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Enhanced electrocatalytic CO_(2)reduction to formic acid using nanocomposites of In_(2)O_(3)@C with graphene

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Nano Research 2024年第6期17卷 5031-5039页

作者： Wenxiang Li Shuo Gao Chuanruo Yang Juntao Yang amjad Nisar Guolei Xiang Junsu Jin Beijing Key Laboratory of Membrane Science and Technology Beijing University of Chemical TechnologyBeijing 100029China Nanomaterials Research Group PDPINSTECHIslamabad 44000Pakistan Institute of Industrial Chemistry College of ChemistryBeijing University of Chemical TechnologyBeijing 100029China

In_(2)O_(3)is an effective electrocatalyst to convert CO_(2)to formic acid(HCOOH),but its inherent poor electrical conductivity limits the efficient charge transfer during the ***,the tendency of In_(2)O_(3)particles to agglomerate during synthesis further limits the exposure of active *** we address these issues by leveraging the template effect of graphene oxide and employing InBDC as a self-sacrificing template for the pyrolysis synthesis of In_(2)O_(3)@*** resulting In_(2)O_(3)@C/rGO-600 material features In_(2)O_(3)@C nanocubes uniformly anchored on a support of reduced graphene oxide(rGO),significantly enhancing the active sites *** conductive rGO network facilitates charge transfer during electrocatalysis,and the presence of oxygen vacancies generated during pyrolysis,combined with the strong electron-donating ability of rGO,enhances the adsorption and activation of CO_(2).In performance evaluation,In_(2)O_(3)@C/rGO-600 exhibits a remarkable HCOOH Faradaic efficiency exceeding 94.0%over a broad potential window of−0.7 to−1.0 V(*** hydrogen electrode(RHE)),with the highest value of 97.9%at−0.9 V(***)in a ***,the material demonstrates an excellent cathodic energy efficiency of 71.6%at−0.7 V(***).The study underscores the efficacy of uniformly anchoring metal oxide nanoparticles onto rGO for enhancing the electrocatalytic CO_(2)reduction performance of materials.

关键词： In_(2)O_(3)@C nanocomposite electrochemical CO_(2)reduction reduced graphene oxide oxygen vacancy

Electronic and thermoelectric properties of YbMg_(2)X_(2)(X=P,As,Sb,Bi)zintl compounds by first-principles method

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Journal of Rare Earths 2024年第1期42卷 147-154,I0006页

作者： Sajid khan Dil Faraz khan R.Neffati Tariq Usman Muhammad Waqar Ahsraf Shamim khan Saeed Ullah Jan G.Murtaza Department of Physics University of Science&Technology BannuBannu28100Pakistan Department of Physics Faculty of ScienceKing Khalid UniversityP.O.Box 9004AbhaSaudi Arabia Laboratoire de Physique de La Matiere Condensee Departement de PhysiqueFaculte des Sciences de TunisUniversite Tunis El ManarCampus Universitaire1060TunisTunisia Department of Physics Shaoxing UniversityShaoxing312000China Department of Mathematics&Natural Sciences Prince Mohammad Bin Fahd UniversityAlkhobar31952Saudi Arabia Materials Modeling Lab Department of PhysicsIslamia College Peshawar25120KhyberPakhtunkhwaPakistan

In this work the structural,electronic and thermoelectric properties of YbMg_(2)X_(2)(X=P,As,Sb,Bi)zintl compounds were investigated comprehensively using first principles *** electronic properties were studied using PBE GGA,TB-mBJ and hybrid(YS-PBE0)*** the structural parameters of optimized structures are in harmonious agreement to the available *** band structure study illustrates that the titled materials manifest metallic and semi metallic nature using PBE and TB-mBJ potentials while they show wide band gap semiconducting behavior by following hybrid(YS-PBE0)*** density of states(TDOS)and partial density of states(PDOS)were also calculated to glimpse the contribution of orbitals of atoms in the formation of *** properties were studied by using BoltzTraP2 code employed to *** get enormous values of Seebeck coefficient(S),power factor(PF)and thermoelectric figure of merit(ZT)for all the samples YbMg_(2)X_(2)(X=P,As,Sb,Bi),Moreover,the overwhelming transport properties for the titled compounds indicate the optimum level of carriers’concentration which pinpoints these materials to be better thermoelectrics in the 1-2-2 zintl family.

关键词： Zintl compounds Hybrid functional Band structure Thermoelectrics Rare earths

Performance of Text-Independent Automatic Speaker Recognition on a Multicore System

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Tsinghua Science and Technology 2024年第2期29卷 447-456页

作者： Rand Kouatly Talha Ali khan Faculty of Tech and Software Engineering University of Europe for Applied SciencesPotsdam 14469Germany

This paper studies a high-speed text-independent Automatic Speaker Recognition(ASR)algorithm based on a multicore system's Gaussian Mixture Model(GMM).The high speech is achieved using parallel implementation of the feature's extraction and aggregation methods during training and testing *** memory parallel programming techniques using both OpenMP and PThreads libraries are developed to accelerate the code and improve the performance of the ASR *** experimental results show speed-up improvements of around 3.2 on a personal laptop with Intel i5-6300HQ(2.3 GHz,four cores without hyper-threading,and 8 GB of RAM).In addition,a remarkable 100%speaker recognition accuracy is achieved.

关键词： Automatic Speaker Recognition(ASR) Gaussian Mixture Model(GMM) shared memory parallel programming PThreads OpenMP

Insight into the dynamics of non-Newtonian Carreau fluid when viscous dissipation,entropy generation,convective heating and diffusion are significant

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Applied Mathematics(A Journal of Chinese Universities) 2024年第1期39卷 34-46页

作者： ZHOU Shuang-shuang Muhammad Ijaz khan Sami Ullah khan Sumaira Qayyum School of Science Hunan City UniversityYiyang 413000China Department of Mechanical Engineering Prince Mohammad Bin Fahd UniversityP.O.Box1664Al-Khobar 31952Kingdom of Saudi Arabia Department of Mathematics Namal UniversityMianwali 42250Pakistan Department of Mathematics Quaid-I-Azam University 45320Islamabad 44000Pakistan

The investigation endorsed the convective flow of Carreau nanofluid over a stretched surface in presence of entropy generation *** novel dynamic of viscous dissipation is utilized to analyze the thermal mechanism of magnetized *** convective boundary assumptions are directed in order to examine the heat and mass transportation of *** thermal concept of thermophoresis and Brownian movements has been re-called with the help of Buongiorno *** problem formulated in dimensionless form is solved by NDSolve *** graphical analysis for parameters governed by the problem is performed with physical *** affiliation of entropy generation and Bejan number for different parameters is inspected in *** numerical data for illustrating skin friction,heat and mass transfer rate is also *** motion of the fluid is highest for the viscosity ratio *** temperature of the fluid rises via thermal Biot *** generation rises for greater Brinkman number and diffusion parameter.

关键词： heat generation surface reaction CNTs based nano uid stretching/shrinking sheet thermal radiation

A novel DLL4 missense mutation in a Chinese patient with Adams-Oliver syndrome

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Chinese Medical Journal 2019年第14期132卷 1755-1757页

作者： Xue Yu Rong-Rong Wang Shi-Rui Han Xiao Bai Xiaerbati Habulieti Yang Sun Li-Wei Sun Han Zhang amjad khan Xue Zhang Institute of Basic Medical Sciences Chinese Academy of Medical SciencesSchool of Basic MedicinePeking Union Medical CollegeBeijing 100005China Key Laboratory of Thalassemia Medicine Chinese Academy of Medical SciencesGuangxi Medical UniversityNanningGuangxi 530021China The Research Center for Medical Genomics China Medical UniversityShenyangLiaoning 110001China

To the Editor:Adams-Oliver syndrome (AOS,including 6 types) was initially reported in a three-generation family by Adams and Oliver in 1945,[1] with an estimated incidence of 1 in 225,000 live births.[2] Approximately 84% of AOS patients have terminal transverse limb defects,including amputations,syndactyly,brachydactyly,or oligodactyly.

关键词： Adams-Oliver syndrome(AOS) DLL4 missense mutation amputations

Interpretable Detection of Malicious Behavior in Windows Portable Executables Using Multi-Head 2D Transformers

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Big Data Mining and Analytics 2024年第2期7卷 485-499页

作者： Sohail khan Mohammad Nauman Computer Science Department Effat College of EngineeringEffat UniversityJeddah 23341Kingdom of Saudi Arabia

Windows malware is becoming an increasingly pressing problem as the amount of malware continues to grow and more sensitive information is stored on *** of the major challenges in tackling this problem is the complexity of malware analysis,which requires expertise from human *** developments in machine learning have led to the creation of deep models for malware ***,these models often lack transparency,making it difficult to understand the reasoning behind the model’s decisions,otherwise known as the black-box *** address these limitations,this paper presents a novel model for malware detection,utilizing vision transformers to analyze the Operation Code(OpCode)sequences of more than 350000 Windows portable executable malware samples from real-world *** model achieves a high accuracy of 0.9864,not only surpassing the previous results but also providing valuable insights into the reasoning behind the *** model is able to pinpoint specific instructions that lead to malicious behavior in malware samples,aiding human experts in their analysis and driving further advancements in the *** report our findings and show how causality can be established between malicious code and actual classification by a deep learning model,thus opening up this black-box problem for deeper analysis.

关键词： machine learning malware vision transformers Windows Protable Executable(PE)

Metabolic complications of psychotropic medications in psychiatric disorders:Emerging role of de novo lipogenesis and therapeutic consideration

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World Journal of Psychiatry 2024年第6期14卷 767-783页

作者： Mohammad M khan Zaw Ali khan Mohsin Ali khan Laboratory of Translational Neurology and Molecular Psychiatry Department of BiotechnologyEra’s Lucknow Medical College and Hospitaland Faculty of ScienceEra UniversityLucknow 226003India Era’s Lucknow Medical College and Hospital Era UniversityLucknow 226003India

Although significant advances have been made in understanding the pathophysiology of psychiatric disorders(PDs),therapeutic advances have not been very *** psychotropic medications can reduce classical symptoms in patients with PDs,their long-term use has been reported to induce or exaggerate various pre-existing metabolic abnormalities including diabetes,obesity and non-alcoholic fatty liver disease(NAFLD).The mechanism(s)underlying these metabolic abnormalities is not clear;however,lipid/fatty acid accumulation due to enhanced de novo lipogenesis(DNL)has been shown to reduce membrane fluidity,increase oxidative stress and inflammation leading to the development of the aforementioned metabolic ***,emerging evidence suggest that DNL dysregulation and fatty acid accumulation could be the major mechanisms associated with the development of obesity,diabetes and NAFLD after long-term treatment with psychotropic medications in patients with *** support of this,several adjunctive drugs comprising of anti-oxidants and antiinflammatory agents,that are used in treating PDs in combination with psychotropic medications,have been shown to reduce insulin resistance and development of *** conclusion,the above evidence suggests that DNL could be a potential pathological factor associated with various metabolic abnormalities,and a new avenue for translational research and therapeutic drug designing in PDs.

关键词： Psychotropic medications Metabolic complications De novo lipogenesis Obesity Diabetes Non-alcoholic fatty liver disease

IoT Smart Devices Risk Assessment Model Using Fuzzy Logic and PSO

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Computers, Materials & Continua 2024年第2期78卷 2245-2267页

作者： Ashraf S.Mashaleh Noor Farizah Binti Ibrahim Mohammad Alauthman Mohammad Almseidin amjad Gawanmeh School of Computer Sciences Universiti Sains MalaysiaPenangMalaysia Department Computer Center Al-Balqa Applied UniversitySaltJordan Department of Information Security Faculty of Information TechnologyUniversity of PetraAmmanJordan Department of Computer Science Tafila Technical UniversityTafilaJordan College of Engineering and IT University of DubaiDubaiUnited Arab Emirates

Increasing Internet of Things(IoT)device connectivity makes botnet attacks more dangerous,carrying catastrophic *** IoT botnets evolve,their dynamic and multifaceted nature hampers conventional detection *** paper proposes a risk assessment framework based on fuzzy logic and Particle Swarm Optimization(PSO)to address the risks associated with IoT *** logic addresses IoT threat uncertainties and ambiguities *** component settings are optimized using PSO to improve *** methodology allows for more complex thinking by transitioning from binary to continuous *** of expert inputs,PSO data-driven tunes rules and membership *** study presents a complete IoT botnet risk assessment *** methodology helps security teams allocate resources by categorizing threats as high,medium,or low *** study shows how CICIoT2023 can assess cyber *** research has implications beyond detection,as it provides a proactive approach to risk management and promotes the development of more secure IoT environments.

关键词： IoT botnet detection risk assessment fuzzy logic particle swarm optimization(PSO) cybersecurity interconnected devices

Can NogoA Be a Suitable Target to Treat Ischemic Stroke?

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Neuroscience Bulletin 2024年第4期40卷 557-560页

作者： Suliman khan Abdul Nasir Medical Research Center The Second Affiliated Hospital of Zhengzhou UniversityZhengzhou540014China

Treating stroke or restoring brain function after stroke remains challenging for clinicians[1,2].Researchers have largely focused on developing neuroprotective strategies and translating these discoveries from rodent experiments to the clinical setting;however,these have been typified by several failures[2].It is known that astrocytes play a crucial role in the pathogenesis of ischemic stroke[3,4].They are activated in response to stimuli arising from injury,characterized by drastic changes to their morphology and function-associated gene *** astrocytes exacerbate secondary neurodegeneration(repair of nervous tissue by the generation of new neurons,glial cells,axons,myelin,or synapses)[5]as well as provide neuroprotection during CNS pathologies[6].It is worth noting that myelin-related neurite growth inhibitors induce the suppression of axon regeneration after stroke[7].

关键词： protective NogoA clinical