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In situ Preparation and Visible-light-driven Photocatalytic Degradation Performance of Nano 3C-SiC@Multilayer Graphene Oxide Heterostructure

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Chemical Research in Chinese Universities 2024年第3期40卷 536-547页

作者： YANG Xiaodan GUO Ziqi XU Yichen li ziliang ZHOU Yangtao YANG Zhenming ZHOU Zishuai GAO Yong ZHANG Jinsong Shenyang National Laboratory for Materials Science Institute of Metal ResearchChinese Academy of SciencesShenyang 110016P.R.China Nano Science and Technology Institute University of Science and Technology of ChinaSuzhou 215123P.R.China Shenyang SCIENCREAT Chemicals Co. Ltd.Shenyang 110144P.R.China School of Materials Science and Engineering Northeastern UniversityShenyang 110819P.R.China

Nano 3C-SiC@multilayer graphene oxide(NS@MGO)heterostructure was in situ prepared by carbothermal reduction of pyrolyzed precursor composed of highly dispersed cured phenolic resin and silicon dioxide derived from tetraethyl *** heterojunction interface,number of layers of MGO,and defect content in graphene are the three most important factors for promoting photocatalytic *** contact between 3C-SiC nanograins and MGO layers facilitates the photogenerated electrons to migrate across the heterojunction interface and avoid the formation of SiO_(2) nanolayers on the surface of SiC *** number of MGO layers is supposed to be less than ten instead of over-thick *** concentrations of oxygenated components,considered the defect contents,decrease with the increase of sintering temperature for NS@MGO 0.175-T-150,and relative carbon content in the multilayer graphene *** to the heterostructures,properties,and photocatalytic reaction performance of the NS@MGO materials,the highest photocatalytic kinetic rate constant of 0.00891/min for NS@MGO 0.175-1500-150 shows that the significant enhancement in photocatalytic degradation activity under visible light(>420 nm)irradiation is ascribed to the advantageous synergistic effects between the nano 3C-SiC particles and the direct contact multilayer graphene oxide with appropriate layers and sufficient oxygen content of 3.51%(atomic fraction)in MGO.

关键词： Photocatalysis Multilayer graphene oxide Nano 3C-SiC Visiblelight degradation

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锻压条件对高强建筑Al-11.5Si-2Cu-0.5Fe铝合金显微组织的影响

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锻压技术 2024年第5期49卷 13-16,83页

作者：郭正烜李子亮山西工程科技职业大学建筑设计学院山西晋中030600 河北科技大学材料科学与工程学院河北石家庄050091

为研究不同锻压条件对近共晶Al-Si合金Al-11.5Si-2Cu-0.5Fe显微组织的影响,在300、400和500℃锻压温度以及1.5和2.0锻压比下,通过收敛模具对Al-11.5Si-2Cu-0.5Fe铝合金进行锻压,并采用光学显微镜和X射线衍射仪对铝合金的显微组织及析出... 详细信息

为研究不同锻压条件对近共晶Al-Si合金Al-11.5Si-2Cu-0.5Fe显微组织的影响,在300、400和500℃锻压温度以及1.5和2.0锻压比下,通过收敛模具对Al-11.5Si-2Cu-0.5Fe铝合金进行锻压,并采用光学显微镜和X射线衍射仪对铝合金的显微组织及析出相进行观察。实验结果表明:铸造态的Al-11.5Si-2Cu-0.5Fe铝合金形成了多种复杂的金属间化合物相,如β-Al_(4.5)FeSi相和Al_(2)Cu相。在锻压过程中Al-11.5Si-2Cu-0.5Fe铝合金的显微组织显著细化,同时,粗大颗粒发生破裂和碎片化。随着锻压温度的升高,Si颗粒长大,晶粒细化减弱;随着锻压比的增加,Si颗粒破碎加剧,晶粒细化更明显。300℃锻压温度、2.0锻压比下可以获得最佳细化效果。可为Al-11.5Si-2Cu-0.5Fe铝合金实际锻造生产过程中显微组织的变化提供理论基础。

关键词： Al-11.5Si-2Cu-0.5Fe铝合金锻压温度锻压比显微组织 Si颗粒尺寸

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基于双三次插值和高斯拟合的光条中心亚像素提取方法

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激光杂志 2024年第6期45卷 100-105页

作者：贺强旅朱艳春李子良李小松太原科技大学太原030024

针对结构光三维测量的高精度要求,提出一种基于双三次插值和高斯拟合的激光线条亚像素提取方法。该方法首先对光条图像进行感兴趣区域提取、高斯滤波等前处理,其次用形态学方法细化激光线条得到初始中心点,然后使用五点拟合法得到光条... 详细信息

针对结构光三维测量的高精度要求,提出一种基于双三次插值和高斯拟合的激光线条亚像素提取方法。该方法首先对光条图像进行感兴趣区域提取、高斯滤波等前处理,其次用形态学方法细化激光线条得到初始中心点,然后使用五点拟合法得到光条法线方向,在光条法线方向上取亚像素的拟合点,利用双三次插值得到亚像素坐标的像素值,最后进行高斯拟合,到光条亚像素中心。实验结果表明,算法平均精度值为0.389147像素,消耗时间为0.056 2 s,具有较高的提取精度和稳定性。

关键词：线结构光中心线提取亚像素坐标高斯拟合双三次插值

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基于可调叶高扩压器的离心压气机构型流动机理研究

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内燃机学报 2024年第4期42卷 343-350页

作者：李紫良赵江彬卢新根朱俊强西北工业大学动力与能源学院陕西西安710072 中国科学院工程热物理研究所轻型动力实验室北京100190 中国科学院大学北京100049

离心叶轮/扩压器匹配关系恶化直接限制了离心压气机的稳定工作范围.以Radiver离心压气机为研究对象,借助经过校核的数值模拟方法开展了基于可调叶高扩压器的离心压气机叶轮/扩压器匹配关系及流动机理研究.结果表明:通过建立能够指导扩... 详细信息

离心叶轮/扩压器匹配关系恶化直接限制了离心压气机的稳定工作范围.以Radiver离心压气机为研究对象,借助经过校核的数值模拟方法开展了基于可调叶高扩压器的离心压气机叶轮/扩压器匹配关系及流动机理研究.结果表明:通过建立能够指导扩压器叶高调节方向和量值的“压气机工作流量-扩压器最佳叶高”正相关对应关系,即可在压气机近失稳点等小流量点主动降低扩压器叶高以改善压气机稳定工作裕度.在设计转速下,引入可调叶高扩压器能够使离心压气机的稳定裕度提升18.8%、流量范围拓宽385%且峰值效率提高0.45%;随着压气机工作点向小流量工况偏移,降低扩压器叶高可以抑制扩压器来流正攻角,优化重构其通道内部涡系结构,减小扩压器吸力面和压力面/轮毂角区的低速区,进而改善叶轮/扩压器匹配关系,抑制扩压器内部流动失稳发生,提升离心压气机稳定裕度和效率指标.

关键词：离心压气机可调叶高扩压器叶轮/扩压器匹配流动机理

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基于随机森林和人工神经网络构建种植体周炎的诊断模型

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华西口腔医学杂志 2024年第2期42卷 214-226页

作者：杨浩然陈宇翔赵安娜程婷婷周建忠李自良昆明医科大学附属口腔医院昆明650000 云南省口腔医学重点实验室昆明650000

目的本研究旨在揭示种植体周炎发生发展过程中参与调控的关键基因,并通过随机森林(RF)和人工神经网络(ANN)构建种植体周炎的诊断模型。方法本研究从GEO数据库中获取GSE33774、GSE106090和GSE57631数据集。对GSE33774和GSE106090数据集... 详细信息

目的本研究旨在揭示种植体周炎发生发展过程中参与调控的关键基因,并通过随机森林(RF)和人工神经网络(ANN)构建种植体周炎的诊断模型。方法本研究从GEO数据库中获取GSE33774、GSE106090和GSE57631数据集。对GSE33774和GSE106090数据集进行差异表达和功能富集分析,通过蛋白质互作网络(PPI)和RF筛选出关键基因,利用ANN建立种植体周炎的诊断模型,并在GSE33774和GSE57631数据集中进行验证。同时,构建转录因子-基因相互作用网络和转录因子-微小RNA (miRNA)调控网络。结果本研究共筛选出124个参与调控种植体周炎的差异表达基因(DEGs)。富集分析结果表明,DEGs主要和免疫受体活性蛋白及细胞因子受体活性相关,主要参与白细胞和中性粒细胞迁移的过程。PPI和RF筛选出6个关键基因,分别为CD38、CYBB、FCGR2A、SELL、TLR4和CXCL8。受试者操作特征曲线(ROC)表明ANN模型具有较好的诊断性。本研究还发现FOXC1、GATA2和NF-κB1可能是种植体周炎中重要的转录因子,hsa-miR-204可能是关键的miRNA。结论 RF和ANN构建的种植体周炎的诊断模型可信度高,CD38、CYBB、FCGR2A、SELL、TLR4和CXCL8是潜在的诊断标志物。FOXC1、GATA2和NF-κB1可能是种植体周炎中重要的转录因子,hsa-miR-204作为关键的miRNA在其中扮演着重要角色。

关键词：种植体周炎生物信息学随机森林人工神经网络诊断模型

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基于Kinect V2和Unity3D的机械臂人机交互系统

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计算机与数字工程 2024年第3期52卷 735-739,745页

作者：李子良李庆党王晓波和学泰青岛科技大学机电工程学院青岛266100 青岛科技大学中德科技学院青岛266100

针对人机交互方式存在不直观、操作复杂等问题,论文利用手部追踪技术开发出一种基于Kinect V2和Unity3D的人机交互系统,用户可以直接挥动手部就可以控制机械臂运动,交互方式更加简单、直观和灵活。该系统是通过Kinect V2来获得手部移动... 详细信息

针对人机交互方式存在不直观、操作复杂等问题,论文利用手部追踪技术开发出一种基于Kinect V2和Unity3D的人机交互系统,用户可以直接挥动手部就可以控制机械臂运动,交互方式更加简单、直观和灵活。该系统是通过Kinect V2来获得手部移动轨迹来实现手部追踪,并在Unity3D平台上进行交互系统的开发。利用FABRIK算法和贝塞尔曲线分别实现了逆运动学求解和运动路径的记录,通过C#编写所需的脚本功能并开发出了两种交互模式,分别为实时控制模式和示教模式,两种模式均可通过UI面板进行选择。最后对两种模式分别进行实验,实验结果证明了该系统的可行性。

关键词：人机交互手部追踪 Kinect V2 Unity3D

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Vortex dynamics and entropy generation in separated transitional flow over a compressor blade at various incidence angles

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Chinese Journal of Aeronautics 2022年第3期35卷 42-52页

作者： Mingyang WANG ziliang li Ge HAN Chengwu YANG Shengfeng ZHAO Yanfeng ZHANG Xin’gen LU Key Laboratory of light-Duty Gas-Turbine Institute of Engineering ThermophysicsChinese Academy of SciencesBeijing 100190China University of Chinese Academy of Sciences Beijing 100049China

The transition process within a Laminar Separation Bubble(LSB)that formed on a compressor blade surface was investigated using Large Eddy Simulations(LESs)at a Reynolds number of 1.5×10;and incidence angles of 0°,+3°,and+5°.The vortex dynamics in the separated shear layers were compared at various incidence angles and its effects on the loss generation were clarified through entropy *** showed that transition onset,which was accurately identified by the linear Stability Theory(LST),was significantly promoted at the increased incidence *** such,the development of LSB was suppressed and the relative role of viscous instability played in the transition process was *** the incidence angle of 0°,two-dimensional spanwise vortices detached from the blade surface and roiled up periodically,which were further stretched and eventually evolved into large-scale hairpin *** time passed,the fully developed hairpin vortices broke down into small-scale ***,the flow near the wall reversely ejected into the outer separated shear layers and a sweeping process happened subsequently,forcing the separated shear layers to reattach and accelerating the generation of turbulent *** comparison,the strength of vortex rolling-up was weakened at higher incidence angles,and the vortex pairing and breakdown of large-scale vortices were less ***,the level of turbulent fluctuations that generated in the separated shear layers was *** entropy analysis showed that the turbulent dissipation effect related to the Reynolds shear stresses determined the largest amount of positive entropy generation,which declined to a lower level as the incidence angle increased from 0°to+5°.Correspondingly,the profile loss was reduced by 50.4%.

关键词： Aerodynamic performance Compressor airfoil Entropy Incidence angle Separation bubble Vortex dynamics

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Resonance and Bifurcation of Fractional Nonlinear Systems with Power Damping Term for Robot Grinding

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Journal of Beijing Institute of Technology 2023年第1期32卷 23-40页

作者： Wei Shi Qingxue Huang Jinzhu Zhang Tao Wang ziliang li Yanjie Zhang Xiaoyan Xiong College of Mechanical and Vehicle Engineering Taiyuan University of TechnologyTaiyuan 030024China Engineering Research Center of Advanced Metal Composites Forming Technology and Equipment Ministry of EducationTaiyuan University of TechnologyTaiyuan 030024China Institute of Advanced Forming and Intelligent Equipment Taiyuan University of TechnologyTaiyuan 030024China

A fractional nonlinear system with power damping term is introduced to study the forced vibration system in order to solve the resonance and bifurcation problems between grinding wheel and steel bar during robot *** robot,grinding wheel and steel bar are reduced to a spring-damping second-order system *** implicit function equations of vibration amplitude of the dynamic system with coulomb friction damping,linear damping,square damping and cubic damping are obtained by average *** stability of the system is analyzed and explained,and the stability condition of the system is ***,the amplitude-frequency characteristic curves of the system under different fractional differential orders,nonlinear stiffness parameters,fractional differential term coefficients and external excitation amplitude are *** is shown that the fractional differential term in the dynamic system is the damping *** the influence of four kinds of damping on the vibration amplitude of the system under the same parameter is investigated and it is proved that the cubic damping suppresses the vibration of the system to the maximum ***,based on the idea that the equilibrium point of the system is the constant part of the Fourier series expansion term,the bifurcation behavior caused by the change of damping parameters in linear damping,square damping and cubic damping systems with different values of fractional differential order is investigated.

关键词： robot grinding fractional system average method power damping resonance and bifurcation

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Stability of dimensionally stable anode for chlorine evolution reaction

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Nano Research 2024年第3期17卷 949-959页

作者： ziliang Deng Shuying Xu Chuhao liu Xueqiang Zhang Mufan li Zipeng Zhao Beijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green Applications Experimental Center of Advanced MaterialsSchool of Materials Science and EngineeringBeijing Institute of TechnologyBeijing 100081China Beijing National Laboratory for Molecular Sciences College of Chemistry and Molecular EngineeringPeking UniversityBeijing 100871China Laser Micro/Nano-Fabrication Laboratory School of Mechanical EngineeringBeijing Institute of TechnologyBeijing 10081China

Chlorine(Cl2)is one of the most important chemicals produced by the electrolysis of brine solutions and is a key raw material for many areas of industrial *** nearly half a century,dimensionally stable anode(DSA)made from a mixture of RuO_(2) and TiO_(2) solid oxides coated on Ti substrate has been the most widely used electrode for chlorine evolution reaction(CER).In harsh operating environments,the stability of DSAs remains a major challenge greatly affecting their *** deactivation of DSAs significantly increases the cost of the chlor-alkali industry due to the corrosion of Ru and the formation of the passivation layer TiO_(2).Therefore,it is urgent to develop catalysts with higher activity and stability,which requires a thorough understanding of the deactivation mechanism of DSA *** paper reviews existing references on the deactivation mechanisms of DSA catalysts,including both experimental and theoretical *** on how CER selectivity affects electrode stability are also ***,studies on the effects of the preparation process,elemental composition,and surface/interface structures on the DSA stability and corresponding improvement strategies are *** development of other non-DSA-type catalysts with comparable stability is also reviewed,and future opportunities in this exciting field are also outlined.

关键词： chlorine evolution reaction(CER) dimensionally stable anode(DSA) RuO_(2)-TiO_(2) metal oxide anode stability

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Interpretable discovery of semiconductors with machine learning

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npj Computational Materials 2023年第1期9卷 1150-1160页

作者： Hitarth Choubisa Petar Todorović Joao M.Pina Darshan H.Parmar ziliang li Oleksandr Voznyy Isaac Tamblyn Edward H.Sargent Department of Electrical and Computer Engineering University of Toronto10 King’s College RoadTorontoON M5S 3G4Canada Department of Physical and Environmental Sciences University of TorontoScarboroughON M1C 1A4Canada Department of Physics University of OttawaOttawaON K1N 6N5Canada Vector Institute for Artificial Intelligence TorontoON M5G 1M1Canada

Machine learning models of material properties accelerate materials discovery,reproducing density functional theory calculated results at a fraction of the cost1–*** bridge the gap between theory and experiments,machine learning predictions need to be distilled in the form of interpretable chemical rules that can be used by *** we develop a framework to address this gap by combining evolutionary algorithm-powered search with machine-learning surrogate *** then couple the search results with supervised learning and statistical *** strategy enables the efficient search of a materials space while providing interpretable design *** demonstrate its effectiveness by developing rules for the design of direct bandgap materials,stable UV emitters,and IR perovskite ***,we conclusively show how DARWIN-generated rules are statistically more robust and applicable to a wide range of applications including the design of UV halide perovskites.

关键词： preta learning perovskite

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