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Clay Materials for Ceramics Application from N’Djamena in the Chad Republic: Mineralogical, Physicochemical and Microstructural Characterization

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Journal of Materials Science and Chemical Engineering 2024年第2期12卷 31-48页

作者： Ndjolba Madjihingam Djoda Pagore Jacques Richard Mache Bebbata Warabi bertin pagna kagonbe Patrick Mountapmbeme Kouotou Department of Civil Engineering National Advanced School of Engineering University of Maroua Maroua Cameroon Department of Mining Engineering School of Geology and Mining Engineering University of Ngaoundere Meiganga Cameroon Local Materials Authority Promotion (MIPROMALO) Yaoundé Cameroon Department of Environmental Sciences Advanced School of Agriculture Forestry Water and Environment University of Ebolowa Ebolowa Cameroon

Herein, we report some characteristics of the clayey materials (CMs) collected from Kaliwa (C1), Kabé (C2) and Malo (C3) district in N’Djamena (Chad). Three samples were characterized applying XRF, XRD, FTIR, SEM. In addition, TGA/DSC were performed to control decomposition/mass loss and show phase transitions respectively of CMs. Geochemical analysis by XRF reveals the following minerals composition: SiO2 (~57% - 66%), Al2O3 (~13% - 15%), Fe2O3 (~6% - 10%), TiO2 (~1% - 2%) were the predominant oxides with a reduced proportion in C1, and (~7%) of fluxing agents (K2O, CaO, Na2O). Negligible and trace of MgO (~1%) and P2O5 was noted. The mineralogical composition by XRD shows that, C1, C2 and C3 display close mineralogy with: Quartz (~50%), feldspar (~20%) as non-clay minerals, whereas clays minerals were mostly kaolinite (~15%), illite (~5%) and smectite (~10%). FTIR analysis exhibits almost seemingly similar absorption bands characteristic of hydroxyls elongation, OH valence vibration of Kaolinite and stretching vibration of some Metal-Oxygen bond. SEM micrographs of the samples exhibit microstructureformed by inter-aggregates particles with porous cavities. TGA/DSCconfirm the existence of quartz (570˚C to 870˚C), carbonates (600˚C - 760˚C), kaolinite (569˚C - 988˚C), illite (566˚C - 966˚C), MgO (410˚C - 720˚C) and smectite (650˚C - 900˚C). The overall characterization indicates that, these clayey soils exhibit good properties for ceramic application.

关键词： Clay Soils Characterization Mineralogy Physicochemical Properties Ceramic Application

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Assessment of Soils Developed on Various Formations in Maroua (Far North, Cameroon) for Production of Compressed Earth Bricks

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Open Journal of Applied Sciences 2023年第6期13卷 874-887页

作者： bertin pagna Kagonbé Bakary Souleymanou Viviane Djaoyang Bakaïné Raphael Essama Boum Belinga Bertrand Tatoh Aziwo Alexis Ngoniri Hamdja Likiby Boubakar Local Materials Promotion Authority (MIPROMALO) Yaounde Cameroon National Institute of Cartography (INC) Yaounde Cameroon

One of the most important materials in the building industry is earth brick. The current work focuses on the evaluation of Maroua soils and their potential usage in the manufacturing of Compressed earth blocks (CEB). Four sites (Frolina, Goubeou, Mambang, and Djoulgouf) were chosen to conduct this study. One sample was collected at each location. Physico-chemical and mineralogical characteristics were obtained by using particle size, Atterberg limits, X-ray diffraction, and X-ray fluorescence analysis. Results revealed that sand is the most abundant fraction (36.9% - 50.5%) followed by clay (22.1% - 28.4%) and silt (11.3% - 23.8%). They mostly correspond to sandy soils. Liquid and Plastic limits range between 22.6% to 41% and 16.1% to 24.9% respectively and the plasticity index spans from 6.5% to 20.3%. Plasticity is low for Mambang and Djoulgouf and medium for Goubeou and Frolina soils. Mineralogical composition revealed the presence of smectite, kaolinite, and illite as clay minerals, associated with variable amounts of quartz, goethite, and K-feldspars. Geochemical analyses indicate a high silica content (47.1% - 72.8%) followed by alumina (10.9% - 22.8%) and iron (6.4% - 13.2%). The mineralogical, chemical and physical properties of the studied soils revealed that they are suitable for the manufacture of CEB according to the Cameroon Standards of CEB.

关键词： Soil Physical Properties Mineralogy Geochemistry CEB Maroua-Cameroon

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Assessment of Soils Developed on Various Formations in Maroua (Far North, Cameroon) for Production of Compressed Earth Bricks

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Open Journal of Applied Sciences（应用科学） 2023年第6期

作者： bertin pagna Kagonbé Bakary Souleymanou Viviane Djaoyang Bakaïné Raphael Essama Boum Belinga Bertrand Tatoh Aziwo Alexis Ngoniri Hamdja Likiby Boubakar

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