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Ammonia pyrolysis oxidation excited by nanosecond pulsed discharge:Global/fluid models hybrid solution

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Journal of Energy Chemistry 2025年第1期100卷 385-396页

作者： Mingming Zhang Hanyu wu Qi Chen Jiaxin Yang Bonan Liu School of Mechanical Electronic and Control EngineeringBeijing Jiaotong UniversityBeijing 100044China China University of Petroleum Beijing 102299China

The kinetic characteristics of plasma-assisted oxidative pyrolysis of ammonia are studied by using the global/fluid models hybrid solution ***,the stable products of plasma-assisted oxidative pyrolysis of ammonia are *** results show that the consumption of NH_(3)/O_(2)and the production of N_(2)/H_(2)change linearly with the increase of voltage,which indicates the decoupling of nonequilibrium molecular excitation and oxidative pyrolysis of ammonia at low ***,the detailed reaction kinetics mechanism of ammonia oxidative pyrolysis stimulated by a nanosecond pulse voltage at low pressure and room temperature is *** on the reaction path analysis,the simplified mechanism is *** detailed and simplified mechanism simulation results are compared with experimental data to verify the accuracy of the simplified ***,based on the simplified mechanism,the fluid model of ammonia oxidative pyrolysis stimulated by the nanosecond pulse plasma is established to study the pre-sheath/sheath behavior and the resultant consumption and formation of key *** results show that the generation,development,and propagation of the pre-sheath have a great influence on the formation and consumption of *** consumption of NH_(3)by the cathode pre-sheath is greater than that by the anode pre-sheath,but the opposite is true for OH and O(1S).However,within the sheath,almost all reactions do not ***,by changing the parameters of nanosecond pulse power supply voltage,it is found that the electron number density,electron current density,and applied peak voltages are not the direct reasons for the structural changes of the sheath and ***,the discharge interval has little effect on the sheath structure and gas mixture *** research results of this paper not only help to understand the kinetic promotion of non-equilibrium excitation in the process of oxidative pyrolysis but also hel

关键词： Nanosecond pulsed discharge Ammonia Oxidative pyrolysis Fluid model Global model

Enhanced dynamics of Al3+/H+ ions in aqueous aluminum ion batteries:Construction of metastable structures in vanadium pentoxide upon oxygen vacancies

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Journal of Energy Chemistry 2025年第2期101卷 562-569页

作者： Zhibao Wang Hanqing Gu Tianci wu Wenming Zhang Zhanyu Li Hebei Key Laboratory of Optic-Electronic Information and Materials National & Local Joint Engineering Laboratory of New Energy Photoelectric Devices College of Physics Science and Technology Hebei University

In recent years,aqueous aluminum ion batteries have been widely studied owing to their abundant energy storage and high theo retical *** in-depth study of vanadium oxide materials is necessary to address the precipitation of insoluble products covered cathode surface and the slow reaction ***,a method using a simple one-step hydrothermal preparation and oxalic acid to regulate oxygen vacancies has been reported.A high starting capacity(400 mAh g-1) can be achieved by Ov-V2O5,and it is capable of undergoing 200 cycles at 0.4 A g-1,with a termination discharge capacity of103 mAh *** analysis demonstrated that metastable structures（AlxV2O5and HxV2O5） were constructed through the insertion of Al3+/H+during discharging,which existed in the lattice intercalation with *** incorporation of oxygen vacancies lowers the reaction energy barrier while improving the ion transport *** addition,the metastable structure allows the electrostatic interaction between Al3+and the main backbone to establish protection and optimize the transport *** parallel,this work exploits ex-situ characterization and DFT to obtain a profound insight into the instrumental effect of oxygen vacancies in the construction of metastable structures during in-situ electrochemical activation,with a view to better understanding the mechanism of the synergistic participation of Al3+and H+in the *** work not only reports a method for cathode materials to modulate oxygen vacancies,but also lays the foundation for a deeper understanding of the metastable structure of vanadium oxides.

关键词： Electrochemical activation Metastable structure Oxygen vacancies Vanadium pentoxide

Biogenic emission as a potential source of atmospheric aromatic hydrocarbons:Insights from a cyanobacterial bloom-occurring eutrophic lake

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Journal of Environmental Sciences 2025年第5期151卷 497-504页

作者： Hua Fang Ting wu Shutan Ma Yuqing Miao Xinming Wang School of Ecology and Environment Anhui Normal UniversityWuhu 241000China Center of Cooperative Innovation for Recovery and Reconstruction of Degraded Ecosystem in Wanjiang City Belt Wuhu 241000China School of Geography and Tourism Anhui Normal UniversityWuhu 241000China State Key Laboratory of Organic Geochemistry and Guangdong Key Laboratory of Environmental Protection and Resources Utilization Guangzhou Institute of GeochemistryChinese Academy of SciencesGuangzhou 510640China CAS Center for Excellence in Deep Earth Science Guangzhou 510640China

As important precursors of ozone(O_(3))and secondary organic aerosol(SOA),reactive aromatic hydrocarbons(AHs)have typically been classified as anthropogenic air ***,biogenic emission can also be a potential source of atmospheric ***,field observations in a eutrophic lake were combined with laboratory incubation experiments to investigate the biogenic AH *** work showed that the water-air fluxes of AHs measured at sites with high cyanobacteria abundance could reach an order of magnitude greater than those at sites with low cyanobacteria abundance,suggesting that cyanobacteria could be the important contributor to measured *** incubation experiments further confirmed the AH emission of cyanobacteria and revealed that the emission could change significantly over the lifespan of cyanobacteria and varied to their growing *** combining field observations and laboratory incubation experiments,it has been suggested that the emission of different AH species from cyanobacteria could be modulated by variable biogeochemical mechanisms and that the biochemical process of toluene could be different from that of other *** study investigates AH emissions from inland aquatic ecosystem and suggests that biogenic emission could be a potential source of atmospheric AHs.

关键词： Aromatic hydrocarbons Biogenic emission Eutrophic lake Cyanobacteria Biosphere-atmosphere exchange

Emerging trends in the selective production of value-added aromatics

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Science China Chemistry 2025年第1期68卷 15-20页

作者： Yuchao wu Houliang Dai Weisheng Yang Yaxing Li Lichen Liu Petrochemical Research Institute Company Limited China National Petroleum CorporationBeijing 102206China Engineering Research Center of Advanced Rare Earth Materials Department of ChemistryTsinghua UniversityBeijing 100084China

1 Introduction Aromatics(mainly benzene,toluene,and xylenes,BTX)are essential intermediates in the chemical *** are employed in the synthesis of a broad spectrum of chemicals and materials,e.g.,various polymers,plastics,resins,solvents,dyes,pharmaceuticals^([1]).The manufacturing pathway of BTX mainly includes petroleum reforming of naphtha,coal-to-aromatics,methanol-to-aromatics^([2]).

关键词： reforming methanol resins

The role of sub-continental lithosphere mantle in deep F and Cl cycling:Insight from the Dabeigou basalts,North China Craton

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Science China Earth Sciences 2025年第2期68卷 564-580页

作者： Yadong wu Jinhui YANG Jinfeng SUN Hao WANG Baoquan ZHOU State Key Laboratory of Lithospheric Evolution Institute of Geology and GeophysicsChinese Academy of SciencesBeijing 100029China College of Earth and Planetary Sciences University of Chinese Academy of SciencesBeijing 100049China Key Laboratory of Computational Geodynamics University of Chinese Academy of SciencesBeijing 100049China

The sub-continental lithosphere mantle(SCLM)represents a mechanical barrier that separate the convecting mantle from the exosphere,and possesses the ability to sequester and release volatiles,making it an integral part in deep volatile *** we explore the SCLM in modulating F and Cl cycling through a case study from the Early Cretaceous Dabeigou basalts in the North China Craton(NCC).These lavas are associated with decratonization of the NCC,a process involving significant removal and replacement of the ancient *** Dabeigou basalts,characterized by arc magma-like trace element signatures,evolved initial^(87)Sr/^(86)Sr(0.70574–0.70578),ε_(Nd)(t)(-11.2–-11.1),andε_(Hf)(t)(-13.7–-13.4)values,along with high Fe/Mn ratios,Ni contents,andδ^(18)O values(5.8‰–6.8‰)of olivine phenocrysts,are compatible with their origination from a veined,pyroxene-rich source formed through the infiltration and interaction of hydrous silicate melts from the subducting Pacific slabs with ambient ***-hosted melt inclusions of the Dabeigou basalts have compositions similar to the whole rocks,indicating that they record pre-eruptive melt compositions forming the whole *** melt inclusions exhibit high F(1371–2316 ppm)and moderate Cl(688–900 ppm)contents,with high F/Cl ratios of 2.1±0.3(1σ).The F and Cl signatures of the Dabeigou basalts are different from those of typical arc magmas,which are commonly characterized by high Cl contents(median of~1200 ppm)and low F/Cl ratios(<1).The observed differences can be attributed to chromatographic reaction that fractionates elements of different compatibility in the metasomatic agents,with amphibole as the main mineral phase for fractionating and preserving F and *** is,amphibole crystallization prefers to retain F rather than Cl,making the metasomes in vein enriched in F and exhibiting elevated F/Cl ratios compared to original metasomatic *** is further suggested that the scenario inferred from the Dabeigou basalts mi

关键词： North China Craton Sub-continental lithosphere mantle Early Cretaceous Dabeigou basalts Melt inclusion F and Cl cycling

煤炭去产能战略下“276工作日”制度的实践与对策

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煤炭经济研究 2017年第9期37卷 43-45页

作者：杜爱红毋进波常二凯山西天地王坡煤业有限公司山西晋城048021

介绍了煤炭去产能战略下"276工作日"制度实施的背景,分析了"276工作日"制度实施以来在煤炭产量、煤炭价格、行业安全等方面取得的成效,认为该制度还需要进一步完善,并提出了相应的优化措施。

关键词：去产能 “276工作日”制度煤炭产量煤炭价格

生物反馈电刺激治疗对产后盆底功能影响的临床分析

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中国卫生产业 2014年第21期11卷 7-9页

作者：杨慧丽杨俊娟吴爱红河南省郑州市妇幼保健院产科河南郑州450003

目的探讨生物反馈电刺激对产后盆底功能的影响。方法选择在我院住院经阴道分娩的初产妇600例随机分为实验组和对照组,实验组进行生物反馈电刺激治疗及盆底肌锻炼,对照组只进行盆底肌锻炼,一个月后对比两组产妇的阴道平均肌电压,尿失禁... 详细信息

目的探讨生物反馈电刺激对产后盆底功能的影响。方法选择在我院住院经阴道分娩的初产妇600例随机分为实验组和对照组,实验组进行生物反馈电刺激治疗及盆底肌锻炼,对照组只进行盆底肌锻炼,一个月后对比两组产妇的阴道平均肌电压,尿失禁发生率和性生活满意度。结果实验组产妇平均肌电压及性生活满意度分别为(25.12±3.7)UV,80%分别高于对照组(24.46±4.6)UV,52%。差异均有统计学意义。实验组尿失禁发生率(1±0.83)次/d,低于对照组(2±0.33)次/d,差异有统计学意义。结论生物反馈电刺激联合盆底肌锻炼在产后盆底功能恢复方面效果显著。

关键词：生物反馈电刺激盆底肌锻炼阴道平均肌电压压力性尿失禁性生活满意度

Boosted solar water oxidation steered by atomically precise alloy nanocluster

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Chinese Chemical Letters 2025年第1期36卷 349-354页

作者： Xian Yan Huawei Xie Gao wu Fang-Xing Xiao College of Materials Science and Engineering Fuzhou University(New Campus)Minhou 350108China Department of Forensic Science The Engineering Research CenterFujian Police CollegeFuzhou 350002China State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China

Atomically precise metal nanoclusters(NCs)have been deemed as a new generation of metal nanomaterials in the field of solar energy conversion due to their unique atomic stacking manner,quantum confinement effects,light-harvesting capability and multitude of active ***,wide-spread application of monometallic NCs is blocked by the ultrashort carrier lifespan,uncontrollable charge transport pathway,and light-induced poor stability,impeding the construction of robust and stable metal NC-based ***,we report the fabrication of stable alloy(Au_(1-x)Pt_(x))NCs photosystem,for which tailor-made negatively charged l-glutathione(GSH)-capped Au_(1-x)Pt_(x)NCs as the building blocks are controllably deposited on the Bi VO_(4)(BVO)by a self-assembly approach for steering enhanced light absorption and interfacial charge transfer over alloy NCs-based photoanodes(Au_(1-x)Pt_(x)/BVO).The self-assembled Au_(1-x)Pt_(x)/BVO composite photoanode exhibits the significantly enhanced photoelectrochemical water oxidation performances compared with pristine BVO and Au_(x)/BVO photoanodes,which is caused by the Pt atom doping into the Au_(x)NCs for elevating photosensitivity and boosting the *** synergy of Au and Pt atoms in alloy NCs protects the gold core from rapid oxidation,improving the photostability and accelerating the surface charge transfer *** work would significantly inspire ongoing interest in unlocking the charge transport characteristics of atomically precise alloy NCs for solar energy conversion.

关键词： Alloy nanoclusters Self-assembly Charge transport Photoanodes Photoelectrochemical water oxidation

Value Assessment Method for the Grid-Alternative Energy Storage Based on Coordinated Planning Framework

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Energy Engineering 2025年第2期122卷 621-649页

作者： Bingqing wu Yunli Yue Yi Zhou Hengyu Zhou Haowen Guan Zhenjiang Shi Zili Chen Zhaoyuan wu State Grid Jibei Electric Power Company Limited Economic Research Institute State Grid Jibei Electric Power Company LimitedBeijing100038China School of Electrical and Electronic Engineering North China Electric Power UniversityBeijing102206China

As the development of new power systems accelerates and the impacts of high renewable energy integration and extreme weather intensify,grid-alternative energy storage is garnering increasing attention for its grid-interaction benefits and clear business ***,assessing the value of grid-alternative energy storage in the systemtransition has become critically *** the performance characteristics of storage,we propose a value assessment frame-work for grid-alternative energy storage,quantifying its non-wires-alternative effects from both cost and benefit *** on this,we developed a collaborative planning model for energy storage and transmission grids,aimed at maximizing the economic benefits of storage systems while balancing investment and operational *** model considers regional grid interconnections and their interactions with system *** participating in system operations,grid-alternative energy storage not only maximizes its own economic benefits but also generates social welfare transfer ***,based on multi-regional interconnected planning,grid-alternative energy storage can reduce system costs by approximately 35%,with the most significant changes observed in generation ***-regional coordinated planning significantly enhances the sys-tem’s flexibility in ***,when the load factor of interconnection lines between regions remains constant,system operational flexibility tends to decrease,leading to a roughly 28.9%increase in storage ***,under regional coordinated planning,the greater the disparity in wind power integration across interconnected regions,the more noticeable the reduction in system costs.

关键词： Coordinated planning grid-alternative energy storage non-wires alternative effects value assessment