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Change in carbonate budget and composition during subduction below metal saturation boundary

Geoscience Frontiers 2023年第1期14卷 79-100页

作者： anton shatskiy anton V.Arefiev Konstantin D.Litasov Vernadsky Institute of Geochemistry and Analytical Chemistry Russian Academy of SciencesMoscow 119991Russia Vereshchagin Institute for High Pressure Physics Russian Academy of SciencesTroitskMoscow 108840Russia

It is generally accepted that carbonates can be subducted to the mantle depths,where they are reduced with iron metal to produce a *** this work,we found that this is not always the *** mantle carbonates from inclusions in diamonds show a wide range of cation compositions(Mg,Fe,Ca,Na,and K).Here we studied the reaction kinetics of these carbonates with iron metal at 6-6.5 GPa and 1000-1500℃.We found that the reduction of carbonate with Fe produces C-bearing species(Fe,Fe-C melt,Fe_(3)C,F e_(7)C_(3),C)and wüistite containing Na_(2)O,CaO,and *** reaction rate constants(k=△x^(2)/2t)are log-linear relative to 1/T and their temperature dependences are determined to be k_(MgcO_(3))(m^(2)/s)=4.37×10^(-3)exp[-251(kJ/mol)/RT]k_(caMg(CO_(3))2)(m^(2)/s)=1.48×10^(-3)exp[-264(kJ/mol)/RT]k_(cacO_(3))(m^(2)/s)=3.06×10^(-5)exp[-245(kJ/mol)/RT]and k_(Na_(2)cO_(3))(m^(2)/s)=1.88×10^(-10)exp[-155(kJ/mol)/RT].According to obtained results at least,45-70 vol%of carbonates preserve during subduction down to the 660-km discontinuity if no melting *** slab stagnation and warming,subsequent carbonate melting,and infiltration into the mantle saturated with iron metal are accompanied by a reduction of carbonate melt with *** established sequence of reactivity of carbonates:FeCO_(3)≥MgCO_(3)>CaMg(CO_(3))2>CaCO_(3)>>Na_(2)CO_(3),where K_(2)CO_(3)does not react at all with iron metal,implies that during reduction carbonate melt with Fe evolves toward *** above conclusions are consistent with the findings of carbonates in inclusions in diamonds from the lower mantle and high concentrations of alkalis,particularly K,in mantle carbonatite melts entrapped by diamonds from kimberlites and placers worldwide.

关键词： Carbonate Reduction of carbonate with Fe Reaction kinetics Carbonatite melt High-pressure experiment Earth's mantle

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Genetic link between saline and carbonatitic mantle fluids:The system NaCl-CaCO_(3)-MgCO_(3)±H_(2)O±Fe^(0) at 6 GPa

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Geoscience Frontiers 2022年第6期13卷 59-74页

作者： anton shatskiy Ivan V.Podborodnikov anton V.Arefiev Altyna Bekhtenova Konstantin D.Litasov Vernadsky Institute of Geochemistry and Analytical Chemistry of the Russian Academy of Science Moscow 119991Russia Vereshchagin Institute for High Pressure Physics of the Russian Academy of Science TroitskMoscow108840Russia

Melt inclusions in kimberlitic minerals and diamonds indicate that chlorides are important constituents of mantle carbonatite ***,alkaline chlorides are important constituents of saline high-density fluids(HDFs)found in diamonds from kimberlites and placers around the *** compositional variations suggest that saline and carbonatitic HDFs could be genetically ***,the essence of this link remains unclear owing to the lack of data on phase relations in the chloridecarbonate systems under *** we studied subsolidus and melting phase relations in the system NaCl–CaCO_(3)–MgCO_(3)at 6 GPa and 1000–1600℃using a Kawai-type multianvil *** found that at 1000℃,subsolidus assemblage consists of halite,magnesite,and *** higher temperatures,the stabilization of dolomite splits the subsolidus area into two partial ternary fields:halite+magnesite+dolomite and halite+dolomite+*** minimum on the liquidus surface corresponds to the halite-dolomite-aragonite ternary eutectic,situated at 1100℃.The eutectic melt has Ca#89 and contains 30 wt.%Na Cl(26 mol%2NaCl).The system has two ternary peritectics:halite+dolomite=magnesite+liquid located near the ternary eutectic and magnesite+dolomite=Mg-dolomite+liquid situated between 1300 and 1400℃.Although under dry conditions incipient melting yields carbonatedominated melt,the addition of water facilitates the fusion of Na Cl and expands the liquid field to Na Cl-rich compositions with up to 70 wt.%Na *** obtained results favor the idea that hydrous saline melts/fluids(brines)found as inclusions in diamonds could be a lower temperature derivative of mantle carbonatite melts and disagree with the hypothesis on chloride melt generation owing to the chloridecarbonate liquid immiscibility since no such immiscibility was *** also studied the interaction of the NaCl–CaCO_(3)–MgCO_(3)system with iron metal and found that carbonate reduction produces Cbearing species(Fe^(0)

关键词： Chloride Carbonate Halite Melting T-X diagram Earth’s mantle

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The Mg-carbonate-Fe interaction:Implication for the fate of subducted carbonates and formation of diamond in the lower mantle

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Geoscience Frontiers 2019年第4期10卷 1449-1458页

作者： Naira S.Martirosyan Konstantin D. Litasov Sergey S. Lobanov Alexander F. Goncharov anton shatskiy Hiroaki Ohfuji Vitali Prakapenka Sobolev Institute of Geology and Mineralogy Russian Academy of ScienceKoptyuga ave.3Novosibirsk630090Russia Geophysical Laboratory Carnegie Institution for ScienceWashingtonDC20015USA Novosibirsk State University Pirogova st.2Novosibirsk630090Russia Geodynamic Research Center Ehime UniversityMatsuyamaEhime790-8577Japan Center for Advanced Radiation Sources University of ChicagoChicagoIL60637USA

The fate of subducted carbonates in the lower mantle and at the core-mantle boundary was modelled via experiments in the MgCO3-Fe^0 system at 70-150 GPa and 800-2600 Kin a laser-heated diamond anvil *** in situ synchrotro n X-ray diffraction and ex situ transmission electron microscopy we show that the reduction of Mg-carbonate can be exemplified by:6 MgCO3+19 Fe=8 FeO+10(Mg0.6Fe^0.4)O+Fe7 C3+3 *** presented results suggest that the interaction of carbonates with Fe^0 or Fe^0-bearing rocks can produce Fe-carbide and diamond,which can accumulate in the D"region,depending on its carbon to Fe *** to the sluggish kinetics of the transformation,diamond can remain metastable at the core-mantle boundary(CMB)unless it is in a direct contact with *** addition,it can be remobilized by redox melting accompanying the generation of mantle plumes.

关键词： Deep carbon cycle Carbonate Carbide High pressure Redox reaction

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高温高压下钛铁矿FeTiO3和（Fe,Mg）SiO3电导率

高温高压下钛铁矿FeTiO3和（Fe,Mg）SiO3电导率

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中国地球物理学会第22届年会

作者：吴小平张宝华 Tomoo Katsura anton shatskiy Takuya Matsuzaki 中国科学技术大学地球与空间科学学院中国科学技术大学地球与空间科学学院日本冈山大学地球内部研究所 Misasa Tottori-ken 682-0193 日本日本冈山大学地球内部研究所 Misasa Tottori-ken 682-0193 日本日本冈山大学地球内部研究所 Misasa Tottori-ken 682-0193 日本

＜正＞钛铁矿FeTiO3通常存在于金伯利岩包体中,在常温常压下FeTiO3表现为稳定的钛铁矿结构,压力超过16GPa时,钛铁矿结构转变为钙钛矿结构。由于钛铁矿结构也是地幔硅酸盐矿物（Fe,Mg）SiO3 在过渡地幔（410-660 km）温压条件下的主要矿...

＜正＞钛铁矿FeTiO3通常存在于金伯利岩包体中,在常温常压下FeTiO3表现为稳定的钛铁矿结构,压力超过16GPa时,钛铁矿结构转变为钙钛矿结构。由于钛铁矿结构也是地幔硅酸盐矿物（Fe,Mg）SiO3 在过渡地幔（410-660 km）温压条件下的主要矿物结构之一,因此钛铁矿FeTiO3的高温高压电导率测量将有助于理解结构类似的硅酸盐矿物（Fe,Mg）SiO3的电导率,进而帮助认识过渡地幔的电导率结构。

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