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Optimized system for combined production of electricity/green hydrogen for multiple energy pathways:a case study of Egypt

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Clean Energy 2024年第4期8卷 219-236页

作者： Reda Ragab Mohamed HamdiHafez a.el Salmawy Mohamed a.ismail Mechanical Power Engineering Department Zagazig UniversityZagazig 44519Egypt Mechanical Engineering Department College of EngineeringKing Faisal UniversityAl-Ahsa 31982Saudi Arabia

By optimal sizing of a wind/photovoltaic hybrid renewable-energy(RE)system,trimming the surplus capacity to reduce the fluctuations in the electricity supplied to the grid,and using it to produce green hydrogen through electrolysis,a stable output with maximum possible capacity factor(CF)is generated to maintain the electricity grid ***,the trimmed energy is used in a secondary conversion path that minimizes the weighted average cost of the energy generated from the entire *** surplus power-to-gas conversion allows the use of green hydrogen to produce electricity,methanol,or ammonia subject to the resource availability,site characteristics,and financial *** on robust site selection criteria,the best performance is obtained at two sites:Ras Ghareb and Minya,achieving the lowest energy cost with some variance in their *** the Ras Ghareb site,the optimally sized RE plant provided the grid with a quasi-steady capacity of 423 MW with a CF of 80.04%and was capable of injecting 2965.8648 GWh throughout the year with the lowest cost of 2.4355¢/kWh.A surplus of 3.9%of the total energy produced from the plant was directed to produce 1922-ton H_(2)/year,achieving the lowest cost of hydrogen production of$1.9745/kg H_(2).For the other selected site,Minya,the clipped energy is used to produce 3330.47-ton H_(2)/year with an optimized lowest cost of$3.5268/kg H_(2).The difference in hydrogen costs was attributed to the number of full operating hours of the electrolyser in both *** cost is mainly affected by the electricity price and the electrolyser *** both tending to decrease,future forecasts show hydrogen cost reductions.

关键词： hybrid renewable-energy system(HRES) green hydrogen electrolysis power-to-gas methanol ammonia

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Availability,sustainability and accessibility of agro crop residue production and solar radiation in Egypt for producing highly chemical products through pyrolysis processes

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Clean Energy 2023年第3期7卷 654-670页

作者： Saad a.el-Sayed Mohamed a.ismail Mohamed E.Mostafa Emad H.Noseir Tarek M.Khass Mechanical Power Engineering Department Faculty of EngineeringZagazig UniversityAl-SharkiaEgypt Mechanical Engineering Department College of EngineeringKing Faisal UniversityAl-AhsaSaudi Arabia Environmental Engineering Department Faculty of EngineeringZagazig UniversityAl-SharkiaEgypt

This study examines the large amount of agricultural waste produced in Egypt between 2010 and 2019 by analysing data from various departments within the Agriculture *** also provides a comprehensive database on the biomass available from agricultural waste in Egypt and its potential applications for producing power,heat and chemical *** biomass-pyrolysis systems powered by solar energy are used,research demonstrates the potential to convert agricultural waste into a variety of chemical *** approach utilizes solar energy,a clean and renewable source,and has wide-ranging industrial and power generation *** Egypt’s reliance on agriculture,the country currently utilizes little biomass for energy production and has not previously used it as a source for creating chemical products,which could potentially save on the imported oil used in these *** findings of the study are graphically presented using histograms,pie charts,*** overall production of residues reached the 30-Mt level in *** it contains the most rice-cultivated land,Dakahlia(Lower Egypt region)produces the highest percentage of the total residue(37.17%).Qena governorate(Upper Egypt region)produces 1.14 metric tons of residues,with sugarcane accounting for 20.3%of the total.

关键词： biomass agro-residue solar radiation pyrolysis chemical products sustainability

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Synthesis and Characterization of Polyesters Based on Diethylketone Moiety

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Chinese Journal of Polymer Science 2014年第11期32卷 1450-1459页

作者： ismail A.Alkskas Bashir a.el-gnidi Khadija M.Ghalieo Faizul Azam Polymer Lab Department of ChemistryFaculty of ScienceMisurata University Faculty of Pharmacy Misurata University

A new class of unsaturated polyesters based on diethylketone have been prepared by interfacial polymerization of 2,4-bis（4-hydroxybenzylidene）-3-pentanone（I） and 2,4-bis（4-hydroxy-3-methoxybenzylidene）-3-pentanone（II） with 4,4’-azodibenzoyl chloride and 3,3’-azodibenzoyl chloride at ambient temperature. The model compounds were synthesized by reaction of（I） and（II） with benzoyl chloride. The new monomers, model compounds and polyesters have been characterized by different spectral analyses. The polyesters have inherent viscosity of 0.55-0.80 d L/g and moderate number average molecular weight（Mn） in the range of 6150-7400 g/mol. Most of the compounds exhibited their solubility in aprotic solvents while partial solubility in various halogenated organic solvents was observed. The temperatures of 10% weight loss were high（225-330 °C） in nitrogen, indicating that these polyesters have excellent thermal stability. Doping with iodine dramatically raised the conductivity and produced brown colored semiconductive polymers with a maximum conductivity of 2.7 × 10-6 --1cm-1. Moreover, the morphological properties of selected example of polyesters were detected by SEM.

关键词： Diethylketone Azo Polyesters Conductivity.

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Amination of biochar surface from watermelon peel for toxic chromium removal enhancement

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Chinese Journal of Chemical Engineering 2021年第8期34卷 199-222页

作者： Mohamed a.el-Nemr Ibrahim M.a.ismail Nabil M.Abdelmonem Ahmed el Nemr Safaa Ragab Department of Chemical Engineering Faculty of EngineeringCairo UniversityGizaEgypt Renewable Energy Program Zewail City of Science and TechnologyEgypt Environmental Division National Institute of Oceanography and FisheriesKayet BeyEl-AnfoushyAlexandriaEgypt

Watermelon peel residues were used to produce a new biochar by dehydration *** new biochar has undergone two methods of chemical modification and the effect of this chemical modification on its ability to adsorb Cr(VI)ions from aqueous solution has been *** biochars,Melon-B,Melon-BO-NH_(2) and Melon-BO-TETA,were made from watermelon peel via dehydration with 50%sulfuric acid to give Melon-B followed by oxidation with ozone and amination using ammonium hydroxide to give Melon-BO-NH_(2) or Triethylenetetramine(TETA)to give *** prepared biochars were characterized by BET,BJH,SEM,FT-IR,TGA,DSC and EDAX *** highest removal percentage of Cr(VI)ions was 69%for Melon-B,98%for Melon-BO-NH_(2) and 99%for Melon-BO-TETA biochars of 100 mg·L^(−1) Cr(VI)ions initial concentration and 1.0 g·L^(−1) adsorbents *** unmodified biochar(Melon-B)and modified biochars(Melon-BO-NH_(2) and Melon-BO-TETA)had maximum adsorption capacities(Q_(m))of 72.46,123.46,and 333.33 mg·g^(−1),*** amination of biochar reduced the pore size of modified biochar,whereas the surface area was *** obtained data of isotherm models were tested using different error function *** Freundlich,Tempkin and Langmuir isotherm models were best fitted to the experimental data of Melon-B,Melon-BO-NH_(2) and Melon-BO-TETA,*** adsorption rate was primarily controlled by pseudo-second–order rate ***,the functional groups interactions are important for adsorption mechanisms and expected to control the adsorption *** adsorption for the Melon-B,Melon-BO-NH_(2) and Melon-BO-TETA could be explained for acid–base interaction and hydrogen bonding interaction.

关键词： Waste treatment Powder technology Citrullus lanatus Hexavalent chromium Biochar amination Adsorption

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Potentiality of Different Seed Priming Agents to Mitigate Cold Stress of Winter Rice Seedling

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Phyton-International Journal of Experimental Botany 2021年第5期90卷 1491-1506页

作者： Md.Parvez Anwar Md.Ariful Islam Khalid A.K.M.Mominul Islam Sabina Yeasmin Sharif Ahmed a.el hadifa.ismail a.ismail Akbar Hossain Ayman el Sabagh Agro Innovation Laboratory Department of AgronomyBangladesh Agricultural UniversityMymensingh2202Bangladesh International Rice Research Institute Bangladesh OfficeDhaka1213Bangladesh Rice Research and Training Center Field Crops Research InstituteAgricultural Research CenterSakha33717Egypt Department of Biology College of ScienceTaif UniversityTaif21944Saudi Arabia Bangladesh Wheat and Maize Research Institute Dinajpur5200Bangladesh Department of Agronomy Faculty of AgricultureKafrelsheikh UniversityKafr Elsheikh33516Egypt

Seed priming has proved to be an effective pre-germination seed invigoration technique for different crops to improve seed and seedling performance under different abiotic *** Bangladesh,winter rice is very often exposed to cold waves just after sowing in the nursery bed resulting in poor seed germination and seedling emergence,yellowish and thin seedlings production,and a very low survival *** priming may mitigate the cold stress during seed germination and seedling emergence and helps in the quality seedling production of winter *** evaluate the efficacy of different seed priming techniques in increasing seedling emergence,growth,vigor and survivability of winter rice cultivars under cold stress,a pot experiment was conducted at the Department of Agronomy,Bangladesh Agricultural University during December 2018 to January *** experiment comprised two factors,(A)Winter rice variety na.ely,(i)BRRI dhan29 and (ii)BRRI dhan36;(B)Seed priming agent na.ely (i)Control(no priming),(ii)20000 ppm NaCl,(iii)30000 ppm NaCl,(iv)20000 ppm KCl,(v)30000 ppm KCl,(vi)20000 ppm CaCl2,(vii)30000 ppm CaCl2,(viii)50 ppm CuSO4,(ix)75 ppm CuSO_(4),(x)10000 ppm ZnSO4,(xi)15000 ppm ZnSO4,(xii)2 ppm Na2MoO4,(xiii)3 ppm Na2MoO4,(xiv)100 ppm PEG(Polyethylene glycol 4000)and (xv)150 ppm *** were sown on two different dates viz.,1st December and 1st January so that seedlings are exposed to cold stress at different *** experiment was laid out in a completely randomized design(CRD)with three *** indicated that(in most of the cases)seed priming has a positive impact on seedling emergence rate(%),root length,shoot length,root shoot ratio,root dry weight,shoot dry weight,seedling dry weight and survival rate(%).Among the priming agents,KCl and CaCl2 performed best;while priming with NaCl and PEG showed no advantages over no priming for both the sowing *** general,BRRI dhan36 performed better than BRRI dhan29 in terms of seedling growth because

关键词： Seed invigoration seedling emergence seedling mortality seedling growth low temperature stress

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Corrosion inhibition of carbon steel in hydrochloric acid by cationic arylthiophenes as new eco-friendly inhibitors: Experimental and quantum chemical study

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Chinese Journal of Chemical Engineering 2021年第12期34卷 197-217页

作者： Abd el-Aziz S.Fouda Mohamed a.ismail Abdulraqeb A.Al-Khamri Ashraf S.Abousalem Department of Chemistry Faculty of ScienceEl-Mansoura UniversityEl-Mansoura 35516Egypt Department of Chemistry Faculty of EducationArts and SciencesUniversity of Saba RegionMaribYemen Quality Control Laboratory Operations DepartmentJotunEgypt

This study describes the adsorption behavior of three arylthiophene derivatives na.ely:2-(4-amidino-3-fluorophenyl)-5-[4-methoxy phenyl] thiophene dihydrochloride salt(MA-1217),2-(4-amidinophenyl)-5-[4-chlorophenyll thiophene dihydrochloride salt(MA-1316) and 2-(4-amidino-3-fluorophenyl)-5-[4-ch lorophenyllthiophene dihydrochloride salt(MA-1312) at C-steel in 1.0 mol·L^(-1) HCl interface using experimental and theoretical *** and mass loss measurements showed that the inhibition efficiency(IE) of the arylthiophene derivatives increases with increasing concentrations and exhibited maximum efficiency 89% at 21×10^(-6) mol·L^(-1)(MA-1217) by mass loss *** investigated arylthiophene derivatives obey the Langmuir adsorption *** polarization studies the arylthiophene derivatives act as mixed-type *** analysis were carried out and *** mode of orientation and adsorption of inhibitor molecules on C-steel surface was studied using molecular dynamics(MD) *** chemical parameters as well as the radial distribution function indices and binding energies confirm the experimental results.

关键词： Carbon steel Corrosion inhibition Adsorption Arylthiophene derivatives Polarization electrochemical frequency modulation

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Some studies of the interaction between two two-level atoms and SU(1,1) quantum systems

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Chinese Physics B 2018年第10期27卷 116-122页

作者： T M el-Shahat M Kh ismail Faculty of Science Al-Azhar University. Assiut 71524 Egypt

Herein, we present an approach to look for the best phenomenon to measure quantum correlation. The system of two isolated qubits each interacting with a single-mode cavity was theoretically created to study the quantum correlation. Some of the phenomena, such as the quantum discord and concurrence, were generated through such a system. The influences of initial state purity, qubit motion, and detuning parameters were discussed for the phenomena. These parameters for a specific value show that the behavior of phenomena are analogous. It is interesting to mention that some values of detuning undergo a sudden death of phenomena, and the quantum discord still captures the qubits quantum correlation. We predict that the quantum discord may be a better measure of quantum correlation than concurrence.

关键词： an isolated atom with a cavity SU (1,1) quantum discord concurrence

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Experimental and computational chemical studies on the cationic furanylnicotinamidines as novel corrosion inhibitors in aqueous solutions

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Chinese Journal of Chemical Engineering 2020年第2期28卷 477-491页

作者： Abdelaziz S.Fouda Mohamed a.ismail Rabab M.Abou-shahba Walaa A.Husien Esraa S.el-Habab Ashraf S.Abousalem Department of Chemistry Faculty of ScienceEl-Mansoura UniversityEl-Mansoura 35516Egypt Department of Chemistry Faculty of ScienceAl-Azhar UniversityEgypt Quality Control Laboratory Operation DepartmentJOTUNEgypt

The corrosion inhibition action of three newly synthesized furanylnicotinamidine derivatives na.ely: 6-[5-{4(dimethylamino)phenyl}furan-2-yl]nicotinamidine(MA-1256), 6-[5-(4-chlorophenyl)furan-2-yl]nicotinamidine(MA-1266), and 6-[5-{4-(dimethylamino)phenyl}furan-2-yl]nicotinonitrile(MA-1250) on carbon steel(C-steel) was investigated in 1.0 mol·L-1 HCl solution by weight loss(WL), potentiodynamic polarization(PP), electrochemical impedance spectroscopy(EIS), and electrochemical frequency modulation(EFM)techniques. Morphological analysis was performed on the uninhibited and inhibited C-steel using atomic force microscope(AFM) and Infrared Spectroscopy(ATR-IR) methods. The effect of temperature was studied and discussed. Inspection of experimental results revealed that the inhibition efficiency(IE) increases with the incremental addition of inhibitors and with elevating the temperature of the acid media. The adsorption of furanylnicotinamidine derivatives on C-steel follows Temkin’s isotherm. PP studies indicated that the investigated compounds act as mixed-type inhibitors and showed that p-dimethylaminophenyl furanylnicotinamidine derivative(MA-1256) was the most efficient inhibitor among the other studied derivatives with IE reached(95%)at 21 × 10-6 mol·L-1. MA-1266 is highly soluble in aqueous solution and has non-toxicity profile with LC50 N 37 mg·L-1. Thus, MA-1266 can be a promising green corrosion inhibitor candidate with IE N 91% at 21× 10-6 mol·L-1. The experiments were coupled with computational chemical theories such as quantum chemical and molecular dynamic methods. The experimental results were in good agreement with the computational outputs.

关键词： Acid corrosion C-steel Furanylnicotinamidines Green inhibitor Computational chemical methods

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Corrosion Penetration and Crystal Structure of AA5022 in HCl Solution and Rare Earth elements

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Journal of Materials Science & Technology 2005年第3期21卷 324-330页

作者： A.a.el-Meligi S.H.Sanad A.a.ismail A.M.Barakat electrochem. and Corrosion Lab. Physical Chemistry Dept. National Research Centre Dokki Cairo EgypElectrochem. and Corrosion Lab. Physical Chemistry Dept. National Research Centre Dokki Cairo EgypElectrochem. and Corrosion Lab. Physical Chemistry Dept. National Research Centre Dokki Cairo EgypChemistry Dept. Faculty of Science Cairo University Cairo Egypt

Al-alloy (AA5022) corrosion penetration (CP) and crystal structure were investigated after running static immersion corrosion tests in 1 mol/L HCl solution and different concentrations of rare earth elements (La3+), (Ce3+) and their combination, at different temperatures. X-ray diffraction (XRD) was used to examine the surface structure before and after immersion, and secondary electron detector (SED) was operated to study surface morphology. In 1 mol/L HCI solution the corrosion penetration increased with increasing temperature and immersion time. The increase of La3+ concentrations up to 1000×10-6 g/L led to the decrease in the corrosion penetration, and the decrease in Ce3+ concentrations up to 50×10-6 g/L decreases the corrosion penetration of the alloy. Mix3 (combination of La3+ and Ce3+) dramatically reduced the corrosion penetration. This suggests that a synergistic effect exists between La3+ and Ce3+. The reaction kinetics both in absence and presence of La3+ and Ce3+ and their combination would follow a parabolic rate law. The XRD patterns revealed that the intensities of certain hkl phases are affected. The crystalline structure has not been deformed either before or after testing and there are no additional peaks except that of the as-received alloy. In the case of accelerating CP, the surface morphology shows that the roughness and voids of surface are increased.

关键词： Al-alloy Corrosion penetration Crystal structure XRD

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electrical Conductivity and Sensitive Characteristics of Ag-Added BaTiO_3-CuO Mixed Oxide for CO_2 Gas Sensing

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Journal of Materials Science & Technology 2011年第1期27卷 35-40页

作者： A.M.el-Sayed F.M.ismail S.M.Yakout Inorganic Chemistry Department National Research CentreTahrir StreetDokki P.C.12622 CairoEgypt

Carbon dioxide gas sensors based on BaTiO3-CuO composite with different concentrations of Ag addition（1,1.5 and 2 wt%） have been prepared by stander ceramic method and sintered at 500 and 700℃ for 5 *** conductivity and gas sensing properties of the prepared samples were *** conductivity measurement was used to characterize the obtained sintered sensor *** was found that electrical conductivity and the sensitivity to CO2 were improved with Ag addition and *** correlation between Ag content at different sintering temperature and sensing characteristics towards CO2 is discussed.

关键词： BaTiO3-CuO composite Ag addition electrical conductivity CO2 sensitive properties

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