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Effect of the Particle Packing Configuration on Fixed Bed Performance

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china petroleum Processing & Petrochemical Technology 2024年第1期26卷 152-160页

作者： Li Ziqi bao Di Zhou Han Tang Xiaojin SINOPEC Research institute of petroleum Processing Co. Ltd.Beijing 100083China

Fixed-bed reactors are generally considered the optimal choice for numerous multi-phase catalytic reactions due to their excellent performance and ***,conventional fixed beds often encounter challenges related to inadequate mass transfer and a high pressure drop caused by the non-uniform void fraction *** enhance the overall performance of fixed beds,the impact of different packing configurations on performance was *** and simulation methods were used to investigate the fluid flow and mass transfer performances of various packed beds under different flow *** was found that structured beds exhibited a significantly lower pressure drop per unit length than conventional packed ***,the packing configurations had a critical role in improving the overall performance of fixed ***,structured packed beds,particularly the H-2 packing configuration,effectively reduced the pressure drop per unit length and improved the mass transfer *** H-2 packing configuration consisted of two parallel strips of particles in each layer,with strips arranged perpendicularly between adjacent layers,and the spacing between the strips varied from layer to layer.

关键词： packing configurations fixed bed Computational Fluid Dynamics simulation pressure drop mass transfer

Multi-scale data joint inversion of minerals and porosity in altered igneous reservoirs—A case study in the South china Sea

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petroleum Science 2024年第1期21卷 206-220页

作者： Xin-Ru Wang bao-Zhi Pan Yu-Hang Guo Qing-Hui Wang Yao Guan College of Geo-exploration Science and Technology Jilin UniversityChangchun130046JilinChina Research institute CNOOC Ltd.-ShenzhenShenzhen518000GuangdongChina

There are abundant igneous gas reservoirs in the South china Sea with significant value of research,and lithology classification,mineral analysis and porosity inversion are important links in reservoir ***,affected by the diverse lithology,complicated mineral and widespread alteration,conventional logging lithology classification and mineral inversion become considerably *** the same time,owing to the limitation of the wireline log response equation,the quantity and accuracy of minerals can hardly meet the exploration requirements of igneous *** overcome those issues,this study takes the South china Sea as an example,and combines multi-scale data such as micro rock slices,petrophysical experiments,wireline log and element cutting log to establish a set of joint inversion methods for minerals and porosity of altered igneous ***,we define the lithology and mineral characteristics through core slices and mineral data,and establish an igneous multi-mineral volumetric *** we determine element cutting log correction method based on core element data,and combine wireline log and corrected element cutting log to perform the lithology classification and joint inversion of minerals and ***,it is always difficult to determine the elemental eigenvalues of different minerals in *** paper uses multiple linear regression methods to solve this ***,an integrated inversion technique for altered igneous formations was *** results show that the corrected element cutting log are in good agreement with the core element data,and the mineral and porosity results obtained from the joint inversion based on the wireline log and corrected element cutting log are also in good agreement with the core data from X-ray *** results demonstrate that the inversion technique is applicable and this study provides a new direction for the mineral inversion research of altered igneous formation

关键词： Joint inversion Altered igneous rock Element correction method Lithology identification Multi mineral volume model

An adaptive finite-difference method for seismic traveltime modeling based on 3D eikonal equation

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petroleum Science 2024年第1期21卷 195-205页

作者： bao-Ping Qiao Qing-Qing Li Wei-Guang He Dan Zhao Qu-Bo Wu CNNC Beijing Research institute of Uranium Geology Beijing 100029China National Key Laboratory of Deep Oil and Gas China University of Petroleum(East China)Qingdao 266580ShangdongChina SINOPEC Geophysical Research institute Nanjing211103JiangsuChina

3D eikonal equation is a partial differential equation for the calculation of first-arrival traveltimes and has been widely applied in many scopes such as ray tracing,source localization,reflection migration,seismic monitoring and tomographic *** recent years,many advanced methods have been developed to solve the 3D eikonal equation in heterogeneous ***,there are still challenges for the stable and accurate calculation of first-arrival traveltimes in 3D strongly inhomogeneous *** this paper,we propose an adaptive finite-difference(AFD)method to numerically solve the 3D eikonal *** novel method makes full use of the advantages of different local operators characterizing different seismic wave types to calculate factors and traveltimes,and then the most accurate factor and traveltime are adaptively selected for the convergent updating based on the Fermat *** with global fast sweeping describing seismic waves propagating along eight directions in 3D media,our novel method can achieve the robust calculation of first-arrival traveltimes with high precision at grid points either near source point or far away from source point even in a velocity model with large and sharp *** numerical examples show the good performance of the AFD method,which will be beneficial to many scientific applications.

关键词： 3D eikonal equation Accurate traveltimes Global fast sweeping 3D inhomogeneous media Adaptive finite-difference method

SAPO-34 facilitates the formation of benzene,toluene and xylenes in direct syngas conversion over MnCrO_(x)-SAPO-34-ZSM-5

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Science china Chemistry 2024年第2期67卷 732-740页

作者： Shuchi Zhang Dengyun Miao Yi Ding Mengyuan Li Shujing Guo Yujuan Zhang Xiulian Pan Xinhe bao State Key Laboratory of Catalysis Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian116023China University of Chinese Academy of Sciences Beijing100049China Shaanxi Yanchang petroleum(Group)Co. Ltd.&Dalian Institute of Chemical Physics Xi’an Clean Energy(Chemical Industry)Research InstituteXi’an710000China

Direct conversion of syngas to aromatics over metal oxide and zeolite(OXZEO) composite catalysts is ***,the selectivity of more valuable products such as benzene,toluene and xylenes(BTX) is limited due to undesired secondary methylation of ***,we report that the introduction of SAPO-34 into MnCrO_(x)-ZSM-5 catalyst enhances significantly the formation of BTX without sacrificing the aromatics *** optimized conditions,the fraction of BTX in aromatics reaches 64.7% versus 28.9% over the catalyst without SAPO-34.A number of model reaction tests and characterizations reveal that SAPO-34 consumes partially the intermediates such as ketene,by converting them to light ***,the methylation of BTX by ketene to heavy aromatics is inhibited over the external acid sites of ZSM-5,leading to an enhanced BTX selectivity in the *** hybrid catalyst provides an efficient method for highly selective synthesis of BTX from syngas.

关键词： selective syngas conversion OXZEO aromatics BTX multi-functional catalysts

Differences in and factors controlling organic matter enrichment in the Ziliujing Formation shale in the Sichuan Basin

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petroleum Science 2024年第1期21卷 77-86页

作者： Peng Li Zhong-bao Liu He Bi Tao Jiang Rui-Kang Bian Peng-Wei Wang Xiao-Yu Shang State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Efficient Development Beijing102206China Key Laboratory of Shale Oil/Gas Exploration and Production Technology SINOPECBeijing102206China petroleum Exploration and Production Research institute SINOPECBeijing102206China Research institute of petroleum Exploration and Development PetroChinaBeijing100083China Chinese Academy of Geological Sciences Beijing100037China No.4 Oil Production Plant in Daqing Oilfield Co Ltd. Daqing163511HeilongjiangChina

Lacustrine shale oil and gas are important fields for unconventional exploration and development in china,and organic-rich shale deposition lays down the critical foundation for hydrocarbon *** are two sets of shale,the Dongyuemiao and Da’anzhai Members,in the Ziliujing Formation in the Sichuan *** identify the differential enrichment characteristics of organic matter and clarify its controlling factors,geochemical analyses of organic and inorganic geochemical analyses were *** results showed that the total organic carbon content of the Dongyuemiao shale(1.36%)is slightly higher than that of the Da’anzhai shale(0.95%).The enrichment of organic matter in the two shales resulted from the comprehensive controls of paleoproductivity,paleoenvironment,and terrigenous input,but different factors have different *** addition,driven by climate,the change in the sulfate concentration in the bottom water further led to the different intensities of bacterial sulfate reduction in early *** made a great difference regarding organic matter accumulation in the two *** general,climate may have played a dominant role in organic matter enrichment in the two sets of shale.

关键词： Lacustrine shale Ziliujing Formation Sichuan Basin Enrichment mechanism of organic matter

Risk assessment of oil and gas investment environment in countries along the Belt and Road Initiative

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petroleum Science 2024年第2期21卷 1429-1443页

作者： bao-Jun Tang Chang-Jing Ji Yu-Xian Zheng Kang-Ning Liu Yi-Fei Ma Jun-Yu Chen Center for Energy and Environmental Policy Research Beijing Institute of TechnologyBeijing100081China School of Management and Economics Beijing Institute of TechnologyBeijing100081China Collaborative Innovation Center of Electric Vehicles in Beijing BeijingChina Sustainable Development Research institute for Economy and Society of Beijing BeijingChina institute of Carbon Neutrality ShanghaiTech UniversityShanghai201210China

With the implementation of the Belt and Road Initiative, china is deepening its cooperation in oil and gas resources with countries along the Initiative. In order to better mitigate risks and enhance the safety of investments, it is of significant importance to research the oil and gas investment environment in these countries for china's overseas investment macro-layout. This paper proposes an indicator system including 27 indicators from 6 dimensions. On this basis, game theory models combined with global entropy method and analytic hierarchy process are applied to determine the combined weights, and the TOPSIS-GRA model is utilized to assess the risks of oil and gas investment in 76 countries along the Initiative from 2014 to 2021. Finally, the GM(1,1) model is employed to predict risk values for 2022-2025. In conclusion, oil and gas resources and political factors have the greatest impact on investment environment risk, and 12 countries with greater investment potential are selected through cluster analysis in conjunction with the predicted results. The research findings may provide scientific decisionmaking recommendations for the Chinese government and oil enterprises to strengthen oil and gas investment cooperation with countries along the Belt and Road Initiative.

关键词： Belt and Road Initiative Oil and Gas Investment Risk assessment

Intelligent architecture modeling for multilevel fluvial reservoirs based on architecture interface and elements

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Energy Geoscience 2024年第1期5卷 293-310页

作者： Bo Niu Xiangyang Hu Shuijian Wei Wenbo Zheng Jie Xu Bin Liu Zhidong bao petroleum Exploration&Production Research institute SinopecBeijing100083China State Key Laboratory of petroleum Resources and Prospecting China University of Petroleum(Beijing)Beijing102249China

At present,the architecture modeling method of fluvial reservoirs are still *** methods usually use grids to characterize architecture interbeds within the *** to the thin thickness of this type of the interlayers,the number of the model grids must be greatly *** number of grids in the tens of millions often makes an expensive computation;however,upscaling the model will generate a misleading *** above confusion is the major reason that restricts the largescale industrialization of fluvial reservoir architecture models in oilfield development and ***,this paper explores an intelligent architecture modeling method for multilevel fluvial reservoirs based on architecture interface and *** on the superpositional relationship of different architectural elements within the fluvial reservoir,this method uses a combination of multilevel interface constraints and non-uniform grid techniques to build a high-resolution 3D geological model for reservoir *** the grid upscaling technology of heterogeneous architecture elements,different upscaling densities are given to the lateral-accretion bedding and lateral-accretion bodies to simplify the model *** new method greatly reduces the number of model grids while ensuring the accuracy of lateral-accretion bedding models,laying a foundation for large-scale numerical simulation of the subsequent industrialization of the architecture *** method has been validated in A layer of X oilfield with meandering fluvial channel sands as reservoirs and B layer of Y oilfield with braided river sands as *** simulation results show that it has a higher accuracy of production history matching and remaining oil distribution forecast of the targeted sand *** numerical simulation results show that in the actual development process of oilfield,the injected water will not displace oil in a uniform diffusive manner as traditionally assu

关键词： Architecture modeling Interface restriction Architectural element Fluvial deposits Mid-channel bar Point bar

Upgrading ethylene via renewable energy-driven electrocatalysis

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Science china Chemistry 2024年

作者： Hanyu Wang Dunfeng Gao Guoxiong Wang Xinhe bao State Key Laboratory of Catalysis Dalian National Laboratory for Clean Energy iChEM (Collaborative Innovation Center of Chemistry for Energy Materials) Dalian Institute of Chemical Physics Chinese Academy of Sciences University of Chinese Academy of Sciences

Ethylene oxide （EO） and ethylene glycol （EG） are two important commodity chemicals and are industrially produced from petroleum-derived ethylene via thermocatalytic processes. The overoxidation of ethylene and the implementation of high temperature and pressure lead to substantial CO2emission. Renewable energy-driven electrocatalysis provides a low-carbon route for upgrading ethylene under mild conditions, especially when it couples with ethylene electrosynthesis from CO2. In this minireview, we summarize recent achievements in the selective electrocatalytic oxidation of ethylene to EO and EG. Three main reaction routes including direct electrocatalytic oxidation with water, indirect electrocatalytic oxidation with halide mediators,and tandem electrocatalytic and thermocatalytic oxidation with hydrogen peroxide intermediate, are discussed. Some representative catalyst systems and reactor designs are exemplified. We discuss the existing scientific and technical challenges of electrocatalytic ethylene upgrading in terms of reaction rate, selectivity, and long-term stability, and propose future research directions and opportunities for pushing the process towards practical application.

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Characterization and Catalytic Properties of a Rapidly Quenched Ni-RE-P-Al Catalyst

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Chemical Research in Chinese Universities 2000年第1期16卷 15-20页

作者： MA Ai-zeng LU Wan-zhen ZONG bao-ning and MIN En-ze (Research institute of petroleum Processing, Beijing, 100083, P. R. china) Res Inst Petr Proc Beijing 100083 Peoples R China

A Ni-RE-P-Al catalyst prepared by alkaline extraction of a rapidly quenched Ni-RE-P-Al alloy was characterized by means of ICP, BET, XRD, XPS and TEM. The results show that the rapidly quenched Ni-RE-P-Al alloy contained less crystalline Al_3Ni than Al-Ni alloy. After alkaline extraction, most of Al in the Ni-RE-P-Al alloy was leached out and the resulted Ni-RE-P-Al catalyst presented a sponge structure similar to Raney Ni. Although crystalline Ni is the major phase in the Ni-RE-P-Al catalyst and Raney Ni, amorphous Ni-P phase has been detected in the Ni-RE-P-Al catalyst. Studies on catalytic hydrogenation of toluene, phenyl ethylene, acetylene benzene, nitrobenzene, cyclohexanone and adiponitrile in liquid phase showed that the activity and selectivity of this Ni-RE-P-Al catalyst are superior to those of Raney Ni, especially at low temperatures. The amorphous phase is considered to be responsible for its superior catalytic properties.

关键词： Catalyst Hydrogenation Ethenyl benzene Nickel Adiponitrile Catalyst characterization