymers without affecting structural stability, but also combines surface MI technology to fully expose and leverage the advantages of active sites. The as prepared molecularly imprinted electrospun nanofibers MIF-Zn-PMAOX/PAN-6/4 catalyzes the degradation of paraoxon with a half-life of 32 min, and MIF-Ag-PMAOX/PAN catalyzes the degradation of parathion with a half-life of 18 min. The maximum catalytic rate evidence rate enhancements nearly 3700-fold of the self-hydrolysis. Thus, the mono-amidoxime based molecularly imprinted fibers demonstrate the versatility and superiority as self-detoxifying for organophosphates.

关键词： Organophosphateshydrolysis Electrospinning Molecular imprinting

维普期刊数据库

Numerical simulation analysis of wind field above pavement surface in different landforms by computational fluid dynamics approach

在线全文

学校读者我要写书评

暂无评论

Journal of Traffic and Transportation Engineering(English Edition) 2024年第3期11卷 559-573页

作者： Jian Ouyang Zhao Jiang Leiyu Ye Jing Li peng cao School of Civil Engineering and Architecture Hainan UniversityHaikou 570000China School of Transportation and Logistics Dalian University of TechnologyDalian 116024China Hexagon Manufacturing Intelligence(Qingdao)Co. Ltd.Qingdao 266000China China Tower Co. Ltd.Dalian BranchDalian 116024China Faculty of Architecture Civil and Transportation EngineeringBeijing University of TechnologyBeijing 100124China

The temperature and moisture of the pavement structure can be greatly influenced by the wind speed above pavement *** wind speed above pavement surface not only is dominated by the wind speed of atmosphere,but also it is highly related to the landform and buildings around ***,currently there are no studies about the wind field above pavement surface in consideration of the effect of the landform and buildings.A simulation method,which is combined with geographic information system(GIS),wind data from meteorological observatory and computational fluid dynamics(CFD)software,is employed to study the effect of the landform and the wind speed of atmosphere on the wind field above pavement *** cases are studied,including an urban road,a coastal road and a mountainous ***,the wind field distribution above road surface in different wind directions was studied in our *** indicate that the wind field above pavement surface can be greatly affected by the landforms,buildings and wind *** simulation method can provide reliable results for the wind field above pavement *** maximum relative errors between simulated and measured wind speed can be less than 20%in the analysis of the three *** is recommended that the CFD simulation method is a good tool to accurately know the wind field above pavement surface.

关键词： Wind field above pavement surface Computational fluid dynamics Landforms Geographic information system Simulation

维普期刊数据库

Current controversies in glia-to-neuron conversion therapy in neurodegenerative diseases

在线全文

学校读者我要写书评

暂无评论

Neural Regeneration Research 2024年第4期19卷 723-724页

作者： peng cao Jianan Li Zhuxi Liu Guobiao Liang Department of Neurosurgery General Hospital of the Northern Theater Command of Chinese People's Liberation Army Key Laboratory of Precision Medical Research on Major Chronic Disease Shengjing Hospital of China Medical University

Loss of neurons and disruption of neural circuits are associated with many neurological diseases,including neurodegenerative diseases and mental *** most prevalent pathological feature of neurodegenerative diseases is the aggregate loss of certain neuronal *** example,the loss of dopamine(DA)neurons in the substantia nigra pars compacta has been defined as a pathological hallmark of Parkinson’s disease(PD;Kamath et al.,2022).

关键词： diseases degenerative al.

维普期刊数据库

Correlation of preoperative inflammatory factors and emotional disorders with postoperative delirium in patients with craniocerebral trauma

在线全文

学校读者我要写书评

暂无评论

World Journal of Psychiatry 2024年第7期14卷 1043-1052页

作者： peng cao Zhe-Yong Jia Tao Zheng Tao Mei Department of Neurosurgery Changde HospitalXiangya School of MedicineCentral South University(The First People’s Hospital of Changde City)Changde 415003Hunan ProvinceChina

BACKGROUND Traumatic brain injury(TBI)imposes a substantial societal and familial burden due to its high disability and fatality rates,rendering it a serious public health *** patients with TBI have poor treatment outcomes and are prone to postoperative delirium(POD),which affects their quality of *** has been linked to increased POD incidence in some studies,while others have found no *** To investigate the correlation of POD risk factors,preoperative inflammatory factors,and mood disorders in patients with *** We retrospectively collected data on the treatment of 80 patients with TBI from November 2021 to September *** were grouped as POD and non-POD,according to their POD status,and the general data of the two groups were *** factor levels were detected preoperatively,and the Hamilton Depression Scale(HAMD)and Hamilton Anxiety Scale(HAMA)were used to investigate the risk factors associated with POD in these *** regression was used to identify the independent risk *** Twenty-one patients(26.25%)developed POD,including 7,10,and 4 cases of the excitatory,inhibitory,and mixed types,*** were 59 cases(73.75%)in the non-POD *** with the non-POD group,the POD group had a significantly higher proportion of patients with low Glasgow Coma Scale(GCS)scores before admission,unilateral mydriasis,preoperative hemorrhagic shock,intraventricular hemorrhage(IVH),and postoperative hyperglycemic hyperosmolar disease(P<0.05).In the POD group,interleukin-6(IL-6),human tumor necrosis factor-α(TNF-α),myeloperoxidase levels,HAMA,and HAMD scores were higher than those in the non-POD group(all P<0.05).Logistic multivariate analysis showed that GCS score at admission,IVH,IL-6,TNF-α,HAMA,and HAMD were independent risk factors for POD in patients with TBI(P<0.05).CONCLUSION Low GCS score at admission,IVH,elevated IL-6 and TNF-α,other inflammatory indicators,anxiety,and depress

关键词： Inflammatory factors Mood disorders Traumatic brain injury Postoperative delirium Relevance Risk factor

An Involution over Dyck Paths Related with Stirling Statistics

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of Mathematical Research with Applications 2024年第04期44卷 437-443页

作者： peng cao Joanna N.CHEN College of Science Tianjin University of Technology

We construct an involution over Dyck paths, which implies the distribution of statistics “the number of peak”, “the number of returns” and “the height of the last peak”. As an application, equidistributions of s... 详细信息

关键词： involutions Dyck paths pattern peak returns

Research on Quantitative Identification of Three-Dimensional Connectivity of Fractured-Vuggy Reservoirs

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Energy Engineering 2024年第5期121卷 1195-1207页

作者： Xingliang Deng peng cao Yintao Zhang Yuhui Zhou Xiao Luo Liang Wang Exploration and Development Research Institute PetroChina Tarim Oilfield CompanyKorla841000China PetroChina Hangzhou Research Institute of Geology Hangzhou310023China School of Petroleum Engineering Yangtze UniversityWuhan430100China

The fractured-vuggy carbonate oil resources in the western basin of China are extremely *** connectivity of carbonate reservoirs is complex,and there is still a lack of clear understanding of the development and topological structure of the pore space in fractured-vuggy ***,effective prediction of fractured-vuggy reservoirs is *** view of this,this work employs adaptive point cloud technology to reproduce the shape and capture the characteristics of a fractured-vuggy *** identify the complex connectivity among pores,fractures,and vugs,a simplified one-dimensional connectivity model is established by using the meshless connection element method(CEM).Considering that different types of connection units have different flow characteristics,a sequential coupling calculation method that can efficiently calculate reservoir pressure and saturation is *** automatic history matching,the dynamic production data is fitted in real-time,and the characteristic parameters of the connection unit are *** results show that the three-dimensional connectivity model of the fractured-vuggy reservoir built in this work is as close as 90%of the fine grid model,while the dynamic simulation efficiency is much higher with good accuracy.

关键词： Fractured-vuggy reservoir three-dimensional connectivity connection unit dynamic prediction automatic history matching

Influence of reduced-port laparoscopic surgery on perioperative indicators, postoperative recovery, and serum inflammation in patients with colorectal carcinoma

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

World Journal of Gastrointestinal Surgery 2024年第6期16卷 1734-1741页

作者： Hong-Biao Wu Dong-Fang Liu Ye-Lei Liu Xiao-Feng Wang Yue-peng cao Department of Colorectal Surgery The First Affiliated Hospital of Ningbo UniversityNingbo 315000Zhejiang ProvinceChina

BACKGROUND Conventional five-port laparoscopic surgery,the current standard treatment for colorectal carcinoma(CRC),has many *** To assess the influence of reduced-port laparoscopic surgery(RPLS)on perioperative indicators,postoperative recovery,and serum inflammation indexes in patients with *** The study included 115 patients with CRC admitted between December 2019 and May 2023,52 of whom underwent conventional five-port laparoscopic surgery(control group)and 63 of whom underwent RPLS(research group).Comparative analyses were performed on the following dimensions:Perioperative indicators[operation time(OT),incision length,intraoperative blood loss(IBL),and rate of conversion to laparotomy],postoperative recovery(first postoperative exhaust,bowel movement and oral food intake,and bowel sound recovery time),serum inflammation indexes[high-sensitivity C-reactive protein(hs-CRP),tumor necrosis factor-α(TNF-α),and interleukin-6(IL-6)],postoperative complications(anastomotic leakage,incisional infection,bleeding,ileus),and therapeutic *** The two groups had comparable OTs and IBL ***,the research group had a smaller incision length;lower rates of conversion to laparotomy and postoperative total complication;and shorter time of first postoperative exhaust,bowel movement,oral food intake,and bowel sound recovery;all of which were ***,hs-CRP,IL-6,and TNF-αlevels in the research group were significantly lower than the baseline and those of the control group,and the total effective rate was *** RPLS exhibited significant therapeutic efficacy in CRC,resulting in a shorter incision length and a lower conversion rate to laparotomy,while also promoting postoperative recovery,effectively inhibiting the inflammatory response,and reducing the risk of postoperative complications.

关键词： Reduced-port laparoscopic surgery Colorectal carcinoma Perioperative indicators Postoperative recovery Serum inflammation indexes

Brain circuits for retching-like behavior

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

National Science Review 2024年第1期11卷 145-160页

作者： Lifang Huo Zhimin Ye Meiling Liu Ziqing He Meizhu Huang Dapeng Li Qian Wu Qian Wang Xiaoqun Wang peng cao Ji Dong Congping Shang School of Basic Medical Sciences Guangzhou National Laboratory The Fifth Afflliated Hospital Guangzhou Medical University Bioland Laboratory (Guangzhou Regenerative Medicine and Health Guangdong Laboratory) Department of Neurobiology School of Basic Medical Sciences Beijing Key Laboratory of Neural Regeneration and Repair Advanced Innovation Center for Human Brain Protection Capital Medical University State Key Laboratory of Cognitive Neuroscience and Learning IDG/McGovern Institute for Brain Research Beijing Normal University Changping Life Science Laboratory National Institute of Biological Sciences

Nausea and vomiting are important defensive responses to cope with pathogens and toxins that invade the body. The nucleus of the solitary tract(NTS) is important for initiating these responses. However, the molecular heterogeneities and cellular diversities of the NTS occlude a better understanding of these defensive responses. Here, we constructed the single-nucleus transcriptomic atlas of NTS cells and found multiple populations of NTS neurons that may be involved in these defensive responses. Among these, we identified Calbindin1-positive(Calb1+) NTS neurons that are molecularly distinct from Tac1+*** Calb1+neurons are critical for nausea and retching induced by cereulide; an emetic toxin secreted by Bacillus Cereus. Strikingly, we found that cereulide can directly modulate vagal sensory neurons that innervate Calb1+NTS neurons, a novel mechanism distinct from that for nausea and retching induced by Staphylococcal enterotoxin A. Together, our transcriptomic atlas of NTS neurons and the functional analyses revealed the neural mechanism for cereulide-induced retching-like behavior. These results demonstrate the molecular and cellular complexities in the brain that underlie defensive responses to the diversities of pathogens and toxins.

关键词： vomiting nausea nucleus of the solitary tract Calbindin1 neural circuits

Modification of the CuO electronic structure for enhanced selective electrochemical CO_(2) reduction to ethylene

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Nano Research 2024年第8期17卷 7194-7202页

作者： Xin Wu Zhuang Tong Yunliang Liu Yaxi Li Yuanyuan Cheng Jingwen Yu peng cao Chunqiang Zhuang Qiuzhong Shi Naiyun Liu Xiang Liu Hongyu Liang Haitao Li Institute for Energy Research School of Energy and Power EngineeringJiangsu UniversityZhenjiang 212013China Faculty of Materials and Manufacturing Beijing University of TechnologyBeijing 100124China Institute of Medicine&Chemical Engineering Zhenjiang CollegeZhenjiang 212013China Institute of Advanced Manufacturing and Modern Equipment Technology School of Mechanical EngineeringJiangsu UniversityZhenjiang 212013China

Electrochemical carbon dioxide reduction reaction(CO_(2)RR)can produce value-added hydrocarbons from renewable electricity,providing a sustainable and promising approach to meet dual-carbon targets and alleviate the energy ***,it is still challenging to improve the selectivity and stability of the products,especially the C^(2+) *** we propose to modulate the electronic structure of copper oxide(CuO)through lattice strain construction by zinc(Zn)doping to improve the selectivity of the catalyst to *** performance and in situ characterization analyses show that the compressive strain generated within the CuO lattice and the electronic structure modulation by Zn doping enhances the adsorption of the key intermediate*CO,thereby increasing the intrinsic activity of CO_(2)RR and inhibiting the hydrogen precipitation *** the best catalysts had significantly improved ethylene selectivity of 60.5%and partial current density of 500 mA·cm^(–2),and the highest C^(2+) Faraday efficiency of 71.47%.This paper provides a simple idea to study the modulation of CO_(2)RR properties by heteroatom doped and lattice strain.

关键词： CO_(2) reduction heteroatom-doped lattice strain ethylene selectivity