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Comparative Studies on Reflection Defect between Textured and Planar Surface Based on TCO Materials

Energy and Power Engineering 2022年第10期14卷 550-557页

作者： alassane diaw Papa Touty Traore Awa Dieye Physics Department Cheikh Anta Diop University Dakar Senegal

This article presents, on the one hand, the performance of ARC by configurations ITO/Si, MgO/Si, and GeO2/Si. On the other hand, we study the impact of thickness on the reflection of OCTs, because the thickness of OCTs plays an important role on the optical properties and the variation of the reflection and transmission of TCO/Si heterojunctions as a function of thickness is also sown. And the last part of the paper, we will make a comparative study between the performance of silicon textured on the front side and that of silicon where the front side is planar. These two forms of silicon will be covered with ARC. For this, we will use the following materials ITO, MgO, and GeO2 and we represent the variation of the reflection of CAR on a planar surface and on a textured surface as a function of the wavelength. The results show that the reflection is low in textured surface compare to the planar surface.

关键词： Reflection TCO Textured Surface

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Optimization and Modeling of Antireflective Layers for Silicon Solar Cells: In Search of Optimal Materials

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Materials Sciences and Applications 2018年第8期9卷 705-722页

作者： Mamadou Moustapha Diop alassane diaw Nacire Mbengue Ousmane Ba Moulaye Diagne Oumar A. Niasse Bassirou Ba Joseph Sarr Laboratory of Semiconductor and Solar Energy Department of Physics Faculty of Science and Techniques University Cheikh Anta Diop Dakar Senegal

Depositing an antireflection coating on the front surface of solar cells allows a significant reduction in reflection losses. It thus allows an increase in the efficiency of the cells. A modeling of the refractive indices and the thicknesses of an optimal antireflection coating has been proposed. Thus, the average reflective losses can be reduced to less than 8% and less than 2.4% in a large wavelength range respectively for a single-layer and double-layer anti-reflective coating types. However, the difficulty of finding these model materials (materials with the same refractive index) led us to introduce two notions: the refractive index difference and the thickness difference. These two notions allowed us to compare the reflectivity of the antireflection layer in silicon surface. Thus, the lower the refractive index difference is, the more the material resembles to the ideal material (in refractive index), and thus its reflective losses are minimal. SiNx and SiO2/TiO2 antireflection layers, in the wavelength range between 400 and 1100 nm, have reduced the average reflectivity losses to less than 9% and 2.3% respectively.

关键词： Antireflection Layer Reflectivity Refractive Index Thickness

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Review of Research on Li-Ion Batteries Waste Management

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Open Journal of Inorganic Chemistry 2022年第2期12卷 19-38页

作者： Rokhaya Sylla Gueye Nango Gaye Mamadou Baldé Adama Diedhiou Ngoné Diouf Seck Gorgui Awa Idrissa Ndoye Yoro Tine Matar Seck Djibril Fall alassane Wele Mahy diaw Laboratory of Physical Inorganic Organic and Therapeutic Chemistry Faculty of Medicine Pharmacy and Odontology Cheikh Anta Diop Dakar University (UCAD) Dakar Senegal Gaston Berger Saint-Louis University (UGB) Saint-Louis Senegal Alioune Diop Bambey University (UADB) Bambey Senegal

Li-ion batteries (Libs) are a mature technology widely used for energy storage in various electronic devices. Nowadays, this technology has become a leading candidate for the portable electronics market and for electric vehicles due to its good performance. As a result, the demand for Libs containing critical metals, rare earth elements and precious metals is increasing day by day with the accelerated upgrades of consumer electronics, which promotes the supply risk of many mining resources. In addition, the problems associated with the production of end-of-life Lib are increasing on a global scale. Used Libs are e-waste containing significant levels of critical raw materials (such as Co, Li, Mn and Ni) along with harmful substances. Without proper management of Lib waste, these precious metals and toxic substances may end up in nature and cause environmental and public health problems. In order to preserve nature, ensure sustainable resource management and stimulate the circular economy, it has become crucial to properly manage and recycle end-of-life Li-ion batteries. By the way, conventional methods focusing on pyrometallurgical treatments combined with hydrometallurgical treatment are widely studied to recover design metals from Libs waste. It is in this context that we have conducted this bibliographic synthesis, focusing on the efficiency of the solvents employed and their competitiveness for a more environmentally friendly economic management. In this manuscript, recent leaching, solvent extraction, electrodeposition and precipitation strategies to recover precious metals from end-of-life Li-ion battery designs are reviewed and the evolution of these processes is discussed.

关键词： Libs Waste Leaching Extraction Rate Affinity Partition Coefficient

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