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Octylamine-Supporting Interlayer Expanded Molybdenum Diselenide as a High-Power Cathode for Rechargeable Mg Batteries

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Energy & Environmental Materials 2023年第6期6卷 191-198页

作者： Dong chen Xin Ren Ting Li zhongxue chen Yu liang Cao Fei Xu Key Laboratory of Hydraulic Machinery Transients Ministry of EducationSchool of Power and Mechanical EngineeringWuhan UniversityWuhan 430072China Key Laboratory of Catalysis and Materials Science of the State Ethnic Affairs Commission&Ministry of Education College of Chemistry and Materials ScienceSouth-Central University for NationalitiesWuhan 430074China Hubei Key Lab of Electrochemical Power Sources College of Chemistry&Molecular ScienceWuhan UniversityWuhan 430072China

Rechargeable Mg batteries(RMBs)are a promising large-scale energy-storage technology with low cost and high safety,but the performance is limited by the inferior kinetics of Mg-intercalation *** the present study,an octylamine-supporting interlayer expanded molybdenum diselenide(e-MoSe_(2))is synthesized and used as cathode for RMBs,in comparison with ordinary crystalline MoSe_(2).The octylamine molecules introduced show a strong interaction with the MoSe_(2)layers and increase the layer spacing significantly from 6.46 to 11.5Å.e-MoSe_(2)shows a high Mg-storage capacity of 238 mAh g^(-1)at 50 mA g^(-1)and a superior rate performance of 39 mAh g^(-1)at 10 A g1,far advantageous over crystalline MoSe_(2).e-MoSe_(2)also shows a considerably high structure stability during repeated magnesiation/demagnesiation,providing an outstanding cycling stability for 1000 *** electrochemical tests demonstrate the high Mg^(2+)diffusion coefficients in e-MoSe_(2).Theoretical computation indicates the interlayer expansion changes the Mg^(2+)diffusion paths from"hollow site→hollow site"to"hollow site→Se atom site→hollow site",largely decreasing the energy barrier and improving the Mg^(2+)diffusion *** present work highlights an efficient strategy for the improvement of Mg-storage performance for RMB cathodes.

关键词： batteries electrodes nanomaterials

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Advances in multi-scale design and fabrication processes for thick electrodes in lithium-ion batteries

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Energy Reviews 2024年第2期3卷 14-30页

作者： Xiuxue Liu Yubin Zeng Wei Yuan Guanhua Zhang Huai Zheng zhongxue chen Key Laboratory of Hydraulic Machinery Transients Ministry of EducationSchool of Power and Mechanical EngineeringWuhan UniversityWuhan430072China School of Mechanical and Automotive Engineering South China University of TechnologyGuangzhou510640GuangdongChina State Key Laboratory of Advanced Design and Manufacturing for Vehicle Body College of Mechanical and Vehicle EngineeringHunan UniversityChangsha410082China Greater Bay Area Institute for Innovation Hunan UniversityGuangzhou511300China

In the contemporary era,lithium-ion batteries have gained considerable attention in various industries such as 3C products,electric vehicles and energy storage systems due to their exceptional *** the rapid progress in the energy storage sector,there is a growing demand for greater energy density in lithium-ion *** the use of thick electrodes is a straightforward and effective approach to enhance the energy density of battery,it is hindered by the sluggish reaction dynamics and insufficient mechanical ***,we comprehensively review recent advances in the field of thick electrodes for lithium-ion batteries to overcome the bottlenecks in the development of thick electrodes and achieve efficient fabrication for high-performance lithium-ion ***,a systematic analysis is performed to identify the factors affecting the performance of the thick *** correlation between electrode materials,structural parameters,and performance is also ***,the viable strategies for constructing thick electrodes with improved properties are summarize,including high throughput,high conductivity and low tortuosity,in both material development and structural *** addition,recent advances in efficient fabrication methods for thick electrode fabrication are reviewed,with a comprehensive assessment of their merits,limitations,and applicable ***,a comprehensive overview of the multiscale design and manufacturing process for thick electrodes in lithium-ion batteries is provided,accompanied by valuable insights into design considerations that are crucial for future advances in this area.

关键词： Lithium-ion battery Thick electrode High energy density Electrode structure Multi-scale design Material development

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Improved Initial Charging Capacity of Na-poor Na0.44MnO2 via Chemical Presodiation Strategy for Low-cost Sodium-ion Batteries

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Chemical Research in Chinese Universities 2021年第2期37卷 274-279页

作者： ZHOU Xi LAI Yangyang WU Xiangjiang chen zhongxue ZHONG Faping Al Xinping YANG Hanxi CAO Yuliang Engineering Research Center of Organosilicon Compounds and Materials of Ministry of Education College of Chemistry and Molecular SciencesWuhan UniversityWuhan430072P.R.China Key Laboratory of Hydraulic Machinery Transients Ministry of EducationSchool of Power and Mechanical EngineeringWuhan UniversityWuhan430072P.R.China National Engineering Research Center of Advanced Energy Storage Materials Hunan410205P.R.China

Sodium-ion batteries(SIBs)are promising for grid-scale energy storage applications due to the natural abundance and low cost of *** various Na insertion cathode materials,Na0.44MnO2 has attracted the most attention because of its cost effectiveness and structural ***,the low initial charge capacity for Na-poor Na0.44MnO2 hinders its practical ***,we developed a facile chemical presodiated method using sodiated biphenly to transform Na-poor Na0.44MnO2 into Na-rich *** presodiation,the initial charge capacity of Na0.44MnO2 is greatly enhanced from 56.5 mA·h/g to 115.7 mA·h/g at 0.1 C(1 C=121 mA/g)and the excellent cycling stability(the capacity retention of 94.1%over 200 cycles at 2 C)is *** presodiation strategy would open a new avenue for promoting the practical applications of Na-poor cathode materials in sodium-ion batteries.

关键词： Sodium-ion battery Na0.44MnO2 Chemical presodiation Sodium biphenyl Initial charge capacity

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Extending the solid solution range of sodium ferric pyrophosphate:Off‐stoichiometric Na_(3)Fe(2.5)(P_(2)O_(7))_(2)as a novel cathode for sodium‐ion batteries

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Carbon Energy 2024年第4期6卷 128-139页

作者： Xiang jun Pu Kunran Yang Zibing Pan Chunhua Song Yangyang Lai Renjie Li Zheng‐Long Xu zhongxue chen Yuliang Cao Hubei Key Laboratory of Electrochemical Power Sources College of Chemistry and Molecular SciencesWuhan UniversityWuhanChina Key Laboratory of Hydraulic Machinery Transients Ministry of EducationSchool of Power and Mechanical EngineeringWuhan UniversityWuhanChina School of Chemistry and Chemical Engineering Jiangsu University of TechnologyChangzhouJiangsuChina Zonergy Corporation ZigongSichuanChina Department of Industrial and Systems Engineering The Hong Kong Polytechnic UniversityHung HomHong Kong SARChina

Iron‐based pyrophosphates are attractive cathodes for sodium‐ion batteries due to their large framework,cost‐effectiveness,and high energy ***,the understanding of the crystal structure is scarce and only a limited candidates have been reported so *** this work,we found for the first time that a continuous solid solution,Na_(4−α)Fe_(2+α)_(2)(P_(2)O_(7))_(2)(0≤α≤1,could be obtained by mutual substitution of cations at center‐symmetric Na3 and Na4 sites while keeping the crystal building blocks of anionic P_(2)O_(7) *** particular,a novel off‐stoichiometric Na_(3)Fe(2.5)(P_(2)O_(7))_(2)is thus proposed,and its structure,energy storage mechanism,and electrochemical performance are extensively investigated to unveil the structure–function *** as‐prepared off‐stoichiometric electrode delivers appealing performance with a reversible discharge capacity of 83 mAh g^(−1),a working voltage of 2.9 V(***^(+)/Na),the retention of 89.2%of the initial capacity after 500 cycles,and enhanced rate capability of 51 mAh g^(−1)at a current density of 1600 mA g^(−1).This research shows that sodium ferric pyrophosphate could form extended solid solution composition and promising phase is concealed in the range of Na_(4−α)Fe_(2+α)_(2)(P_(2)O_(7))_(2),offering more chances for exploration of new cathode materials for the construction of high‐performance SIBs.

关键词： extending solid‐solution range off‐stoichiometric Na_(3)Fe_(2.5)(P_(2)O_(7))_(2) sodium‐ion batteries structure-function relationship

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The Reconstruction of Helmholtz Plane Enables Robust F-Rich Interface for Long-Life and High-Safe Sodium-Ion Batteries

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Wuhan University Journal of Natural Sciences 2024年第4期29卷 297-300页

作者： chen Long chen Ming chen zhongxue Key Laboratory of Hydraulic Machinery Transients Ministry of EducationSchool of Power and Mechanical EngineeringWuhan UniversityWuhan 430072HubeiChina School of Energy and Power Engineering Huazhong University of Science&TechnologyWuhan 430074HubeiChina

Carbonate-based electrolytes still retain their top preference in sodium-ion battery(SIB)as in lithium-ion battery(LIBs)owing to their cost-effectiveness and ***,extensive studies have consistently demonstrated a mismatch between the hard carbon(HC)anode and carbonate-based electrolytes[1,2].Specifically,as for lowconcentration carbonate-based electrolytes(LCEs).

关键词： battery carbonate Helmholtz

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Bioinspired smart dual-layer hydrogels system with synchronous solar and thermal radiation modulation for energy-saving all-season temperature regulation

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Journal of Energy Chemistry 2025年第2期101卷 175-190页

作者： Meng-chen Huang Chao-Hua Xue zhongxue Bai Jun cheng Yong-Gang Wu Chao-Qun Ma Li Wan Long Xie Hui-Di Wang Bing-Ying Liu Xiao-Jing Guo College of Bioresources Chemical and Materials Engineering Shaanxi University of Science & Technology School of Manufacture Science and Engineering Key Laboratory of Testing Technology for Manufacturing Process Ministry of Education Southwest University of Science and Technology School of Life Science and Engineering Southwest University of Science and Technology Northwest Institute for Nonferrous Metal Research Shaanxi Key Laboratory of Biomedical Metal Materials

All-season thermal management with zero energy consumption and emissions is more crucial to global decarbonization over traditional energy-intensive cooling/heating ***,the static single thermal management for cooling or heating fails to self-regulate the temperature in dynamic seasonal temperature ***,inspired by the dual-temperature regulation function of the fur color changes on the backs and abdomens of penguins,a smart thermal management composite hydrogel(PNA@H-PM Gel) system was subtly created though an "on-demand" dual-layer structure design *** PNA@H-PM Gel system features synchronous solar and thermal radiation modulation as well as tunable phase transition temperatures to meet the variable seasonal thermal requirements and energy-saving demands via self-adaptive radiative cooling and solar heating ***,this system demonstrates superb modulations of both the solar reflectance(ΔR=0.74) and thermal emissivity(ΔE=0.52) in response to ambient temperature changes,highlighting efficient temperature regulation with average radiative cooling and solar heating effects of 9.6℃ in summer and 6.1℃ in winter,***,compared to standard building baselines,the PNA@H-PM Gel presents a more substantial energy-saving cooling/heating potentials for energy-efficient buildings across various regions and *** novel solution,inspired by penguins in the real world,will offer a fresh approach for producing intelligent,energy-saving thermal management materials,and serve for temperature regulation under dynamic climate conditions and even throughout all seasons.

关键词： Energy-saving Radiative cooling Self-adaptive thermal management Spectral modulation Thermochromic hydrogel

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无运放高阶温度补偿的基准电路设计

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固体电子学研究与进展 2016年第2期36卷 159-164页

作者：陈忠学唐杰章国豪广东工业大学信息工程学院广州510006

基于带隙基准源的工作原理以及如何提高温度特性的思想,设计了一种无运算放大器且具有新型高阶温度补偿的带隙基准电路。通过对传统带隙基准电路结构的改进,提出一种新的高阶温度补偿方法。该电路在不使用运放的情况下,分别产生较为精... 详细信息

基于带隙基准源的工作原理以及如何提高温度特性的思想,设计了一种无运算放大器且具有新型高阶温度补偿的带隙基准电路。通过对传统带隙基准电路结构的改进,提出一种新的高阶温度补偿方法。该电路在不使用运放的情况下,分别产生较为精准的正、负温度系数电流,通过共源-共栅电流镜将负温度系数电流降阶,并对其一阶、二阶温度系数进行补偿。电路采用0.18μm CMOS工艺实现,芯片尺寸为240μm×220μm,电源抑制比(PSRR)-64dB。测试结果表明:输出基准电压均值为580.6 mV,在-45~120℃范围内温度系数为7.5×10-6/℃,整个电路的功耗为45μW。

关键词：无运放高阶补偿温度系数带隙基准源

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桩基非线性轴向振动的多时间尺度分析

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振动与冲击 2007年第5期26卷 54-59页

作者：胡春林程昌钧陈中学上海大学上海市应用数学与力学研究所力学系上海200072 武汉理工大学土木工程与建筑学院武汉430070

假定桩基及桩周土的材料满足非线性弹性和线性粘弹性本构关系,给出了分析桩基轴向振动的非线性偏微分方程。用多时间尺度法推导出一端固定、另一端自由的桩基非线性轴向自由振动的n-阶主频率和位移的近似表达式,给出了数值算例,考察了... 详细信息

假定桩基及桩周土的材料满足非线性弹性和线性粘弹性本构关系,给出了分析桩基轴向振动的非线性偏微分方程。用多时间尺度法推导出一端固定、另一端自由的桩基非线性轴向自由振动的n-阶主频率和位移的近似表达式,给出了数值算例,考察了参数的影响。研究结果表明:非线性系统的n-阶主频率不仅与线性系统的n-阶固有频率有关,而且也与振幅、阻尼系数和材料的非线性特征量有关;系统的响应中除含有主频率的谐波外,还含有2倍、3倍的主频率的高次谐波和二个或三个主频率的和或差的谐波存在。

关键词：桩的非线性轴向自由振动主频率和响应的近似表达式多时间尺度法参数的影响

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水系锌离子电池嵌入负极材料TiX_(2)(X=S,Se)的储锌机制

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物理化学学报 2023年第8期39卷 143-153页

作者：唐生龙王春蕾蒲想俊顾向奎陈重学武汉大学动力与机械学院水力机械过渡过程教育部重点实验室武汉430072 香港理工大学工业与系统工程系中国香港999077

水系锌离子电池(ZIBs)以其低成本、高安全性和环境友好的优点受到了研究者的广泛关注,成为大规模电化学储能系统的理想选择之一。然而锌金属负极在应用时面临着锌枝晶生长、腐蚀反应和副反应等难以克服的障碍,严重制约了水系锌离子电池... 详细信息

水系锌离子电池(ZIBs)以其低成本、高安全性和环境友好的优点受到了研究者的广泛关注,成为大规模电化学储能系统的理想选择之一。然而锌金属负极在应用时面临着锌枝晶生长、腐蚀反应和副反应等难以克服的障碍,严重制约了水系锌离子电池的发展。探索可替代锌金属的储锌负极是应对上述问题的有效策略,因此研究者围绕过渡金属氧化物、硫化物和导电聚合物开展了深入研究。以TiX_(2)(X=S,Se)为代表的二维过渡金属硫族化合物(TMDs)具有较大的层间距和快速的离子传输通道,可作为锌离子电池的负极,但其储锌反应机制尚未得到完整的揭示。在本文中,我们使用密度泛函理论(DFT)计算方法系统地研究锌离子在TiX_(2)中的嵌入反应。首先我们采用群论去描述嵌锌TiX_(2)的稳定层间构型的特点,定义了一个依赖于超胞并且只涉及平移旋转两种对称操作的群,其子群可以用来描述层间构型的对称性,而且用来描述最稳定构型的子群总是倾向于有最大的阶数。基于该计算得到的一系列对应于不同放电深度的TiX_(2)的稳定结构,我们发现TiS_(2)和TiSe_(2)两种材料在锌嵌入/脱出过程中的开路电压(OCV)均低于0.5V。态密度(DOS)的计算结果表明TiX_(2)具有很好的电子导电性,而分波态密度(PDOS)的结果显示随着锌的嵌入闭壳层的Ti^(4+)还原成开壳层的Ti^(3+),并且伴随着Zn―X键的生成。Bader电荷分析的结果表明随着X的嵌入,X相比Ti得到了更多的负电荷,意味着X也参与了TiX_(2)的氧化还原过程。爬坡弹性带方法(CINEB)计算的结果证实了Zn^(2+)在TiX_(2)中具有较低的扩散能垒(对于TiS_(2)是0.333 e V,对于TiSe_(2)是0.338e V)。本文的研究结果不仅从本质上证明了TiX_(2)适合作为锌离子电池的嵌锌负极材料,而且为其他高性能TMDs电池材料的DFT研究提供了新的见解。

关键词：锌离子电池 TiX_(2)负极第一性原理计算群论

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TGP超前预报系统在岩溶隧道中的实践应用

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地下空间与工程学报 2012年第A01期8卷 1621-1625页

作者：陈中学胡百万刘彦波重庆市交通规划勘察设计院隧道所重庆401121

在岩溶地区修建隧道,经常会遇到溶洞、暗河、突水、突泥等地质灾害,给施工带来巨大损失。介绍了TGP系统的基本工作原理、数据采集和处理过程。与其它预报方法相比,TGP在准确性和预报距离以及可操作性等具有一定的优势,本文基于TGP系统对... 详细信息

在岩溶地区修建隧道,经常会遇到溶洞、暗河、突水、突泥等地质灾害,给施工带来巨大损失。介绍了TGP系统的基本工作原理、数据采集和处理过程。与其它预报方法相比,TGP在准确性和预报距离以及可操作性等具有一定的优势,本文基于TGP系统对城(口)万(源)快速公路通道八台山隧道进口避难通道溶洞进行了预报,通过TGP系统软件得到深度偏移图、同侧综合预报成果图、3D横断面扫描图等,通过分析波速、反射界面等,均证实了有溶洞存在,仪器测出的各项数据相互验证,具有一定的互补性,同时也具有一定的准确性。对照实际开挖情况,验证分析了该系统的实用性和可信性以及在指导施工方面所起的重要作用,这对于促进TGP系统在我国工程界的运用起到一定的推动作用。

关键词： TGP 地质超前预报岩溶八台山隧道

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