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Phenol contaminated municipal wastewater treatment using date palm frond biochar:Optimization using response surface methodology

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Emerging Contaminants 2023年第1期9卷 53-67页

作者： Yohanna Haile Fseha Jamal Shaheen banu sizirici Department of Civil Infrastructure and Environmental Engineering Khalifa University of Science and TechnologyP.O.Box 127788Abu DhabiUnited Arab Emirates

Phenol is classified as an emerging contaminant which can be very toxic even at low concentrations and should be removed from wastewaters before reaching the *** this study date palm frond and leaf were pyrolyzed at different temperatures to identify the best adsorbent(feedstock)and pyrolysis temperature to remove phenol from aqueous *** palm frond pyrolyzed at 600℃,termed DPF600,achieved the highest phenol removal rates of 64%and adsorption capacity of 15.93 mg/*** surface methodology approach using Box-Behnken design was implemented to obtain the optimal pH(6),contact time(20 h)and dosage(0.1 g)for the maximum phenol adsorption.A predicted adsorption capacity was found as 16.62 mg/g which was in close agreement with the experimental adsorption capacity of 17.38 mg/*** and kinetic models in both linear and non-linear forms indicated that Freundlich model(R^(2)=0.99,χ^(2)=0.02,RMSE=1.09)and pseudo-second order model(R^(2)=0.99,χ^(2)=0.85,RMSE=5.41)fit best the obtained experimental *** calculations affirmed that the adsorption of phenol onto DPF600 biochar was endothermic and *** point of zero charge was found to be at 6.5 for DPF600 *** electron microscopy coupled with energy dispersive X-ray,Fourier transform infrared spectroscopy and X-ray diffraction confirmed adsorption of phenol onto DPF600 *** of DPF600 biochar to remove phenol from synthetic primary and secondary treated wastewater samples achieved 60 and 85%removal rates and 241 mg/g and 22.28 mg/g adsorption capacities,*** studies showed promising adsorption capacities indicating the efficacy of DPF600 for the removal of phenol from wastewater.

关键词： Phenol contaminated wastewater Date palm frond Biochar Box-behnken design Response surface methodology Adsorption capacity

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Fate,transport,and risk assessment of widely prescribed pharmaceuticals in terrestrial and aquatic systems:A review

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Emerging Contaminants 2022年第1期8卷 216-228页

作者： Jamal F.Shaheen banu sizirici Ibrahim Yildiz Department of Civil Infrastructure and Environmental Engineering Khalifa University of Science and TechnologyP.O.Box 127788Abu DhabiUnited Arab Emirates Department of Chemistry Khalifa University of Science and TechnologyP.O.Box 127788Abu DhabiUnited Arab Emirates

Rapid development of pharmaceuticals outpaces the efforts to regulate and monitor their trace concentrations in the *** emerging issue can only be solved through field studies,solid fate and transport models,and adequate risk assessment of the concerned *** approach requires the availability of toxicological information about the contaminants along with an understanding of their full potential in different media of the *** review paper focuses on commonly used seven pharmaceutical families across the globe:antacids,antibiotics,antidepressants,antiepileptics,beta blockers,lipid lowering drugs,and nonsteroidal anti-inflammatory *** each family,pharmaceuticals which are widely prescribed,studied,and frequently detected in environment were *** concentration levels in the environment,updated physicochemical properties,main natural removal mechanism,and ecological risk assessment towards the receptors of those pharmaceuticals in aquatic and terrestrial systems were *** following results were observed in the literature:1)removal of the pharmaceuticals from wastewater treatment plants is reduced when the dissolved organic matter present;2)many studies have cited older physicochemical properties of the concerned pharmaceuticals assuming relative conditions in their studies which can affect the accuracy of a model;3)the number of studies are very limited for fate and transport in the soil;and 4)there is lack of cumulative risk assessment of mixed pharmaceutical ***,this review will provide modeler with updated physiochemical properties;it will guide researchers to focus on removal of those contaminants at different lifecycle stages;and it will provide guidance to policy makers to develop effective policies and regulations.

关键词： Emerging contaminants Pharmaceuticals Fate and transport Risk assessment Removal mechanism

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Wind energy feasibility and wind turbine selection studies for the city Surat,India

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Clean Energy 2024年第3期8卷 166-173页

作者： Arshi banu P S Maanat Bhadani Hindustan Institute of Technology and Science ChennaiIndia The Doon School UttarakhandDehradunIndia

Wind energy represents a clean,abundant and cost-effective power source,fostering job growth and environmental *** wind energy harnesses several gigawatts today,its availability hinges on diverse factors,with geographical location standing *** turbines,with varying capacity ranges,saturate the *** site-specific suitability and matching the appropriate turbine to meet specific requirements are of paramount *** study aims to assess the feasibility of wind energy in Surat,Gujarat,India and select an optimal small commercial turbine for residential *** research involves Rayleigh and Weibull probability distribution functions based on yearlong velocity *** distributions are fitted with actual data,revealing the most probable velocity(v_(mf)=3 m/s)and velocity at maximum power(v_(pmax)=5 m/s).The power availability of the site has been assessed as 42.6 W/m^(2)using both graphical and analytical *** commercial turbines have been shortlisted based on on-site power criteria and their specifications are evaluated against site power availability.A comparative analysis culminates in identifying the most suitable turbine for the *** best suitable turbine for the site with an annual energy yield of 8 MW has been suggested amongst selected turbines for small-scale residential applications.

关键词： site feasibility wind energy commercial wind turbine probability distribution function rated power

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Computational study of flow separation in truncated ideal contour nozzles under high-altitude conditions

International Journal of Fluid Engineering

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International Journal of Fluid Engineering 2024年第1期 21-30页

作者： Ijas Muhammed V V Shamsia banu N Abhilash Suryan Vincent Lijo David Simurda Heuy Dong Kim College of Engineering Trivandrum Government Engineering College Thrissur Faculty of Mechanical Engineering Technical University of Liberec Andong National University

Flow separation in rocket nozzles has been studied mostly under sea-level conditions, which fail to take into account changes in ambient density and ambient pressure during the flight of a rocket. In the present study, numerical analysis is conducted of flow characteristics within a truncated ideal contour(TIC) nozzle to investigate the influence of ambient density and pressure on flow separation. Six different altitudes from a typical flight are considered, from a very low altitude to a high altitude. The flow is analyzed by varying the nozzle pressure ratios corresponding to these altitudes. Both cold flow and hot flow simulations are conducted. The locations of separation positions at various altitude conditions are accurately captured and are found to be in good agreement with experimental results. The results of the study establish that for a given nozzle pressure ratio, the flow separation point is shifted upstream with increasing altitude. This clearly points to a dependence of separation position on the altitude of operation for TIC rocket nozzles.

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均相和非均相催化微藻脂质提取和酯交换制备生物燃料的研究进展

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Chinese Journal of Catalysis 2024年第4期59卷 97-117页

作者： Vinoth Kumar Ponnumsamy Hussein E.Al-Hazmi Sutha Shobana Jeyaprakash Dharmaraja Dipak Ashok Jadhav Rajesh banu J Grzegorz Piechota Bartłomiej Igliński Vinod Kumar Amit Bhatnagar Kyu-Jung Chae Gopalakrishnan Kumar 高雄医科大学药物与应用化学系环境医学研究中心中国台湾高雄高雄医科大学医学研究部中国台湾高雄格但斯克理工大学土木与环境工程学院波兰纳鲁特维察格但斯克范朗大学工程与技术学院建筑绿色技术与可持续发展研究组越南胡志明市工程技术学院科学与人文系化学部印度泰米尔纳德邦韩国海洋大学海洋科学与工程学院环境工程系韩国釜山泰米尔纳德邦中央大学生命科学系印度泰米尔纳德邦 GPCHEM沼气研究与分析实验室波兰尼古拉斯哥白尼大学化学系波兰克兰菲尔德大学水与能源学院英国拉彭兰塔工业大学工程科学学院分离科学系芬兰韩国海洋大学海洋可再生能源工程专业韩国釜山延世大学土木与环境工程学院韩国首尔斯塔万格大学科学技术学院化学、生物科学与环境工程研究所挪威斯塔万格

随着化石燃料燃烧导致的二氧化碳排放不断加剧气候变化,且化石燃料储量日益减少,寻求可再生能源已成为一项紧迫的任务.其中,藻类衍生可持续燃料因具有成本优势和可运输性,在解决全球能源危机方面展现出广阔前景,备受关注.利用化学转化... 详细信息

随着化石燃料燃烧导致的二氧化碳排放不断加剧气候变化,且化石燃料储量日益减少,寻求可再生能源已成为一项紧迫的任务.其中,藻类衍生可持续燃料因具有成本优势和可运输性,在解决全球能源危机方面展现出广阔前景,备受关注.利用化学转化技术从微藻中提取脂质,并通过酯交换反应可以将其转化为脂肪酸甲酯,是生产绿色生物燃料的有效途径.这一过程涉及游离脂肪酸、磷脂和甘油三酯的提取,并且生产过程能耗低,成为满足日益增长的能源需求的一种理想解决方案.本文综述了微藻脂质提取和酯交换制备生物燃料的相关研究进展.首先,介绍了微藻脂质的提取方法,包括溶剂提取法、索氏提取法、布利格和戴耶法、超临界二氧化碳提取以及离子液体溶剂法等,并分析了各方法的优缺点.随后,重点阐述了酯交换技术在微藻脂质转化中的应用,包括酸碱催化、酶催化以及原位酯交换反应等,并探讨了这些技术的反应机理、催化剂选择、反应器设计以及生物油生产工艺等方面的研究进展.通过综述上述研究进展,为微藻脂质的生产和应用提供了理论指导.研究表明,通过优化催化剂种类、反应条件以及提取方法,可以有效提高微藻脂质的转化效率和生物油品质.同时,本文也指出了当前微藻脂质生产中面临的挑战,如微藻栽培和生长条件优化、高效转化技术的开发等.随着可持续能源日益受到重视,微藻脂质作为一种可再生能源具有巨大的发展潜力.未来研究应进一步关注微藻的规模化栽培、生长条件优化以及高效转化技术的研发,以提高微藻脂质的产量和品质.同时,应进一步推动和实现微藻生物燃料的实际应用,从而为应对气候变化和能源危机提供有效的解决方案.

关键词：微藻脂质提取酯交换催化酶催化原位技术

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An incidental case of triple gallbladder

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World Journal of Gastroenterology 2007年第13期13卷 2004-2006页

作者： banu Alicioglu Department of Radiology Trakya University School of Medicine Edirne 22030 Turkey

Triplication of the gallbladder is a very rare congenital anomaly of the biliary tract; there are only eleven reported cases to date. Gallbladder multiplications are not likely to be discovered unless associated with cholelithiasis, sludge, cholecystitis and carcinoma. Here we report an incidentally diagnosed triplicate gallbladder in a patient with sigmoid diverticulitis; two of the triplicate gallbladder were demonstrated with ultrasound and computed tomography, and an additional galballder was found at surgery.

关键词： Biliary system Biliary tract imaging Multiplegallbladders Triple gallbladder

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Use of polymeric sub-micron ion-exchange resins for removal of lead,copper,zinc,and nickel from natural waters

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Journal of Environmental Sciences 2019年第1期31卷 247-254页

作者： Audrey Murray banu ?rmeci Department of Civil and Environmental Engineering Carleton University

This research investigated the removal capacity of polymeric sub-micron ion-exchange resins(SMR) for removal of lead, copper, zinc, and nickel from natural waters in competition with natural organic matter(NOM). Polymeric SMR particles were created and tested to ensure that they were adequately dispersed in the solution. They removed little NOM(10%or less) from river water and wastewater, indicating that competition from NOM was not a major concern. SMR were able to remove 82% ± 0.2% of lead, 46% ± 0.6% of copper, 55% ±20% of zinc, and 17% ± 2% of nickel from river water spiked with 500 μg/L of each. Similarly,in wastewater, they were able to remove 86% ± 0.1% of lead, 38% ± 0.8% of copper, 28% ± 1%of zinc, and 11% ± 1% of nickel.

关键词： Water Wastewater Heavy metals Ion exchange Polymeric submicron resin Natural organic matter (NOM)

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Competitive effects of humic acid and wastewater on adsorption of Methylene Blue dye by activated carbon and non-imprinted polymers

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Journal of Environmental Sciences 2018年第4期30卷 310-317页

作者： Audrey Murray banu Ormeci Department of Civil and Environmental Engineering Carleton UniversityOttawa ON K1S 5B6 Canada

Natural organic matter（NOM）, present in natural waters and wastewater, decreases adsorption of micropollutants, increasing treatment costs. This research investigated mechanisms of competition for non-imprinted polymers（NIPs） and activated carbon with humic acid and wastewater. Three different types of activated carbons（Norit PAC 200,Darco KB-M, and Darco S-51） were used for comparison with the NIP. The lower surface area and micropore to mesopore ratio of the NIP led to decreased adsorption capacity in comparison to the activated carbons. In addition, experiments were conducted for single-solute adsorption of Methylene Blue（MB） dye, simultaneous adsorption with humic acid and wastewater, and pre-loading with humic acid and wastewater followed by adsorption of MB dye using NIP and Norit PAC 200. Both the NIP and PAC 200 showed significant decreases of 27% for NIP（p = 0.087） and 29% for PAC 200（p = 0.096） during simultaneous exposure to humic acid and MB dye. There was no corresponding decrease for NIP or PAC 200 pre-loaded with humic acid and then exposed to MB. In fact, for PAC 200, the adsorption capacity of the activated carbon increased when it was pre-loaded with humic acid by 39%（p = 0.0005）. For wastewater, the NIP showed no significant increase or decrease in adsorption capacity during either simultaneous exposure or pre-loading. The adsorption capacity of PAC 200 increased by 40%（p = 0.001） for simultaneous exposure to wastewater and MB. Pre-loading with wastewater had no effect on MB adsorption by PAC 200.

关键词： Molecularly imprinted polymer Non-imprinted polymer Water treatment Wastewater treatment Activated carbon Micropollutants Pore-blocking Adsorption

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An Effective Discrete Artificial Bee Colony Based SPARQL Query Path Optimization by Reordering Triples

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Journal of Computer Science & Technology 2021年第2期36卷 445-462页

作者： Zeynep banu Ozger Nurgul Yuzbasioglu Uslu Department of Computer Engineering Sutcu Imam UniversityKahramanmaras 46040Turkey Department of Computer Engineering Yildiz Technical UniversityIstanbul 34220Turkey

Semantic Web has emerged to make web content machine-readable,and with the rapid increase in the number of web pages,its importance has *** description framework(RDF)is a special data graph format where Semantic Web data are stored and it can be queried by SPARQL query *** challenge is to find the optimal query order that results in the shortest period of *** this paper,the discrete Artificial Bee Colony(dABCSPARQL)algorithm is proposed,based on a novel heuristic approach,namely reordering SPARQL *** processing time of queries with different shapes and sizes is minimized using the dABCSPARQL *** performance of the proposed method is evaluated on chain,star,cyclic,and chain-star queries of different sizes from the Lehigh University Benchmark(LUBM)*** results obtained by the proposed method are compared with those of ARQ(a SPARQL processor for Jena)query engine,the Ant System,the Elitist Ant System,and MAX-MIN Ant System *** experiments demonstrate that the proposed method significantly reduces the processing time,and in most queries,the reduction rate is higher compared with other optimization methods.

关键词： artificial bee colony resource description framework(RDF) query optimization reordering triple pattern SPARQL

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Synthesis and characterization of monosize magnetic poly(glycidyl methacrylate) beads

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China Particuology 2007年第1期5卷 174-179页

作者： Evrim banu Alt■ntas■ Lokman Uzun Adil Denizli Department of Chemistry Biochemistry Division Hacettepe University Ankara Turkey

Monosize, 1.6 μm, magnetic beads of poly（glycidyl methacrylate） [M-poly（GMA）], were prepared by dispersion polymerization in the presence of Fe3O4 nano-powder. Monosize M-poly（GMA） beads were characterized by swelling tests, density measurements, electron spin resonance （ESR）, vibrating sample magnetometer （VSM） and scanning electron microscopy （SEM）. The characteristic functional groups of M-poly（GMA） beads were analyzed by Fourier transform infrared spectrometer （FTIR）. The M-poly（GMA） beads are highly uniform in size and have a spherical shape and non-porous structure. Polydispersity index （PDI） of M-poly（GMA） beads was calculated to be around 1.008. The hydrated density of the M-poly（GMA） beads measured at 25 ℃ was 1.14 g/cm^3. The content of oxirane groups on the surface of the M-poly（GMA） sample was found to be 3.46 mmol/g by using perchloric acid titration. The specific surface area of the M-poly（GMA） beads was determined to be 3.2 m^2/g. The equilibrium swelling ratio was 52%. The volume fraction of magnetite nanopowder in the M-poly（GMA） beads was found to be 4.5%. The g factor, that can be considered as a quantity characteristic of the molecules in which the unpaired electrons are located, was found to be 2.28 for M-poly（GMA）. The external magnetic field at resonance was calculated to be 2055 Gs which was found sufficient to excite all of the dipole moments present in 1.0 g of M-poly（GMA） sample.

关键词： Polyglycidyl methacrylate Monosize beads Magnetic materials

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