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Durable poly(binaphthyl-co-p-terphenyl piperidinium)-based anion exchange membranes with dual side chains

Journal of Energy Chemistry 2024年第2期89卷 324-335,I0008页

作者： Weiting Gao Xuelang Gao Qiugen Zhang aimei zhu Qinglin Liu Department of Chemical&Biochemical Engineering Fujian Provincial Key Laboratory of Theoretical and Computational ChemistryThe College of Chemistry and Chemical EngineeringXiamen UniversityXiamen 361005FujianChina Department of Chemistry Pohang University of Science and Technology(POSTECH)Pohang 790-784South Korea

Building well-developed ion-conductive highways is highly desirable for anion exchange membranes(AEMs).Grafting side chain is a highly effective approach for constructing a well-defined phaseseparated morphological structure and forming unblocked ion pathways in AEMs for fast ion *** of side chains can further enhance phase separation due to the superhydrophobic nature of fluorine ***,their electronic effect on the alkaline stability of side chains and membranes is rarely ***,fluorine-containing and fluorine-free side chains are introduced into the polyaromatic backbone in proper configuration to investigate the impact of the fluorine terminal group on the stability of the side chains and membrane *** poly(binaphthyl-co-p-terphenyl piperidinium)AEM(QBNp TP)has the highest molecular weight and most dimensional stability due to its favorable backbone arrangement among ortho-and meta-terphenyl based ***,by introducing both a fluorinated piperidinium side chain and a hexane chain into the p-terphenyl-based backbone,the prepared AEM(QBNp TP-QFC)presents an enhanced conductivity(150.6 m S cm^(-1))and a constrained swelling at 80℃.The electronic effect of fluorinated side chains is contemplated by experiments and *** results demonstrate that the presence of strong electro-withdrawing fluorine groups weakens the electronic cloud of adjacent C atoms,increasing OH^(-)attack on the C atom and improving the stability of piperidinium *** QBNp TP-QFC possesses a robust alkaline stability at 80℃(95.3%conductivity retention after testing in 2 M Na OH for 2160 h).An excellent peak power density of 1.44 W cm^(-2)and a remarkable durability at 80℃(4.5%voltage loss after 100 h)can be observed.

关键词： Anion exchange membranes Backbone structure Fluorinated side chain Alkaline stability

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太平洋富稀土深海沉积物标准物质研制

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岩矿测试 2024年第1期43卷 189-199页

作者：朱爱美石学法刘季花汪虹敏王小静白亚之崔菁菁自然资源部第一海洋研究所山东青岛266061 自然资源部海洋地质与成矿作用重点实验室山东青岛266061 青岛海洋科学与技术试点国家实验室海洋地质过程与环境功能实验室山东青岛266237 山东省深海矿产资源开发重点实验室山东青岛266061

深海稀土被认为是继多金属结核、富钴结壳和多金属硫化物之后发现的第四种深海矿产资源,以富含中-重稀土元素为显著特征。中国目前深海沉积物标准物质数量较少,不成系列,而且现有海洋沉积物标准物质中稀土元素总量最高为475.9μg/g,远... 详细信息

深海稀土被认为是继多金属结核、富钴结壳和多金属硫化物之后发现的第四种深海矿产资源,以富含中-重稀土元素为显著特征。中国目前深海沉积物标准物质数量较少,不成系列,而且现有海洋沉积物标准物质中稀土元素总量最高为475.9μg/g,远未达到富稀土深海沉积物中的稀土元素总量(>1000μg/g)。目前国内外尚未有富稀土深海沉积物成分分析标准物质,为满足深海稀土资源勘查需要,本文报道了国家一级标准物质太平洋富稀土深海沉积物(GBW07590)研制过程。该标准物质候选物实物样品采集自4300m东南太平洋海底,经过自然风干、粉碎、混匀和灭活加工制备后,对沉积物成分进行均匀性和稳定性检验,各成分统计结果显示样品具有良好的均匀性和稳定性。国内外11家实验室采用多种分析方法对该标准物质的62种成分进行定值,确定各项成分的标准值和不确定度,稀土总量达到2103μg/g。该标准物质的研制进一步丰富了国内外深海沉积物标准物质品类,为科学研究、深海资源开发评价和地球化学分析测试等提供科技支撑。

关键词：富稀土深海沉积物标准物质定值不确定度

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Copper and zinc isotope variations in ferromanganese crusts and their isotopic fractionation mechanism

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Acta Oceanologica Sinica 2021年第9期40卷 43-52页

作者： Lianhua He Jihua Liu Hui Zhang Jingjing Gao aimei zhu Ying Zhang Key Laboratory of Marine Geology and Metallogeny First Institute of OceanographyMinistry of Natural ResourcesQingdao 266061China Laboratory for Marine Geology Pilot National Laboratory for Marine Science and Technology(Qingdao)Qingdao 266061China

Ferromanganese(Fe-Mn)crusts are potential archives of the Cu and Zn isotope compositions of seawater through *** this study,the Cu and Zn isotopes of the top surface of 28 Fe-Mn crusts and 2 Fe-Mn nodules were analysed by MC-ICP-MS using combined sample-standard bracketing for mass bias *** Zn isotope compositions of the top surface of Fe-Mn crusts are in the range of 0.71‰to 1.08‰,with a mean δ^(66)Zn value of 0.94‰±0.21‰(2 SD,n=28).The δ^(65)Cu values of the top surface of Fe-Mn crusts range from 0.33‰to0.73‰,with a mean value of 0.58‰±0.20‰(2 SD,n=28).The Cu isotope compositions of Fe-Mn crusts are isotopically lighter than that of dissolved Cu in deep seawater(0.58‰vs.0.9‰).In contrast,the δ^(66)Zn values of Fe-Mn crusts appear to be isotopically heavy compared to deep seawater(0.94‰±0.21‰vs.0.51‰±0.14‰).The isotope fractionation between Fe-Mn crusts and seawater is attributed to equilibrium partitioning between the sorption to crusts and the organic-ligand-bound Cu and Zn in *** Cu and Zn isotopes in the top surface of Fe-Mn crusts are not a direct reflection of the Cu and Zn isotopes,but a function of Cu and Zn isotopes in modern *** study proposes that Fe-Mn crusts have the potential to be archives for paleoceanography through Cu and Zn isotope analysis.

关键词： ferromanganese crusts Cu isotopes Zn isotopes paleoceanography

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Records of the East Asian winter monsoon from the mud area on the inner shelf of the East China Sea since the mid-Holocene

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Chinese Science Bulletin 2010年第21期55卷 2306-2314页

作者： LIU ShengFa SHI XueFa LIU YanGuang QIAO ShuQing YANG Gang FANG XiSheng WU YongHua LI ChaoXin LI XiaoYan zhu aimei GAO JingJing Institute of Oceanology Chinese Academy of Sciences Qingdao 266071 China Key Laboratory of Marine Sedimentology and Environmental Geology First Institute of Oceanography State Oceanic Administration Qingdao 266061 China Graduate University of Chinese Academy of Sciences Beijing 100049 China

AMS14C dating and analysis of grain size,major elements and clay minerals were applied to Core MZ01 from the mud area on the inner shelf of the East China *** on the environmentally sensitive grain size,clay mineral and major element assemblages,the history of the East Asia winter monsoon since the mid-Holocene could be *** three proxies,mean grain size(>9.71μm),chemical index of alteration(CIA)and ratio of smectite to kaolinite in particular,show similar fluctuation patterns. Furthermore,10 extreme values corresponding to the contemporary cooling events could be recognized since the mid-Holocene;these extreme values are likely to have been caused by the strengthening of the East Asia winter *** cooling events correlated well with the results of theδ18O curves of the Dunde ice core and GISP2,which therefore revealed a regional response to global climate *** stages of the East Asia winter monsoon were identified,i.e.8300-6300 a BP,strong and unstable;6300-3800 a BP,strong but stable;3800-1400 a BP,weak and unstable;after 1400 a BP,weak but stable.

关键词：东亚冬季风中全新世 Sea 内陆架中期中国亚洲面积

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Carbon Emission Effects Driven by Evolution of Chinese Dietary Structure from 1987 to 2020

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Chinese Geographical Science 2024年第1期34卷 181-194页

作者： zhu Yuanyuan ZHANG Yan zhu Xiaohua Key Laboratory of Geographic Process Analysis&Simulation Hubei Province Central China Normal UniversityWuhan430079China Institute of Geographic Sciences and Natural Resources Research Chinese Academy of SciencesBeijing100101China

Exploring carbon emission effects based on the evolution of residents’ dietary structure to achieve the carbon neutrality goal and mitigate climate change is an important *** study took China as the research object(data excluding Hong Kong,Macao and Taiwan) and used the carbon emission coefficient method to quantitatively measure the food carbon emissions from 1987–2020,then analyzed the carbon emission effects under the evolution of dietary *** results showed that during the study period,the Chinese dietary structure gradually changed to a high-carbon consumption *** dietary structure of urban residents developed to a balanced one,while that of rural residents developed to a high-quality *** the study period,the per capita food carbon emissions and total food consumption of Chinese showed an increasing *** per capita food carbon emissions of residents in urban and rural showed an overall upward *** total food carbon emissions in urban increased significantly,while that in rural increased first and then *** influence of beef and mutton on carbon emissions is the highest in dietary *** with the balanced dietary pattern,the food carbon emissions of Chinese residents had not yet reached the peak,but were evolving to a high-carbon consumption pattern.

关键词： dietary structure structural evolution carbon emission effects carbon neutrality China

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Synergistic catalysis of the N-hydroxyphthalimide on flower-like bimetallic metal-organic frameworks for boosting oxidative desulfurization

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Petroleum Science 2024年第1期21卷 674-682页

作者： Jing He Kun zhu Wei Jiang Dong-Ao zhu Lin-Hua zhu Hai-Yan Huang Wen-Shuai zhu Hua-Ming Li Institute for Energy Research Jiangsu UniversityZhenjiang212013JiangsuChina College of Chemistry and Chemical Engineering Hainan Normal UniversityKey Laboratory of Water Pollution Treatment and Resource Reuse of Hainan ProvinceHaikou571158HainanChina

Synergic catalytic effect between active sites and supports greatly determines the catalytic activity for the aerobic oxidative desulfurization of fuel *** this work,Ni-doped Co-based bimetallic metal-organic framework(CoNi-MOF)is fabricated to disperse N-hydroxyphthalimide(NHPI),in which the whole catalyst provides plentiful synergic catalytic effect to improve the performance of oxidative desulfurization(ODS).As a bimetallic MOF,the second metal Ni doping results in the flower-like morphology and the modification of electronic properties,which ensure the exposure of NHPI and strengthen the synergistic effect of the overall *** with the monometallic Co-MOF and naked NHPI,the NHPI@CoNi-MOF triggers the efficient activation of molecular oxygen and improves the ODS performance without an *** sulfur removal of dibenzothiophene-based model oil reaches 96.4%over the NHPI@CoNi-MOF catalyst in 8 h of ***,the catalytic product of this aerobic ODS reaction is sulfone,which is adsorbed on the catalyst surface due to the difference in *** work provides new insight and strategy for the design of a strong synergic catalytic effect between NHPI and bimetallic supports toward high-activity aerobic ODS materials.

关键词： Metal-organic frameworks Doped Bimetallic N-hydroxyphthalimide Aerobic processes Oxidative desulfurization

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Efficient Removal of Phosphate from Aqueous Solutions Using Corundum-hollow-spheres Supported Caclined Hydrotalcite Porous Thin Films

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Journal of Wuhan University of Technology(Materials Science) 2024年第1期39卷 44-49页

作者：刘云才 zhu Chen School of Architecture and Materials Engineering Hubei Second Normal UniversityWuhan 430205China

Phosphate was removed from aqueous environment by corundum-hollow-spheres supported caclined hydrotalcite (cHT) thin films. Mg-Al-CO3 hydrotalcite (HT) thin films were deposited on corundumhollow-sphere substrates by hydrothermal homogeneous precipitation at 120℃for 30-240 min and cHT thin films were obtained by annealing of the HT thin films at 500℃for 180 min. Their crystal phase, morphology and microstructure were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM).The results show that homogeneous, well-crystallized and hierarchical flower-like thin films were deposited firmly on the surface of the corundum. The mechanism of nucleation and growth of the HT thin films was fitted well with the anion coordination polyhedron growth unit model. To determine the absorption of phosphate by this adsorbent, different bed depth (10-30 cm) and flow rate (1.0-3.0 m L/min) were examined by column experiments. The highest removal efficiency of phosphate amounted to 98.5%under optimum condition (pH=7.2). The adsorption capacity increased as the bed depth increased and decreased as the flow rate increased.

关键词： adsorption phosphate hydrotalcite corundum-hollow-sphere hydrothermal homogeneous precipitation thermal anneal

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A review of recent advances in the effects of surface and interface properties on marine propellers

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Friction 2024年第2期12卷 185-214页

作者： Manfu zhu Liran MA State Key Laboratory of Tribology in Advanced Equipment Tsinghua UniversityBeijing 100084China

Marine propellers are important propulsion devices for both surface ships and underwater *** severe environmental problems have required further performance enhancement for ***,traditional methods to improve propeller performances through geometrical and structural optimizations have been extensively investigated,while the underlying mechanisms of the effects of surface and interface properties on marine propellers are still far from being fully *** paper presented a comprehensive review of recent advances in the effects of surface and interface properties,such as surface roughness and surface wettability,on marine propellers with an emphasis on the significant improvements in both hydrodynamic and cavitation performances,hoping to arouse more in-depth investigations in the field of surface/interface science and technologies on marine propellers,and also promote the state-of-the-art technologies,such as superlubricity technology,into practical applications.

关键词： marine propellers hydrodynamics cavitation surface roughness surface wettability

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Engineering applications and technical challenges of active array microsystems

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Frontiers of Information Technology & Electronic Engineering 2024年第3期25卷 342-368页

作者： Jiaguo LU Haoran zhu East China Research Institute of Electronic Engineering Hefei 230039China School of Electronic and Information Engineering Anhui UniversityHefei 230601China

In the post-Moore era,the development of active phased array antennas will inevitably trend towards active array *** this paper,the characteristics and composition of the active array antenna are briefly *** to the high efficiency,low profile,and light weight of the active array microsystems,the application prospects and advantages in the engineering of multi-functional airborne radar,spaceborne radar,and communication systems are ***,according to the characteristics of the post-Moore era of integrated circuits,scientific and technological problems in the active array microsystems are presented,including multi-scale,multi-signal,and multi-physics field *** challenges are also discussed,such as new architectures and algorithms,miniaturization of passive components,novel materials and processes,ultra-wideband technology,and new interdisciplinary technological *** paper is expected to inspire in-depth research on active array microsystems.

关键词： Microelectronics Heterogeneous integration Packaging materials Antenna array microsystems Multi-functional radar Communication

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Leaching kinetics of fluorine during the aluminum removal from spent Li-ion battery cathode materials

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Journal of Environmental Sciences 2024年第4期138卷 312-325页

作者： Shengjie Li Jianxin zhu Research Center for Eco-Environmental Sciences Chinese Academy of SciencesBeijing 100085China University of Chinese Academy of Sciences Beijing 100049China

The high content of aluminum(Al)impurity in the recycled cathode powder seriously affects the extraction efficiency of Nickel,Cobalt,Manganese,and Lithium resources and the actual commercial value of recycled materials,so Al removal is crucially important to conform to the industrial standard of spent Li-ion battery cathode *** this work,we systematically investigated the leaching process and optimum conditions associated with Al removal from the cathode powder materials collected in a wet cathode-powder peeling and recycling production line of spent Li-ion batteries(LIBs).Moreover,we specifically studied the leaching of fluorine(F)synergistically happened along with the removal process of Al,which was not concerned about in other studies,but one of the key factors affecting pollution prevention in the recovery *** mechanism of the whole process including the leaching of Al and F from the cathode powder was indicated by using NMR,FTIR,and XPS,and a defluoridation process was preliminarily investigated in this *** leaching kinetics of Al could be successfully described by the shrinking core model,controlled by the diffusion process and the activation energy was 11.14 kJ/***,the leaching of F was attributed to the dissolution of LiPF6and decomposition of PVDF,and the kinetics associated was described by Avrami *** interaction of Al and F is advantageous to realize the defluoridation to some *** is expected that our investigation will provide theoretical support for the large-scale recycling of spent LIBs.

关键词： Al removal F leaching Cathode powder Heating alkali leaching Leaching kinetics

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