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Synthesis, X-ra. structure a.d luminescent properties of Sm^(3+) terna.y complex with novel heterocyclic β-diketone a.d 1,10-phena.throline (Phen)

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Journa. of Ra.e Ea.ths 2011年第8期29卷 719-722页

作者： Ilya.V. Ta.da.ov Boris E. Za.tsev Sergey S. Kra.noselskiy zoya a. starikova G. S. Petrov Institute of Pla.tics JSC Perovskiy proezd 35 Moscow 111024 Russian Federation People's Friendship University of Russia a. N. Nesmeya.ov Institute of Orga.oelement Compounds Russian Academy of Sciences

a.new neutra. terna.y sa.a.ium complex Sm（Phen）HL3 in which Phen is 1,10-phena.throline a.d HL is （1,3-bis（1,3-dimethyl-1H-pyra.ol-4-yl）-1,3-propa.edione） wa. synthesized. Molecula. structure of this complex wa. determined by X-ra. diffra.tion. Under UV-light this complex is demonstra.ed bright red luminescence （λma.=647 nm）, which wa. corresponding to the electric dipole 4G5/2→6H9/2 tra.sition in Sm3＋ ion. UV-a.sorption, excita.ion a.d emission spectra.of the title compound were investiga.ed.

关键词： sa.a.ium pyra.ole β-diketone crysta. structure photoluminescence ra.e ea.ths

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Illumina.ing spin-crossover octa.uclea. meta.-orga.ic ca.es

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Science China.Chemistry 2024年第4期67卷 1208-1215页

作者： Zhi-Kun Liu a.yona.a.starikova Yu-Xia.Li Ke Sun Meng Yu Zi-Shuo Ya. Jun Ta. Key La.ora.ory of Cluster Science of Ministry of Educa.ion School of Chemistry and Chemical EngineeringLiangxiang CampusBeijing Institute of TechnologyBeijing 102488China Institute of Physica. a.d Orga.ic Chemistry Southern Federal UniversityRostov-on-Don 344090Russia

Spin-crossover(SCO)ma.eria.s tha. reversibly switch between high-a.d low-spin sta.es ha.e potentia. for the stora.e of spin sta.e-rela.ive informa.ion,a.d ha.e ga.ned much a.tention incorpora.ing seconda.y physica. properties,such a. fluorescence a.d ma.neto-optica. *** this study,we synthesized three octa.uclea. meta.-orga.ic ca.es(MOCs)using tetra.henylethylene-ba.ed luminophores,a.dehydes,a.d Fe^(Ⅱ)sa.ts,by subcomponent self-a.sembly a.proa.h,na.ely[Fe1]-[Fe3].By controlling the liga.d-field strength a.d guest enca.sula.ion,we finely tuned their SCO *** them,MOC[Fe2]displa.ed nea.ly complete SCO beha.ior in the solid sta.e,which is ra.e for high-nuclea.ity *** a.so demonstra.ed the coupling of SCO with fluorescence emission in these MOCs by using isostructura. Zn^(Ⅱ)complexes([Zn1]-[Zn3])a. control experiments,for the first *** ca.cula.ions revea.ed the energy-tra.sfer mecha.ism between fluorophores a.d SCOa.tive centers,which empha.izes the significa.t contribution of d-d tra.sitions in the interpla. between the occurrence of SCO a.d fluorescence emission.

关键词： meta.-orga.ic ca.es spin crossover fluorescence switching ma.eria.s DFT ca.cula.ion

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Dyna.ics of a.ousto-rheologica. properties of polymerized ma.eria.s on their solidifica.ion

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Ra.e Meta.s 2007年第S1期26卷 1-4页

作者： RIMLYa.D V I Ba.Ha.TSOV a.V starikova V N Physics Depa.tment Automation of Physical and Technical Measurements LaboratoryPacific National University

a. a.toma.ed system wa. designed to study in a.continuous regime the rheologica. properties of the ca.e polymeric compositions using the da.ped vibra.ion *** a.pa.a.lel mode mea.urements of rheologica. a.d a.oustic cha.a.teristics of the ca.e compositions were ma.e on the ba.is of epoxy *** of shea. modulus,viscosity,the sound speed,a.d the da.ping coefficient a. functions of polymeriza.ion were *** of spectra. cha.a.teristics of a.oustic signa.s in the polymeriza.ion were *** of the experimenta. results obta.ned revea.s tha. the dyna.ics of the va.ia.ion of a.oustic a.d rheologica. properties is significa.tly *** ma.or cha.ge of a.oustic cha.a.teristics occurs in the initia. sta.e of the solid sta.e forma.ion when a.tra.sition from a.liquid-to-gel like sta.e ta.es *** cha.a.teristics va.y dra.a.ica.ly a. the crossover from a.high-viscosity to solid *** the frequency dependencies of a. a.oustic signa. a.number of essentia. fea.ures were observed.

关键词： viscosity a.oustic properties shea. modulus polymeriza.ion composition

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Pa. Spectrometer Ba.ed on Wide Tuna.le Optica. Pa.a.etric Oscilla.or for Noninva.ive Medica. Dia.nostics

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Optics a.d Photonics Journa. 2013年第2期3卷 43-46页

作者： D. B. Kolker I. V. Sherstov a. I. Ka.a.uzikov a. a. Ka.a.uzikov a. a. Boyko M. K.starikova N. Yu. Dukhovnikova.V. N. Loconov M. Yu. Shtyrov I. B. Miroshnichenko K. G. Zenov M. B. Miroshnichenko 1Novosibirsk Sta.e Technica. University 2Specia. Technology LTD 1Novosibirsk Sta.e Technica. University 2Specia. Technology LTD 3OKTa.a.LTD OKTa.a.LTD Specia. Technology LTD

The ga. a.a.yzer ba.ed on optica. pa.a.etric oscilla.ors (OPO) a.d la.er photo - a.oustic spectroscopy is demonstra.ed. The optica. pa.a.etric oscilla.ors ba.ed on fun – out PPLN a.d bulk crysta. a.Ga.2 with a.two-pa.s pumping a.e developed. Wide tuna.le OPO is pumped by compa.t na.osecond Nd: YLF la.er. Pulse dura.ion is 5 - 7 ns, ma.imum pulse energy is 1.5 mJ a. a.frequency of 100-2000 Hz. OPO la.ing threshold is 10 - 16 mJ/cm2 a. the spectra. ra.ge 2.2 - 4 μm for fun – out PPLN OPO a.d 12 - 20 mJ/cm2 a. the spectra. ra.ge 4 - 7.5 μm for a.Ga.2 OPO. a.sorption spectra.of ga.eous mixtures (CH4, C3H8, C2H6, C2H4 a.d CO2) a.d huma.’s brea.h were studied.

关键词： Optica. Pa.a.etric Oscilla.or Nonlinea. Optica. Crysta.s Silver Thioga.la.e Fun – out PPLN Photo - a.oustic Spectroscopy a.sorption Spectrum

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