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Expanded Porphyrin Exhibiting Off-Centered Out-of-Plane Coordination to Dysprosium

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CCS Chemistry 2024年第7期6卷 1731-1738页

作者： Dmitry I.Nazarov Jorge Labella alexey V.kuzmin Maxim A.Faraonov Evgenii N.Ivanov Salavat S.Khasanov Tomas Torres Mikhail K.Islyaikin Dmitri V.Konarev Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry RAS 142432 Chernogolovka Department of Organic Chemistry Universidad Autonoma de Madrid28049 Madrid Institute of Solid-State Physics RAS 142432 Chernogolovka Research Institute of Macroheterocycles Ivanovo State University of Chemistry and Technology15300 Ivanovo G.A.Krestov Institute of Solution Chemistry of the Russian Academy of Sciences 153045 Ivanovo Institute for Advanced Research in Chemical Sciences Universidad Autonoma de Madrid28049 Madrid IMDEA-Nanociencia 28049 Madrid

The complexation of high-spin lanthanides to porphyrinoids is a powerful strategy for the development of advanced molecular *** this context,the use of expanded porphyrinoids remains elusive since their coordination chemistry is challenging to ***,taking inspiration from on-surface chemistry,we explored the coordination of Dy^(3+)to a six-membered porphyrinoid,namely,the hemihexaphyrazine ***,we observed the selective formation of a mono-nuclear off-centered,out-of-plane H_(2)Hhp-Dy^(3+)complex when performing the complexation under reductive *** this reaction,the oxidation state of the macrocycle did not *** X-ray diffraction analysis,we found that the coordination number of Dy in this complex was *** macrocycle cocrystallized with decamethylcobaltocene(Cp_(2)^(*)Co)molecules,giving rise to a wellordered solid-state packing,governed byπ-π*** a result of this organization,a small magnetic coupling between the neighboring molecules was *** in all,this work provides key insights into the coordination of magnetically active metals with expanded porphyrinoids,thus motivating the development of advanced spintronic devices.

关键词： porphyrins dysprosium macrocycle coordination chemistry magnetism

Use of KDP crystal as a Kerr nonlinear medium for compressing PW laser pulses down to 10 fs

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High Power Laser Science and Engineering 2021年第4期9卷 86-92页

作者： Andrey Shaykin Vladislav Ginzburg Ivan Yakovlev Anton Kochetkov alexey kuzmin Sergey Mironov Ilya Shaikin Sergey Stukachev Vladimir Lozhkarev Artem Prokhorov Efim Khazanov Institute of Applied Physics of the Russian Academy of Sciences Nizhny Novgorod 603950Russia

The input pulse of the laser PEARL with energy of 18 J and pulse duration of about 60 fs was compressed to 10 fs after passage through a 4-mm-thick KDP crystal and reflection at two chirped mirrors with sum dispersion of-200 fs^(2).The experiments were performed for the B-integral values from 5 to 19 without visible damage to the optical elements,which indicates that small-scale self-focusing is not a significant *** was shown that,by virtue of the low dispersion of the group velocity,the KDP crystal has some advantages over silica:a larger pulse compression coefficient,especially at a small value of the B-integral(B=5,...,9),lower absolute values of chirped mirror dispersion,and also a possibility to control the magnitude of nonlinearity and dispersion by changing crystal orientation.

关键词： CafCA petawatt lasers post-compression self-phase modulation small-scale self-focusing thin film compression third-order nonlinearity

eXawatt Center for Extreme Light Studies

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High Power Laser Science and Engineering 2023年第6期11卷 101-129页

作者： Efim Khazanov Andrey Shaykin Igor Kostyukov Vladislav Ginzburg Ivan Mukhin Ivan Yakovlev Alexander Soloviev Ivan Kuznetsov Sergey Mironov Artem Korzhimanov Denis Bulanov Ilya Shaikin Anton Kochetkov alexey kuzmin Mikhail Martyanov Vladimir Lozhkarev Mikhail Starodubtsev Alexander Litvak Alexander Sergeev Gaponov-Grekhov Institute of Applied Physics of the Russian Academy of Sciences Nizhny Novgorod 603950Russia

The eXawatt Center for Extreme Light Studies project aimed to create a large scientific infrastructure based on lasers with giant peak *** project relies on the significant progress achieved in the last *** planned infrastructure will incorporate a unique light source with a pulse power of 600 PW using optical parametric chirped pulse amplification in large-aperture KD_(2)PO_(4),deuterated potassium dihydrogen phosphate *** interaction of such laser radiation with matter represents a completely new fundamental *** direct study of the space-time structure of vacuums and other unknown phenomena at the frontier of high-energy physics and the physics of superstrong fields will be *** applications will include the development of compact particle accelerators,the generation of ultrashort pulses of hard X-ray and gamma radiation for material science enabling one to probe material samples with unprecedented spatial and temporal resolution,the development of new radiation and particle sources,*** paper is translation from Russian[Kvantovaya Elektronika 53,95(2023)].

关键词： high-power femtosecond lasers interaction of ultrarelativistic field with matter

Middle Jurassic vertebrate assemblage of Berezovsk coal mine in western Siberia (Russia)

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Global Geology 2016年第4期19卷 187-204页

作者： Alexander Averianov Thomas Martin Pavel Skutschas Igor Danilov Julia Schultz Rico Schellhorn Ekaterina Obraztsova alexey Lopatin Evgenia Sytchevskaya Ivan kuzmin Sergei Krasnolutskii Stepan Ivantsov Zoological Institute of the Russian Academy of Sciences Saint Petersburg 199034Russia Laboratory of Mesozoic and Cenozoic Continental Ecosystems Tomsk State UniversityTomsk 634050Russia Steinmann-Institut fur Geologie Mineralogie und PalaontologieUniversitat BonnBonn 3115Germany Vertebrate Zoology Department Saint Petersburg State UniversitySaint Petersburg 199034Russia Department of Organismal Biologyand Anatomy University of ChicagoChicagoIL 60637USA Borissiak Paleontological Institute of the Russian Academy of Sciences Moscow 117997Russia Sharypovo Regional Museum SharypovoKrasnoyarsk Territory 662311Russia

The Berezovsk coal mine in western Siberia has yielded the most diverse Middle Jurassic limnic and terrestrial vertebrate assemblage of Asia. The vertebrate remains were recovered by screen washing from floodplain deposits on top of a thick coal seam of the Bathonian Itat Formation. A total of 29 vertebrate taxa has been recorded so far,including hybodontiform sharks,acipenseriforms,palaeonisciforms,amiiforms,dipnoans,anurans,caudates,turtles,squamates,choristoderans,crocodyliforms,pterosaurs,dinosaurs,tritylodontids,and a diverse mammaliaform and mammalian assemblage( eleutherodontids,docodontans,? amphilestids,dryolestids,and zatherians). The caudates are among the oldest in the fossil record and the anurans represent the oldest Asian record of this group. Among the mammals,Anthracolestes is the oldest and most basal known member of Dryolestidae and so far the only record from Asia. The vertebrate assemblage from the Berezovsk coal mine is very similar to that from the British Forest Marble Formation( Bathonian) and suggests a limited provincialism in the Middle Jurassic Laurasian landmass.

关键词： vertebrate assemblage Berezovsk coal mine Middle Jurassic western Siberia Russia