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cha.a.te.iza.ion of a.royo Ve.de.e.ithe.ma. De.osit:Pa.a.e.e.is,Mine.a. Ge.che.istry,Ge.chronology a.d Fluid Inclusions in Lowe. chon a.ke.Volca.ism,a.ge.tina

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Journa. of e.0}th Scie.ce 2024年第1期35卷 62-84页

作者： ce.ilia.Pa.ón Pive.ta.Le.na.do Be.e.ini Pa.lo ma.cos ma.a.ustina.cócola.Me.ce.e. Virginia.Ba.ros Da.ie. Gre.ori Le.na.do Stra.ze.e.a.de.son costa.dos Sa.tos ma.ro c.Ge.a.de. Instituto Ge.logico de. Sur(INGe.SUR) Universidad Nacional del Sur(UNS)-Consejo Nacional de Investigaciones Cientificas y Tecnicas(CONICET)Bahia Blanca 8000Argentina Dpto.de.Ge.logia Universidad Nacional del Sur(UNS)Bahia Blanca 8000Argentina Unive.sida. Na.iona. de.Rio Ne.ro Instituto de Investigacion en Paleobiologia y GeologiaGeneral Roca 8332Argentina Unive.sida.e.do e.ta.o do Rio de.Ja.e.ro Faculdade de GeologiaDepartamento de Mineralogia e Petrologia igneaRiodeJaneiro20559-900Brazil Ge.biote. Departamento de GeocienciasUniversidade de AveiroAveiro 3800-002Portuga

a.royo Ve.de.e.ithe.ma. de.osit,in the.North Pa.a.onia.re.ion of a.ge.tina.is loca.e. within the.Lowe. chon a.ke.volca.ism a.d is de.e.ope. be.we.n 192.6±2.5 ma.mine.a.iza.ion host rock)a.d 189.5±2.6 ma.ove.lying la.a..ma.ifil volca.ic comple. is the.host rock for the.e.ve.ns,ve.nle.s a.d *** pa.ticula. sma.l de.osit ha. de.e.ope. low to inte.me.ia.e.sulphida.ion cha.a.te.istics,with ga.gue.mine.a. te.ture. a.socia.e. with se.e.a. ore.*** probe.microa.a.ysis de.e.mine. e.e.trum,silve. mine.a.s such a. a.a.thite.a.d te.ra.e.rite.re.a.e. a.-cu mine.a.s like.ja.pa.te.mckinstryite.strome.e.ite.a.d ba.e.me.a.s like.cha.copyrite.spha.e.ite.ga.e.a.a.d *** inclusions in qua.tz of two out of five.e.e.ts indica.e.tha. the.e.Low Jura.sic ve.ns we.e.forme. due.to subtle.boiling a.d dilution me.ha.isms a.d by low-sa.inity(3.4 wt.%to 6.7 wt.%Na.l e.)ma.ma.ic-hydrothe.ma. fluid a. 225 to 310℃.The.fluid inclusion me.0}ure.e.ts tha. indica.e.boiling(e.e.t 3)we.e.plotte.,a.d ba.e. on this da.a.we.inte.pre. tha. the.a.royo Ve.de.de.osit ha. be.n e.ode. be.we.n 550 a.d 700 *** pa.ticula. cha.a.te. ha. not be.n pre.iously re.orde. for othe. se.tors of the.e.0}te.n north Pa.a.onia. re.ion.

关键词： e.ithe.ma. de.osit a. mine.a.s mine.a. ge.che.istry fluid inclusions chon a.ke.ge.chronology

Ga.-prope.le. na.omotors a.le.ia.e.colitis through the.re.ula.ion of inte.tina. immunoe.vironme.t-he.6}ope.is-microbiota.circuits

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a.ta.Pha.ma.e.tica.Sinica.B 2024年第6期14卷 2732-2747页

作者： Bo Xia. Yuqi Lia.g Ga.Liu Lingshua.g Wa.g Zha. Zha.g Libin Qiu Ha.ting Xu Se.0} ca.r Xia.xia. Shi Rui LRe.s Subha. cKundu Zhe.ghua.Zhu De.a.tme.t of Ga.troe.te.ology the First Affiliated Hospital of Nanchang UniversityNanchang 330006China colle.e.of Se.iculture Textileand Biomass SciencesSouthwest UniversityChongqing 400715China De.a.tme.t of Ne.rology School of MedicineEmory UniversityAtlantaGA 30322USA a.la.ta.Ve.e.a.s a.fa.rs Me.ica. ce.te. DecaturGA 30033USA De.a.tme.t of Surge.y School of MedicineEmory UniversityAtlantaGA 30322USA Bs Re.e.0}ch Group I3Bs—Research Institute on BiomaterialsBiodegradables and BiomimeticsUniversity of MinhoHeadquarters of the European Institute of Excellence on Tissue Engineering and Regenerative MedicineAveParkBarcoGuimaraes 4805-017Portugal

The.progre.sion of ulce.a.ive.colitis(Uc)is a.socia.e. with immunologic de.a.ge.e.t,inte.tina. he.orrha.e.a.d microbiota.*** tra.itiona. me.ica.ions ma.nly focus on mitiga.ing infla.ma.ion,it re.11}ns cha.le.ging to a.dre.s multiple.***,a.ve.sa.ile.ga.-prope.le. na.omotor wa. constructe. by mild fusion of post-ultra.onic ca._(2) na.osphe.e. with cu_(2)O *** re.ulting ca._(2)–cu_(2)O posse.se. a.de.ira.le.dia.e.e.(291.3 nm)a.d a.uniform size.*** could be.e.ficie.tly inte.na.ize. by colonic e.ithe.ia. ce.ls a.d ma.ropha.e.,sca.e.ge.intra.e.lula. re.0}tive.oxyge./nitroge. spe.ie.,a.d a.le.ia.e.immune.re.0}tions by pro-pola.izing ma.ropha.e. to the.a.ti-infla.ma.ory M2 *** na.omotor wa. found to pe.e.ra.e.through the.mucus ba.rie. a.d a.cumula.e.in the.colitis mucosa.due.to the.driving force.of the.ge.e.a.e. oxyge. *** a.ministra.ion of ca._(2)–cu_(2)O could sta.ch the.ble.ding,re.a.r the.disrupte. colonic e.ithe.ia. la.e.,a.d re.uce.the.infla.ma.ory re.ponse. through its inte.a.tion with the.ge.e. re.e.a.t to blood coa.ula.ion,a.ti-oxida.ion,wound he.0}ing,a.d ***,it re.tore. inte.tina. microbiota.ba.a.ce.by e.e.a.ing the.proportions of be.e.icia. ba.te.ia.e.g.,Odoriba.te. a.d Bifidoba.te.ium)a.d de.re.0}ing the.a.unda.ce. of ha.mful ba.te.ia.e.g.,Pre.ote.la.e.0} a.d He.icoba.te.).Our ga.-drive. ca._(2)–cu_(2)O offe.s a.promising the.a.e.tic pla.form for robust tre.0}me.t of Uc via.the.re.ta. route.

关键词： Na.omotor a.ti-infla.ma.ion Blood coa.ula.ion Immune.re.ula.ion He.0}ope.is Microbiota.re.a.a.ce Ulce.a.ive.colitis Re.ta. a.ministra.ion

Blood Pre.sure.Profile.a.d Glyce.ic control of Type.2 Dia.e.ics a.d Hype.te.sive. a. the.Ya.ga.o Oue.ra.go Unive.sity Hospita.: a.Re.ie. of 116 ca.e.

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World Journa. of ca.diova.cula. Dise.0}e. 2024年第1期14卷 61-76页

作者： G. R. c. Millogo a. Thia. Y. Ka.biré e. Nongkouni S. e. Da.iré L. J. Ka.a.béga.J. K. Kologo V. N. Ya.éogo P. Za.sonré De.a.tme.t of ca.diology Yalgado Ouédraogo University Hospital Ouagadougou Burkina Faso De.a.tme.t of ca.diology Tengandogo University Hospital Ouagadougou Burkina Faso

Obje.tive. The.a.socia.ion hype.te.sion a.d dia.e.e. is importa.t. The.two pa.hologie. ma. influe.ce.e.0}h othe.. The.a.m wa. to study the.corre.a.ion be.we.n glyce.ic control a.d blood pre.sure.control a.d to de.e.mine.the.fa.tors a.socia.e. with blood pre.sure.control. Me.hodology: This wa. a.de.criptive.cross-se.tiona. study with a. a.a.ytica. focus ove. 7 months. Pa.ie.ts we.e.re.ruite. a. outpa.ie.ts a.d a.l unde.we.t a.bula.ory blood pre.sure.me.0}ure. glyca.e. he.oglobin a.d cre.0}inine.me.0}ure.e.ts, a.d a.se.sme.t of complia.ce.with tre.0}me.t. Re.ults: During this pe.iod 116 pa.ie.ts we.e.colle.te.. The.pre.omina.ce.wa. fe.6}e.69%. The.me.0} a.e.of the.pa.ie.ts wa. 62 ± 7 ye.0}s with a.pe.0} be.we.n 60 a.d 70 ye.0}s. The.a.e.a.e.a.e.of hype.te.sion wa. 12 ye.0}s a.d tha. of dia.e.e. 6 1/2 ye.0}s. The.most fre.ue.tly a.socia.e. ca.diova.cula. risk fa.tor wa. a.se.e.ta.y life.tyle.(71.5%) a.te. a.e. 57.8% of pa.ie.ts we.e.not controlle. a. the.office. with a.pre.omina.ce.of systolic hype.te.sion (58.2%). 61.6% of pa.ie.ts we.e.controlle. by a.bula.ory blood pre.sure.me.0}ure. a.ra.e.of 47.8% of white.coa. hype.te.sion. Glyce.ic control wa. obse.ve. in 42.2% of ca.e. a.d 87% of pa.ie.ts ha. good re.a. function (glome.ula. filte. ra.e.≥ 60 ml/mn). The.a.e.tic complia.ce.wa. good in 53.4% of ca.e. a.d dua. the.a.y wa. the.most use. the.a.e.tic moda.ity 44.8% (52 pa.ie.ts) followe. by triple.the.a.y. The.fa.tors a.socia.e. with poor blood pre.sure.control we.e.glyce.ic imba.a.ce. non-complia.ce.a.d monothe.a.y. Dua. the.a.y ha. a.prote.tive.e.fe.t. conclusion: The.a.socia.ion of hype.te.sion a.d type.2 dia.e.e. is fre.ue.t. The.risk of occurre.ce.incre.0}e. with a.e. a.bula.ory blood pre.sure.me.0}ure.is the.be.t me.hod to a.se.s blood pre.sure.control. Optimiza.ion of blood pre.sure.control should a.so include.optimiza.ion of glyce.ic control.

关键词： Blood Pre.sure.control Glyce.ic control Hype.te.sive.a.d Dia.e.ic Pa.ie.ts

M1-pola.ize. ma.ropha.e.de.ive. ce.lula. na.ove.icle.coa.e. lipid na.opa.ticle. for e.ha.ce. ca.ce. tre.0}me.t through hybridiza.ion of ge.e.the.a.y a.d ca.ce. immunothe.a.y

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a.ta.Pha.ma.e.tica.Sinica.B 2024年第7期14卷 3169-3183页

作者： Ha.e.n Shin Jun-Hye.k Ha. Se.ngyong Shin Ga.Hyun Ba. Bora. Son Ta.-Hyung Kim He. Ho Pa.k chun Gwon Pa.k Woora. Pa.k De.a.tme.t of Inte.ra.ive.Biote.hnology Sungkyunkwan University(SKKU)SuwonGyeonggi 16419Republic of Korea De.a.me.t of Inte.ige.t Pre.ision He.0}thca.e.conve.ge.ce SKKUSuwonGyeonggi 16419Republic of Korea De.a.tme.t of Me.a.ioHe.0}th SKKU Institute for ConvergenceSKKUSuwonGyeonggi 16419Republic of Korea De.a.tme.t of Bioe.gine.ring Hanyang UniversitySeoul 04763Republic of Korea De.a.tme.t of Inte.ra.ive.e.gine.ring Chung-Ang UniversitySeoul 06974Republic of Korea De.a.tme.t of Biome.ica. e.gine.ring SKKUSuwonGyeonggi 16419Republic of Korea Kore.0}Institute.of Scie.ce.a.d Te.hnology(KIST) Seoul 02792Republic of Korea

Optimum ge.e.ic de.ive.y for modula.ing ta.ge. ge.e. to dise.0}e. tissue.is a.ma.or obsta.le.for profita.le.ge.e.*** na.opa.ticle.(LNPs),conside.e. a.prospe.tive.ve.icle.for nucle.c a.id de.ive.y,ha.e.de.onstra.e. e.fica.y in huma. use.during the.cOVID-19 *** study introduce. a.nove. bioma.e.ia.-ba.e. pla.form,M1-pola.ize. ma.ropha.e.de.ive. ce.lula. na.ove.icle.coa.e. LNPs(M1-c-LNPs),spe.ifica.ly e.gine.re. for a.combine. ge.e.immunothe.a.y a.proa.h a.a.nst solid *** dua.-function syste. of M1-c-LNPs e.ca.sula.e. Bcl2-ta.ge.ing siRNa.within LNPs a.d immune.modula.ing cytokine. within M1 ma.ropha.e.de.ive. ce.lula. na.ove.icle.(M1-NVs),e.fe.tive.y fa.ilita.ing a.optosis in ca.ce. ce.ls without impa.ting T a.d NK ce.ls,which a.tiva.e.the.intra.umora. immune.re.ponse.to promote.gra.ule.me.ia.ing killing for solid tumor *** re.e.tion within tumor wa. obse.ve. upon intra.umora. a.ministra.ion of M1-c-LNPs,owing to the.pre.e.ce.of a.he.ion mole.ule. on M1-NVs,the.e.y contributing to supe.ior tumor growth *** findings re.re.e.t a.promising stra.e.y for the.de.e.opme.t of ta.ge.e. a.d e.fe.tive.na.opa.ticle.ba.e. ca.ce. ge.e.ic-immunothe.a.y,with significa.t implica.ions for a.va.cing bioma.e.ia. use.in ca.ce. the.a.e.tics.

关键词： Ge.e.ic-immunothe.a.y M1 ma.ropha.e.de.ive. ce.lula. na.ove.icle. Lipid na.opa.ticle.(LNPs) Ge.e.the.a.y siRNA ca.ce. immunothe.a.y Solid tumor Tumor microe.vironme.t(TMe.

e.a.ua.ion of a.tibiotic Pre.cribing in the.Pe.ia.ric De.a.tme.t of Ga.rie. TouréTe.0}hing Hospita., Ba.0}o, ma.i

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Ope. Journa. of Pe.ia.rics 2024年第3期14卷 645-656页

作者： Pie.re.Togo Ha.a.Kona.é ma.ia. ma.ga.Ka.a.oko Sa.ko Djénéba.Kona.é a.doul Ka.im Doumbia.a.a.0}De.bélé Ouma. couliba.y a.ina.a.Sa.ga.é Moha.e. e.mouloud cissé Fousse.ni Tra.ré Be.co ma.ga.Ibra.im a.a.0}ou a.ina.a.Doumbia.La.a.N’Dra.y Sidibé a.0}ou Touré Ya.ouba.a.a.couliba.y Ka.irou Tra.ré Ta.i Sima.a.Soule.ma.e.Sa.a.a.Le.la.Ba.na.ma.ga.Bory Tra.ré a.doul a.iz Dia.ité Fa.ouma.a.Dicko ma.ia. Sylla.Sounka.o Da. Bouba.a. Togo Pa.dia.ric De.a.tme.t Gabriel Tour&#233 Teaching Hospital Bamako Mali Pe.ia.ric De.a.tme.t Distric VI Reference Health Center Bamako Mali Infe.tious Dise.0}e. De.a.tme.t Point G Teaching Hospital Bamako Mali

Obje.tive.: The.ma.n obje.tive.wa. to e.a.ua.e.a.tibiotic pre.cribing in the.De.a.tme.t of Pe.ia.rics a. Ga.rie. Touré te.1}hing hospita.. Me.hods: This wa. a.prospe.tive.de.criptive.study conducte. from Se.te.be. 1 to Nove.be. 31, 2018, in the.De.a.tme.t of Pe.ia.rics a. Ga.rie. Touré te.1}hing hospita.. a.l childre. a.e. 0 to 15 ye.1}s hospita.ize. for a.y pa.hology during the.study pe.iod a.d ha.ing re.e.ve. a. le.1}t one.a.tibiotic ha. be.n include.. Re.ults: We.colle.te. 445 childre.’s re.ords out of 1032 a.missions during the.study pe.iod, re.re.e.ting a.hospita. fre.ue.cy of 43.1%. The.se. ra.io wa. 1.3%. The.2 - 5 a.e.group a.counte. for 48.1%. Fe.e. wa. the.re.1}on for consulta.ion in 45.6% of ca.e.. Pa.ie.ts’ ge.e.a. condition wa. a.te.e. in 60% of ca.e.. The.fa.he.s we.e.blue.colla. worke.s in 65.4% a.d the.mothe.s house.ive. in 85%, a.d ha. no e.uca.ion in 42.9% a.d 64.5% re.pe.tive.y. He.a.ome.a.y wa. pre.e.t in 18.2%, sple.ome.a.y in 9.6% a.d pe.iphe.a. a.e.opa.hy in 3.1%. The.site.of infe.tion wa. pulmona.y in 37.6% a.d e.T in 9.2%. Ba.te.ia. infe.tion wa. a.sume. on a.mission in 54% of ca.e., a.d me.ingitis in 57.7%. The.discha.ge.dia.nosis wa. ma.a.ia.in 54.6%, se.e.e.a.ute.ma.nutrition in 18.6% a.d me.ingitis in 6.7%. The.de.1}h ra.e.wa. 3.8%. Ne.trophilic le.kocytosis wa. pre.e.t in 47.3% of pa.ie.ts. cRP wa. positive.in 85% of pa.ie.ts. Blood culture. ta.e. in 27.6% of pa.ie.ts we.e.positive.in 5. cSF a.a.ysis in 30% of pa.ie.ts showe. e.e.a.e. le.kocyte. in 6.5%. No culture. we.e.positive. a.tibiotic pre.cription wa. justifie. by infe.tious hypothe.e. in 43.1% of pa.ie.ts. β-la.ta. a.tibiotics we.e.pre.cribe. in 98.6%. a.tibiotic the.a.y wa. not a.a.te. to na.iona./inte.na.iona. re.omme.da.ions in 68.3% of ca.e., a.d wa. not justifie. in 16.3% of ca.e. on D5 of hospita.iza.ion. conclusion: a.tibiotic use.wa. justifie. in more.tha. ha.f of pa.ie.ts, but re.0}ne. ina.e.ua.e.in a.most two-thirds of ca.e., in line.with na.iona. a.d inte.na.iona. re.omme.d

关键词： a.tibiotic Pre.cription Hospita.iza.ion child

Uniform de.omposition of ve.ocity gra.ie.t te.sor

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Journa. of Hydrodyna.ics 2024年第1期36卷 24-34页

作者： che.xi ma.cha.qun Liu De.a.tme.t of ma.he.1}ics University of Texas at ArlingtonArlingtonTXUSA

In this pa.e.,the.principa. de.omposition of the.ve.ocity gra.ie.t te.sor[∇v]is discusse. in 3 ca.e. ba.e. on the.discrimina.t∆:∆0 with 3 distinct re.0} e.ge. va.ue.,a.d∆=0 with 1 or 2 distinct re.0} e.ge. *** ve.ocity ... 详细信息

In this pa.e.,the.principa. de.omposition of the.ve.ocity gra.ie.t te.sor[∇v]is discusse. in 3 ca.e. ba.e. on the.discrimina.t∆:∆e.0} e.ge. va.ue.a.d a.pa.r of conjuga.e.comple. e.ge. va.ue.,∆>0 with 3 distinct re.0} e.ge. va.ue.,a.d∆=0 with 1 or 2 distinct re.0} e.ge. *** ve.ocity gra.ie.t te.sor ca. a.so be.cla.sifie. a. rota.ion point,which ca. be.de.ompose. into thre. pa.ts,i.e.,rota.ion[R],she.0}[S]a.d stre.ching/compre.sion[Sc],a.d non-rota.ion point,we.de.ine. a.ne. re.ista.ce.te.m[L],a.d the.te.sor ca. be.de.ompose. into thre. pa.ts,i.e.,re.ista.ce.L],she.0}[S]a.d stre.ching/compre.sion[Sc].e.a.ple.ma.ric a.e.a.so displa.e. to de.onstra.e.the.ne. *** of principa. de.omposition be.we.n 3 diffe.e.t ca.e.,a.d be.we.n Re.ista.ce.a.d Liute. will a.so be.discusse..

关键词： Ve.ocity gra.ie.t Liute. re.ista.ce fluid kine.0}ics

Tre.ds in colore.ta. ca.ce. incide.ce.a.cording to a. incre.0}e.in the.numbe. of colonoscopy ca.e. in Kore.

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World Journa. of Ga.trointe.tina. Oncology 2024年第1期16卷 51-60页

作者： Ga.He. Kim Ye.ng cha. Le. Ta. Jun Kim Sung Noh Hong Dong Kyung cha.g Young-Ho Kim Dong-Hoon Ya.g cha.g Mo Moon Kyunga.Kim Hyun Gun Kim e.n-Ra. Kim Division of Ga.troe.te.ology Department of Internal MedicineAsan Medical CenterUniversity of Ulsan College of MedicineSeoul 05505South Korea De.a.tme.t of Digita. He.0}th Samsung Advanced Institute for Health Science and TechnologySungkyunkwan University School of MedicineSeoul 06351South Korea Division of Ga.troe.te.ology Department of Internal MedicineSamsung Medical CenterSungkyunkwan University School of MedicineSeoul 06351South Korea Division of Ga.troe.te.ology Department of Internal MedicineEwha Womans UniversitySeoul 07985South Korea Biome.ica. Sta.istics ce.te. Samsung Medical CenterSeoul 06351South Korea Division of Ga.troe.te.ology Department of Internal MedicineSoonchunhyang University College of MedicineSeoul 04401South Korea

Ba.KGROUND The.incide.ce.of colore.ta. ca.ce.(cRc)a.d pre.nva.ive.cRc(e.g.,e.0}ly colon ca.ce. a.d a.va.ce. a.e.oma.is gra.ua.ly incre.0}ing in se.e.a. *** To e.a.ua.e.the.tre.d in incide.ce.of cRc a.d pre.nva.ive.cRc a.cording to the.incre.0}e.in the.numbe. of colonoscopie. pe.forme. in *** This re.rospe.tive.cohort study e.rolle. Kore.0} pa.ie.ts from 2002 to 2020 to e.a.ua.e.the.incide.ce.of cRc a.d pre.nva.ive.cRc,a.d a.se.s the.numbe.s of dia.nostic colonoscopie. a.d colonoscopic ***-re.a.e. complica.ions by a.e.group we.e.a.so *** The.incide.ce.of cRc showe. a.ra.id incre.0}e.the. de.re.0}e. a.te. 2012 in the.50-75 ye.0}-a.e.*** the.study pe.iod,the.ra.e.of incide.ce.of pre.nva.ive.cRc incre.0}e. a. a.simila. le.e. in pa.ie.ts unde. 50 a.d 50-75 ye.0}s of *** 2009,the.incre.0}e.ha. be.n ra.id,showing a.pa.te.n simila. to the.incre.0}e.in *** ra.e.of colonoscopic polype.tomy in pa.ie.ts a.e. unde. 50 wa. simila. to the.ra.e.in pa.ie.ts ove. 75 ye.0}s of a.e.a.te. *** ra.e.of complica.ions a.te. colonoscopy a.d re.a.e. de.0}hs within 3 mo wa. high for those.ove. 75 ye.0}s of *** The.dia.nosis of pre.nva.ive.cRc incre.0}e. with the.incre.0}e.in the.numbe. of colonoscopie. *** the.risk of colonoscopy-re.a.e. hospita.iza.ion a.d de.0}h is high in the.e.de.ly,if e.0}ly le.ions a. risk of de.e.oping cRc a.e.dia.nose. a.d tre.0}e. unde. or a. the.a.e.of 75,colonoscopy-re.a.e. complica.ions ca. be.re.uce. for those.a.e. 76 ye.0}s or ove..

关键词： colore.ta. ca.ce. Pre.nva.ive.colore.ta. ca.ce. colore.ta. polype.tomy colonoscopy

Me.a.-Orga.ic Fra.e.orks Housing a.tive.Mole.ule. a. Bioinspire. ca.a.ysts

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ccS che.istry 2024年第6期6卷 1380-1402页

作者： Yin Zha.g Pe.e. e.Va.Na.ta.Junyu Re. She.gqia. ma De.a.tme.t of che.istry University of North TexasDentonTexas 76201 De.a.tme.t of che.ica. a.d Biomole.ula. e.gine.ring National University of SingaporeSingapore 117585

Optimiza.ion of a.tivity,se.e.tivity,a.d sta.ility of ca.a.ysts for pra.tica. a.plica.ion is a.long-soughta.te. *** progre.s in the.a.va.ce.e.t of ra.iona. ca.a.yst de.ign routine.y ta.e. que.e. from ***,e.zyme. a.e.re.owne. for the.r high e.ficie.cy a.d se.e.tivity in dive.se.a.d significa.t re.0}tions unde. mild *** the.we.l-known me.its of e.zyme.,the. ofte. re.24}n unsuita.le.for industria. ca.a.ysis due.to issue.,including limite. e.vironme.t(solve.t/te.pe.a.ure.pH)compa.ibility,conside.a.le.structura. unce.ta.nty,a.d highly spe.ific re.0}tion *** the.conte.t of bioinspire. ca.a.ysis de.ign,the.de.e.opme.t of synthe.ic he.e.oge.e.us ca.a.yst a.a.ogs,which ma. not only mimic e.zyme. to re.roduce.or e.e. surpa.s the.r pe.forma.ce.but a.so bypa.s the.r intrinsic limita.ions,is thus,de.ira.le.a.d ha. be.n e.te.sive.y studie. in the.conte.t of porous *** me.a.-orga.ic fra.e.ork(MOF)is a.supe.ior ca.dida.e.for porous ma.e.ia.s towa.ds this goa.,tha.ks to fa.ile.a.d modula. pre.a.a.ion,e.plicit crysta.line.composition/structure.tuna.le.pore.size.e.vironme.t,a.d e.ce.le.t *** introduction of a.tive.mole.ula. spe.ie. such a. bioa.tive.mole.ule.(e.g.,prote.ns,e.zyme.,pe.tide.,a.ino a.ids,porphyrins)a.d che.ica.ly a.tive.mole.ule.(e.g.,frustra.e. Le.is pa.rs)into me.a.-orga.ic fra.e.orks(MOFs)via.pore.e.ca.sula.ion,che.ica. postmodifica.ion,or bottom-up construction ha. be.n shown to fa.ilita.e.the.coope.a.ive.e.ha.ce.e.t of ca.a.ysis through the.e.force.e.t of proximity,e.ha.ce.e.t of control/a.tivity,a.d e.e. induce.e.t of une.pe.te. *** this minire.ie.,we.sought to summa.ize.the.la.t 5 ye.0}s of fruitful progre.s,e.ploiting MOFs housing a.tive.mole.ule. for substa.tia. ca.a.ysis a.plica.ions,including a.ymme.ric re.0}tions,cO_(2)conve.sion(re.uction,cycloa.dition),bioca.a.ytic H_(2)O_(2)/dye.de.ra.a.ion,a.d so on,a.d discuss cha.le.ge. a.d opportunitie. in the.prospe.tive.e.plora.ion of the.e.syste.

关键词： me.a.-orga.ic fra.e.ork bioinspire. ca.a.yst a.tive.mole.ula. spe.ie.

3D Printe. Polyimide.Silica.composite.a.roge.s for customiza.le.The.ma. Insula.ion from-50℃ to 1300℃

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chine.e.Journa. of Polyme. Scie.ce 2024年第7期42卷 936-945,I0007页

作者： Dingyi Yu Tia.tia. Xue.Zhuoche.g ma.Za.yin Hu Lijua. Long Yue.e.Mia. We. Fa. Tia.xi Liu Sta.e.Ke. La.ora.ory for Modifica.ion of che.ica. Fibe.s a.d Polyme. ma.e.ia.s College of Materials Science and EngineeringDonghua UniversityShanghai201620China Ke. La.ora.ory of Synthe.ic a.d Biologica. colloids Ministry of EducationSchool of Chemical and Material EngineeringJiangnan UniversityWuxi214122China Guizhou a.rospa.e.Wujia.g e.e.tro-Me.ha.ica. e.uipme.t co. Ltd.Zunyi563000China School of ma.e.ia.s a.d a.chite.tura. e.gine.ring Guizhou Normal UniversityGuiyang550025China

a.roge.s a.e.wide.y use. a. the.ma. insula.ion ma.e.ia.s be.a.se.of the.r high porosity a.d low bulk ***,the.insula.ion pe.forma.ce.of a.roge.s is limite. to a.na.row te.pe.a.ure.***,the.pre.a.a.ion of a.roge. ma.e.ia.s with pre.ise.y controlle. a.d comple. a.chite.ture. is still ***,we.re.ort 3D printe. polyimide.silica.a.roge. pa.ticle.PI/Sa.)composite.a.roge.s for the.ma. insula.ion in a.wide.ra.ge.of te.pe.a.ure.with customize. *** printa.ility a.d sha.e.fide.ity of 3D printe. composite.a.roge.s is improve. by a.ding hydrophilic Sa. a. a.rhe.logy *** re.ulting PI/Sa. composite.a.roge. e.hibits e.ce.le.t fla.e.re.a.da.t prope.tie. a.d the.ma. insula.ion from-50℃ to 1300℃.More.ve.,the.PI/Sa. composite.a.roge. with customize. sha.e.ca. be.a.plie. for ba.te.y insula.ion a. subze.o te.pe.a.ure.,promising to be.use. a. customiza.le.a.d sta.le.insula.ing ma.e.ia.s in a.va.ie.y of comple. a.d e.tre.e.a.plica.ions.

关键词： 3D printing Polyimide a.roge. Silica The.ma. insula.ion