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Electrocatalytic oxidation of hydrazine on magnetic bar carbon paste electrode modified with benzothiazole and iron oxide nanoparticles: Simultaneous determination of hydrazine and phenol

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Chinese Journal of Catalysis 2016年第4期37卷 549-560页

作者： Ali Benvidi Shahriar Jahanbani Bibi-Fatemeh Mirjalili Reza zare 亚兹德大学化学系

A magnetic bar carbon paste electrode （MBCPE） modified with Fe3O4 magnetic nanoparticles （Fe3O4NPs） and 2‐（3,4‐dihydroxyphenyl） benzothiazole （DPB） for the electrochemical determina‐tion of hydrazine was developed. The DPB was firstly self‐assembled on the Fe3O4NPs, and the re‐sulting Fe3O4NPs/DPB composite was then absorbed on the designed MBCPE. The MBCPE was used to attract the magnetic nanoparticles to the electrode surface. Owing to its high conductivity and large effective surface area, the novel electrode had a very large current response for the electrocat‐alytic oxidation of hydrazine. The modified electrode was characterized by voltammetry, scanning electron microscopy, electrochemical impedance spectroscopy, infrared spectroscopy, and UV‐visible spectroscopy. Voltammetric methods were used to study the electrochemical behaviour of hydrazine on MBCPE/Fe3O4NPs/DPB in phosphate buffer solution （pH = 7.0）. The MBCPE/Fe3O4NPs/DPB, acting as an electrochemical sensor, exhibited very high electrocatalytic activity for the oxidation of hydrazine. The presence of DPB was found to reduce the oxidation potential of hydrazine and increase the catalytic current. The dependence of the electrocatalytic current on the hydrazine concentration exhibited two linear ranges, 0.1–0.4 μmol/L and 0.7–12.0 μmol/L, with a detection limit of 18.0 nmol/L. Additionally, the simultaneous determination of hydrazine and phe‐nol was investigated using the MBCPE/Fe3O4NPs/DPB electrode. Voltammetric experiments showed a linear range of 100–470 μmol/L and a detection limit of 24.3 μmol/L for phenol, and the proposed electrode was applied to the determination of hydrazine and phenol in water samples.

关键词： Modified electrode Electerocatalytic oxidation Hydrazine Phenol Magnetic bar modified carbon paste electrode Fe3O4 nanoparticle

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以四丁铵六钨酸盐为可重复使用非均相催化剂无溶剂合成1,8-二氧十氢吖啶(英文)

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催化学报 2012年第11期33卷 1797-1801页

作者： Abolghasem DAVOODNIA Atefeh zare-BIDAKI Hossein BEHMADI Department of Chemistry Mashhad BranchIslamic Azad UniversityMashhadIran

Tetrabutylammonium hexatungstate,[TBA]2[W6O19],has been used as an efficient,inexpensive,and recyclable green catalyst for the one-pot three-component synthesis of 1,8-dioxodecahydroacridines by the reaction of dimedone with aromatic or aliphatic aldehydes in the presence of a nitrogen source(ammonium acetate or aromatic amines) under neat *** are several advantages to the current process over the standard procedures available in the literature,including shorter reaction times(7-14 min),higher yields,facile work-up,and minimal environmental ***,the catalyst can be conveniently recovered and reused.

关键词： LFCO XRD 化学化学动力学

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A facile one-pot synthesis of new thieno-[2,3-d]pyrimidine-2,4(1H,3H)-dione derivatives

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Chinese Chemical Letters 2007年第10期18卷 1163-1165页

作者： A.Davoodnia H.Behmadi A.zare Bidaki M.Bakavoli N.Tavakoli Hoseini Department of Chemistry School of SciencesIslamic Azad UniversityMashhad 91735-413Iran

A facile one-pot synthesis of new 3-arylthieno[2,3-d]pyrimidine-2,4（1H,3H）-diones via base-catalyzed cyclocondensation of ethyl 2-amino-4,5-dimethylthiophene-3-carboxylate with aryl isocyanates is described.

关键词： 3-Arylthieno[2,3-d]pyrimidine-2,4(1H,3H)-diones Aryl isocaynates Base-catalyzed cyclocondensation One-pot synthesis

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Magnetic and optical properties of zinc chromite nanostructures prepared by microwave method

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Transactions of Nonferrous Metals Society of China 2015年第12期25卷 3980-3986页

作者： Zahra MOUSAVI Mahdiyeh ESMAEILI-zare Masoud SALAVATI-NIASARI Institute of Nano Science and Nano Technology University of Kashan

The nanostructures of zinc chromite（Zn Cr2O4） were fabricated by the microwave method. It was shown that the well-crystallized spinel structure is formed after annealing at 700 °C. The influence of reaction time and irradiation power of oven on the size and shape of the as-prepared Zn Cr2O4 samples was studied. The synthesized samples were characterized by X-ray diffraction（XRD）, scanning electron microscopy（SEM）, energy dispersive X-ray（EDX）, transmission electron microscopy（TEM）, diffuse reflectance spectroscopy（DRS）, photoluminescence（PL） spectroscopy, Fourier transform infrared（FTIR） spectra and vibrating sample magnetometry（VSM）, respectively. The optical band gap calculated using DRS was found to be 3.50 e V for Zn Cr2O4 nanostructures. Photoluminescence measurements also confirmed this result.

关键词： zinc chromite nanostructures superhydrophilicty magnetic property optical property

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A comprehensive review of the influence of physicochemical properties of biodiesel on combustion characteristics,engine performance and emissions

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Journal of Traffic and Transportation Engineering(English Edition) 2021年第4期8卷 510-533页

作者： Tikendra Nath Verma Pankaj Shrivastava Upendra Rajak Gaurav Dwivedi Siddharth Jain Ali zare Anoop Kumar Shukla Puneet Verma Department of Mechanical Engineering Maulana Azad National Institute of Technology(MANIT)Bhopal 462007India Department of Mechanical Engineering Prestige Institute of Engineering Management and ResearchIndore 452010India Department of Mechanical Engineering Rajeev Gandhi Memorial College of Engineering and TechnologyNandyal 518501India Energy Centre Maulana Azad National Institute of Technology(MANIT)Bhopal 462007India Department of Mechanical Engineering College of Engineering Roorkee(COER)Roorkee 247667India Flow Aerosols and Thermal Energy(FATE)Research GroupSchool of EngineeringDeakin UniversityBurwoodVIC 3216Australia Department of Mechanical Engineering Amity UniversityNoida 201313India School of Chemistry Physics and Mechanical EngineeringQueensland University of TechnologyBrisbaneQLD 4001Australia

Energy is a basic requirement for development in the *** continuously rising demand for energy resources and the fast depletion of fossil fuel is raises researcher's concern to focus on alternative sources of energy that can replace the shortage of fossil fuels *** is recognized as one of the potential alternative renewable energy fuels that can be easily available in a wide range in every part of the *** paper reviews biodiesel's prospect and focuses on the different fuel properties(physicochemical)of 100 biodiesels from first-,second-and third-generation followed by the evaluation of CI engine *** has been observed that the fuel properties of first-,second-and third-generation biodiesel are compatible with the ASTM *** present paper discussed the potential of various generations of biodiesel feedstocks from production *** paper also examined many aspects of these feedstocks which include different biodiesel feedstock sources,biodiesel conversion technology,and second-generation biodiesel performance and emission *** of the studies showed that biodiesel derived from plant feedstock is costly than ***,more influence is to be given to non-edible ***,the engine characteristics are shown promising behavior with biodiesel and a slight increase in NOX is also reported on using various biodiesel.

关键词： Biodiesel Physicochemical Combustion Ignition Emission

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Probiotic microorganisms affect the reproductive and nervous systems of male rats treated with acrylamide

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Asian pacific Journal of Reproduction 2024年第4期13卷 178-186页

作者： Seyedhossein Hekmatimoghaddam Maryam Yadegari Fateme zare Fatemeh Zakizadeh Seyed Mohammad Seifati Hematology and Oncology Research Center Shahid Sadoughi University of Medical SciencesYazdIran Department of Laboratory Sciences School of ParamedicineShahid Sadoughi University of Medical SciencesYazdIran Neuroendocrine Research Center Shahid Sadoughi University of Medical SciencesYazdIran Department of Anatomy and Cell Biology Faculty of MedicineShahid Sadoughi University of Medical SciencesYazdIran Reproductive Immunology Research Center Shahid Sadoughi University of Medical SciencesYazdIran

Objective:To evaluate the protective effects of probiotic microorganisms on the reproductive and nervous systems of male rats treated with ***:Thirty-two rats were randomly divided into 4 groups and received normal saline through gavage(control),acrylamide 20 mg/kg body weight,acrylamide plus probiotic microorganisms(Lactobacillus acidophilus,Lactobacillus casei,Lactobacillus bulgaricus,Lactobacillus rhamnosus,Bifidobacterium breve,Bifidobacterium infantis,Streptococcus thermophilus and fructooligosaccharides,all mixed in sachets)20 or 200 mg/kg body weight,*** 30 days,the testis,prostate,seminal vesicle and cerebellum were removed,fixed and stained with hematoxylin-eosin(H&E).The Johnsen score was used to classify ***'s principle method was used to evaluate the total volume(in mm3)of the *** number of each intratubular cell type as well as intertubular Leydig cells in whole samples was measured using the physical dissector counting *** analysis and the grids were used to determine the volume of cerebellar layers as well as the Purkinje cell ***:The testis weight decreased significantly in the acrylamide-treated group compared to the other groups(P<0.001).The number of spermatogonia,spermatocytes,spermatids and Leydig cells in the acrylamide-treated group were significantly less compared to the control group(P<0.05),while they were increased significantly in the acrylamide+200 mg/kg probiotic group(P<0.05;P<0.01).The mean Johnsen score in the acrylamide-treated group was lower than in the control group(P<0.001).Acrylamide-induced changes including congestion,vacuolization in the secretory epithelial cells,and epithelial rupture were observed in the prostate and seminal *** volumes of cerebellar layers were decreased in the acrylamide group compared to the control group while recovered in both probiotic treated ***:Probiotic microorganisms alleviate acryl

关键词： Acrylamide Cerebellum Microorganisms Probiotics Prostate Rats Testis

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Selective Sensing Characteristics of Ca Doped BeO Nano-sized Tube toward H20 and NH3

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Chinese Journal of Chemical Physics 2013年第5期26卷 612-616,I0004页

作者： Maziar Noei Vali zare-Shahabadi Seyedeh Najmeh Razi Department of Chemistry Mahshahr Branch Islamic Azad University Mahshahr Iran Young and Elite Reaserchers Club Mahshahr Branch Islamic Azad University Mahshahr Iran

By means of density functional calculations, the structural and electronic properties of chemical modification of pristine and Ca-doped BeO nanotubes were investigated with NH3 and H20 molecules. It was found that the NH3 and H20 molecules can be adsorbed on the Be atom of the tube sidewall with the adsorption energies of about 36.1 and 39.0 kcal/mol, respectively. Density of states analysis shows that the electronic properties of the BeONT are slightly changed after the adsorption processes. Substitution of a Be atom in the tube surface with a Ca atom increases the adsorption energies by about 7.4 and 14.7 kcal/mol for NH3 and H20, respectively. Unlike the pristine tube, the electronic properties of Ca-doped BeONT are sensitive to NH3 and H20 molecules. Also, the Ca-doped tube is much more sensitive to H20 molecule than NH3 one.

关键词： Doping Density functional theory Sensor B3LYP

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Nanomaterial-assisted wearable glucose biosensors for noninvasive real-time monitoring:Pioneering point-of-care and beyond

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Nano Materials Science 2024年第3期6卷 263-283页

作者： Moein Safarkhani Abdullah Aldhaher Golnaz Heidari Ehsan Nazarzadeh zare Majid Ebrahimi Warkiani Omid Akhavan YunSuk Huh Navid Rabiee NanoBio High-Tech Materials Research Center Department of Biological Sciences and BioengineeringInha UniversityIncheon22212Republic of Korea Department of Chemistry Sharif University of TechnologyTehranIran School of Natural Sciences Massey UniversityPrivate Bag 11222Palmerston North4410New Zealand School of Chemistry Damghan UniversityDamghan36716-45667Iran School of Biomedical Engineering University of Technology SydneySydneyNSW2007Australia Department of Physics Sharif University of TechnologyP.O.Box 11155-9161TehranIran Centre for Molecular Medicine and Innovative Therapeutics Murdoch UniversityPerthWA 6150Australia School of Engineering Macquarie UniversitySydneyNew South Wales2109Australia

This review explores glucose monitoring and management strategies,emphasizing the need for reliable and userfriendly wearable sensors that are the next generation of sensors for continuous glucose *** addition,examines key strategies for designing glucose sensors that are multi-functional,reliable,and cost-effective in a variety of *** unique features of effective diabetes management technology are highlighted,with a focus on using nano/biosensor devices that can quickly and accurately detect glucose levels in the blood,improving patient treatment and control of potential diabetes-related *** potential of next-generation wearable and touch-sensitive nano biomedical sensor engineering designs for providing full control in assessing implantable,continuous glucose monitoring is also *** challenges of standardizing drug or insulin delivery doses,low-cost,real-time detection of increased blood sugar levels in diabetics,and early digital health awareness controls for the adverse effects of injectable medication are identified as unmet ***,the market for biosensors is expected to expand significantly due to the rising need for portable diagnostic equipment and an ever-increasing diabetic *** paper concludes by emphasizing the need for further research and development of glucose biosensors to meet the stringent requirements for sensitivity and specificity imposed by clinical diagnostics while being cost-effective,stable,and durable.

关键词： Glucose sensor Biosensor Wearable devices Noninvasive Real-time monitoring

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High-efficiency CdTe/CdS core/shell nanocrystals in water enabled by photo-induced colloidal hetero-epitaxy of CdS shelling at room temperature

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Nano Research 2015年第7期8卷 2317-2328页

作者： Hakimeh zare Maziar Marandi Somayeh Fardindoost Vijay Kumar Sharma Aydan Yeltik Omid Akhavan Hilmi Volkan Demir Nima Taghavinia Institute for Nanoscience and Nanotechnology Shafif University of Technology Tehran 14588 Iran Department of Physics Faculty of Sciences Arak University Arak 38156-8-8349 Iran Department of Physics Department of Electrical and Electronics Engineering and UNAM-Institute of Materials Science and Nanotechnology Bilkent University Ankara Turkey Luminous Center of Excellence for Semiconductor Lighting and Displays Microelectronics Division School of Electrical and Electronics Engineering and Physics and Applied Physics Division School of Physical and Mathematical Sciences Nanyang Technological University Singapore 639798 Singapore Physics Department ShafifUniversity of Technology Tehran 14588 Iran

We report high-efficiency CdTe/CdS core/shell nanocrystals synthesized in water by epitaxially growing CdS shells on aqueous CdTe cores at room temperature, enabled by the controlled release of S species under low-intensity ultraviolet （UV） light illumination. The resulting photo-induced dissociation of S2O2- ions conveniently triggers the formation of critical two-dimensional CdS epitaxy on the CdTe surface at room temperature, as opposed to initiating the growth of individual CdS core-only nanocrystals. This controlled colloidal hetero-epitaxy leads to a substantial increase in the photoluminescence （PL） quantum yield （QY） of the shelled nanocrystals in water （reaching 64%）. With a systematic set of studies, the maximum PL QY is found to be almost independent of the illuminating UV intensity, while the shell formation kinetics required for reaching the maximum QY linearly depends on the illuminating UV intensity. A stability study of the QD films in air at various temperatures shows highly improved thermal stability of the shelled QDs （up to 120 ℃ in ambient air）. These results indicate that the proposed aqueous CdTe/CdS core/shell nanocrystals hold great promise for applications requiring efficiency and stability.

关键词： CdTe/CDs,core/shell nanocrystal thermal stability photochemical

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Evaluation of Characteristics of Interfacial Phases Produced in Al/Ni<sub>3</sub>Al Composite during Manufacturing

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Materials Sciences and Applications 2011年第9期2卷 1340-1348页

作者： Seyed abdolkarim Sajjadi Maryam Abbasi Mazyar Azadbeh 不详

Metal matrix composites (MMCs) are currently being investigated because of their superior properties. The properties are mainly attributed to the efficiency of the load transfer from the matrix to the reinforcements through the matrix-reinforcement interface. The aim of this study is to investigate the effect of manufacturing parameters on the microstructure and morphology of the interface and the aluminide phases formed at the matrix-reinforcement interfaces. The parameters are: milling time to fabricate Ni3Al, method of mixing of Ni3Al and Al powders, compaction pressure and sintering temperature. The composite studied in this research was Al/5 Vol% Ni3Al made from two different types of Ni3Al powders. The results showed that compacting and sintering at higher levels lead to the transformation of Ni3Al particles to thin layers of Al3Ni. It was also shown that the prolonged milling time to produceNi3Alreinforcements and the prolonged ball milling procedure for mixing the powders, both, promote the diffusion process at reinforcement/matrix interface.

关键词： Metal-Matrix Composites (MMCs) Interface X-Ray Diffraction (XRD) Powder Processing

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