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Efficient and Stable Photoassisted lithium‑Ion Battery Enabled by Photocathode with Synergistically Boosted Carriers Dynamics

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Nano-Micro Letters 2025年第3期17卷 440-454页

作者： Zelin ma Shiyao Wang Zhuangzhuang ma Juan li Luomeng Zhao Zhihuan li Shiyuan Wang Yazhou Shuang Jiulong Wang Fang Wang Weiwei Xia Jie Jian Yibo He Junjie Wang Pengfei Guo Hongqiang Wang State Key Laboratory of Solidification Processing Center for Nano Energy MaterialsSchool of Materials Science and EngineeringNorthwestern Polytechnical University and Shaanxi Joint Laboratory of Graphene(NPU)Xi’an 710072People’s Republic of China State Key Laboratory of Solidification Processing School of Materials Science and Engineering DepartmentNorthwestern Polytechnical UniversityXi’an 710072People’s Republic of China State Key Laboratory of Solidification Processing Center of Advanced Lubrication and Seal MaterialsSchool of Materials Science and EngineeringNorthwestern Polytechnical UniversityXi’an 710072People’s Republic of China Research and Development Institute of Northwestern Polytechnical University in Shenzhen Shenzhen 518063People’s Republic of China Key Laboratory of Applied Surface and Colloid Chemistry Shaanxi Key Laboratory for Advanced Energy DevicesShaanxi Engineering Lab for Advanced Energy TechnologySchool of Materials Science and EngineeringNational Ministry of EducationShaanxi Normal UniversityXi’an 710119People’s Republic of China

Efficient and stable photocathodes with versatility are of significance in photoassisted lithium-ion batteries(PliBs),while there is always a request on fast carrier transport in electrochemical active *** work proposes a general approach of creating bulk heterojunction to boost the carrier mobility of photocathodes by simply laser assisted embedding of plasmonic *** employed in PliBs,it was found effective for synchronously enhanced photocharge separation and transport in light charging ***,experimental photon spectroscopy,finite difference time domain method simulation and theoretical analyses demonstrate that the improved carrier dynamics are driven by the plasmonic-induced hot electron injection from metal to TiO_(2),as well as the enhanced conductivity in TiO2 matrix due to the formation of oxygen vacancies after Schottky *** from these merits,several benchmark values in performance of TiO2-based photocathode applied in PliBs are set,including the capacity of 276 mah g^(−1) at 0.2 A g^(−1) under illumination,photoconversion efficiency of 1.276%at 3 A g^(−1),less capacity and Columbic efficiency loss even through 200 *** results exemplify the potential of the bulk heterojunction strategy in developing highly efficient and stable photoassisted energy storage systems.

关键词： Photoassisted lithium-ion batteries Bulk heterojunction Carrier dynamics TiO2 nanofiber Plasmonic metal nanocrystals

Synthesis of intermetallic PtCo fuel cell catalysts from bimetallic core@shell structured nanoparticles

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Journal of Energy Chemistry 2025年第2期101卷 1-6页

作者： Le Zhang Lei Tong Shuai li Chang-Song ma Kun-Ze Xue Hai-Wei liang Hefei National Research Center for Physical Sciences at the Microscale Department of Chemistry University of Science and Technology of China

The high activity and stability of intermetallic PtCo nanocatalysts toward oxygen reduction reaction make them a top candidate as low-Pt cathode catalysts in proton exchange membrane fuel cells（PEMFCs）.However,forming intermetallic structures typically requires high-temperature annealing,posing a challenge for achieving well-size control and highly ordered *** we report the design and synthesis of bimetallic co re@shell structured precursors for affording high-performance intermetallic PtCo *** fabrication of the core@shell precursor involves using a molecular ligand containing both sulfur and oxygen donors to selectively bind with Pt colloidal nanoparticles as the core and chelate Co ions as the *** high-temperature annealing,the ligand transforms into carbon coatings around alloy nanoparticles,preventing particle sintering;meanwhile,Co ions in the shell can easily diffuse into the Pt core,which helps to increase the thermodynamic driving force for forming intermetallic *** benefits enable us to obtain the catalyst with finely dispersed nanoparticles（～3.5 nm）and a high ordering degree of 72%.With 0.1 mgPt/cm2cathode loading,the catalyst delivers superior performance and durability in PEMFCs,showing an initial mass activity of 0.56 A/mgPt,an initial power density of 1.05 W/cm2at 0.67 V（H2-air）,and a voltage loss of 26 mV at 0.8 A/cm2after the accelerated durability test.

关键词： Bimetallic structure Fuel cells Intermetallic PtCo Oxygen reduction reaction

Combined anisotropic and cyclic constitutive model for laser powder bed fusion fabricated aluminum alloy

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Chinese Journal of Aeronautics 2025年第1期38卷 165-184页

作者： Fei-Fan li Jihong ZHU Weihong ZHANG Shifeng WEN Jingwen SONG Jun ma Gang FANG State IJR Center of Aerospace Design and Additive manufacturing School of Mechanical EngineeringNorthwestern Polytechnical UniversityXi’an 710072China Research&Development Institute of Northwestern Polytechnical University in Shenzhen Shenzhen 518063China School of materials Science and Engineering Northwestern Polytechnical UniversityXi'an 710072China Department of Mechanical and Industrial Engineering Norwegian University of Science and TechnologyTrondheim 7491Norway State Key Laboratory of Tribology in Advanced Equipment Department of Mechanical EngineeringTsinghua UniversityBeijing 100084China

This study presents new methods to effectively model the anisotropic yielding and hardening behavior of laser powder bed fusion fabricated aluminum alloy under both monotonic and cyclic loading *** proposed model combines the yield surface-interpolation method to accurately describe the anisotropic hardening rates in various directions,with the Chaboche kinematic hardening rule to precisely reflect the cyclic *** numerical implementation of the combined anisotropic and cyclic constitutive model,a fully implicit stress integration algorithm based on return mapping method is ***,the multiple parameters associated with the model are categorized and identified in an uncoupled *** isotropic and cyclic hardening parameters are determined by an inverse method,and the stability of the optimization outcomes is validated by applying different starting points for the ***,the back-stress effect on the identification of anisotropic parameters associated with the stress invariant-based Hill48 yield function is considered for the first *** consideration leads to an improved prediction accuracy compared to the identification of anisotropic parameters without considering back-stress *** combined anisotropic and cyclic constitutive model,along with the calibrated parameters,are proven capable of accurately reproducing the intricate deformation behavior of laser powder bed fusion fabricated AlSi10Mg.

关键词： Constitutive models Anisotropy Kinematic hardening Laser powder bed fusion Aluminum alloys

Hypidone hydrochloride(YL-0919)ameliorates functional deficits after traumatic brain injury in mice by activating the sigma-1 receptor for antioxidation

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Neural Regeneration Research 2025年第8期20卷 2325-2336页

作者： Yafan Bai Hui ma Yue Zhang Jinfeng li Xiaojuan Hou Yixin Yang Guyan Wang Yunfeng li Department of Anesthesiology Beijing Tongren HospitalCapital Medical UniversityBeijingChina Beijing Institute of Basic Medical Sciences BeijingChina Hebei North University ZhangjiakouHebei ProvinceChina Beijing Institute of Pharmacology and Toxicology State Key Laboratory of Toxicology and Medical CountermeasuresBeijing Key Laboratory of NeuropsychopharmacologyBeijingChina

Traumatic brain injury involves complex pathophysiological mechanisms,among which oxidative stress significantly contributes to the occurrence of secondary *** this study,we evaluated hypidone hydrochloride(YL-0919),a self-developed antidepressant with selective sigma-1 receptor agonist properties,and its associated mechanisms and targets in traumatic brain *** experiments to assess functional deficits were followed by assessment of neuronal damage through histological analyses and examination of blood-brain barrier permeability and brain ***,we investigated the antioxidative effects of YL-0919 by assessing the levels of traditional markers of oxidative stress in vivo in mice and in vitro in HT22 ***,the targeted action of YL-0919 was verified by employing a sigma-1 receptor antagonist(BD-1047).Our findings demonstrated that YL-0919 markedly improved deficits in motor function and spatial cognition on day 3 post traumatic brain injury,while also decreasing neuronal mortality and reversing blood-brain barrier disruption and brain ***,YL-0919 effectively combated oxidative stress both in vivo and in *** protective effects of YL-0919 were partially inhibited by *** results indicated that YL-0919 relieved impairments in motor and spatial cognition by restraining oxidative stress,a neuroprotective effect that was partially reversed by the sigma-1 receptor antagonist ***-0919 may have potential as a new treatment for traumatic brain injury.

关键词： antidepressant drug blood-brain barrier cognitive function hypidone hydrochloride(YL-0919) neurological function nuclear factor-erythroid 2 related factor 2 oxidative stress sigma-1 receptor superoxide dismutase traumatic brain injury

Research on the balance optimization algorithm of image recognition accuracy and speed based on autocollimator measurement

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Optoelectronics Letters 2025年第2期21卷 121-128页

作者： li Renpu ma Long CUI Jiwen GUO Junqi Andrei KUliKOV WEN Dandan Chongqing Engineering Research Center of Intelligent Sensing Technology and Microsystem Chongqing University of Post and TelecommunicationsChongqing 400065China School of Instrumentation Science and Engineering Harbin Institute of TechnologyHarbin 150080China Higher School of Engineering and Technology ITMO UniversitySaint Petersburg 197101Russia

The autocollimator is an important device for achieving precise,small-angle,non-contact *** primarily obtains angular parameters of a plane target mirror indirectly by detecting the position of the imaging *** is limited report on the core algorithmic techniques in current commercial products and recent scientific *** paper addresses the performance requirements of coordinate reading accuracy and operational speed in autocollimator image *** proposes a cross-image center recognition scheme based on the Hough transform and another based on Zernike moments and the least squares *** experimental evaluation of the accuracy and speed of both schemes,the optimal image recognition scheme balancing measurement accuracy and speed for the autocollimator is *** these,the center recognition method based on Zernike moments and the least squares method offers higher measurement accuracy and stability,while the Hough transform-based method provides faster measurement speed.

关键词： image optimization recognition

Mainchain conformation ordering self-assembly tailored room temperature phosphorescence emission

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Science China Chemistry 2025年第1期68卷 329-336页

作者： Yuzhu li Yumeng Gao Feng Tian Yu Wang Yuan Yao Shaoliang lin Xiang ma Binbin Xu Shanghai Key Laboratory of Advanced Polymeric materials Key Laboratory for Ultrafine Materials of Ministry of EducationSchool of Materials Science and EngineeringEast China University of Science and TechnologyShanghai 200237China Key Laboratory for Advance materials and Feringa Noble Prize Scientist Joint Research Centre Frontiers Science for Materiobiology and Dynamic ChemistrySchool of Chemistry and Molecular EngineeringEast China University of Science&TechnologyShanghai 200237China Shanghai Synchrotron Radiation Facility Shanghai Advanced Research InstituteChinese Academy of SciencesShanghai 201204China

Developing organic room-temperature phosphorescence(RTP)materials with a wide range of tunable-emission is significant in expanding the applications of RTP ***,we rationally designed amphiphilic alternating copolymers poly(1,2-bis(4-alkoxyphenyl)ethane-1,2-dione-alt-(ethylene glycol)x)(P(Bz-alt-EGx))that combined the advantage of alternating benzil and EGxskeleton,and tunable mainchain *** a mainchain conformation ordering assembly(COA)process,P(Bz-alt-EGx)self-assembled into well-defined platelets,and such assemblies emitted blue RTP at ca.425 nm due to the ordered folded-chain conformation and confined *** contrast,traditional self-assembly(TA)of P(Bz-alt-EGx)obtained less ordered aggregates,such as asymmetric worms,vesicles,and rod-like *** resultant less ordered aggregates exhibited yellow-green RTP at ca.550 *** wide-tuning RTP emission in solution(between blue and yellow-green,over125 nm)is realized using the P(Bz-alt-EG_(x))alternating copolymers under the treatment of different self-assembly *** study uncovers a new strategy to tailor the RTP emission through different self-assembly pathways and holds great promise for the fabrication of advanced optical materials.

关键词： self-assembly conformation ordering alternating copolymer phosphorescence emission

Effect of Cu/HZSM-5 sorbents with different Si/Al ratios on the adsorption and oxidation performance of H_(2)S

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Journal of Environmental Sciences 2025年第5期151卷 161-173页

作者： Kaini ma Kai li Ping Ning Jiayu Feng Jiacheng Bao Lei Shi Xiangyu Wang Xin Sun Faculty of Environmental Science and Engineering Kunming University of Science and TechnologyKunming 650500China National-Regional Engineering Center for Recovery of Waste Gases from Metallurgical and Chemical Industries Kunming University of Science and TechnologyKunming 650500China

This study employed a wet impregnation method to synthesize five types of Cu/HZSM-5 adsorbents with Si/Al ratios of 25,50,85,200,and 300,used for the removal of H_(2)S in lowtemperature,low-oxygen *** impact of different Si/Al ratios on the adsorption oxidative performance of Cu_(30)/HZSM-5–85 adsorbents was *** to the performance test results,Cu_(30)/HZSM-5–85 exhibited the highest breakthrough capacity,reaching 231.75 mg H_(2)S/g_(sorbent).Cu/HZSM-5 sorbent maintains a strong ability to remove H_(2)S even under humid conditions and shows excellent water ***,BET,and XPS results revealed that CuO is the primary active species,with Cu_(30)/HZSM-5–85 having the largest surface area and highest CuO content,providing more active sites for H_(2)S adsorption.H_(2)-TPR and O_(2)-TPD results confirmed that Cu_(30)/HZSM-5–85 sorbent exhibits outstanding redox properties and oxygen storage capacity,contributing to excellent oxygen transferability in the molecular sieve adsorption-oxidation *** notable characteristics such as a large surface area,high desulfurization efficiency,and water resistance,Cu_(30)/HZSM-5–85 sorbents hold significant importance for industrial applications.

关键词： H_(2)S Si/Al ratio Adoration-oxidation Cu/HZSM-5-85(HZSM-5 with Si/Al ratio of 85 loaded Cu)

Investigation of oxidative potential of fresh and O_(3)-aging PM_(2.5)from various emission sources across urban and rural regions

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Journal of Environmental Sciences 2025年第5期151卷 608-615页

作者： Shuaishuai ma Dongsheng Cheng Yingying Tang Younuo Fan Qiong li Chengxiang He Zhiqing Zhao Tianyou Xu College of Chemical and material Engineering Quzhou UniversityQuzhou 324000China Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention Department of Environmental Science&EngineeringFudan UniversityShanghai 200433China

Inhalation of atmospheric PM_(2.5)can induce the generation of excessive reactive oxygen species(ROS)in human alveoli,triggering local and systemic inflammation,which can directly or indirectly result in respiratory and cardiovascular *** this study,we assessed the oxidative potential(OP)of fresh and O_(3)-aged PM_(2.5)particles from various urban and rural emission sources using the dithiothreitol(DTT)*** results revealed variations in the OP of fresh PM_(2.5)among different emission sources,with biomass burning sources exhibiting the highest OP,followed by industrial areas,vehicular emissions,cooking emissions,and suburban areas,***-soluble organics and transition metals might potentially exert significant influence on particle OP.O_(3)aging notably decreased the OP of PM_(2.5)particles,possibly due to the oxidation of highly DTT-active components into low redox-active small ***,the evolution of OP in different PM_(2.5)components,including methanol-soluble and insoluble fractions,exhibited distinct responses to O_(3)aging for source-oriented PM_(2.5).Additionally,differences in chemical composition between fresh and aged PM_(2.5)were further elucidated through measurements of component-dependent hygroscopic behaviors and phase *** study systematically delineates variances in the toxic potential of fresh and O_(3)-aged PM_(2.5)from various anthropogenic *** findings highlight the intrinsic compositional dependence of particle OP and provide essential insights for assessing the health effects of source-oriented PM_(2.5),as well as for formulating human health protection policies.

关键词： Atmospheric PM_(2.5) Oxidative potential Emission sources DTT assay O_(3)aging

maX-DOAS observations of pollutant distribution and transboundary transport in typical regions of China

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Journal of Environmental Sciences 2025年第5期151卷 652-666页

作者： Hongmei Ren Ang li Zhaokun Hu Hairong Zhang Jiangman Xu Xinyan Yang Jinji ma Shuai Wang School of Physics and Electronic Information Anhui Normal UniversityWuhu 241000China Key Laboratory of Environmental Optics and Technology Anhui Institute of Optics and Fine MechanicsHefei Institutes of Physical ScienceChinese Academy of SciencesHefei 230031China University of Science and Technology of China Hefei 230026China School of Geography and Tourism Anhui Normal UniversityWuhu 241000China China National Environmental Monitoring Centre Beijing 100012China

Studying the spatiotemporal distribution and transboundary transport of aerosols,NO_(2),SO_(2),and HCHO in typical regions is crucial for understanding regional pollution *** a 2-year study using multi-axis differential optical absorption spectroscopy in Qingdao,Shanghai,Xi’an,and Kunming,we investigated pollutant distribution and transport across Eastern China-Ocean,Tibetan Plateau-Central and Eastern China,and China-Southeast Asia ***,pollutant distributionwas ***,frequently clouded and misty,exhibited consistently high aerosol optical depth throughout the *** Qingdao and Shanghai,NO_(2)and SO_(2),as well as SO_(2)in Xi’an,increased in *** HCHO in summer in Shanghai and Xi’an,especially Xi’an,suggests potential ozone pollution ***,pollutant transportation across interfaces was *** the Eastern China-Ocean interface,the gas transport flux was the largest among other interfaces,with the outflux exceeding the influx,especially in winter and *** input of pollutants from the Tibetan Plateau to central-eastern Chinawas larger than the output in winter and spring,with SO_(2)having the highest transport flux in *** pollution input from Southeast Asia to China significantly exceeded the output,with spring and winter inputs being 3.22 and 3.03 times the output,***,the transportation characteristics of a pollution event at Kunming were *** this period,pollutants were transported from west to east,with themaximum SO_(2)transport flux at an altitude of 2.87 km equaling 27.74μg/(m^(2)·s).It is speculated that this pollution was caused by the transport from Southeast Asian countries to Kunming.

关键词： Multi-Axis Differential Optical Absorption Spectroscopy (maX-DOAS) Pollutants Spatiotemporal distribution Transboundary transport