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Polyoxometalate as the assembly material to self-assembled Ni(OH)_(2) nanosheets with electrocatalytic performance

Nano Research 2024年第8期17卷 7061-7067页

作者： Danyang He Tianyang Li Luozhen Jiang Fei Wang zihao xing Nan Wang Zhiyu Jia Guo-Yu Yang Key Laboratory of Cluster Science Ministry of EducationSchool of Chemistry and Chemical EngineeringBeijing Institute of TechnologyBeijing 100081China Shanghai Advanced Research Institute Chinese Academy of ScienceShanghai 201210China Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education Facluty of ChemistryNortheast Normal UniversityChangchun 130024China

Developing non-noble metal-based electrocatalyst with high catalytic activity is essential for advancing hydrogen energy *** study introduces a hydrothermal method for synthesizing order Ni(OH)_(2) nanosheets,with H_(3)O_(40)PW_(12)(denoted as PW_(12))loaded onto reduced graphene oxide(rGO)coated on nickel foam(referred to as PW_(12)-Ni(OH)_(2)/rGO).This method contrasts with the electrodeposition of Ni(OH)_(2),where PW_(12) is added to the synthetic system to direct the assembly and morphology of the Ni(OH)_(2) through a hydrothermal *** this work,the nickel foam acts dual roles as both the substrate and the source of nickel for the formation of Ni(OH)_(2).The PW_(12)-Ni(OH)_(2)/rGO nanosheets,when successfully prepared and loaded onto the nickel foam(NF),exhibited superior electrocatalytic activity for the hydrogen evolution reaction(HER)in an alkaline electrolyte,achieving a current density of 10 mA·cm^(-2) at an overpotential of 69 ***,we endeavored to expand the application of this material towards the oxygen evolution reaction(OER)by preparing PW_(12)-(Fe/Co)Ni(OH)_(2)/rGO through the addition of metal *** nanocomposite displayed outstanding electrocatalytic activity in alkaline electrolytes,with a current density of 10 mA·cm^(-2)at an overpotential of 211 mV,and demonstrated excellent stability over a 50 h period in a 1 M KOH *** results presented in this paper offer an effective strategy for the preparation of polyoxometalate-based inorganic materials with diverse functionalities,applicable to both HER and OER.

关键词： polyoxometalate Ni(OH)_(2) assembly hydrogen evolution reaction oxygen evolution reaction

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Nanocomposite: Keggin-type Co_(4)-polyoxometalate@cobaltporphyrin linked graphdiyne for hydrogen evolution in seawater

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Nano Research 2024年第3期17卷 1281-1287页

作者： Jiejie Ping Danyang He Fei Wang Nan Wang Yi-cheng Fu zihao xing Zhiyu Jia Guo-Yu Yang Key Laboratory of Cluster Science Ministry of EducationSchool of Chemistry and Chemical EngineeringBeijing Institute of TechnologyBeijing 100081China Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education Facluty of Chmeistry Northeast Normal UniversityChangchun 130024China Peking University Third Hospital Beijing 100190China

Polyoxometalate-based nanocomposites with electrocatalytic activity have been applied in hydrogen evolution reactions(HER).Seawater as the main water resource on the earth should be developed as the water electrolysis to prepare high-purity *** this paper,we used two synthesis strategies to prepare the nanocomposite Co_(4)-POM@Co-PGDY(Co_(4)-POM:the Kegging-type microcrystals of K_(10)[Co_(4)(PW_(9)O_(3)4)2]and Co-PGDY:cobalt-porphyrin linked graphdiyne)with excellent activity for ***-PGDY as the porous material is applied not only as the protection of microcrystals towards the metal ion in seawater but also as the co-electrocatalyst of Co_(4)-***_(4)-POM@Co-PGDY exhibits excellent HER performance in seawater electrolytes with low overpotential and high stability at high ***,we have observed a key H_(3)O+intermediate emergence on the surface of nanocomposite during hydrogen evolution process in seawater by Raman synchrotron radiation-based Fourier transform infrared(SR-FTIR).The results in this paper provide an effective strategy for preparing polyoxometalate-based electrocatalysts with high-performance toward hydrogen evolution reaction.

关键词： polyoxometalate graphdiyne seawater hydrogen evolution reaction

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GLUL stabilizes N-Cadherin by antagonizing β-Catenin to inhibit the progresses of gastric cancer

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Acta Pharmaceutica Sinica B 2024年第2期14卷 698-711页

作者： Qiwei Jiang Yong Li Songwang Cai xingyuan Shi Yang Yang zihao xing Zhenjie He Shengte Wang Yubin Su Meiwan Chen Zhesheng Chen Zhi Shi Department of Cell Biology&Institute of Biomedicine National Engineering Research Center of Genetic MedicineState Key Laboratory of Bioactive Molecules and Druggability AssessmentMOE Key Laboratory of Tumor Molecular BiologyGuangdong Provincial Key Laboratory of Bioengineering MedicineCollege of Life Science and TechnologyJinan UniversityGuangzhou 510632China Department of Gastrointestinal Surgery&General Surgery the Guangdong Provincial People’s HospitalGuangdong Academy of Medical SciencesGuangzhou 510080China Department of Thoracic Surgery The First Affiliated Hospital of Jinan UniversityGuangzhou 510632China Department of Radiation Oncology The Fifth Hospital of Guangzhou Medical UniversityGuangzhou 510150China State Key Laboratory of Quality Research in Chinese Medicine Institute of Chinese Medical SciencesUniversity of MacaoMacao 519000China Department of Pharmaceutical Sciences College of Pharmacy and Health SciencesSt.John’s UniversityQueensNY 11439USA

Glutamate-ammonia ligase(GLUL, also known as glutamine synthetase) is a crucial enzyme that catalyzes ammonium and glutamate into glutamine in the ATP-dependent condensation. Although GLUL plays a critical role in multiple cancers, the expression and function of GLUL in gastric cancer remain unclear. In the present study, we have found that the expression level of GLUL was significantly lower in gastric cancer tissues compared with adjacent normal tissues, and correlated with N stage and TNM stage, and low GLUL expression predicted poor survival for gastric cancer patients. Knockdown of GLUL promoted the growth, migration, invasion and metastasis of gastric cancer cells in vitro and in vivo, and vice versa, which was independent of its enzyme activity. Mechanistically, GLUL competed with β-Catenin to bind to N-Cadherin, increased the stability of N-Cadherin and decreased the stability of β-Catenin by alerting their ubiquitination. Furthermore, there were lower N-Cadherin and higher β-Catenin expression levels in gastric cancer tissues compared with adjacent normal tissues. GLUL protein expression was correlated with that of N-Cadherin, and could be the independent prognostic factor in gastric cancer. Our findings reveal that GLUL stabilizes N-Cadherin by antagonizing β-Catenin to inhibit the progress of gastric cancer.

关键词： Gastric cancer GLUL N-Cadherin β-Catenin Enzyme

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基于高密度电测法的西沙东岛地下淡水透镜体识别

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资源科学 2024年第3期46卷 635-646页

作者：韩冬梅曹国亮蔡砥柱宋献方邢子浩孟庆杰中国地质调查局海口海洋地质调查中心海口571127 中国科学院地理科学与资源研究所陆地水循环及地表过程重点实验室北京100101 中国科学院大学资源与环境学院北京100049 中国地质大学(北京)水利部地下水保护重点实验室(筹) 北京100083 中国地质大学(北京)水资源与环境学院北京100083

[目的]珊瑚岛地下淡水透镜体是维持岛上居民生产生活、生态涵养所必需的重要资源。准确识别珊瑚岛地下淡水透镜体的形态,揭示地下淡水补给机制,是珊瑚岛地下水资源评价的重要基础,对实现科学管理海岛地下水资源至关重要。[方法]本文以... 详细信息

[目的]珊瑚岛地下淡水透镜体是维持岛上居民生产生活、生态涵养所必需的重要资源。准确识别珊瑚岛地下淡水透镜体的形态,揭示地下淡水补给机制,是珊瑚岛地下水资源评价的重要基础,对实现科学管理海岛地下水资源至关重要。[方法]本文以西沙群岛的东岛为研究对象,结合水文地质调查,对高密度电阻率法实测剖面数据进行反演解译,基于电阻率和地下水总溶解固体浓度关系识别了咸淡水界面。[结果]①根据高密度电阻率法反演电阻率首次识别了西沙东岛地下淡水透镜体发育特征,该方法在西沙珊瑚岛具有较好的适用性;②东岛淡水透镜体主要发育于岛屿西北和南侧沙堤,厚度较薄,仅3~7m,局部地区甚至无地下淡水;③东岛地下咸淡水界面形态说明沙堤以内植被根系吸水是造成淡水透镜体较薄的主要原因,植被分布对东岛地下淡水资源具有重要影响。[结论]在保护西沙珊瑚岛生态系统的前提下,适当减少人工椰树林种植面积,可有效增加岛屿降雨形成的地下淡水资源,有利于发挥珊瑚岛地下淡水透镜体对岛屿水安全的保障作用。

关键词：珊瑚岛淡水透镜体高密度电法咸淡水界面西沙东岛

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Structure engineering of PtCu_(3)/C catalyst from disordered to ordered intermetallic compound with heat-treatment for the methanol electrooxidation reaction

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Nano Research 2022年第5期15卷 3866-3871页

作者： zihao xing Jun Li Shun Wang Chenliang Su Huile Jin Institute of New Materials&Industry Technology Wenzhou UniversityWenzhou 325024China Institute of Microscale Optoelectronics Shenzhen UniversityShenzhen 518060China

Platinum based alloys are hereinto the mostly used methanol oxidation ***,there are limited ways to improve the methanol oxidation reaction(MOR)performance of catalysts in terms of both activity and *** we developed a simple heat-treatment method to synthesize PtCu_(3)/C intermetallic compound catalyst with lattice *** as-prepared PtCu_(3)/C-1000 exhibited high specific activity of 3.23 mA·cm^(-1) and mass activity of 1,200 mA·mgPt^(-1),which is much higher than the PtCu_(3)/C-untreated and commercial Pt/C catalysts,*** XAS and DFT results shows the high activity of the catalyst towards MOR comes from the tightening of the Pt-M bond,which leads to the decrease of Fermi energy level and the make it difficulty in adsorbing carbon intermediates,thus releasing more active sites to promote the improvement of MOR ***,the PtCu_(3)/C-1000 shows better stability which is due to the surface-rich Pt prevents Cu from dissolution.

关键词： methanol electrooxidation PtCu_(3)alloy catalyst lattice compression composition reconstruction heat-treatment

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三亚崖州湾海域上新世以来地震层序地层研究

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海洋地质前沿 2024年第8期40卷 65-75页

作者：崔浩楠吴能友谈明轩黄诚龙军桥颜历胡旋邢子浩邢景峰郭泽俊李央河海大学海洋学院南京210098 中国地质调查局海口海洋地质调查中心海口5571127 崂山实验室青岛266236

地质环境的稳定是支持人类社会生存和发展的基础条件之一,对三亚崖州湾海域地层地震相和沉积相进行研究,对该地区的演化过程及未来演化趋势具有科学意义。根据二维地震资料,以层序地层学为理论指导将崖州湾海域地层划分出3个三级层序,... 详细信息

地质环境的稳定是支持人类社会生存和发展的基础条件之一,对三亚崖州湾海域地层地震相和沉积相进行研究,对该地区的演化过程及未来演化趋势具有科学意义。根据二维地震资料,以层序地层学为理论指导将崖州湾海域地层划分出3个三级层序,自下而上依次命名为SQA、SQB、SQC。在SQA和SQB层序内部以最大海侵面为界划分了海侵体系域和高位体系域,SQC层序还未发育完全,只存在海侵体系域。在研究区的层序地层格架内识别出平行-亚平行反射地震相、下凹状地震相和前积反射地震相3种地震相类型。根据地震相展布特征,认为崖州湾海域沉积地层主要发育三角洲、滨海及浅海3种沉积相类型。上新世以来随着海平面的升降、气候变化及受其影响的物源供给水平变化,研究区由浅海相过渡到三角洲相,最后到现在的滨海相。

关键词：崖州湾上新世地震层序地震相沉积演化

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Chemical Scissors Tailored Nano‑Tellurium with High‑Entropy Morphology for Efficient Foam‑Hydrogel‑Based Solar Photothermal Evaporators

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Nano-Micro Letters 2024年第3期16卷 149-168页

作者： Chenyang xing zihao Li Ziao Wang Shaohui Zhang Zhongjian Xie Xi Zhu Zhengchun Peng State Key Laboratory of Radio FrequencyHeterogeneous Integration Shenzhen UniversityShenzhen 518060People’s Republic of China Center for Stretchable Electronics and NanoSensors College of Physics and Optoelectronic EngineeringShenzhen UniversityShenzhen 518060People’s Republic of China School of Science and Engineering The Chinese University of Hong KongShenzhenShenzhen 518172People’s Republic of China Institute of Pediatrics Shenzhen Children’s HospitalShenzhen 518038GuangdongPeople’s Republic of China International Collaborative Laboratory of 2D Materials for Optoelectronics Science and Technology of Ministry of Education Institute of Microscale OptoelectronicsShenzhen UniversityShenzhen 518060People’s Republic of China

The development of tellurium(Te)-based semiconductor nanomaterials for efficient light-to-heat conversion may offer an effective means of harvesting sunlight to address global energy ***,the nanosized Te(nano-Te)materials reported to date suffer from a series of drawbacks,including limited light absorption and a lack of surface ***,we report the preparation of nano-Te by electrochemical exfoliation using an electrolyzable room-temperature ionic ***,cations,and their corresponding electrolytic products acting as chemical scissors can precisely intercalate and functionalize bulk *** resulting nano-Te has high morphological entropy,rich surface functional groups,and broad light *** also constructed foam hydrogels based on poly(vinyl alcohol)/nano-Te,which achieved an evaporation rate and energy efficiency of 4.11 kg m^(−2)h^(−1)and 128%,respectively,under 1 sun ***,the evaporation rate was maintained in the range 2.5-3.0 kg m^(−2)h^(−1)outdoors under 0.5-1.0 sun,providing highly efficient evaporation under low light conditions.

关键词： Tellurium High entropy Electrochemical modification Solar absorption Evaporation rate

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Li-Zn alloy patch for defect-free polymer interface film enables excellent protection effect towards stable Li metal anode

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Chinese Chemical Letters 2024年第10期35卷 473-477页

作者： zihao Wang Jing Xue Zhicui Song Jianxiong xing Aijun Zhou Jianmin Ma Jingze Li School of Materials and Energy University of Electronic Science and Technology of China Huzhou Key Laboratory of Smart and Clean Energy Yangtze Delta Region Institute (Huzhou) University of Electronic Science and Technology of China School of Mathematics and Physics Weinan Normal University School of Chemistry Tiangong University

Constructing a smart polymer film with favorable lithium（Li） transport capability and mechanical flexibility for suppressing Li dendrite growth is an effective strategy. Unfortunately, the porosity and the swelling of the polymer membrane cannot completely prevent liquid electrolyte from sweeping through the artificial protection film, severely deteriorating the cyclic performance. Herein, we propose a defectfree hybrid film that consists of Li+conductive lithium polyacrylate（LiPAA） polymer interface layer and Li-Zn alloy patch to tackle the critical problems of traditional polymer composite passivation film. The pinhole leaks of the polymer matrix are self-filled by Li-Zn alloy patches, enhancing the integrity of LiPAA film. Consequently, a defect-free hybrid film is nailed flat against the Li metal anode, exhibiting extraordinary stability in the liquid electrolyte and enabling perfect protection effect. This facile strategy produces a promising anode for next generation Li batteries.

关键词： Hybrid film Li metal anode Li-Zn alloy LiPAA Patch

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AHA1 upregulates IDH1 and metabolic activity to promote growth and metastasis and predicts prognosis in osteosarcoma

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Signal Transduction and Targeted Therapy 2021年第2期6卷 507-518页

作者： Diwei Zheng Weihai Liu Wenlin Xie Guanyu Huang Qiwei Jiang Yang Yang Jiarong Huang zihao xing Mengling Yuan Mengning Wei Yao Li Junqiang Yin Jingnan Shen Zhi Shi Department of Cell Biology&Institute of Biomedicine National Engineering Research Center of Genetic MedicineMOE Key Laboratory of Tumor Molecular BiologyGuangdong Provincial Key Laboratory of Bioengineering MedicineCollege of Life Science and TechnologyJinan UniversityGuangzhouGuangdong 510632China Department of Musculoskeletal Oncology.the First Alilated Hospital of Sun Yat-sen University GuangzhouGuangdong 510080China Guangdong Provincial Key Laboratory of Orthopedics and Traumatology GuangzhouGuangdong 510080China Department of Pathology the Seventh Aflited Hospital of Sun Yat-sen UniversityShenzhenGuangdong 518017China

Osteosarcoma(OS)is the most common primary malignant bone tumor in children and *** activator of HSP90 ATPase activity 1(AHA1)is reported to be a potential oncogene,its role in osteosarcoma progression remains largely *** metabolism reprogramming is involved in tumorigenesis and cancer metastasis,the relationship between AHA1 and cancer metabolism is *** this study,we found that AHA1 is significantly overexpressed in osteosarcoma and related to the prognosis of osteosarcoma ***1 promotes the growth and metastasis of osteosarcoma both in vitro and in ***,AHA1 upregulates the metabolic activity to meet cellular bioenergetic needs in ***,we identifed that isocitrate dehydrogenase 1(IDH1)is a novel client protein of Hsp90 ***,the IDH1 protein level was positively correlated with AHA1 in *** IDH1 overexpression could partially reverse the effect of AHA1 knockdown on cell growth and migration of ***,high IDH1 level was also associated with poor prognosis of osteosarcoma *** study demonstrates that AHA1 positively regulates IDH1 and metabolic activity to promote osteosarcoma growth and metastasis,which provides novel prognostic biomarkers and promising therapeutic targets for osteosarcoma patients.

关键词： IDH1 osteosarcoma metastasis

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Marine red yeast supplementation improves laying performance by regulating small intestinal homeostasis in aging chickens

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ANIMAL NUTRITION 2024年第3期18卷 177-190页

作者： Zhao, Yudian Si, Sujin Ren, Yangguang Wu, xing Zhang, zihao Tian, Yixiang Li, Jing Li, Yijie Hou, Meng Yao, Xueyang Xu, Zhaoheng Jiang, Ruirui Kang, Xiangtao Gong, Yujie Li, Qiang Tian, Yadong Henan Agr Univ Coll Anim Sci & Technol Zhengzhou 450046 Peoples R China Henan Key Lab Innovat & Utilizat Chicken Germplasm Zhengzhou 450046 Peoples R China Henan Coll Anim Husb & Econ Zhengzhou 450046 Peoples R China Henan Inst Sci & Technol Coll Anim Sci & Vet Med Xinxiang 453003 Peoples R China AB Vista Marlborough SN8 4AN England

Recent studies have shown that age-related aging evolution is accompanied by imbalances in intestinal homeostasis. Marine red yeast (MRY) is a functional probiotic that has been shown to have antioxidant, immune and other properties. Therefore, we chose 900 healthy Hy-Line Brown hens at 433 d old as the research subjects and evaluated the correlation between intestinal health, laying performance, and egg quality in aged hens through the supplementation of MRY. These laying hens were assigned into 5 groups and received diet supplementation with 0%, 0.5%, 1.0%, 1.5%, and 2% MRY for 12 weeks. The results showed that MRY supplementation increased egg production rate, average egg weight, and egg quality, and decreased feed conversion ratio and daily feed intake (P < 0.05). The MRY supplement improved antioxidant indicators such as superoxide dismutase (SOD), catalase (CAT), glutathione peroxidase (GSH-Px), stimulated villus height, and increased the villus height to crypt depth ratio (V/C ratio) in the intestine (P < 0.05). It also regulated the expression of intestinal inflammatory factors (transforming growth factor-beta [TGF-beta], interleukin [IL]-1 beta, IL-8, tumor necrosis factor-alpha [TNF-alpha]) while increasing serum immunoglobulin G (IgG) levels (P < 0.05). Furthermore, MRY supplementation upregulated the mRNA expression of tight junction proteins (occludin and zonula occludens-1 [ZO-1]), anti-apoptotic gene (Bcl-2), and autophagy-related proteins (beclin-1 and light chain 3I [LC3I]) in the intestine (P < 0.05). The MRY supplement also led to an increase in the concentration of short-chain fatty acids in the cecum, and the relative abundance of the phylum Bacteroidetes, and genera Bacteroides and Rikenellaceae_RC9_gut_group. The LEfSe analysis revealed an enrichment of Sutterella and Akkermansia muciniphila. In conclusion, the results of this experiment indicated that the additional supplementation of MRY can improve the production performance of laying hens

关键词： Marine red yeast Laying hen Senescence Intestinal homeostasis EGG-PRODUCTION BACILLUS-LICHENIFORMIS ANTIOXIDANT ACTIVITY IN-VITRO MORPHOLOGY MICROBIOTA QUALITY HENS INFLAMMATION FERMENTATION

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