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Experimental and mathematical modeling of Cr(Ⅵ) removal using nano-magnetic Fe3O4-coated perlite from the liquid phase

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Chinese Journal of Chemical Engineering 2020年第6期28卷 1582-1590页

作者： Ismail m.ahmed mostafa m.Hamed Sayed S.metwally Chemistry Department College of ScienceJouf UniversitySkakaSaudi Arabia Hot Laboratories and Waste management Center Atomic Energy Authority13759 CairoEgypt

modification of perlite using nano-magnetic iron oxide was implemented to produce nano-magneticFe3O4-coated perlite composite(Fe3O4/Perlite).The prepared composite was characterized using Scanning Electron microscopy,Fourier-Transform Infrared spectroscopy and Powder X-ray *** potentiality of both perlite and Fe3O4/Perlite composite to eliminate Cr(VI)from the environmentally relevant water was *** influence of main factors which could affect the adsorption was studied including;pH of medium,shaking time and Cr(VI)ions *** experimental outcome demonstrated that the modification of perlite by nano-magnetic Fe3O4 showed a significantly enhanced Cr(VI)removal efficiency relative to that of unmodified *** the kinetic studies,the experimental data fitted well with the pseudo-second-order ***,it proposes that Langmuir isotherm is more adequate than the Freundlich isotherm for both perlite and modified *** results recommended that Fe3O4/Perlite composite had a great potential as an economic and efficient adsorbent of Cr(VI)from contaminated water,which has huge application potential.

关键词： Nano-magnetic Composite Kinetics Isotherm Perlite Adsorption

Spirulina platensis extract improves the production and defenses of the common bean grown in a heavy metals-contaminated saline soil

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Journal of Environmental Sciences 2023年第7期129卷 240-257页

作者： mostafa m.Rady ahmed S.Elrys Eman Selem ahmed A.A.mohsen Safaa m.A.I.Arnaout ahmed H.El-Sappah Khaled A.El-Tarabily El-Sayed m.Desoky Botany Department Faculty of AgricultureFayoum UniversityFayoum 63514Egypt College of Tropical Crops Hainan UniversityHaikou 570228China Soil Science Department Faculty of AgricultureZagazig UniversityZagazig 44511Egypt Botany and microbiology Department Faculty of ScienceZagazig UniversityZagazig 44511Egypt Horticulture Department Faculty of AgricultureZagazig UniversityZagazig 44511Egypt Botany Department Faculty of AgricultureZagazig UniversityZagazig 44511Egypt Genetics Department Faculty of AgricultureZagazig UniversityZagazig 44511Egypt Department of Biology College of ScienceUnited Arab Emirates UniversityAl-Ain 15551United Arab Emirates Khalifa Center for Genetic Engineering and Biotechnology United Arab Emirates UniversityAl-Ain 15551United Arab Emirates Harry Butler Institute Murdoch UniversityMurdoch 6150Australia

Plants have to cope with several abiotic stresses,including salinity and heavymetals(Hms).Under these stresses,several extracts have been used as effective natural biostimulants,however,the use of Spirulina platensis(SP)extract(SPE)remains *** effects of SPE were evaluated as soil addition(SA)and/or foliar spraying(FS)on antioxidant defenses and Hms content of common bean grown in saline soil contaminated with ***(40 or 80 mg SPE/hill added as SA or 20 or 40 mg SPE/plant added as FS)or integrative(SA+FS)applications of SPE showed significant improvements in the following order:SA-80+FS-40>SA-80+FS-20>SA-40+FS-40>SA-40+FS-20>SA-80>SA-40>FS-40>FS-20>***,the integrative SA+FS with 40 mg SP/plant was the most effective treatment in increasing plant growth and production,overcoming stress effects and minimizing contamination of the edible *** significantly increased plant growth(74%–185%)and yield(107%–227%)by enhancing net photosynthetic rate(78.5%),stomatal conductance(104%),transpiration rate(124%),and contents of carotenoids(60.0%),chlorophylls(49%–51%),and NPK(271%–366%).These results were concurrent with the marked reductions in malondialdehyde(61.6%),hydrogen peroxide(42.2%),nickel(91%–94%),lead(80%–9%),and cadmium(74%–91%)contents due to the improved contents of glutathione(87.1%),ascorbate(37.0%),andα-tocopherol(77.2%),and the activities of catalase(18.1%),ascorbate peroxidase(18.3%),superoxide dismutase(192%),and glutathione reductase(52.2%)as reinforcing ***,this most effective treatment is recommended to mitigate the stress effects of salinity and Hms on common bean production while minimizing Hms in the edible part.

关键词： Antioxidant defense system Biostimulants Heavy metals microalgae extracts Saline soil Soil pollution

melting phenomenon in magneto hydro-dynamics steady flow and heat transfer over a moving surface in the presence of thermal radiation

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Chinese Physics B 2013年第3期22卷 57-62页

作者： Reda G.Abdel-Rahman m.m.Khader ahmed m.megahed Department of mathematics Faculty of ScienceBenha University

The Lie group method is applied to present an analysis of the magneto hydro-dynamics（mHD） steady laminar flow and the heat transfer from a warm laminar liquid flow to a melting moving surface in the presence of thermal *** using the Lie group method,we have presented the transformation groups for the problem apart from the scaling *** application of this method reduces the partial differential equations（PDEs） with their boundary conditions governing the flow and heat transfer to a system of nonlinear ordinary differential equations（ODEs） with appropriate boundary *** resulting nonlinear system of ODEs is solved numerically using the implicit finite difference method（FDm）.The local skin-friction coefficients and the local Nusselt numbers for different physical parameters are presented in a table.

关键词： Lie group method magneto hydro-dynamics melting phenomenon Newtonian fluid radiation

Chemically reactive and radiative von Kármán swirling flow due to a rotating disk

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Applied mathematics and mechanics(English Edition) 2018年第9期39卷 1295-1310页

作者： m.KHAN J.ahmed L.AHmAD Department of mathematics Quaid-i-Azam UniversityIslamabad 44000Pakistan Department of Basic Sciences University of Engineering and TechnologyTaxila 47050Pakistan Department of mathematics Shaheed Benazir Bhutto UniversitySheringal Upper Dir 18000Pakistan

A new mathematical model is presented to study the heat and mass transfer characteristics of magnetohydrodynamic(mHD) maxwell fluid flow over a convectively heated stretchable rotating disk. To regulate the fluid temperature at the surface, a simple isothermal model of homogeneous-heterogeneous reactions is employed. The impact of nonlinear thermal radiative heat flux on thermal transport features is studied. The transformed nonlinear system of ordinary differential equations is solved numerically with an efficient method, namely, the Runge-Kutta-Felberg fourth-order and fifth-order(RKF45)integration scheme using the mAPLE software. Achieved results are validated with previous studies in an excellent way. major outcomes reveal that the magnetic flux reduces the velocity components in the radial, angular, and axial directions, and enhances the fluid temperature. Also, the presence of radiative heat flux is to raise the temperature of fluid. Further, the strength of homogeneous-heterogeneous reactions is useful to diminish the concentration of reaction.

关键词： rotating stretchable disk magnetic field nonlinear radiative heat flux homogeneous-heterogeneous chemical reaction

Biological silicon nanoparticles improve Phaseolus vulgaris L. yield and minimize its contaminant contents on a heavy metals-contaminated saline soil

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Journal of Environmental Sciences 2021年第8期33卷 1-14页

作者： mohamed T.El-Saadony El-Sayed m.Desoky ahmed m.Saad Rania S.m.Eid Eman Selem ahmed S.Elrys Department of Agricultural microbiology Faculty of AgricultureZagazig UniversityZagazig 44511Egypt Botany Department Faculty of AgricultureZagazig UniversityZagazig 44511Egypt Biochemistry Department Faculty of AgricultureZagazig UniversityZagazig 44511Egypt Agricultural Botany Department Faculty of AgricultureBenha University13736Egypt Botany and microbiology Department Faculty of ScienceZagazig University44511Egypt Soil Science Department Faculty of AgricultureZagazig University44511ZagazigEgypt

The synthesis of biological silicon nano-particles(Bio-Si-NPs)is an eco-friendly and lowcost *** is no study focusing on the effect of Bio-Si-NPs on the plants grown on saline soil contaminated with heavy *** this study,an attempt was made to synthesis Bio-Si-NPs using potassium silica florid substrate,and the identified Aspergillus tubingensis Am11 isolate that separated from distribution systems of the potable water.A twoyear field trial was conducted to compare the protective effects of Bio-Si-NPs(2.5 and 5.0 mmol/L)and potassium silicate(10 mmol/L)as a foliar spray on the antioxidant defense system,physio-biochemical components,and the contaminants contents of Phaseolus vulgaris *** on saline soil contaminated with heavy *** findings showed that all treatments of Bio-Si-NPs and potassium silicate significantly improved plant growth and production,chlorophylls,carotenoids,transpiration rate,net photosynthetic rate,stomatal conductance,membrane stability index,relative water content,free proline,total soluble sugars,N,P,K,Ca2+,K+/Na+,and the activities of peroxidase,catalase,ascorbic peroxidase and superoxide oxide *** of Bio-Si-NPs and potassium silicate significantly decreased electrolyte leakage,malondialdehyde,H2 O2,O2·-,Na+,Pb,Cd,and Ni in leaves and pods of Phaseolus vulgaris *** to ***-Si-NPs were more effective compared to potassium *** of Bio-Si-NPs at the rate of 5 mmol/L was the recommended treatment to enhance the performance and reduce heavy metals content on plants grown on contaminated saline soils.

关键词： Bean Silicon Nano-silicon Aspergillus tubingensis Am11 Salinity Heavy metals

Some aspects affecting the response of RC compartment structures subjected to internal blast loads

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Earthquake Engineering and Engineering Vibration 2022年第1期21卷 135-148页

作者： Osman m.O.Ramadan m.Galal El Sherbiny ahmed m.Khalil Faculty of Engineering Cairo UniversityCairo 12411Egypt Higher Technological Institute(HTI)at 10th of Ramadan City Sharqia 13658Egypt Structural Engineering and Construction management Department Faculty of Engineering&TechnologyFutureUniversity in Egypt-FUECairo 16383Egypt

Protective compartments are typically used to protect some specific structures from internal explosions,such as industrial buildings that contain devices that may explode in certain *** research investigates how the response of reinforced concrete(RC)compartment structures subjected to internal blast loads are affected by the following aspects:introduction of material nonlinearity in the analysis,reinforcement ratio,and aspect ratio of the *** achieve this goal,a calibrated and sophisticated FE numerical model is introduced,and a parametric study for the intended aspects is carried out.A discussion of the results and conclusions are offered,which show the role of each aspect in the dynamic performance of the compartment *** main conclusions are as follows:introduction of material nonlinearity in this type of analysis and for these structures is very important and significant in obtaining accurate outputs that are similar to actual behavior;the reinforcement ratio has a significant effect on the response and its effect varies depending on the thickness of the compartment;in general,increasing the reinforcement ratio enhances the behavior and reduces the stresses in the compartment;and the aspect ratio of the compartment does not show a clear pattern on the response of such structures under internal blast loads.

关键词： blast loads protective structures nonlinear analysis explicit dynamic analysis

mitigation of the blast load effects on a building structure using newly composite structural configurations

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Defence Technology（防务技术） 2021年第1期17卷 75-84页

作者： ahmed K.Taha m.S.Zahran Zhengguo Gao School of Transportation Science and Engineering Beihang University(Beijing University of Aeronautics and Astronautics)Beijing100191PR China Department of Civil Engineering Military Technical CollegeEgypt

In this study,a nonlinear three-dimensional hydrocode numerical simulation was carried out using AUTODYN-3D to investigate the effect of blasting of a high explosive material(TNT)against several configurations of the composite *** numerical models were carried out to study the effect of varying the thickness of the walls and the effect of adding an air layer or aluminum foam layer inside two layers of concrete in mitigating the effect of blast waves on the structure *** results showed that increasing the thickness of walls has a good effect on mitigating the effect of blast *** a layer of air was added,the effect of blast waves was exaggerated,while when a layer of aluminum foam was added the blast wave effects were mitigated with a reasonable percentage.

关键词： Concrete structures Blast waves Numerical simulation TNT

Evaluating the potential of surface-modified silica nanoparticles using internal olefin sulfonate for enhanced oil recovery

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Petroleum Science 2020年第3期17卷 722-733页

作者： Afaque ahmed Ismail mohd Saaid Abdelazim Abbas ahmed Rashidah m.Pilus mirza Khurram Baig Petroleum Engineering Department Universiti Teknologi PETRONASSeri IskandarMalaysia Center of Research in Enhanced Oil Recovery Universiti Teknologi PETRONASSeri IskandarMalaysia Department of Physics University of OkaraOkaraPunjabPakistan

Recently,nanoparticles have proven to enhance oil recovery on the core-flood scale in challenging high-pressure high-temperature *** generally appear to improve oil production through wettability alteration and reduction in interfacial tension between oil and water ***,they are environmentally friendly and cost-effective enhanced oil recovery *** the rheological properties of nanoparticles is critical for field *** instability of nanoparticle dispersion due to aggregation is considered as an unfavorable phenomenon in nanofluid flooding while conducting an EOR *** this study,wettability behavior and rheological properties of surface-treated silica nanoparticles using internal olefins sulfonates(IOS20–24 and IOS19–23),anionic surfactants were *** modification effect on the stability of the colloidal solution in porous media and oil recovery was *** rheology of pure and surfacetreated silica nanoparticles was investigated using a HPHT *** and particle size distributions of pure and coated silica nanoparticles were studied using a field emission scanning electron microscope.A series of core-flood runs was conducted to evaluate the oil recovery *** coated silica nanoparticles were found to alter rheological properties and exhibited a shear-thinning behavior as the stability of the coated silica nanoparticles could be improved *** low shear rates,the viscosity slightly increases,and the opposite happens at higher shear ***,the surfacemodified silica nanoparticles were found to alter the wettability of the aqueous phase into strongly water-wet by changing the contact angle from 80°to 3°measured against glass slides representing sandstone ***–water IFT results showed that the surface treatment by surfactant lowered the oil–water IFT by 30%.Also,the viscosity of brine increased from 0.001 to 0.008 Pa s by introducing SiO2 nano

关键词： Silica nanoparticles Anionic surfactant Rheological properties of nano fluids Wettability alteration Enhanced oil recovery

Comparison of Ground Water Bacterial Cell Sizes from the Agricultural, Domestic and Industrial Areas of mysore District, Karnataka State, India

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应用与环境生物学报 2008年第4期14卷 503-509页

作者： Wadie ahmed mokbel Sadanand m Yamakanamardi Aquatic microbial Ecology Research Laboratory Department of Studies in Zoology University of Mysore Manasagangotri Mysore-570006 Karnataka State India

A two-year study on temporal variations in the ground water heterotrophic bacterial cell sizes of free living bacteria (FLB) and particle bound bacteria (PBB) from the agricultural, domestic and industrial areas was carried out from February 2005 to January 2007. The overall mean cell length of FLB and PBB was similar in all the ground water studied. However, the season wise grouped data revealed significant seasonal changes in cell length of FLB and PBB, as smaller bacteria were noticed during rainy season in the ground water in agricultural area in both the years, and only in the second year of study in domestic and industrial areas. Generally, it was noticed that there were summer maximum and rainy minimum values of the cell length of PBB in the ground water in agricultural, domestic and industrial areas in the second year of study. The Pearson's correlations showed the presence of 8 (in agricultural area), 5 (in domestic) and 3 (in industrial) significant correlations with environmental (Physico-chemical) parameters, respectively. The regression analysis revealed that as much as 12% of variation in the mean length of FLB was due to NO3 (+) in agricultural area and 9% due to total solids (+) in domestic area. However, the 8 % variation in bacterial cell size of FLB was due to mg (+) in industrial area. Whereas, 13 % variation in mean length of PBB was due to SO4 (+) in agricultural area and 10% due to total anions of strong acid (TASA) (+) in domestic area. Furthermore, 10 % of variation was due to PO4 (+) in industrial area. Thus, the statistical analysis revealed that several environmental variables were potentially responsible for some of the temporal variations in aquatic heterotrophic bacterial cell size, suggesting probably the stressed environment in these ecosystems.

关键词：地下水微生物细胞环境保护