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Dual‑Donor‑Induced crystallinity Modulation Enables 19.23% Efficiency Organic Solar cells

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Nano-Micro Letters 2025年第3期17卷 376-388页

作者： Anhai Liang Yuqing Sun Sein chung jiyeong Shin Kangbo Sun chaofeng Zhu jingjing zhao Zhenmin zhao Yufei Zhong Guangye Zhang Kilwon cho Zhipeng Kan center On Nanoenergy Research Institute of Science and Technology for Carbon Peak&NeutralitySchool of Physical Science&TechnologyGuangxi UniversityNanning 530004People’s Republic of China Department of chemical Engineering Pohang University of Science and TechnologyPohang 37673South Korea college of New Materials and New Energies Shenzhen Technology UniversityShenzhen 518118People’s Republic of China Zhejiang Engineering Research center for Fabrication and Application of Advanced Photovoltaic Materials School of Materials Science and EngineeringNingboTech UniversityNingbo 315100People’s Republic of China State Key Laboratory of Featured Metal Materials and Life-cycle Safety for composite Structures Nanning 530004People’s Republic of China

Trap-assisted charge recombination is one of the primary limitationsof restricting the performance of organic solar cells. However, effectivelyreducing the presence of traps in the photoactive layer remains ***, wide bandgap polymer donor PTzBI-dF is demonstrated as an effectivemodulator for enhancing the crystallinity of the bulk heterojunction active layerscomposed of D18 derivatives blended with Y6, leading to dense and orderedmolecular packings, and thus, improves photoluminescence quenching *** a result, the photovoltaic devices exhibit reduced trap-assisted charge recombinationlosses, achieving an optimized power conversion efficiency of over 19%.Besides the efficiency enhancement, the devices comprised of PTzBI-dF as athird component simultaneously attain decreased current leakage, improved chargecarrier mobilities, and suppressed bimolecular charge recombination, leading toreduced energy losses. The advanced crystalline structures induced by PTzBI-dFand its characteristics, such as well-aligned energy level, and complementaryabsorption spectra, are ascribed to the promising performance *** findings suggest that donor phase engineering is a feasible approach to tuning the molecular packings in the active layer, providingguidelines for designing effective morphology modulators for high-performance organic solar cells.

关键词： Trap-assisted charge recombination Photoluminescence Miscibility current leakage Power conversion efficiency

Summarizing the evidence for robotic-assisted bladder neck reconstruction: Systematic review of patency and incontinence outcomes

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Asian journal of Urology 2024年第3期11卷 341-347页

作者： Tenny R.Zhang Ashley Alford Lee c.zhao Department of Urology NewYork-Presbyterian Hospital/Weill Cornell MedicineNew YorkNYUSA Department of Urology NYU Langone Medical CenterNew YorkNYUSA

Objective:Bladder neck contracture and vesicourethral anastomotic stenosis are difficult to manage endoscopically,and open repair is associated with high rates of *** recent years,there have been increasing reports of robotic-assisted bladder neck reconstruction in the ***,existing studies are small,heterogeneous case *** objective of this study was to perform a systematic review of robotic-assisted bladder neck reconstruction to better evaluate patency and incontinence ***:We performed a systematic review of PubMed from first available date to May 2023 for all studies evaluating robotic-assisted reconstructive surgery of the bladder neck in adult *** in non-English,author replies,editorials,pediatric-based studies,and reviews were *** of interest were patency and incontinence rates,which were pooled when ***:After identifying 158 articles on initial search,we included only ten studies that fit all aforementioned criteria for robotic-assisted bladder neck *** were case series published from March 2018 to March 2022 ranging from six to 32 men,with the median follow-up of 5e23 months.A total of 119 patients were included in our analysis.A variety of etiologies and surgical techniques were *** rates ranged from 50%to 100%,and pooled patency was 80%(95/119).De novo incontinence rates ranged from 0%to 33%,and pooled incontinence was 17%(8/47).Our findings were limited by small sample sizes,relatively short follow-ups,and heterogeneity between studies.

关键词： Bladder neck continence Incontinence Patency Posterior urethra Reconstructive surgery Robotic surgery Stenosis Stricture Surgical outcome

Low-cost and fluoride-free synthesis of MFI zeolite nanosheets with enhanced stability for benzene alkylation with ethanol

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journal of Energy chemistry 2025年第1期100卷 458-468页

作者： Peng Zhu cun Liu Yiren Yu Guoshu Gao Yumeng zhao Xiongfu Zhang Guodong Liu Guohui Yang State Key Laboratory of Fine chemicals School of Chemical Engineering Dalian University of Technology State Key Laboratory of catalysis Dalian Institute of Chemical Physics Chinese Academy of Sciences

Zeolite nanosheets with a short b-axis thickness are highly desirable in lots of catalytic reactions due to their reduced diffusion resistance. Nevertheless, conventional synthesis methods usually require expensive structure-directing agents(SDAs), pricey raw materials, and eco-unfriendly fluorine-containing additives. Here, we contributed a cost-effective and fluoride-free synthesis method for synthesizing high-quality MFI zeolite nanosheets through a Silicalite-1(Sil-1) seed suspension and urea cooperative strategy, only with inexpensive colloidal silica as the Si source. Our approach was effective for synthesizing both Sil-1 and aluminum-containing ZSM-5 nanosheets. By optimizing key synthesis parameters,including seed aging time, seed quantity, and urea concentration, we achieved precise control over the crystal face aspect ratio and b-axis thickness. We also revealed a non-classical oriented nanosheet growth mechanism, where Sil-1 seeds induced the formation of quasi-ordered precursor particles, and the(010)crystal planes of these particles facilitated urea adsorption, thereby promoting c-axis-oriented *** obtained ZSM-5 nanosheets exhibited exceptional catalytic performance in the benzene alkylation with ethanol, maintaining stability for over 500 h, which is 5 times longer than traditional ZSM-5 catalysts. Furthermore, large-scale production of ZSM-5 nanosheets was successfully carried out in a 3 L highpressure autoclave, yielding samples consistent with those from laboratory-scale synthesis. This work marks a significant step forward in the sustainable and efficient production of MFI nanosheets using inexpensive and environmentally friendly raw materials, offering the broad applicability in catalysis.

关键词： Aspect ratio

A functional tacrolimus-releasing nerve wrap for enhancing nerve regeneration following surgical nerve repair

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Neural Regeneration Research 2025年第1期20卷 291-304页

作者： Simeon c.Daeschler Katelyn j.W.So Konstantin Feinberg Marina Manoraj jenny cheung jennifer Zhang Kaveh Mirmoeini jPaul Santerre Tessa Gordon Gregory HBorschel SickKids Research Institute Neuroscience and Mental Health ProgramTorontoONCanada Institute of Biomaterials and Biomedical Engineering University of TorontoTorontoONCanada Indiana University School of Medicine IndianapolisINUSA Division of Plastic and Reconstructive Surgery the Hospital for Sick ChildrenTorontoONCanada Translational Biology and Engineering Program Ted Rogers Centre for Heart ResearchInstitute of Biomedical EngineeringFaculty of DentistryUniversity of TorontoTorontoONCanada

Axonal regeneration following surgical nerve repair is slow and often incomplete,resulting in poor functional recovery which sometimes contributes to lifelong ***,there are no FDA-approved therapies available to promote nerve *** accelerates axonal regeneration,but systemic side effects presently outweigh its potential benefits for peripheral nerve *** authors describe herein a biodegradable polyurethane-based drug delivery system for the sustained local release of tacrolimus at the nerve repair site,with suitable properties for scalable production and clinical application,aiming to promote nerve regeneration and functional recovery with minimal systemic drug *** is encapsulated into co-axially electrospun polycarbonate-urethane nanofibers to generate an implantable nerve wrap that releases therapeutic doses of bioactive tacrolimus over 31 *** and drug loading are adjustable for applications in small and large caliber nerves,and the wrap degrades within 120 days into biocompatible *** released from the nerve wrap promotes axon elongation in vitro and accelerates nerve regeneration and functional recovery in preclinical nerve repair models while off-target systemic drug exposure is reduced by 80%compared with systemic *** its surgical suitability and preclinical efficacy and safety,this system may provide a readily translatable approach to support axonal regeneration and recovery in patients undergoing nerve surgery.

关键词： biodegradable local drug delivery nerve injury nerve regeneration nerve wrap tacrolimus

A quasi-in-situ EBSD study of the thermal stability and grain growth mechanisms of cocrNi medium entropy alloy with gradient-nanograined structure

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journal of Materials Science & Technology 2022年第14期109卷 54-63页

作者： P.-c.zhao B.Guan Y.-G.Tong R.-Z.Wang X.Li X.-c.Zhang S.-T.Tu Key Laboratory of Pressure Systems and Safety Ministry of EducationSchool of Mechanical and Power EngineeringEast China University of Science and TechnologyShanghai 200237China college of Materials Science and Engineering Chongqing UniversityChongqing 400044China college of Automobile and Mechanical Engineering Changsha University of Science and TechnologyChangshaChina

The thermal stability and mechanical properties of a gradient-nanograined structure(GNS)cocrNi medium entropy alloy(MEA)processed by ultrasonic surface rolling were studied by using isothermal/isochronal annealing tests combined with quasi-in-situ electron backscatter diffraction(EBSD)characterization and Vickers micro-hardness(HV)measurements.A layer by layer high-throughput investigation method was used to quantitatively study the grain growth kinetics and grain boundary evolution with different initial grain sizes,which could effectively save specimen and time *** grain nucleation and growth,as well as shrink and disappearance process throughΣ3 coincidence site lattice boundary migration with slightly lattice rotation during annealing were directly *** layer by layer grain growth kinetics and calculated activation energy indicate that the thermal stability of nanograined top surface layer is relatively higher than that of nano-twined subsurface layer for the gradient cocrNi MEA processed by ultrasonic surface *** analysis show that the grain boundary relaxation and dynamic recrystallization of the topmost nano-grains led to the decrease of grain boundary energy,thus improving their thermal *** present work provided theoretical basis for the application of cocrNi MEA at high ***,the high-throughput method on the investigation of grain stability by using gradient structure can be easily extended to other materials and it is of great significance for understanding the microstructural evolution of gradient materials.

关键词： Medium entropy alloy Grain growth Gradient materials Nanostructured materials Annealing High throughput

Status and prospects for symmetric organic redox flow batteries

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journal of Energy chemistry 2025年第1期100卷 125-143页

作者： Md Al Raihan c.Adam Dyker Department of chemistry University of New Brunswick

As environmental concerns from fossil fuel consumption intensify, large-scale energy storage becomes imperative for the integration of renewable sources like wind, hydro, and solar with the electrical *** flow batteries, particularly those employing organic molecules, are positioned as a key technology for this purpose. This review explores the growing field of symmetric organic redox flow batteries(ORFBs) within this context. Unlike traditional asymmetric designs based on unique active materials for each electrode, symmetric ORFBs involve a single bipolar species for both electrodes. This review highlights the benefits of a symmetric design, and categorizes five distinct classes of organic bipolar molecules used in both aqueous and non-aqueous solvents. By providing a comprehensive overview of their cell cycling and performance characteristics, the strengths and weaknesses of the diverse categories of bipolar molecules are highlighted for both solvent systems, as are opportunities for future development. This should guide new research directions and advance the development of practical symmetric ORFBs.

关键词： Redox flow battery Symmetric battery Organic battery Aqueous electrolyte Non-aqueous electrolyte

Design of TRIP Steel With High Welding and Galvanizing Performance in Light of Thermodynamics and Kinetics

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journal of Iron and Steel Research International 2007年第6期14卷 37-41页

作者： LI Lin DE cOOMAN B c LIU Ren-dong vleugels j ZHANG Mei SHI Wen School of Materials Shanghai University Shanghai 200072 China Postech Graduate School of Ferrous Technology Pohang University of Science and Technology Pohang 790784 South Korea Technique center of Ansteel Ansteel Company Anshan 114001 Liaoning China Department of MTM Katholieke Universiteit Leuven Kasteelpark Arenberg 44 B-3001 Belgium

A new type of transformation induced plasticity （TRIP） steel with not only high strength and high ductility but also superior welding and galvanizing properties was designed and developed recently. Low carbon and low silicon content were preliminarily selected with the aim of meeting the requirements of superior quality in both welding and galvanizing. Phosphorus was chosen as one of the alloying elements, because it could reduce carbon activity in cementite and increase the stability of austenite. In addition, the possibility of phosphorus segregating at grain boundary was also discussed by thermodynamics as well as kinetics. Phase diagram was estimated at high temperature and the composition of the steel was then selected in the hyperperitectic range to avoid problems, which might occur in sheet steel continuous casting. Phase diagram in the *** temperature was estimated for the steel to obtain the starting temperature of fast cooling. For understanding the minimum rate of fast cooling, pearlite growth kinetics was calculated with self-developed diffusion coefficients of elements in grain boundary. Overaging temperature was determined through the calculation of To temperature by both equilibrium and para-equilibrium assumptions, which was different from the current determination, which is only based on an equilibrium estimation.

关键词： TRIP steel design thermodynamics kinetics weldability galvanization property

Gas Line Pressure Fluctuation Analysis of a Gas-Liquid Reactor

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journal of Thermal Science 2005年第3期14卷 267-271页

作者： j.j.j. cHEN j.c. zhao chemical & Materials Engineering Department The University of Auckland Private Bag 92019 Auckland New Zealand ProfessorChemical & Materials Engineering Department The University of Auckland Private Bag 92019 Auckland New Zealand

To ensure efficient operation of metallurgical gas-liquid reactors, the gas bubbles must be uniformly distributed. For high temperature metallurgical reactors, it is impractical and unsafe to carry out visual observations. An air-water model was used to study the relationship between the bubble flow patterns and the pressure fluctuation signals. The fluctuation signals captured in the time domain were transformed into the frequency domain. Various parameters obtained from the transformed data were analysed for their suitability for delineating the bubble flow patterns observed. These parameters and the flow patterns were found to be well-correlated using the gas flow number.

关键词： gas liquid reactors bubble distribution signal analysis

computer-aided designing and manufacturing of advanced steels

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Rare Metals 2006年第5期25卷 407-411页

作者： LI Lin HE Yanlin B.c. De cooman P. Wollants S. G. Huang j. vleugels Department of Materials Science and Engineering Shanghai University Shanghai 200072 China Laboratory for Iron and Steelmaking Universiteit Gent Zwijnaarde B-9052 Belgium Dept. MTM Katholieke Universiteit Leuven Leuven B-3001 Belgium

Suitable optimization and simulation were performed using a powerful software package with a mature database as well as modem measurement facilities, which led to the successful designing and manufacturing of advanced steels. In the course of designing, the composition of a large section of prehardened mold steel for plastics was estimated so as to lower the quantities of oxide inclusions to change the type of carbides and to raise the machinability. The composition and process were adjusted to obtain satisfactory surface quality for the prevailing galvanization in transformation-induced plasticity （TRIP） steel. The refuting process of low-carbon steel was simulated in the light of both Thermo-calc and Factsage. Thermodynamic and kinetic analyses were always conducted during the test and the procedure.

关键词： material science advanced steel computer-aided design refining thermodynamics kinetics