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Molecule‑Level Multiscale Design of Nonflammable Gel Polymer Electrolyte to Build Stable SEI/CEI for Lithium Metal Battery

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Nano-Micro Letters 2025年第1期17卷 404-423页

作者： Qiqi Sun Zelong Gong Tao Zhang Jiafeng Li Xianli zhu Ruixiao zhu Lingxu Wang Leyuan Ma Xuehui Li Miaofa Yuan Zhiwei Zhang Luyuan Zhang Zhao Qian Longwei Yin Rajeev Ahuja Chengxiang Wang Key Laboratory for Liquid‑Solid Structural Evolution and Processing of Materials(Ministry of Education) School of Materials Science and EngineeringShandong UniversityJinan 250061People’s Republic of China Condensed Matter Theory Department of Physics and AstronomyUppsala UniversityUppsala 75120Sweden

The risk of flammability is an unavoidable issue for gel polymer electrolytes(GPEs).Usually,flameretardant solvents are necessary to be used,but most of them would react with anode/cathode easily and cause serious interfacial instability,which is a big challenge for design and application of nonflammable ***,a nonflammable GPE(SGPE)is developed by in situ polymerizing trifluoroethyl methacrylate(TFMA)monomers with flame-retardant triethyl phosphate(TEP)solvents and LiTFSI–LiDFOB dual lithium *** is strongly anchored to PTFMA matrix via polarity interaction between-P=O and-CH_(2)CF_(3).It reduces free TEP molecules,which obviously mitigates interfacial reactions,and enhances flame-retardant performance of TEP *** TEP molecules are also inhibited in solvation of Li^(+),leading to anion-dominated solvation sheath,which creates inorganic-rich solid electrolyte interface/cathode electrolyte interface *** coordination structure changes Li^(+)transport from sluggish vehicular to fast structural transport,raising ionic conductivity to 1.03 mS cm^(-1) and transfer number to 0.41 at 30℃.The Li|SGPE|Li cell presents highly reversible Li stripping/plating performance for over 1000 h at 0.1 mA cm^(−2),and 4.2 V LiCoO_(2)|SGPE|Li battery delivers high average specific capacity>120 mAh g^(−1) over 200 *** study paves a new way to make nonflammable GPE that is compatible with Li metal anode.

关键词： Anchoring effect Nonflammable gel electrolyte In situ cross-linked Electrode-electrolyte interface Li metal battery

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Characteristics of a coherent jet enshrouded in a supersonic fuel gas

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International Journal of Minerals,Metallurgy and Materials 2020年第2期27卷 173-180页

作者： Fei Zhao Rong zhu wen-rui Wang Key Laboratory of Fluid Interaction with Material University of Science and Technology BeijingBeijing 100083China National Center for Materials Service Safety University of Science and Technology BeijingBeijing 100083China School of Metallurgical and Ecological Engineering University of Science and Technology BeijingBeijing 100083China School of Mechanical Engineer University of Science and Technology BeijingBeijing 100083China

Based on a current coherent jet,this study proposes a supersonic combustion(SC)coherent jet in which the main oxygen jet is surrounded by a supersonic fuel *** characteristics of the proposed coherent jet are analyzed using experimental methods and numerical simulations in the high-temperature environment of electric arc furnace(EAF)*** SC coherent jet achieved stable combustion in the EAF steelmaking *** simulated combustion temperature of the supersonic shrouding methane gas was 2930 K,slightly below the theoretical combustion temperature of methane–oxygen *** high speed and temperature of the supersonic flame effectively weakened the interaction between the main oxygen jet and the external ambient gas,inhibiting the radial expansion of the main oxygen jet and maintaining its high speed and low turbulence over a long *** features improved the impact capacity of the coherent jet and strengthened the stirring intensity in the EAF bath.

关键词： EAF steelmaking coherent jet supersonic shrouding fuel gas supersonic combustion field characteristics

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Alternative Strategy for Development of Dielectric Calcium Copper Titanate‑Based Electrolytes for Low‑Temperature Solid Oxide Fuel Cells

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Nano-Micro Letters 2025年第1期17卷 310-332页

作者： Sajid Rauf Muhammad bilal Hanif Zuhra Tayyab Matej Veis MAKYousaf Shah Naveed Mushtaq Dmitry Medvedev Yibin Tian Chen Xia Martin Motola bin zhu College of Mechatronics and Control Engineering Shenzhen UniversityShenzhen 518060People’s Republic of China Department of Inorganic Chemistry Faculty of Natural SciencesComenius University BratislavaIlkovicova684215 BratislavaSlovakia Energy Storage Joint Research Center School of Energy and EnvironmentSoutheast UniversityNanjing 210096People’s Republic of China Hydrogen Energy Laboratory Ural Federal University620002 EkaterinburgRussia Laboratory of Electrochemical Devices Based on Solid Oxide Proton Electrolytes Institute of High Temperature Electrochemistry620066 EkaterinburgRussia School of Microelectronics Hubei UniversityWuhan 430062People’s Republic of China

The development of low-temperature solid oxide fuel cells(LT-SOFCs)is of significant importance for realizing the widespread application of *** has stimulated a substantial materials research effort in developing high oxide-ion conductivity in the electrolyte layer of *** this context,for the first time,a dielectric material,CaCu_(3)Ti_(4)O_(12)(CCTO)is designed for LT-SOFCs electrolyte application in this *** individual CCTO and its heterostructure materials with a p-type Ni_(0.8)Co_(0.15)Al_(0.05)LiO_(2−δ)(NCAL)semiconductor are evaluated as alternative electrolytes in LT-SOFC at 450–550℃.The single cell with the individual CCTO electrolyte exhibits a power output of approximately 263 mW cm^(-2) and an open-circuit voltage(OCV)of 0.95 V at 550℃,while the cell with the CCTO–NCAL heterostructure electrolyte capably delivers an improved power output of approximately 605 mW cm^(-2) along with a higher OCV over 1.0 V,which indicates the introduction of high hole-conducting NCAL into the CCTO could enhance the cell performance rather than inducing any potential short-circuiting *** is found that these promising outcomes are due to the interplay of the dielectric material,its structure,and overall properties that led to improve electrochemical mechanism in CCTO–***,density functional theory calculations provide the detailed information about the electronic and structural properties of the CCTO and NCAL and their heterostructure CCTO–*** study thus provides a new approach for developing new advanced electrolytes for LT-SOFCs.

关键词： LT-SOFCs Dielectric CaCu_(3)Ti_(4)O_(12) Semiconductor Ni_(0.8)Co_(0.15)Al_(0.05)LiO_(2−δ) Ionic conductivity Heterostructure electrolyte

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Third generation biosensor based on myoglobin-TiO_2/MWCNTs modified glassy carbon electrode

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Chinese Chemical Letters 2008年第8期19卷 965-968页

作者： Lei Zhang Dan bi Tian Jun Jie zhu College of Science Nanjing University of Technology Nanjing 210009 China Laboratory of Analytical Chemistry for Life Science Department of Chemistry Nanjing University Nanjing 210093 China

TiO2 nanoparticles were homogeneously coated on multi-walled carbon nanotubes by hydrothermal deposition, this nanocomposite may be a promising material for myoglobin immobilization in view of its high biocompatibility and large surface. The glassy carbon electrode modified with Mb-TiO2/MWCNTs films exhibited a pair of weU defined, stable and nearly reversible cycle voltammetric peaks. The electron transfer between Mb and electrode surface, Ks of 3.08 s^-1, was greatly facilitated in the TiO2/ MWCNTs film. The electrocatalytic reductions of hydrogen peroxide were studied, the apparent Michaelis-Menten constant is calculated to be 83.10 μmol/L, which shows a large catalytic activity of Mb in the TiO2/MWCNTs film to H2O2.

关键词： Myoglobin Multi-walled carbon nanotubes TiO2 Electrocatalysis Electrochemistry

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Nonliner Analysis of a Synthesized Optimal Velocity Model for Traffic Flow

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Communications in Theoretical Physics 2008年第8期50卷 505-510页

作者： zhu wen-Xing JIA Lei School of Control Science and Engineering Shandong University Jinan 250061 China Department of Automation Shanghai Jiao Tong University Shanghai 200240 China

We analyze a new car-following model described by a differential-difference equation with a synthesized optimal velocity function (SOVF),which depends on the front interactions between every two adjacent vehicles instead of the weighted average *** model is analyzed with the use of the linear stability theory and nonlinear analysis *** stability and neutral stability condition are *** also derive the modified KdV (Korteweg-de Vries) equation and the kink-antikink soliton solution near the critical point.A simulation is conducted with integrating the differential-difference equation by the Euler *** results of the numerical simulation verify the validity of the new model.

关键词： multi-interaction nonlinear analysis modified KdV equation SOVF

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Composition Operators on α-Bloch Spaces of the Unit Ball

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Acta Mathematica Sinica,English Series 2007年第11期23卷 1991-2002页

作者： Min zhu ZHANG wen XU Department of Mathematics Nanjing Normal University Nanjing 210097 P. R. China Department of Mathematics Southeast University Nanjing 210096 P. R. China Department of Physics and Mathematics University of Joensuu Fin-80101 Joensuu Finland

The authors characterize the boundedness and compactness of composition operators between α-Bloch spaces of the unit ball.

关键词： α-Bloch space composition operator boundedness compactness

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Influencing factors for catalytic oxidation of mine gas to methanol in liquid phase

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Chinese Journal Of Geochemistry 2014年第2期33卷 183-186页

作者： zhu Lihua XU Feng bi Yewu SHEN bin Heilongjiang University of Science and Technology

The influencing factors for liquid phase catalytic oxidation of mine gas to methanol(in form of CH3COOCH3) are studied using the self-established experimental apparatus. The results show that CH3COOCH3(target product) is obtained by using CH3COOH as reaction solvent, and the yield of target product increases with the increasing of reaction temperature, gas pressure and reaction time. In the mine gas-Pd(OAc)2-CH3COOH system, the yield of CH3COOCH3 increases with the increasing of addition of Pd(OAc)2 which is redox catalyst for mine gas conversion. The yield of CH3COOCH3 will be greatly improved by composite additional oxidant which is obtained by equimolar mix of p-benzoquinone with NO2.

关键词：液相催化氧化矿井瓦斯影响因素甲醇还原催化剂实验装置反应溶剂反应温度

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Comparison of three filters in asteroid-based autonomous navigation

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Research in Astronomy and Astrophysics 2014年第3期14卷 329-344页

作者： wen Cui Kai-Jian zhu State Key Laboratory of Astronautic Dynamics Xi’an Satellite Control Center

At present, optical autonomous navigation has become a key technologyin deep space exploration programs. Recent studies focus on the problem of orbit de-termination using autonomous navigation, and the choice of filter is one of the mainissues. To prepare for a possible exploration mission to Mars, the primary emphasisof this paper is to evaluate the capability of three filters, the extended Kalman filter（EKF）, unscented Kalman filter （UKF） and weighted least-squares （WLS） algorithm,which have different initial states during the cruise phase. One initial state is assumedto have high accuracy with the support of ground tracking when autonomous navi-gation is operating; for the other state, errors are set to be large without this *** addition, the method of selecting asteroids that can be used for navigation fromknown lists of asteroids to form a sequence is also presented in this study. The simula-tion results show that WLS and UKF should be the first choice for optical autonomousnavigation during the cruise phase to Mars.

关键词： celestial mechanics asteroids equation of state methods: data analysis techniques: image processing

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Developments in metastatic pancreatic cancer:Is gemcitabine still the standard?

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World Journal of Gastroenterology 2012年第8期18卷 736-745页

作者： Jie-Er Ying Li-Ming zhu bi-Xia Liu Department of Medical Ontology Zhejiang Cancer HospitalHangzhou 310022Zhejiang ProvinceChina

In the past 15 years, we have seen few therapeutic advances for patients with pancreatic cancer, which is the fourth leading cause of cancer-related death in the United States. Currently, only about 6% of patients with advanced disease respond to standard gemcitabine therapy, and median survival is only about 6 mo. Moreover, phase Ⅲ trials have shown that adding various cytotoxic and targeted chemotherapeutic agents to gemcitabine has failed to improve overall survival, except in cases in which gemcitabine combined with erlotinib show minimal survival benefi t. Several metaanalyses have shown that the combination of gemcitabine with either a platinum analog or capecitabine may lead to clinically relevant survival prolongation, especially for patients with good performance status. Meanwhile, many studies have focused on the pharmacokinetic modulation of gemcitabine by fi xed-dose administration, and metabolic or transport enzymes related to the response and toxicity of gemcitabine. Strikingly, a phase Ⅲ trial in 2010 showed that, in comparison to gemcitabine alone, the FOLFIRINOX regimen in patients with advanced disease and good performance status, produced better median overall survival, median progression-free survival, and objective response rates. This regimen also resulted in greater, albeit manageable toxicity.

关键词： Chemotherapy Palliative therapy Metasta-sis biomarkers Pancreatic neoplasms

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Constructing Donor–Acceptor‑Linked COFs Electrolytes to Regulate Electron Density and Accelerate the Li^(+)Migration in Quasi‑Solid‑State Battery

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Nano-Micro Letters 2025年第1期17卷 456-471页

作者： Genfu Zhao Hang Ma Conghui Zhang Yongxin Yang Shuyuan Yu Haiye zhu Yongjiang Sun Hong Guo School of Materials and Energy International Joint Research Center for Advanced Energy Materials of Yunnan ProvinceYunnan UniversityKunming 650091People’s Republic of China Yunnan Yuntianhua Co. LtdR&D CenterKunming 650228People’s Republic of China Southwest United Graduate School Kunming 650091People’s Republic of China

Regulation the electronic density of solid-state electrolyte by donor–acceptor(D–A)system can achieve highly-selective Li^(+)transportation and conduction in solid-state Li metal *** study reports a high-performance solid-state electrolyte thorough D–A-linked covalent organic frameworks(COFs)based on intramolecular charge transfer *** other reported COFbased solid-state electrolyte,the developed concept with D–A-linked COFs not only achieves electronic modulation to promote highly-selective Li^(+)migration and inhibit Li dendrite,but also offers a crucial opportunity to understand the role of electronic density in solid-state Li metal *** introduced strong electronegativity F-based ligand in COF electrolyte results in highlyselective Li^(+)(transference number 0.83),high ionic conductivity(6.7×10^(-4)S cm^(−1)),excellent cyclic ability(1000 h)in Li metal symmetric cell and high-capacity retention in Li/LiFePO_(4)cell(90.8%for 300 cycles at 5C)than substituted C-and N-based *** is ascribed to outstanding D–A interaction between donor porphyrin and acceptor F atoms,which effectively expedites electron transferring from porphyrin to F-based ligand and enhances Li^(+)***,we anticipate that this work creates insight into the strategy for accelerating Li^(+)conduction in high-performance solid-state Li metal batteries through D–A system.

关键词： Electronic modulation engineering Donor-acceptor-linked covalent organic frameworks Quasi-solid-state Li metal battery

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