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Advances in Materials Physics and Chemistry 2024年第8期14卷 137-145页

作者： Wedjers Max Robin Manouan Bi Irié Hervé Gouré Doubi Lébé Prisca Marie-Sandrine Kouakou Atta kouam. Brice Koffi alfred niamien kouam. Namory Méité UFR Sciences et Technologies Universit de Man Man Cte dIvoire UFR Sciences Biologiques Universit Peleforo GON COULIBALY Korhogo Cte dIvoire Laboratoire de constitution et de raction de la matire Universit Felix Houphout-Boigny Abidan Cte dIvoire

This work was devoted to the study of the physico-chemical properties of two clay minerals from the Mountain District (West Côte d'Ivoire) referenced ME1 and ME2. These samples were characterized by the experimental techniques, such as X-ray diffraction (XRD), Infrared spectroscopy (IR), Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES), Differential Thermal Analysis and Thermogravimetry (DTA-TG), Brunauer, Emett and Teller method (BET), laser particle size analysis and Scanning Electron Microscope (SEM). The main results of these analyses reveal that the two clay samples mainly contain quartz (52.91% for ME1 and 51.72% for ME2), kaolinite (36.60% for ME1 and 41.6% for ME2) and associated phases, namely goethite and hematite (13.47% for ME1 and 11.00% for ME2). The specific surface values obtained for samples ME1 and ME2 are 34.78 m2/g and 29.18 m2/g respectively. The results obtained show that the samples studied belong to the kaolinite family. After calcination, they could have good pozzolanic activity and therefore be used in the manufacture of low-carbon cements.

关键词： Quartz Kaolinite Mountain District Low-Carbon Cements

Thermal Conductivity of Compressed Earth Bricks Strengthening by Shea Butter Wastes with Cement

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Materials Sciences and Applications 2017年第12期8卷 848-858页

作者： Herve Goure Doubi alfred niamien kouam. Léon Koffi Konan Monique Tognonvi Samuel Oyetola Unité de Formation et de Recherche des Sciences biologiques Université Péléforo Gon Coulibaly de Korhogo Korhogo C&ocirc te d’Ivoire Laboratoire de Chimie des Matériaux Inorganiques (LCMI) Université Félix Houphou&euml t-Boigny de Cocody-Abidjan Abidjan C&ocirc te d’Ivoire

Currently, in a context of sustainable development, the economic and environmental challenges incite, to valorize local materials such as clays and agro-industrial waste. It is in this approach that a new category of compressed earth bricks (BTC) stabilized with shea meal (TK) and cement was proposed. The purpose of this paper is to investigate the effect of shea meal rate on the thermal conductivity properties of cement stabilized earth bricks. A lateritic clay (Lat) mainly composed of kaolinite (38.44%), quartz (24.94%), goethite (12.28%), hematite (4.44%) and illite (19.9%) was used to make bricks. Different mix designs made up of lateritic clay and 5% cement were studied. The shea meal is added as a partial lateritic clay replacement in different proportions. The thermal conductivity was determined by hot disk method and correlated to both porosity and density of elaborated materials. The results obtained show that the thermal conductivity and density of bricks decrease respectively from 0.72 W·m-1·K-1 to 0.52 W·m-1·K-1 and from 2.77 g·cm-3 to 2.52 g·cm-3. The presence of shea meal within the material generates pore formation, which may partly explain the improvement of the thermal insulation properties. A positive correlation was noted between density and thermal conductivity of these materials.

关键词： Lateritic Clay Shea Meal Compressed Earth Brick (CEB) Thermal Conductivity and Eco-Materials

Diagnosis of Wastewater Contamination by Metalic Trace Elements (MTE) in the Areas of Yopougon (South Abidjan) and Marcory, Koumassi (North Abidjan) from March to July 2021

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Journal of Materials Science and Chemical Engineering 2023年第10期11卷 19-28页

作者： Lydie Nina Amon Aboubakar Sidik Diaby alfred niamien kouam. kouam. Eric Yao Ali Sanou Léon Koffi Konan Kalpy Julien Coulibaly Mireille Dosso Institut Pasteur of Cô te d’Ivoire Environment and Health Department Abidjan C&#244te d’Ivoire Ivorian Anti-Pollution Center Abidjan C&#244te d’Ivoire Laboratory of Composition and Reaction of Matter Félix Houphou&#235t-Boigny University Abidjan C&#244te d’Ivoire Laboratory of Hydrobiology Felix Houphouet Boigny University Abidjan C&#244te d’Ivoire Institut National Polytechnique of Félix Houphouë t-Boigny (INP-HB) Laboratory of Industrial Synthesis Processes Environment and New Energies (LAPISEN) Yamoussoukro C&#244te d’Ivoire

Contamination of the aquatic environment by Metallic Trace Elements (MTE) is a major problem encountered in our environment today. In Côte d’Ivoire, in some municipals, residential and industrial areas in the city of Abidjan, waste water of worrying quantity is discharged into the rainwater drainage channels which flow directly into the Ebrié lagoon. In order to identify the origin of the pollution by metallic trace elements (MTE) transported by this water, samples of wastewater were collected and then analyzed. ICP-MS was used for MTE (Cu, Fe, Zn, Al, Pb, Cd) analyses and results were statistically processed in multivariate form using PCA and Excel. The results showed high concentrations of metals, with the exception of Cd. The typological structure represents 85.74% of the total information for the MTE. Plan F1 represents 63.90% of the variance and describes water pollution by copper (0.95), zinc (0.90), iron (0.84) and aluminum (0.84). Plan F2 represents 21.84% and describes the enrichment of water with lead (0.84). It seems more than necessary to make manufacturers aware of the need to install wastewater treatment systems in order to avoid their discharge into the environment.

关键词： MTE Wastewater Typology

Microbiological and chemical hazards of commercial attieke (a fermented cassava product) produced in the south of Côte d’Ivoire

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Food Quality and Safety 2019年第3期3卷 187-190页

作者： kouam. Kohi alfred Bouatenin Koffi Maizan Jean Pau Djeni N’Dede Théodore Dje Koffi Marcellin Department of Food Sciences and Technology Laboratory of Biotechnology and food MicrobiologyUniversity of Nangui AbrogouaAbidjanCôte d’Ivoire Food Security Research Group Centre Suisse de Recherche ScientifiqueAbidjanCote d’Ivoire

Objectives:Information on the distribution and presence of microbiology and chemical hazard of commercial attieke(a fermented cassava product)produced in the south of Côte d’Ivoire were *** and Methods:Microbiological analyses and chemical were carried out,which included the total viable bacteria,Staphylococcus aureus,Salmonella and Bacillus spores,heavy metal(pb,Cd,Mn,Fe,Cu,and Cr).Results and Conclusions:The results revealed that the viable bacteria counts ranged from in all of *** aureus counts in the samples were comprised between(1.8±0.4)10^(2)(Jacqueville localitie)and(4.3±1.8)10^(3)(Abidjan localitie).While that of Bacillus cereus was ranged from(1.1±0.9)10^(2)(Adzopélocalitie)and(5.1±3.2)10^(2)(Abidjan localitie).Salmonella *** not *** levels of Pb in all samples were between 2.2±0.1 mg/kg(Grand-lahou localitie)and 4.5 mg/kg±0.15(Abidjan localitie)while the Cd levels of the samples varied between 0.02±0.1 mg/kg(Adzopélocalitie)and 0.07±0.1 mg/kg(Divo localitie).The levels of Cr in the samples were comprised between 0.1±0.03 mg/kg(Adzopélocalitie)and 0.95±0.1 mg/kg(Abidjan localitie)while Fe(7.3±1.5 mg/kg)and Cu(1.7±0.2 mg/kg)levels were the highest,respectively in Sikensi and Grand-Lahou *** from Divo localitie contained high amounts of Mn(1.6±0.1 mg/kg).The occurrence of some microbiological and chemical hazard that commercial attieke collected in Cote d’Ivoire may act as a reservoir of pathogenic micro-organisms and heavy metal for human.

关键词： attieke heavy metal microbiogical and chemical hazard

Physico-Chemical Characterization of Two Dabou Clays with a View to Use Them in the Treatment of Dyeing Wastewater

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Journal of Minerals and Materials Characterization and Engineering 2022年第6期10卷 505-517页

作者： Wilfried Aristide Atsé Marc Marie-Maurice Mélèdge Essi Bi Irié Hervé Gouré Doubi Mahamadou Kamagaté Aké Pierre Aké alfred niamien kouam. Laboratory of Constitution and Reaction of Matter Félix Houphou&#235 t Boigny University Abidjan C&#244 te d’Ivoire Biological Sciences Training and Research Unit Péléforo Gon Coulibaly University Korhogo C&#244 te d’Ivoire Central Analysis Laboratory University of Man Man C&#244 te d’Ivoire

This work falls within the general framework of the valorization of the clays of Ivory Coast in order to propose innovative solutions in the resolution of certain problems related to development such as the depollution of water. Its main objective is therefore to study the physico-chemical properties of two Dabou clays with a view to using them in chemical processes for the treatment of dyeing wastewater. The results of the chemical analysis and the ray diffraction showed that the DAB 1 and DAB 2 samples are clays of the kaolinitic type consisting mainly of kaolinite with 51.17% for DAB 1 against 65.81% for DAB 2 and quartz with respectively 41.76% and 25.8% for DAB 1 and DAB 2. They also contain relatively large amounts of goethite with 9.96% for DAB 1 and 12.8% for DAB 2. The specific surfaces measured in both samples are greater than 25 m2/g. All the results of the physico-chemical characterization, in particular the presence in significant quantity of clay minerals, the presence of iron compounds and the large specific surface area of both samples, allow the conclusion that they can be used in adsorption studies and in the heterogeneous Fenton process for water treatment.

关键词： Clays Physico-Chemicals Water Treatment

Assessing Levels and Health Risks of Fluoride and Heavy Metal Contamination in Drinking Water

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Journal of Geoscience and Environment Protection 2022年第11期10卷 15-34页

作者： Ali Sanou Namory Méité Amadou Kouyaté Elisephane Irankunda alfred niamien kouam. Aka Eric Koffi Koffi Jean-Paul Bohoussou Lébé Prisca M.-S. Kouakou Institut National Polytechnique Félix Houphouë t-Boigny (INP-HB) Laboratoire des Procédés Industriels de Synthèses de l’Environnement et des Energies Nouvelles (LAPISEN) Yamoussoukro C&#244 te d’Ivoire Institut National Polytechnique Félix Houphouë t-Boigny (INP-HB) Laboratoire de Thermodynamique Traitement et Sciences des Surfaces et Interfaces Ingénierie et Physicochimie des Procédés et de Mécanique des Matériaux (L2-TSIPM) Yamoussoukro C&#244 te d’Ivoire Ecole Normale Supérieure (ENS) Laboratoire des Sciences Physiques Fondamentales et Appliquées (LSPFA) Abidjan C&#244 te d’Ivoire Université Félix Houphouë t-Boigny (UFHB) UFR SSMT Laboratoire de Constitution et Réaction de la Matière (LCRM) Abidjan C&#244 te d’Ivoire Université Félix Houphouë t-Boigny (UFHB) UFR SSMT Laboratoire de Constitution et Réaction de la Matière (LCRM) Abidjan C&#244te d’Ivoire Laboratoire des Sciences et Technologies de l’Environnement UFR Environnement Université Jean Lorougnon Guédé Daloa C&#244 te d’Ivoire School of Computer Science and Information Technology The East African University Kajiado Kenya

A systematic study was carried out to assess the level of contamination with fluorides and heavy metals in the drinking water of the city of Daloa as well as the risks to the health of consumers. The waters of 11.11% of the sites sampled exceeded the fluoride limit for drinking water with a contamination index (CI) greater than 0. All the waters recorded concentrations of cadmium (Cd), copper (Cu), iron (Fe), manganese (Mn) and lead (Pb) above the recommended values with CI > 0. However, 22.22% of the sites recorded concentrations below the standard for zinc (Zn) with IC 1 for children in 22.22% of drinking water studied. HQs have an average of less than 1 for fluorine and greater than 1 for all metals. Moreover, the danger indices have values greater than 1. The incremental lifetime cancer risk (ILCR) and the total ILCR are above the recommended values. These results showed that the drinking water sampled is of poor quality due to higher levels of heavy metals, which can constitute a danger to human health. Long-term use of one of these poor quality waters can lead to cancer in consumers. It is therefore necessary to treat this water in order to eliminate the metals before using it for drinking. This study can help decision-makers and competent authorities in charge of water management.

关键词： Physico-Chemical Parameters Fluoride Heavy Metals Drinking Water Sanitary Risks

Characterization of Two Clay Raw Materials from Côte d’Ivoire with a View to Enhancing Them in Eco-Construction

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Journal of Minerals and Materials Characterization and Engineering 2022年第2期10卷 198-208页

作者： Lébé Prisca M.-S. Kouakou alfred niamien kouam. Bi Irié Hervé Gouré Doubi Namory Méité Jean Thierry Kangah Esmel Privat Zokou Léon Koffi Konan Yao Jonas Andji-Yapi Laboratory of Constitution and Reaction of Matter University Felix Houphouet Boigny Abidjan Cote d’Ivoire Unit for Training and Research of Biological Sciences University Peleforo Gon Coulibaly Korhogo Cote d’Ivoire

This study was carried out with a view to appreciate the value of clay, raw materials in eco-construction. To achieve this, we sampled two clay raw materials denoted Aga and Bak and then characterized. The results obtained from geotechnical and mineralogical tests have shown that the clay samples Aga and Bak are fine soils moderately plastic class A soils consisting essentially of quartz with 73.13% and 74.56% respectively for Aga and Bak and clay minerals (kaolinite and illite) with 12.73% kaolinite and 8.55% illite for Aga against 8.31% kaolinite and 13.72% for Bak. Moreover, these samples do not contain swelling clays and contain a sufficient quantity of iron oxides which allows them to be valued in ceramics, in particular in compressed earth bricks (CEB).

关键词： Clays Compressed Earth Bricks Eco-Material Physico-Chemical and Geotechnical Properties

Mapping of the Sedimentary Facies of the Bottom of the Ouladine Lagoon in Grand-Bassam (Ivory Coast_West Africa)

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Journal of Geoscience and Environment Protection 2022年第10期10卷 163-175页

作者： Bi Kassia Francis Koffi Samassy Rokyatou Epouse Yeo Kouassi kouam. alfred Laboratory of Environmental Sciences and Technologies Department of Earth Sciences Jean Lorougnon Guédé University Daloa Ivory Coast

The Ouladine lagoon has an irregular bottom lined with different substrates. The lithological characteristics make it possible to observe sediments ranging from silts to sands and mixed sediments of variable color. These different fractions have varying proportions. The coarse fraction (>63 μm) has percentages ranging from 0 to 77% and the fine fraction ( μm) from 22.46 to 100% in the different sediments collected. The minority fraction of fine sands occupies the northern banks where the greatest depths of the section parallel to the coastal strip are observed. On the other hand, the sandy fractions occupy the southern shore up to the vicinity of the Azuretti mangrove island. This sandy fraction is also present on almost the entire section from the Comoé-Ebrié lagoon confluence to the closed mouth. The grain size characters of the sediments, such as the diagram of the classification coefficient So and the mean Mz, show well-classified sands. These sediments are deposited in a slightly agitated environment coming mainly from dunes and rivers. The sands of the estuarine complex were emplaced by saltation for most samples and by rotation.

关键词： Substrate Lithology Silts Sediments Barrier Beach Mouth Granulometric Estuarine Saltation

Assessment of Knowledge,Attitudes and Practices of Food Handlers in Attieke Production Units in Relation to Food Hygiene and Safety in Cote d’Ivoire in 2012

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Food and Nutrition Sciences 2014年第10期5卷 896-904页

作者： Theodore N.Djéni alfred K.kouam. Youssouf Traoré Rose K.Nevry Marcellin K.Dje Department of Food Sciences and Technology Laboratory of Biotechnology and food MicrobiologyUniversity Nangui AbrogouaAbidjanCote d’Ivoire Département Santé Publique et Informatique Médicale UFR Sciences MédicalesUniversité Félix Houphouet BoignyAbidjanCote d’Ivoire

The aims of this study were to investigate the food safety knowledge and practices of food handlers and to assess the sanitary conditions of attieke production units in the South of C?te d’Ivoire. A cross-sectional study was conducted during 4 months in 2012 in 7 localities and data were collected using questionnaire and observation checklist and microbiological analysis of hands. A total of 775 attieke production units were involved in this survey. Seventy-one percent (71%) were located on public domains and only 70 production units (9%) used septic tank as a mean of final deposal for liquid waste. Hygiene conditions and practices of food handlers in attieke production units were inadequate. The presence of specific microorganisms such as Staphylococcus aureus, Klebsiella pneumoniae, Enterobacter agglomerans, Citrobacter youngae, Klebsiella oxytoca and Citrobacter freundi was indicative of a degree of ignorance on the part of food handlers towards proper hygienic practices.

关键词： Attieke Food Handlers Hygienic Practices Production Units