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World Journal of Nano Science and Engineering 2012年第3期2卷 117-125页

作者： Nadiia A.Ivashchenko Wojciech Gac valentyn A.Tertykh viktor v.Yanishpolskii Sergei A.Khainakov alla v.dikhtiarenko Sylwia Pasieczna-Patkowska Witold Zawadzki Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine KyivUkraine Faculty of Chemistry Maria Curie-Skłodowska UniversityLublinPoland Department of Organic and Inorganic Chemistry Faculty of ChemistryUniversity of OviedoOviedoSpain

Novel in-situ reduction approach was applied for the synthesis of palladium nanoparticles in the pores of mesoporous silica materials with grafted siliconhydride groups. Matrices possessing different structural properties (MCM-41, SBA-15 and Silochrom) were used. Samples were studied by nitrogen adsorption-desorption method, low-angle X-ray diffraction, transmission electron microscopy (TEM) and FT-IR/PAS spectroscopy. The temperature-programmed oxidation (TPO) and reduction (TPR) methods were applied to examine reducibility of palladium species. Palladium containing catalysts were tested in methane oxidation reaction. It was demonstrated that relatively large pores in SBA-15 type silica facilitated formation of well-dispersed palladium nanoparticles confined in the pores channels. In the case of MCM-41 support, metallic palladium nanoparticles were formed on the external surface. The obtained materials showed high catalytic activity. Lower activity of the samples containing small crystallites located in the pore volume at high temperatures was related to worse accessibility of active sites to the reation mixture.

关键词： Palladium Nanoparticles Siliconhydride Groups Mesoporous Ordered Silica MCM-41 SBA-15 Palladium-Containing Nanocomposites Methane Oxidation

Artificial enhancement of sturgeon stock in freshwater reservoirs:A case study on sterlet Acipenser ruthenus of the Kama reservoir

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Aquaculture and Fisheries 2024年第2期9卷 287-294页

作者： Pavel B.Mikheev Semyon N.Kazarinov alla G.Melnikova Stanislav v.Ponosov Nikolai G.Petrenko Andrei I.Nikiforov Alexey Yu Puzik Olga N.Elchenkova Perm State National Research University Perm614990Russia Khabarovsk Branch of the Federal State Budget Scientific Institution“Russian Federal Research Institute of Fisheries and Oceanography”“KhabarovskNIRO” Khabarovsk680038Russia Perm Branch of the Federal State Budget Scientific Institution“Russian Federal Research Institute of Fisheries and Oceanography”“PermNIRO” Perm614991Russia Federal State Budget Scientific Institution“Russian Federal Research Institute of Fisheries and Oceanography”“vNIRO” Moscow117454Russia Moscow State Institute of International Relations(University)of the Ministry for Foreign Affairs of Russia“MGIMO” Moscow117454Russia Department of State Control Supervision and Protection of Aquatic Biological Resources for Perm KraiMiddle-Volga Regional Office of the Federal Fishery AgencyPerm614990Russia

The paper presents the results of the sterlet sturgeon Acipenser ruthenus reintroduction into the Kama Reservoir(Perm Krai,Russia)by sterlet fry from hatcheries into the reservoir since *** effectiveness of hatchery releases was evaluated by monitoring gillnet sampling *** results showed that the species was reported throughout entire Kama Reservoir,which contrasts with 1988-1994 data,when the species was registered only at the upper part of the reservoir near the Kama River *** highest number and biomass values of catch per unit effort(CPUE)of the sterlet were found in submerged river channels-the deepest habitats with flow conditions which are close to the ecological requirements of the *** distribution of the sterlet within the channel biotopes of the reservoir is defined by reduced *** biggest individuals and the widest size range of the sterlet were typical for the upper area of the reservoir and Chusovskoy Bay,which have the greatest *** smallest sizes were typical for fish from catches near the dam of the reservoir,which is consistent with the published data on the distribution of sterlet in reservoir *** presented results may indicate the artificial formation of the sterlet stock in the Kama Reservoir maintained by hatchery *** revealed distribution of the sterlet in the reservoir determines the direction of further research on natural reproduction and thus formation of an artificially formed ***,future studies are required to assess the possibility of hybridization of the sterlet of artificial origin with natural populations of the species,since the low genetic diversity of the sterlet released into the Kama Reservoir which can lead to irreversible loss of genetic individuality of the natural stocks of the species in the catchment of upper course of the Kama River.

关键词： Sterlet Acipenser ruthenus Kama reservoir Hatchery releases CPUE Artificial stock formation

Thermobarometry of Inclusions: Implications to the Structure of Lithospheric Mantle and Evolution in Time and Diamond Formation

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Acta Geologica Sinica(English Edition) 2021年第S1期95卷 18-21页

作者： Igor v.ASHCHEPKOv alla M.LOGvINOvA Zdislav v.SPETSIUS v.S.Sobolev Institute of Geology and Mineralogy SB RAS Novosibirsk 630090Russia Alrosa Stock Company Mirny 678174Russia

Thermobarometric calculations for mineral diamond inclusions and associations(DIA)provide a systematic comparison of PTXFO2 conditions for different cratons worldwide,using a database of 4440 mineral EPMA analyses(Ash... 详细信息

关键词： diamond inclusions craton garnet clinopyrogene orthopyroxene geothermal regime manle lithosphere

Early Holocene climate signals from stable isotope composition of ice wedges in the Chara Basin,northern Transbaikalia,Russia

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Geoscience Frontiers 2018年第2期9卷 471-483页

作者： Yurij K.vasil’chuk alla C.vasil’chuk Julia v.Stanilovskaya Geography and Geology Departments Lomonosov Moscow State UniversityMoscowRussia Sergeev Environmental Geoscience Institute of the Russian Academy of Sciences Russia

Stable isotope composition of syngenetic and epigenetic ice wedges, radiocarbon age, and pollen spectra of the surrounding deposits were studied during long term investigations at the "Belyi Klyuch" site on the first(6-8 m height) terrace of the Chara River(720 m.a.s.l.) in northern Transbaikalia to assess climatic conditions during ice-wedge formation. It was revealed that Holocene ice wedges had been formed from 10 to 7.5 ka 14 C BP. The isotope composition(δ^(18)O, δ~2 H) of relict ice wedges is the lightest and amounts-23‰ and-185‰, correspondingly. The isotopic compositions of ice lenses from sandy loam above ice wedges are-15.7‰, and-133‰; of small ice wedge in peat and sand are-15.3‰ and-117.9‰, *** of the ice wedge isotope composition has yielded that mean winter temperatures during cold stages of Holocene optimum were lower than today, during warm stages they were close to modern ones. During the coldest stages of Holocene optimum the total annual freezing index varied from-5100 to-5700 ℃ degree days, i.e. 300-600 ℃ degree days colder than during extremely severe modern winters. The total annual thawing index varied from 1300 to 1800 ℃ degree days, which was slightly higher than modern ones.

关键词： Holocene Ice wedge Stable isotopes Southern permafrost areas Northern Transbaikalia

Pulsed laser reshaping and fragmentation of upconversion nanoparticles-from hexagonal prisms to ID nanorods through“Medusa”-like structures

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Nano Research 2021年第4期14卷 1141-1148页

作者： Laszlo Sajti Denis N.Karimov vasilina v.Rocheva Nataliya A.Arkharova Kirill v.Khaydukov Oleg I.Lebedev Alexey E.voloshin alla N.Generalova Boris N.Chichkov Evgeny v.Khaydukov AIT Austrian Institute of Technology GmbH Wiener Neustadt2700Austria Federal Scientific Research Centre“Crystallography and Photonics”Russian Academy of Sciences Moscow119333Russia Laboratoire CRISMAT UMR6508CNRS-ENSIACENUniversite CaenCaen14050France Shemyakin-Ovchinnikov Institute of Bioorganic Chemistry of the Russian Academy of Sciences Moscow 117997Russia Institutfiir Quantenoptik Leibniz Universitat HannoverHannover30167Germany Center of Biomedical Engineering Institute of Molecular Medicine Sechenov First Moscow State Medical UniversityMoscow119991Russia

One dimensional(1D)nanostructures attract considerable attention,enabling a broad application owing to their unique ***,the precise mechanism of 1D morphology attainment remains a matter of *** this study,ultrafast picosecond(ps)laser-induced treatment on upconversion nanoparticles(UCNPs)is offered as a tool for 1 D-nanostructures ***,reshaping through recrystallization process and bioadaptation of initially hydrophobic(β-Na_(1.5)Y_(1.5_)F_(6):Yb^(3+),Tm^(3+)/β-Na_(1.5)Y_(1.5_)F_(6))core/shell nanoparticles by means of one-step laser treatment in water are demonstrated.“True”1D nanostructures through"Medusa^-like structures can be obtained,maintaining anti-Stokes luminescence functionalities.A matter of the one-dimensional UCNPs based on direction of energy migration processes is *** proposed laser treatment approach is suitable for fast UCNP surface modification and nano-to-nano transformation,that open unique opportunities to expand UCNP applications in industry and biomedicine.

关键词： upconversion nanoparticles fluoride crystals upconversion nanorods one-dimensional(1D)structures laser-induced reshaping

Thinning of Emulsion Water-in-Oil Films Stabilized with Modified Aluminum Hydroxide under Influence of Applied Pressure Drop

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Soft 2014年第1期3卷 11-17页

作者： alla v. Nushtaeva Department of Physics and Chemistry Penza State University of Architecture and Building Penza Russia

The results of studies of thinning free water-in-oil emulsion films stabilized by solid particles by the Applied Pressure Drop Technique (APDT) are reported. The quasi-equilibrium film thickness achieved by slow increasing the pressure drop was smaller than the rupture thickness obtained by sharp increasing the pressure. It is shown that non-equilibrium films ruptured with thicknesses corresponding to adjustment of the packing of solid particles in the films. It is supposed that the restructuring package is the cause of the earlier breakthrough of the film.

关键词： Solid Emulsifier Emulsions Films Pressure Drop Technique

Tumor cell death visualization of renal cell carcinoma under the combined effect of the Gratiola officinalis extract and cyclophosphamide using fluorescent staining methods

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Journal of Innovative Optical Health Sciences 2021年第5期4卷 46-52页

作者： Artyom Mylnikov Nikita Navolokin Dmitry Mudrak Natalya Polukonova alla Bucharskaya Galina Maslyakova Saratov State Medical University named after V.I.Razumovsky 112 Bolshaya Kazachia Street Saratov 410012Russia National Research Saratov State University 83 Astrakhanskaya Street Saratov 410012Russia National Research Tomsk State University 36 Lenin Avenue Tomsk 634050Russia

Objective of the study:We used fluorescence imaging methods of apoptosis and necrosis in human renal carcinoma A498 tumor cells in vitro to reveal the indicated forms of cell death under the combined effect of flavonoid-containing extract of Gratiola officinalis and cytostatic(cyclo-phosphamide).Materials and methods:The dyes were propidium iodide and acridine orange,which were used in the"alive and dead"*** test helped us to identify the total number of dead cells in the forms of necrosis and apoptosis and the number of cells in which apoptosis had started,it was characterized by the appearance of apoptotic bodies or nucleus ***:We found the most pronounced cytotoxic activity at the ratio of extract of Gratiola officinalis and cyclophosphamide concentrations of 1∶*** number of living cells decreased when exposed to the ratio of extract and cytostatic concentrations of 2∶*** the ratio of concentration of the extract relative to the cytostatic increased to 3∶1,the cytostatic activity of the extract began to appear,the total number of tumor cells *** number of cells with nucleus pyknosis and the number of cells with apoptosis signs significantly increased at a 3∶1 ratio of extract and cytostatic concentrations,which confirms the presence of pro-apoptotic activity of the studied *** trend indicates the dependence of a certain form of cell death(apoptosis,necrosis)on the ratio of extract and cytostatic doses,and it also demon-strates the cytostatic and cytotoxic effects of this ***:Fluorescence methods of investigation in the"alive and dead"test allowed us to visualize the forms of cell death of human kidney carcinoma A498 by combined exposure to the fiavonoid-containing extract of Gratiola officinalis and cytostatic(cyclophosphamide)24 h after *** found that the combination with a concentration ratio of the extract and cyclophosphamide of 3:1 has the greatest effectiveness due to stimulation of t

关键词： A498 cell line Gratiola officinalis extract antitumor activity cytostatic activity flavonoids fluorescent methods kidney cancer

Maximum power point tracking using decision-tree machine-learning algorithm for photovoltaic systems

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Clean Energy 2022年第5期6卷 762-775页

作者： P.venkata Mahesh S.Meyyappan RamaKoteswara Rao alla Department of Electronics and Instrumentation Engineering Annamalai UniversityChidambaramIndia Department of Instrumentation Engineering Madras Institute of TechnologyChennaiIndia Department of EEE RVR&JC College of EngineeringGunturIndia

This work presents a machine-learning(ML)algorithm for maximum power point tracking(MPPT)of an isolated photovoltaic(Pv)*** to the dynamic nature of weather conditions,the energy generation of Pv systems is *** there is no specific method for effectively dealing with the non-linear data,the use of ML methods to operate the Pv system at its maximum power point(MPP)is desirable.A strategy based on the decision-tree(DT)regression ML algorithm is proposed in this work to determine the MPP of a Pv *** data were gleaned from the technical specifications of the Pv module and were used to train and test the *** algorithms predict the maximum power available and the associated voltage of the module for a defined amount of irradiance and *** boost converter duty cycle was determined using predicted *** simulation was carried out for a 10-W solar panel with a short-circuit current of 0.62 A and an open-circuit voltage of 21.50 v at 1000 W/m^(2) irradiance and a temperature of 25℃.The simulation findings demonstrate that the proposed method compelled the Pv panel to work at the MPP predicted by DTs compared to the existing topologies such asβ-MPPT,cuckoo search and artificial neural network *** the proposed algorithm,efficiency has been improved by>93.93%in the steady state despite erratic irradiance and temperatures.

关键词： boost converter decision tree maximum power point tracking photovoltaic system regression machine learning

A detailed reconstruction of changes in the factors and parameters of soil erosion over the past 250 years in the forest zone of European Russia(Moscow region)

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International Soil and Water Conservation Research 2022年第1期10卷 149-160页

作者： Andrey Zhidkin Daria Fomicheva Nadezhda Ivanova Tomas Dostal alla Yurova Mikhail Komissarov Josef Krasa v.v.dokuchaev soil science institute pyzhevskiy pereulok 7moscow119017russian federation Faculty of geography lomonosov moscow state universityleninskie gorygsp-1moscow119991russian federation Department of landscape water conservation faculty of civil engineeringczech technical university in praguethakurova 7prague16629czech republic Ufa institute of biology ufrc russian academy of sciencespr.oktyabrya 69ufa450054russian federation

Accelerated soil erosion is a major threat to soil,and there are great variations in the rate of soil erosion over time due to natural and human-induced *** temperate forest zone of Russia is character-ized by complex stages of land-use history(*** urbanization,agricultural development,land abandonment,etc.).We have for the first time estimated the rates of soil erosion by the WaTEM/SEDEM model(rainfall erosion)and by a regional model(snowmelt erosion)over the past 250 years(from 1780 to 2019)for a 100-km2 study site in the Moscow region of *** calculations were made on the basis of a detailed historical reconstruction of the following factors:the location of the arable land,crop rotation,the rain erosivity factor,and the maximum snow water *** area of arable land has decreased more than 3.5-fold over the past 250 *** the end of the 20th century,the rates of gross erosion had declined more than 5.5-fold(from 28×10^(3) to 5×10^(3) t·ha^(-1)yr^(-1))in comparison with the end of the 18th *** in the boundaries of arable land and also the relief features had led to a significant intra-slope accumulation of *** a result of sediment redeposition within the arable land,the variation in net soil erosion was significantly lower than the variation in gross soil *** changes in arable land area and in crop composition are the factors that have to the greatest extent determined the changes in soil erosion in this territory.

关键词： Anthropogenic soil erosion Soil erosion history Crop rotation Magnetic tracer method WaTEM/SEDEM

On an Axiomatic about Functional Means

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Analysis in Theory and Applications 2018年第1期34卷 36-44页

作者： Mustapha Raissouli Mohamed Chergui Abdellah alla Department of Mathematics Science Faculty Taibah University AI Madinah AI Munawwarah P.O.Box 30097 Zip Code 41477 Saudi Arabia Department of Mathematics Science Faculty Moulay Ismail University Meknes Morocco Department of Mathematics LaREAMA Lab Centre Regional des Metiers de l'Education et de la Formation (CRMEF) Kenitra Morocco Department of Mathematics Mohammed V University Faculty of Sciences LAMA-ANLIMAD Rabat Morocco

In this paper, we introduce an axiomatic approach about functional means. This includes that of operator means already introduced in the literature.

关键词： Functional mean operator mean convex function.