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Nicotinamide Inhibition Properties for Copper Corrosion in 3.5% NaCl Solution: Experimental and Theorical Investigations

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Journal of Materials Science and Chemical Engineering 2018年第3期6卷 100-121页

作者： Coulibaly Nagnonta Hippolyte brou yapi serge Akpa Sagne Juan Creus Trokourey Albert Laboratoire de Chimie Physique (LCP) Université Félix Houphouet-Boigny d’Abidjan Abidjan Cote d’Ivoire Laboratoire de Chimie Organique et de Substances Naturelles (LCOSN) Université Félix Houphouet-Boigny d’Abidjan Abidjan Cote d’Ivoire Laboratoire des Sciences de l’Ingénieur pour l’Environnement (LaSIE) Université de La Rochelle La Rochelle France

This work reports the inhibition properties of nicotinamide (NAM) for copper protection during its applications in seawater systems such as water pipelines, shipbuilding, seawater desalination and heat exchange systems. The efficiency of NAM as a copper corrosion inhibitor in simulated seawater (3.5% NaCl solution) was investigated by Tafel extrapolation and linear polarization methods in the temperature range from 20℃ to 50℃. The corrosion parameters and the adsorption isotherms were determined using potentiodynamic polarization techniques. It was found that the inhibition efficiency (η) and the coverage rate (θ) increase up 80% at 25℃ for nicotinamide concentration of 10 mM but decrease as the temperature of the solution increases. Moreover, the obtained thermodynamic parameters using Langmuir model suggested a physical adsorption type. A correlation was found between the corrosion inhibition efficiency and the global theoretical parameters obtained by the functional density method B3LYP/ 6-31 + G (d, p). Local parameters such as condensed Fukui functions [f(r)] and condensed local softness [s(r)] indices have also been determined to obtain a chemical insight into atoms that have a significant tendency toward donation or acceptance of whole or fraction of electrons.

关键词： Nicotinamide Copper Corrosion Inhibition Electrochemical Techniques

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Electrochemical Study of the Synergistic Effect of Two Copper Corrosion Inhibitors, Nicotinic Acid (NAC) and Nicotinamide (NAM) in Two Different Media

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Open Journal of Physical Chemistry 2019年第4期9卷 193-203页

作者： yapi serge brou Nagnonta Hippolyte Coulibaly N’Guessan Yao Silvère Diki Juan Creus Albert Trokourey Laboratoire de Chimie Physique (LCP) Université Félix Houphouët-Boigny d’Abidjan Abidjan Côte d’Ivoire Laboratoire des Sciences de l’Ingénieur pour l’Environnement (LaSIE) UMR 7356 CNRS Université de La Rochelle La Rochelle France

Inhibitive properties of NAC and NAM as well as their mixture have been investigated in two different corrosive media through potentiodynamic polarization and electrochemical impedance spectroscopy at 298 K. These electrochemical measurements indicate that the inhibition efficiency increases with the concentration for each of the inhibitors used separately as well as for their mixture. In both cases, the combination behaves as mixed type inhibitor with a great cathodic tendency. NaCl 3.5% highlights an antagonist effect of NAM which reduces the effectiveness of NAC whereas HNO3 1M shows a synergistic effect between them.

关键词： NAC NAM Antagonist Effect Synergistic Effect

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Desorption of Methylene Blue Adsorbed on Activated Carbon from Cocoa Pod Shell

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Open Journal of Applied Sciences 2023年第5期13卷 605-617页

作者： David Léonce Kouadio Yapo Aristide Hermann yapi Djedjess Essoh Jules César Meledje Kacou Alain Paterne Dalogo Djamatché Paul Valery Akesse brou Dibi Karim Sory Traore Laboratoire des Sciences et Technologie de l’Environnementale Université Jean Lorougnon Guede C&#244te d’Ivoire Laboratoire des Sciences Physiques Fondamentales et appliquées école Normale Supérieure (Abidjan) Abidjan C&#244te d’Ivoire Laboratoire des Sciences de l’Environnement Université Nangui Abrogoua C&#244te d’Ivoire

Environmental protection has become a concern for the world. For this reason, the objective of this work is to remove methylene blue adsorbed on activated carbon. The coal used comes from cocoa pod shells. Before pyrolysis, the shells were ground, sieved and impregnated with orthophosphoric acid. Before desorption, the activated carbons were initially saturated with MB. These saturated coals were brought into contact with a sodium chloride (NaCl) solution and then stirred. The evolution of the resorbed MB concentration was monitored by spectrophotometry. The desorption tests showed a remarkable elimination from the first 10 minutes. The desorption kinetics comprises two phases: a rapid kinetics between 0 and 30 minutes and a slow kinetics between 30 and 60 minutes. The desorption of the dye reaches a concentration aqual to 0.84 mg/l at pH = 4 at temperature = 80°C. For modeling, the coefficient of the Langmuir II model is greater than or equal to O.9893. The model of Langmuir III is less than or equal to 0.9373. The Freundlich model coefficient is 0.9842 or less. The desorption is thefore carried out on energy-homogeneous adsorption sites and without any interaction between the adsorbed cations of the dye. Experimental parameters such as pH, temperature and concentration of sodium chloride (NaCl) solution influence the desorption of MB. And the model of Langmuir II describes well the process of desorption of the MB.

关键词： Desorption Activated Carbon Methylene Blue Isotherm Sodium Chloride

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Assessment of the Quality of Sediments and Agricultural Soils: Case of the Ity-Floleu Area in the Prefecture of Zouan-Hounien, Western Côte d’Ivoire

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Journal of Geoscience and Environment Protection 2020年第12期8卷 255-275页

作者： Konan Kouakou Séraphin Gbamélé Kouassi serge Doffou Richard Jean Olive brou Loukou Alexis Kouassi Kouakou Lazare Dongui Bini Kouamé Laboratory of Geosciences and Environment University Jean Lorougnon Guede Daloa C&ocirc te d’Ivoire Departement of Geology University Jean Lorougnon Guede Daloa C&ocirc te d’Ivoire

The objective of this study is to assess the level of metal contamination of sediments and agricultural soils in the Ity-Floleu zone. The concentrations of trace elements (Fe, Mn, As, Cd, Cr, Cu, Hg, Ni, Pb and Zn) were measured in different seasons over two successive years. The sediment pollution index made it possible to note that the sediments and agricultural soils of the various stations studied are highly polluted in all seasons. The calculation of the geoaccumulation index indicates that surface water sediments most often experience extreme or moderate pollution in As, Cd, Cu, Hg and Zn in the dry or rainy season except in Pb in some cases. We observed that the sediments of the Cavally river present a serious pollution due to extreme anthropic activities carried out along the river. Over the entire region, the results of the potential ecological risk index (RI) indicate that all the sediments and agricultural soils analysed present a moderate ecological risk in terms of Pb and Zn in certain cases and an ecological risk is observed low bound to other metals in all seasons. This metallic pollution generated by human activities in this region can have consequences for the environment and biodiversity.

关键词： Anthropogenic Activities Cavally River Contamination Factors Contamination Indices Metallic Trace Elements Sediments and Agricultural Soils

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Evaluation of Pollution Due to Gold Mining at Ity-Floleu Area in Sub-Prefecture of Zouan-Hounien, Western Côte d’Ivoire

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Journal of Geoscience and Environment Protection 2019年第12期7卷 20-41页

作者： Gbamélé Kouassi serge Konan Kouakou Séraphin Kouassi Kouakou Lazare brou Loukou Alexis Konan Koffi Félix Bini Kouamé Dongui Laboratory of Geosciences and Environment University Jean Lorougnon Guede Daloa Côte d’Ivoire Departement of Geology University Jean Lorougnon Guede Daloa Côte d’Ivoire Laboratory of Ecology Biodiversity and Evolution University Jean Lorougnon Guede Daloa Côte d’Ivoire Laboratory of Environment Chemistry and Materials University Jean Lorougnon Guede Daloa Côte d’Ivoire

This study aims to evaluate the mineral pollution of a gold mining environment in the sub-Prefecture of Zouan-Hounien (C?;te d’Ivoire). Samples were taken from surface water and flesh and skin samples of the Cavally River fish species over a period of two successive years. Concentrations in major elements, trace elements (As, Cd, Cr, Cu, Hg, Ni, Pb and Zn), nutrients () and physico-chemical parameters in situ were measured. The results obtained show that the surface waters have very low pH with an average of 5.70. For nutrient salts, the deterioration of water quality in the study area is mainly related to alterations by nitrates, phosphates and sulphates. The concentrations of Fe, Cu, Hg and Pb are above the existing standards (international, FAO/WHO) for the majority of the stations, thus causing the deterioration of the surface water quality. Therefore, their use for agricultural irrigation could have negative impact on the health of the population and on biodiversity. Regarding the bioindicating species, the results obtained after analysis of samples showed that the fish (carp and machoiron) have Fe, Cu, Hg and Pb concentrations higher than the existing standards (international, FAO/WHO) exposing consumers to high health risks. This study showed good correlation between the high values of surface water turbidity and the proximity of gold washing sites. The use of the principal component analysis (PCA) of the physicochemical dataset revealed comparable behaviors for certain minerals within the groups (Fe, K, Mg, Mn and Na) and (As, Cd, Cu, Ni, Pb, Zn and Ca) in water. The Ascending Hierarchical Classification (AHC) analysis has defined three different classes of surface water in the study area. The presence of mineral trace elements in these receiving environments is of natural origin but would be strongly accentuated by human activities.

关键词： Cavally River Fish Gold Mining Major Elements Nutritious Salts Surface Water Trace Elements

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SARS-CoV-2 Infection Is Associated with Vitamin D Deficiency in Côte d’Ivoire

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Advances in Microbiology 2022年第2期12卷 43-52页

作者： Lydie Boyvin yapi Guillaume Yayé Gnogbo Alexis Bahi Aya Jeanne Armande Aké Kipré Laurent Séri Daouda Sévédé serge Eholié Mireille Dosso Allico Joseph Djaman Department of Fundamental & Medical Biochemistry Institut Pasteur of C&ocirc te d’Ivoire (IPCI) Abidjan C&ocirc te d’Ivoire Biology and Health Laboratory University Félix Houphou&euml t-Boygny (UFHB) Abidjan C&ocirc te d’Ivoire Department of Biochemistry-Microbiology University of Jean Lorougnon Guédé Daloa C&ocirc te d’Ivoire Department of Bacteriology-Virology Institut Pasteur of C&ocirc te d’Ivoire (IPCI) Abidjan C&ocirc te d’Ivoire Department of Infectious Diseases of the Treichville University Hospital Center Abidjan C&ocirc te d’Ivoire

In 2019, the coronavirus pandemic broke out as a serious public health issue worldwide. In Côte d’Ivoire, the number of cases of COVID-19 has increased rapidly. The Severe Acute Respiratory Syndrome virus (SARS-CoV-2) binds to angiotensin converting enzyme 2 (ACE2) receptors in the respiratory tracts and enters the respiratory and alveolar cells of infected patients. Deficiency of fat-soluble vitamin D3 is associated with respiratory distress syndrome and pulmonary fibrosis by activation of the renin-angiotensin system. In Côte d’Ivoire, very little research is being done on SARS-CoV-2 and vitamin D. The objective of this study was to assess the vitamin D status of people infected and suffering from COVID-19 in order to contribute to their medical treatment. The study involved 100 adults infected with SARS-CoV-2 (24 women and 76 men). After confirmation of the patient’s SARS-CoV-2 status by RT-PCR, the 25 (OH) vitamin D assay was performed on the Cobas 6000 device and compared to control subjects, the non-COVID-19 positive. A significant decrease in 25-hydroxy vitamin D3 concentrations (44 ± 1.29 nmole/L) was observed in patients infected with SARS-CoV-2, compared to control (78 ± 0.68 nmole/L) (p 3 deficiency requires vitamin D supplementation in the management of hospitalized patients infected with SARS-CoV-2.

关键词： Côte d’Ivoire SARS-CoV-2 Vitamin D Deficiency

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Evaluation of the Use of Long-Lasting Impregnated Mosquito Nets (LLINs) in the Health District of Dimbokro (Center of Côte d’Ivoire)

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Journal of Biosciences and Medicines 2024年第3期12卷 44-61页

作者： Ellélé Aimé Marius yapi Tanoh Amany serge Raymond N’krumah Bi Yourou Guillaume Zamina Martial Bama Assikohon Pulchérie Gouzilé Amoin Nadège Abo Issaka Tiembre General Hygiene Department Institut National d’HygiènePublique (INHP) Abidjan C&ocircte d’Ivoire Animal Biology Department Peléféro Gon Coulibaly University Korhogo C&ocircte d’Ivoire Environment and Health Department Swiss Center for Scientific Research Abidjan C&ocircte d’Ivoire Public Health Emergency Operations Center National Institute of Public Hygiene (INHP) Abidjan C&ocircte d’Ivoire Malaria Department National Institute of Public Hygiene (INHP) Abidjan C&ocircte d’Ivoire Epidemiological Surveillance Service Health District Dimbokro C&ocircte d’Ivoire Vaccinology Sub-Directorate National Institute of Public Hygiene (INHP) Abidjan C&ocircte d’Ivoire Department of Public Health Félix Houphou&eumlt Boigny University Abidjan C&ocircte d’Ivoire

The Dimbokro health district has one of the highest incidences of malaria in Côte d’Ivoire, despite numerous campaigns to distribute Long-Acting Impregnated Mosquito Nets (LLINs). Given this observation, what are the population’s attitudes towards LLINs that could explain the high endemicity of malaria in Dimbokro? The aim of this study is to assess the knowledge, attitudes and practices of people in the health area of Nofou, one of the villages in the Dimbokro health district where malaria is most prevalent, with a view to strengthening malaria control strategies. A collection of historical health data (malaria cases and LLIN usage rates) and a cross-sectional questionnaire survey was carried out from July 20 to August 03, 2022 in 400 households selected by systematic random sampling. Data were entered using Epi Info 7 and multivariate statistical analyses were performed using IBM SPSS 22 software. In the Dimbokro health district, the rate of LLIN use was negatively correlated (r = -0.771) with malaria incidence over the six years of historical data collection. Households had an average of 53% good knowledge, 68.6% good practices and 28.4% good attitudes towards LLINs. The study also revealed that the main factors explaining LLIN use in the Nofou health area are mosquito bite (ORa = 5.29 (1.12 - 25.04)), age of household members (ORa = 1.07 (1.01 - 1.14)) and marital status (ORa = 8.45 (1.70 - 45.02)). Awareness-raising on the use of LLINs should be intensified in the Dimbokro health district. Other control strategies, such as vector control and environmental sanitation, should be considered to combat malaria.

关键词： Malaria LLINs Knowledge Attitudes Practices Dimbokro Côte d’Ivoire

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