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Vapor dealloying of ultra-thin films: a promising concept for the fabrication of highly flexible transparent conductive metal nanomesh electrodes

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npj Flexible electronics 2019年第1期3卷 50-55页

作者： Adrien Chauvin Willigis Txia Cha Heu Joze Buh Pierre-Yves Tessier abdel-aziz el mel Institut des Matériaux Jean Rouxel IMNUniversitéde NantesCNRS2 rue de la Houssinière B.P.3222944322 Nantes cedex 3France Jožef Stefan Institute Complex matter departmentJamova cesta 391000 LjubljanaSlovenia Center of Excellence on Nanoscience and Nanotechnology Nanocenter Jamova 391000 LjubljanaSlovenia

The booming market of flexible electronic displays has urged the development of highly flexible transparent conductive electrodes(FTCE)1–3 with the ability to replace indium tin oxide(ITO)thin films routinely used as transparent conductive electrodes in photoelectronic *** high cost of indium and the poor mechanical stability of ITO under deformation are the main driving forces behind the development of this research area.4 The use of metal nanomeshes as FTCE is a promising concept with a real potential to substitute ITO in photoelectronic devices.5,6 However,the development of a low-cost fabrication approach allowing producing metal nanomesh electrodes with competitive prices and a high performance remains a real bottleneck for the photoelectronic *** this paper,we report on a robust approach very easy to implement allowing producing highly flexible metal nanomesh electrodes with high performance at a very low *** approach lies on a concept consisting in applying dealloying process to ultra-thin Au-Cu alloy thin films using acidic vapors instead of a liquid phase as routinely done in the *** an appropriate procedure,the nanomeshes can be transferred to any planar or curved support where they can serve as a *** a proof of concept,we demonstrate that using this approach,one can easily fabricate gold nanomesh electrodes transferred onto polyethylene terephthalate(PET)film surface with 79%of transmittance and a sheet resistance as low as 44Ω□^(−1) while maintaining exceptional stability under severe mechanical deformations.

关键词： alloying alloy electrodes

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Improved photoconductive properties of composite nanofibers based on aligned conjugated polymer and single-walled carbon nanotubes

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Nano Research 2013年第2期6卷 149-158页

作者： Florian Massuyeau Yuanchun Zhao abdel aziz el mel Abu Yaya Frederic Geschier Eric Gautron Serge Lefrant Jean Yves Mevellec Chris Ewels Chain-Shu Hsu Eric Faulques Jany Wery Jean Luc Duvail fnstitut des Materiaux Jean Rouxel UMR6502 CNRS Universite de Nantes 2 rue de la Houssiniere F-44322 Nantes France Department of Applied Chemistry Chiao Tung University 1001 Ta Hsueh Road Hsin-Chu 30010 Taiwan China

We successfully address the challenge of aligning single-walled carbon nanotubes （SWNTs） and conjugated polymer chains in composite nanofibers for enhancing their opto-electrical properties. A pore-filling template strategy has been developed to prepare such nanocomposites from SWNTs and poly（para-phenylene vinylene）（PPV） chains, with both species well-oriented aligned along the pore axis. Addition of the SWNTs leads to a remarkable increase in photocurrent of four orders of magnitude as compared to equivalent pristine PPV nanofibers. Further analysis indicates that the strong photocurrent enhancement is not simply an effect of alignment, but additionally benefits from alignment-enhanced interaction of polymer chains with SWNTs, as supported by density functional theory （DFT） calculations.

关键词： Tubular nanocomposites single-walled carbonnanotube (SWNT) photoconductivity transport properties conjugated polymer density functional theory (DFT)calculation

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MXene@c-MWCNT Adhesive Silica Nanofiber Membranes Enhancing electromagnetic Interference Shielding and Thermal Insulation Performance in Extreme Environments

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Nano-Micro Letters 2024年第10期16卷 82-98页

作者： Ziyuan Han Yutao Niu Xuetao Shi Duo Pan Hu Liu Hua Qiu Weihua Chen Ben Bin Xu Zeinhom mel-Bahy Hua Hou Eman Ramadan elsharkawy Mohammed AAmin Chuntai Liu Zhanhu Guo Key Laboratory of Materials Processing and Mold(Zhengzhou University) Ministry of EducationNational Engineering Research Center for Advanced Polymer Processing TechnologyZhengzhou UniversityZhengzhou 450002People's Republic of China School of Nano-Tech and Nano-Bionics University of Science and Technology of ChinaHefei 230026People's Republic of China Key Laboratory of Multifunctional Nanomaterials and Smart Systems Advanced Materials DivisionSuzhou Institute of Nano-Tech and Nano-BionicsChinese Academy of SciencesSuzhou 215123People's Republic of China Shaanxi Key Laboratory of Macromolecular Science and Technology School of Chemistry and Chemical EngineeringNorthwestern Polytechnical UniversityXi'an 710072People's Republic of China College of Chemistry&Green Catalysis Center Zhengzhou UniversityZhengzhou 450001People's Republic of China Mechanical and Construction Engineering Faculty of Engineering and EnvironmentNorthumbria UniversityNewcastle Upon Tyne NE18UK Department of Chemistry Faculty of ScienceAl-Azhar UniversityNasr City 11884CairoEgypt Department of Chemistry Faculty of ScienceNorthern Border UniversityArarSaudi Arabia Department of Chemistry College of ScienceTaif UniversityP.O.Box 1109921944 TaifSaudi Arabia

A lightweight flexible thermally stable composite is fabricated by com-bining silica nanofiber membranes(SNM)with MXene@c-MWCNT hybrid *** flexible SNM with outstanding thermal insulation are prepared from tetraethyl orthosilicate hydrolysis and condensation by electrospinning and high-temperature calcination;the MXene@c-MWCNT_(x:y)films are prepared by vacuum filtration *** particular,the SNM and MXene@c-MWCNT_(6:4)as one unit layer(SMC_(1))are bonded together with 5 wt%polyvinyl alcohol(PVA)solution,which exhibits low thermal conductivity(0.066 W m^(-1)K^(-1))and good electromagnetic interference(EMI)shielding performance(average EMI SE_(T),37.8 dB).With the increase in func-tional unit layer,the overall thermal insulation performance of the whole composite film(SMC_(x))remains stable,and EMI shielding performance is greatly improved,especially for SMC_(3)with three unit layers,the average EMI SET is as high as 55.4 *** addition,the organic combination of rigid SNM and tough MXene@c-MWCNT_(6:4)makes SMC_(x)exhibit good mechanical tensile ***,SMC_(x)exhibit stable EMI shielding and excellent thermal insulation even in extreme heat and cold ***,this work provides a novel design idea and important reference value for EMI shielding and thermal insulation components used in extreme environmental protection equipment in the future.

关键词： SiO_(2)nanofiber membranes MXene@c-MWCNT Composite film Thermal insulation electromagnetic interference shielding

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Efficient Deep-Learning-Based Autoencoder Denoising Approach for Medical Image Diagnosis

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Computers, Materials & Continua 2022年第3期70卷 6107-6125页

作者： Walid el-Shafai Samy Abd el-Nabi el-Sayed mel-Rabaie Anas M.Ali Naglaa F.Soliman Abeer D.Algarni Fathi E.Abd el-Samie Department of electronics and electrical Communications Faculty of Electronic EngineeringMenoufia UniversityMenouf32952Egypt Alexandria Higher Institute of Engineering&Technology(AIET) AlexandriaEgypt Department of Information Technology College of Computer and Information SciencesPrincess Nourah Bint Abdulrahman UniversityRiyadh84428Saudi Arabia

Effective medical diagnosis is dramatically expensive,especially in third-world *** of the common diseases is pneumonia,and because of the remarkable similarity between its types and the limited number of medical images for recent diseases related to pneumonia,themedical diagnosis of these diseases is a significant ***,transfer learning represents a promising solution in transferring knowledge from generic tasks to specific ***,experimentation and utilization of different models of transfer learning do not achieve satisfactory *** this study,we suggest the implementation of an automatic detectionmodel,namelyCADTra,to efficiently diagnose pneumonia-related *** model is based on classification,denoising autoencoder,and transfer ***,pre-processing is employed to prepare the medical *** depends on an autoencoder denoising(AD)algorithm with a modified loss function depending on a Gaussian distribution for decoder output to maximize the chances for recovering inputs and clearly demonstrate their features,in order to improve the diagnosis ***,classification is performed using a transfer learning model and a four-layer convolution neural network(FCNN)to detect *** proposed model supports binary classification of chest computed tomography(CT)images and multi-class classification of chest X-ray ***,a comparative study is introduced for the classification performance with and without the denoising *** proposed model achieves precisions of 98%and 99%for binary classification and multi-class classification,respectively,with the different ratios for training and *** demonstrate the efficiency and superiority of the proposed CADTra model,it is compared with some recent state-of-the-art CNN *** achieved outcomes prove that the suggested model can help radiologists to detect pneumonia-related diseases and improve the diagnostic efficiency compared to the exis

关键词： Medical images CADTra AD CT and X-ray images autoencoder

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Post-synthetic metalation of organic cage for enhanced porosity and catalytic performance

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Science China Chemistry 2023年第6期66卷 1763-1770页

作者： Miao Yang Xun Chen Yifei Xie el-Sayed mel-Sayed Ning Xu Wenjing Wang Kongzhao Su Daqiang Yuan State Key Lab of Structure Chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China University of the Chinese Academy of Sciences Beijing 100049China College of Chemistry Fuzhou UniversityFuzhou 310116China Chemical Refining Laboratory Refining DepartmentEgyptian Petroleum Research InstituteNasr City 11727Egypt

Porous organic cages(POCs)have shown great potential in many applications,and post-synthetic modification(PSM)has been confirmed to be an effective strategy to tailor their structures and related ***,it is extremely challenging to develop a general platform for simple-to-make functional POCs for advanced applications by PSM ***,we reported that octahedral calix[4]resorcinarene-based hydrazone-linked porous organic cage(HPOC-401)provides an excellent platform for post-synthetic metalation by various transition metal(TM)ions under mild conditions due to the abundance of coordination sites in its *** metalated products(HPOC-401-TM)exhibit Brunauer-Emmett-Teller(BET)surface area up to1,456 m^(2)g^(-1),much higher than that of the pristine HPOC-401,which has a BET value of 474 m^(2)g^(-1).Moreover,the metalation and porosity increases further influence their gas capture,separation,as well as catalytic *** instance,HPOC-401-TM products exhibit higher CO_(2),H_(2),and C2 hydrocarbon gas uptake,as well as higher C_(2)H_(6)/C_(2)H_(4) selectivity than ***,the HPOC-401-TM also shows better catalytic performance in the cycloaddition of CO_(2) with epoxides compared to *** findings uncover a simple yet effective approach for modifying the porosity characteristics of organic cages,which will undoubtedly expand their future implementations.

关键词： porous organic cage(POC) calixresorcinarene post-synthetic metalation(PSM) gas adsorption and separation CO_(2)cycloaddition

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Tunable Cage-Based Three- Dimensional Covalent Organic Frameworks

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CCS Chemistry 2022年第9期4卷 3095-3105页

作者： Chunqing Ji Kongzhao Su Wenjing Wang Jianhong Chang el-Sayed mel-Sayed Lei Zhang Daqiang Yuan State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002 University of the Chinese Academy of Sciences Beijing 100049 State Key Laboratory of Inorganic Synthesis and Preparative Chemistry Jilin UniversityChangchun 130012 Chemical Refining Laboratory Refining DepartmentEgyptian Petroleum Research InstituteNasr City 11727 College of Materials Science and Engineering Fujian University of TechnologyFuzhou 350118 Fujian Science and Technology Innovation Laboratory for Optoelectronic Information of China Fuzhou 350002

It is extremely challenging to construct three-dimensional(3D)crystalline covalent organic frameworks(COFs)with flexible building blocks and to further explore their tunable or adaptive characteristics due to crystallization and structure determination ***,we constructed three crystalline isostructural 3D-OC-COFs based on a newly synthesized flexible organic cage(6NH_(2)-OC.4HCl)through a novel in situ acid–base neutralization strategy.

关键词： organic cages covalent organic frameworks tunable gas adsorption and separation breakthrough experiment

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Vertically Aligned Silicon Carbide Nanowires/Boron Nitride Cellulose Aerogel Networks Enhanced Thermal Conductivity and electromagnetic Absorbing of Epoxy Composites

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Nano-Micro Letters 2022年第7期14卷 209-227页

作者： Duo Pan Gui Yang Hala MAbo-Dief Jingwen Dong Fengmei Su Chuntai Liu Yifan Li Ben Bin Xu Vignesh Murugadoss Nithesh Naik Salah mel-Bahy Zeinhom mel-Bahy Minan Huang Zhanhu Guo Key Laboratory of Materials Processing and Mold(Zhengzhou University) Ministry of EducationNational Engineering Research Center for Advanced Polymer Processing TechnologyZhengzhou UniversityZhengzhou 450002People’s Republic of China Department of Chemistry College of ScienceTaif UniversityP.O.Box 11099Taif 21944Saudi Arabia Mechanical and Construction Engineering Faculty of Engineering and EnvironmentNorthumbria UniversityNewcastle upon Tyne NE18STUK Integrated Composites Laboratory(ICL) Department of Chemical and Biomolecular EngineeringUniversity of TennesseeKnoxvilleTN 37996USA Advanced Materials Division Engineered Multifunctional Composites(EMC)Nanotech LLCKnoxvilleTN 37934USA College of Materials Science and Engineering Taiyuan University of Science and TechnologyTaiyuan 030024People’s Republic of China Department of Mechanical and Manufacturing Engineering Manipal Institute of TechnologyManipal Academy of Higher EducationManipalKarnataka 576104India Department of Chemistry Turabah University CollegeTaif UniversityP.O.Box 11099Taif 21944Saudi Arabia Department of Chemistry Al-Azhar UniversityNasr CityCairo 11884Egypt

With the innovation of microelectronics technology, the heat dissipation problem inside the device will face a severe test. In this work, cellulose aerogel(CA) with highly enhanced thermal conductivity(TC) in vertical planes was successfully obtained by constructing a vertically aligned silicon carbide nanowires(SiC NWs)/boron nitride(BN) network via the ice template-assisted strategy. The unique network structure of SiC NWs connected to BN ensures that the TC of the composite in the vertical direction reaches 2.21 W m^(-1) K^(-1) at a low hybrid filler loading of 16.69 wt%, which was increased by 890% compared to pure epoxy(EP). In addition, relying on unique porous network structure of CA, EP-based composite also showed higher TC than other comparative samples in the horizontal direction. Meanwhile, the composite exhibits good electrically insulating with a volume electrical resistivity about 2.35 × 10^(11) Ω cm and displays excellent electromagnetic wave absorption performance with a minimum reflection loss of-21.5 dB and a wide effective absorption bandwidth(ellent multifunctional performances in microelectronic packaging applications.

关键词： Epoxy Ice template Vertical alignment Thermal conductivity Multifunctionality

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Serum homocysteine,lipid profile and BMI as atherosclerotic risk factors in children with numerical chromosomal aberrations

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World Journal of Pediatrics 2022年第6期18卷 443-448页

作者： Eman R.Youness Sherien mel-Daly Hanaa Reyad Abdallah Hala T.el-Bassyouni Hisham Megahed Azzah A.Khedr Marwa elhady Walaa Alsharany Abuelhamd Medical Biochemistry Department Medical Research DivisionNational Research CentreGizaEgypt Biological Anthropology Department Medical Research DivisionNational Research CentreGizaEgypt Clinical Genetics Department Human Genetics and Genome Research DivisionNational Research CentreEl-Tahrir StreetPO:12622GizaEgypt Human Cytogenetics Department Human Genetics and Genome Research DivisionNational Research CentreGizaEgypt Pediatric Department Faculty of Medicine for GirlsAl-Azhar UniversityCairoEgypt Department of Pediatrics Faculty of MedicineCairo UniversityCairoEgypt

Down syndrome,Turner syndrome,and Klinefelter syndrome are the most common chromosomal disorders *** syndrome is caused by an extra copy of the 21st chromosome and has an incidence of 1 in 800 to 1000 live *** syndrom... 详细信息

关键词： chromosomal Turner Serum

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Importance of Quercus *** diversity and biomass of vascular epiphytes in a managed pine-oak forest in Southern Mexico

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Forest Ecosystems 2022年第3期9卷 366-377页

作者： Nayely Martínez-meléndez Neptalí Ramírez-Marcial José G. García-Franco Manuel Jesús Cach-Pérez Pablo Martínez-Zurimendi Departamento de Conservacion de la Biodiversidad El Colegio de la Frontera Sur(ECOSUR)San Cristobal de Las Casas29290ChiapasMexico Red de Ecología Functional Instituto de EcologíaA.C.Xalapa91073VeracruzMexico Departamento de Agricultura Sociedad y AmbienteEl Colegio de la Frontera Sur(ECOSUR)Villahermosa86280TabascoMexico

Background:Forestry management modifies the diversity,structure,and functioning of intervened *** extraction reduces tree density and basal area,leading to changes in the communities of vascular *** objective of this study was to evaluate the diversity and biomass of vascular epiphytes in Quercus trees remaining in two pine-oak forest stands that have been subjected to two stages of the Silvicultural Development Method(release cutting,and thinning)in comparison with an unharvested old-secondary forest in southern *** each treatment,richness of epiphytes present on 60 oak trees was recorded and their dry biomass *** calculated the true diversity(Hill numbers)and beta diversity using the Jaccard coefficient of similarity,and generated rank abundance curves per taxonomic epiphyte group(bromeliads,orchids,ferns and others).For each treatment,the relationships between overall diversity and epiphyte biomass to the host trees basal area were analyzed using log linear ***:We recorded a total of 67 species of epiphytes species belonging to 10 families hosted by five species of *** greatest species richness(^(0)D)was recorded in the old-secondary *** common(^(1)D)and dominant(^(2)D)species were recorded in the release cutting than in the other *** diversity and biomass were both slightly related to host tree basal *** of epiphytes was similar(60%)among treatments,although orchids,bromeliads,and other families were more diverse in the old-secondary *** bromeliad species were shared across all treatments,although orchids presented the most exclusive species in the unharvested *** bromeliad Tillandsia seleriana provided the greatest contribution to biomass in all treatments,followed by the orchid Camaridium *** linear models indicated that epiphyte diversity was significantly related to treatment,and epiphyte biomass to basal area of host ***:Alt

关键词： Bromeliads Chiapas Ferns Orchids Richness Sierra Madre Silvicultural development method(SDM)

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New imaging technologies for robotic kidney cancer surgery

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Asian Journal of Urology 2022年第3期9卷 253-262页

作者： Stefano Puliatti Ahmed Eissa Enrico Checcucci Pietro Piazza Marco Amato Stefania Ferretti Simone Scarcella Juan Gomez Rivas Mark Taratkin Jose Marenco Ines Belenchon Rivero Karl-Friedrich Kowalewski Giovanni Cacciamani Ahmed el-Sherbiny Ahmed Zoeir abdelhamid mel-Bahnasy Ruben De Groote Alexandre Mottrie Salvatore Micali Urology Department University of Modena&Reggio EmiliaModenaItaly ORSI Academy MelleBelgium Urology Department Faculty of MedicineTanta UniversityTantaEgypt Department of Surgery Candiolo Cancer InstituteFPO-IRCCSCandioloTurinItaly Division of Urology IRCCS Azienda Ospedaliero-Universitaria di BolognaBolognaItaly Department of Urology Polytechnic University of Marche RegionUmberto I Hospital“Ospedali Riuniti”AnconaItaly Uro-technology and SoMe Working Group of the Young Academic Urologists Working Party European Association of UrologyArnhemthe Netherlands Department of Urology Hospital Clinico San CarlosMadridSpain Institute for Urology and Reproductive Health Sechenov UniversityMoscowRussia Department of Urology Fundacio´n Instituto Valenciano de Oncologı´aValenciaSpain Urology and Nephrology Department Virgen del Rocı´o University HospitalManuel Siurot Sin NumeroSevilleSpain Department of Urology and Urological Surgery University Medical Centre MannheimMannheimGermany USC Institute of Urology University of Southern CaliforniaLos AngelesCAUSA Department of Urology Onze-Lieve-VrouwziekenhuisAalstBelgium

Objective:Kidney cancers account for approximately 2%of all newly diagnosed cancer in *** the primary treatment options for kidney cancer,urologist may choose between radical or partial nephrectomy,or ablative ***,robotic-assisted partial nephrectomy(RAPN)for the management of renal cancers has gained popularity,up to being considered the gold ***,RAPN is a challenging procedure with a steep learning ***:In this narrative review,different imaging technologies used to guide and aid RAPN are ***:Three-dimensional visualization technology has been extensively discussed in RAPN,showing its value in enhancing robotic-surgery training,patient counseling,surgical planning,and intraoperative *** imaging technologies such as intracorporeal ultrasound,near-infrared fluorescent imaging,and intraoperative pathological examination can also be used to improve the outcomes following ***,artificial intelligence may play a role in the field of RAPN ***:RAPN is a complex surgery;however,many imaging technologies may play an important role in facilitating it.

关键词： Kidney cancer Imaging Technology Robotic

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