检索结果-南通市图书馆

Nano Research 2024年第9期17卷 8627-8637页

作者： Shan-Fei Wang Yangyang Li Haiyan Wang Jin-Xia Liang Chun zhu Botao Qiao School of Chemistry and Chemical Engineering Guizhou UniversityGuiyang 550025China CAS Key Laboratory of Science and Technology on Applied Catalysis Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023China University of Chinese Academy of Sciences Beijing 100049China

Oxide-supported metal single-atom catalysts(SACs)have exhibited excellent catalytic performance for water-gas shift(WGS)***,we report the single-atom catalyst Pt1/FeOx exhibits excellent medium temperature catalytic performance for WGS reactions by the density functional theory(DFT)calculations and experimental *** calculations indicate that H_(2)O molecules are easily dissociated at oxygen vacancies,and the formed*OH and*O are adsorbed on Pt1 single atoms and the adjacent O atoms,*** studying four possible reaction mechanisms,it is found that the optimal WGS reaction pathway is proceeded along the carboxyl mechanism(pathway III),in which the formation of*COOH intermediates can promote the stability of Pt1/FeOx SAC and the easier occurrence of WGS *** energy barrier of the rate-determining step during the entire reaction cycle is only 1.16 eV,showing the high activity for the medium temperature WGS reaction on Pt1/FeOx SAC,which was verified by experimental ***,the calculated turnover frequencies(TOFs)of CO_(2)and H_(2)formation on Pt1/FeOx at 610 K(337℃)can reach up to 1.14×10^(-3)s^(-1)·site^(-1)through carboxyl *** this work,we further expand the application potential of Pt1/FeOx SAC in WGS reaction.

关键词： water-gas shift(WGS)reaction single-atom catalyst(SAC) density functional theory(DFT) thermocatalysis

Electron beam lithography on nonplanar and irregular surfaces

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Microsystems & Nanoengineering 2024年第2期10卷 1-23页

作者： Chenxu zhu Huseyin Ekinci Aixi Pan Bo Cui Xiaoli zhu Department of Electrical and Computer Engineering and Waterloo Institute for Nanotechnology(WIN) University of WaterlooWaterlooONCanada

E-beam lithography is a powerful tool for generating nanostructures and fabricating nanodevices with fine features approaching a few nanometers in ***,alternative approaches to conventional spin coating and development processes are required to optimize the lithography procedure on irregular *** this review,we summarize the state of the art in nanofabrication on irregular substrates using e-beam *** overcome these challenges,unconventional methods have been *** instance,polymeric and nonpolymeric materials can be sprayed or evaporated to form uniform layers of electron-sensitive materials on irregular ***,chemical bonds can be applied to help form polymer brushes or self-assembled monolayers on these *** addition,thermal oxides can serve as resists,as the etching rate in solution changes after e-beam ***,e-beam lithography tools can be combined with cryostages,evaporation systems,and metal deposition chambers for sample development and lift-off while maintaining low *** nanopyramids can be fabricated on an AFM tip by utilizing ice as a positive ***,Ti/Au caps can be patterned around a carbon ***,3D nanostructures can be formed on irregular surfaces by exposing layers of anisole on organic ice surfaces with a focused *** advances in e-beam lithography on irregular substrates,including uniform film coating,instrumentation improvement,and new pattern transferring method development,substantially extend its capabilities in the fabrication and application of nanoscale structures.

关键词： lithography beam coating

县域经济高质量发展评价指标体系研究——以H省为例

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

行政管理改革 2023年第12期12卷 57-64页

作者：朱红梅王小虎湖南农业大学资源学院

对县域经济高质量发展进行研究,有助于全面推进社会主义现代化建设。以H省为例,从经济、创新、协调、绿色、开放和共享等发展维度选取25个指标,构建了县域经济高质量发展综合评价指标体系,结合改进熵值法研究了2012—2021年县域经济高... 详细信息

对县域经济高质量发展进行研究,有助于全面推进社会主义现代化建设。以H省为例,从经济、创新、协调、绿色、开放和共享等发展维度选取25个指标,构建了县域经济高质量发展综合评价指标体系,结合改进熵值法研究了2012—2021年县域经济高质量发展水平。结果表明:县域经济高质量发展综合指数整体不高但呈上升趋势,其中,经济发展维度增幅较大,其余维度变化较小;县域经济高质量发展水平在县域间和县域内都不均衡,强县存在短板,弱县亦有长处,总体依靠经济和绿色发展推动,创新发展不足。基于以上结论,提出进一步推动县域经济高质量发展水平的政策建议。

关键词：县域经济高质量发展评价指数

基于孤立森林与KDE-LOF的冷水机组故障检测

在线全文

学校读者我要写书评

暂无评论

计算机应用与软件 2023年第1期40卷 84-89页

作者：熊坤丁强祝红梅杭州电子科技大学自动化学院浙江杭州310018

为了提升冷水机组微小故障的检测率,提出一种核密度估计的局部异常因子算法(KDE-LOF)结合孤立森林(iForest)的冷水机组故障检测策略。该策略通过使用孤立森林对实验数据异常值进行剔除,计算正常数据的LOF值作为统计量,并使用KDE确定控... 详细信息

为了提升冷水机组微小故障的检测率,提出一种核密度估计的局部异常因子算法(KDE-LOF)结合孤立森林(iForest)的冷水机组故障检测策略。该策略通过使用孤立森林对实验数据异常值进行剔除,计算正常数据的LOF值作为统计量,并使用KDE确定控制限来完成模型的训练。通过监测数据LOF值是否超过设定的控制限进而判断是否出现故障。采用ASHRAE RP-1043数据集进行验证,并分析了该方法与主元分析和单类支持向量机的方法的优劣,结果表明该方法检测效果要优于其他两种模型,该方法在微小故障下检测率超过80%,性能最佳。

关键词：故障检测冷水机组局部异常因子核密度估计孤立森林

Few-shot incremental radar target recognition framework based on scattering-topology properties

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of Aeronautics 2024年第8期37卷 246-260页

作者： Chenxuan LI Weigang zhu Bakun zhu Yonggang LI Graduate School Space Engineering UniversityBeijing 101400China Department of Electronic and Optical Engineering Space Engineering UniversityBeijing 101400China

The continuous emergence of new targets in open scenarios leads to a substantial decrease in the performance of Inverse Synthetic Aperture Radar(ISAR)recognition ***,data scarcity further exacerbates the challenge of identifying new classes of ISAR *** this paper,a few-shot incremental target recognition framework based on Scattering-Topology Properties(STPIL)is ***,STPIL extracts scattering-topology properties of ISAR targets as recognition ***,the pseudo-incremental training strategy effectively alleviates the algorithm’s forgetting of old knowledge,and improves compatibility with new ***,a feature embedding network,with few parameters,is designed based on the graph neural *** embedding network is highly adaptable to changes in data ***,STPIL fully considers the joint distribution and marginal distribution in scattering features,and uses the Brownian distance metric module to make the scattering-topology features more *** results on both the simulation dataset and the public measured data indicate that STPIL can effectively balance new classes with old classes,and has superior performance to other advanced methods in the incremental recognition of targets.

关键词： Brownian distance metric Graph neural networks Incremental learning Inverse Synthetic Aperture Radar(ISAR) Scattering

UAV-assisted cooperative offloading energy efficiency system for mobile edge computing

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Digital Communications and Networks 2024年第1期10卷 16-24页

作者： Xue-Yong Yu Wen-Jin Niu Ye zhu Hong-Bo zhu Jiangsu Key Laboratory of Wireless Communications Nanjing University of Posts and Telecommunications Nanjing210003China Engineering Research Centerof Health Service System Based on Ubiquitous Wireless Networks Ministry of EducationNanjng Universityof Posts and Telecommunications Nanjing210003China

Reliable communication and intensive computing power cannot be provided effectively by temporary hot spots in disaster areas and complex terrain ground *** this has greatly developed the application and integration of UAV and Mobile Edge Computing(MEC)to the Internet of Things(loT).However,problems such as multi-user and huge data flow in large areas,which contradict the reality that a single UAV is constrained by limited computing power,still *** to allowing UAV collaboration to accomplish complex tasks,cooperative task offloading between multiple UAVs must meet the interdependence of tasks and realize parallel processing,which reduces the computing power consumption and endurance pressure of *** the computing requirements of the user terminal,delay constraint of a computing task,energy constraint,and safe distance of UAV,we constructed a UAV-Assisted cooperative offloading energy efficiency system for mobile edge computing to minimize user terminal energy ***,the resulting optimization problem is originally nonconvex and thus,difficult to solve *** tackle this problem,we developed an energy efficiency optimization algorithm using Block Coordinate Descent(BCD)that decomposes the problem into three convex ***,we jointly optimized the number of local computing tasks,number of computing offloaded tasks,trajectories of UAV,and offloading matching relationship between multi-UAVs and multiuser *** results show that the proposed approach is suitable for different channel conditions and significantly saves the user terminal energy consumption compared with other benchmark schemes.

关键词： Computation offloading Internet of things(IoT) Mobile edge computing(MEC) Block coordinate descent(BCD)

The recombinant jasmonate ZIM-domain(JAZ)protein functions as a novel insecticidal protein against Lepidopteran pests

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Science China(Life Sciences) 2024年第8期67卷 1777-1778页

作者： Yuxian zhu Institute for Advanced Studies Wuhan UniversityWuhan 430072China

Lepidopterans,including butterflies and moths,make up one-tenth of all described agricultural pests on Earth,and many of them,such as fall armyworm,cotton bollworm,corn borer and rice leaf folder,are major agricultura... 详细信息

关键词： pests agricultural cotton

同方期刊数据库

Modulating the degree of O vacancy defects to achieve selective control of electrochemical CO_(2) reduction products

在线全文

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2024年第5期35卷 482-486页

作者： Tianbo Jia Lili Wang Zhouhao zhu Baikang zhu Yingtang Zhou Guoxing zhu Mingshan zhu Hengcong Tao School of Petrochemical Engineering&Environment Zhejiang Ocean UniversityZhoushan 316022China Department of General Practice First Medical CenterChinese PLA General HospitalBeijing 100853China National&Local Joint Engineering Research Center of Harbor Oil&Gas Storage and Transportation Technology Zhoushan 316022China School of Chemistry and Chemical Engineering Jiangsu UniversityZhenjiang 212013China Guangdong Key Laboratory of Environmental Pollution and Health School of EnvironmentJinan UniversityGuangzhou 511443China

Conversion of CO_(2) into high-value products using electrochemical CO_(2) reduction(ECR)technology is an effective way to alleviate global warming and reach carbon *** oxygen vacancies in heterogenous catalysis are generally considered as a powerful method to enhance the performance of ECR by promoting CO_(2) adsorption and ***,the extent of defects in oxygen vacancies-activity relation has rarely been ***,we prepared Cu-Cd bimetallic catalysts with adjustable oxygen defect degree by controlling the amount of cadmium *** transform infrared spectroscopy characterization results reveal that the formation of oxygen vacancies is attributed to the asymmetric stretching of Cu-O by the addition of *** results show that the oxygen defect degree can modulate the selectivity of ECR products.A low degree of oxygen defects(CuO)is generally associated with lower product Faraday efficiency(FE_(C2)/FE_(C1)≈114%),but overabundant oxygen vacancies(CuO_(2.625)-CdO_(0.375))are not entirely favorable to improving ECR activity(FE_(C2)/FE_(C1)≈125%)and single selectivity,while an appropriate degree of oxygen vacancies(CuO_(2.75)-CdO_(0.25))can facilitate the ECR process toward single product selective production(FE_(C2)/FE_(C1)≈296%).The theoretical calculation showed that the O vacancy formed on CuO and the interface between CdO and CuO were conducive to enhancing the formation of ^(*)COOH intermediate and promoting the generation of ethylene *** study provides a new approach and insight into the selective production of single products for future industrial applications of ECR.

关键词： CO_(2) O-vacancies Bimetallic catalysts Copper oxide Cadmium oxide Selective

Structure and ion transport properties of organic ionic compounds revealed by NMR

在线全文

学校读者我要写书评

暂无评论

Magnetic Resonance Letters 2024年第2期4卷 2-12页

作者： Haijin zhu Guangdong Provincial Key Laboratory of Materials and Technologies for Energy Conversion Guangdong Technion-Israel Institute of TechnologyShantou515063China

Organic ionic plastic crystals(OIPCs)are emerging as an important material family for solid-state electrolytes and many other *** have significant advantages over conventional electrolyte materials,such as high ionic conductivity,non-flammability,and *** nuclear magnetic resonance(NMR)spectroscopy techniques including solid-state NMR,pulsed-field gradient(PFG)NMR,and magnetic resonance imaging(MRI)etc.,provide us a versatile toolkit to understand the fundamental level structures,molecular dynamics,and ionic interactions in these *** article reviews the commonly used NMR methods including solid-and solution-state NMR,PFG-NMR,dynamic nuclear polarization(DNP)and the application of these methods in revealing the microscopic level structures and ion-transport mechanisms in OIPC materials.

关键词： NMR Electrolyte Organic ionic plastic crystals Defects Diffusion Microstructure

EGFR-targeted and gemcitabine-incorporated chemogene for combinatorial pancreatic cancer treatment

在线全文

学校读者我要写书评

暂无评论

Nano Research 2024年第2期17卷 848-857页

作者： Miao Xie Qiushuang Zhang Yuanyuan Guo Lijuan zhu Xinyuan zhu Chuan Zhang School of Chemistry and Chemical Engineering Frontiers Science Center for Transformative MoleculesInstitute of Molecular MedicineSixth people’s HospitalSchool of MedicineShanghai Key Laboratory for Molecular Engineering of Chiral DrugsShanghai Jiao Tong UniversityShanghai 200240China Department of Radiology Shanghai Jiao Tong University Affiliated Sixth People’s HospitalSchool of MedicineShanghai Jiao Tong UniversityShanghai 200233China Institute of Molecular Medicine Shanghai Jiao Tong University Affiliated Renji HospitalSchool of MedicineShanghai Jiao Tong UniversityShanghai 200127China

Pancreatic cancer stands out as a recognized intractable tumor due to its high malignancy and mortality rates,which are largely attributed to the insensitivity of current clinical chemotherapies or *** chemo and gene therapy that integrates different therapeutic targets,may increase the chemosensitivity of pancreatic cancer and synergistically enhance the antitumor ***,conventional co-delivery of gene and chemo drugs is intensively dependent on complex nanoparticle delivery systems,thus would be limited by unstable drug packaging,nonspecific biodistribution,and biosafety ***,we rationally designed an epidermal growth factor-receptor(EGFR)-targeted and gemcitabine-incorporated oligonucleotide(termed as chemogene)with anti-Bcl-2 sequence,which achieves simple and precise integration of gemcitabine into a gene regulative agent,as well as the EGFR-targeted delivery for pancreatic cancer *** solid-phase synthesis,gemcitabine,as the first-line chemodrug for pancreatic cancer,is introduced to the antisense oligonucleotide to replace all cytosine nucleosides to obtain the gemcitabine-integrated chemogene(Ge-ASO^(Bcl-2)).Thereafter,Ge-ASO^(Bcl-2)is covalently coupled with EGFR nanobody to construct the final targeted chemogene without any exogenous ***,this nanobody-conjugated chemogene exhibits remarkable tumor targeting capability and antitumor effects both in vitro and in vivo,which initiates a first step toward the application of combinatorial chemo and gene therapy for future pancreatic cancer treatment.

关键词： antisense oligonucleotide chemogene nanobody drug delivery system pancreatic cancer