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Journal of Energy Chemistry 2024年第1期88卷 28-38,I0002页

作者： Zijing Wan Xiaozhen Chen Ziqi Zhou Xiaoliang zhong Xiaobing Luo Dongwei Xu State Key Laboratory of Coal Combustion School of Energy and Power EngineeringHuazhong University of Science and TechnologyWuhan 430074HubeiChina

Solid-state electrolyte Li_(10)GeP_(2)S_(12)(LGPS)has a high lithium ion conductivity of 12 mS cm^(-1)at room temperature,but its inferior chemical stability against lithium metal anode impedes its practical *** all solutions,Ge atom substitution of the solid-state electrolyte LGPS stands out as the most promising solution to this interface problem.A systematic screening framework for Ge atom substitution including ionic conductivity,thermodynamic stability,electronic and mechanical properties is utilized to solve *** fast screening,an enhanced model Dop Net FC using chemical formulas for the dataset is adopted to predict ionic ***,Li_(10)SrP_(2)S_(12)(LSrPS)is screened out,which has high lithium ion conductivity(12.58 mS cm^(-1)).In addition,an enhanced migration of lithium ion across the LSr PS/Li interface is ***,compared to the LGPS/Li interface,LSrPS/Li interface exhibits a larger Schottky barrier(0.134 eV),smaller electron transfer region(3.103?),and enhanced ability to block additional electrons,all of which contribute to the stabilized *** applied theoretical atom substitution screening framework with the aid of machine learning can be extended to rapid determination of modified specific material schemes.

关键词： Atom substitution Solid-state electrolyte Machine learning Stabilized interface

Sono-assembly of folate-decorated curcumins/alginate core-shell microcomplex and its targeted delivery and pH/reduction dual-triggered release

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Particuology 2024年第1期84卷 168-177页

作者： Qingye Meng Shuangling zhong Jingfei Wang Zhenqian Zhang Yan Gao Xuejun Cui College of Chemistry Jilin University Changchun130012China College of Resources and Environment Jilin Agricultural University Changchun130118China State Key Laboratory of Supramolecular Structure and Materials Jilin UniversityChangchun130012China Weihai Institute for Bionics-Jlin University Weihai264400China

In this study,sodium alginate(SA),a non-toxic natural polysaccharide with good biocompatibility and biodegradability,was developed for targeted delivery of curcumin(CUR)in tumor *** strategy is to sulfhydrylate the folic acid(FA)modified SA,and the CUR dissolved in ethyl acetate(EAC)phase is coated in microcapsules by a quick,efficient and environment-friendly sonochemical *** EAC in the microcapsule core is volatile,which can be recycled and reused to reduce *** prepared mi-crocapsules(FA-RSMCs@CUR)exhibited similar toxicity to free curcumin in anti-tumour evaluation in ***-RSMCs@CUR also exhibited effective antibacterial properties in the antibacterial evaluation in *** is expected to become a low-cost tumor targeting vector in the future,and has the potential to be promoted in clinical application.

关键词： Reductive-responsive Sodium alginate Microcapsule Targeted delivery Sonochemical

Recent progress and prospects of electrolytes for electrocatalytic nitrogen reduction toward ammonia

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Chinese Chemical Letters 2024年第4期35卷 3-16页

作者： Sajid Mahmood Haiyan Wang Fang Chen Yijun zhong Yong Hu Key Laboratory of the Ministry of Education for Advanced Catalysis Materials Department of ChemistryZhejiang Normal UniversityJinhua 321004China The Center for Applied Mathematics and Bioinformatics(CAMB) Gulf University for Science and TechnologyMishref 32093Kuwait Hangzhou Institute of Advanced Studies Zhejiang Normal UniversityHangzhou 311231China

Electrochemical nitrogen reduction reaction(ENRR) provides a promising strategy to achieve sustainable synthesis of ammonia. However, despite great efforts devoted to this research field, the problems such as low energy efficiency and weak selectivity still impede its practical implementation. Most of the research to date has been concentrated on creating sophisticated electrocatalysts, and adequate knowledge of electrolytes is still lacking. Herein, the recent progress in electrolytes for ENRR, including alkaline, neutral,acidic, water-in-salt, organic, ionic liquid, and mixed water-organic electrolytes, is thoroughly reviewed to obtain an in-depth understanding of their effects on electrocatalytic performance. Recently developed representative electrocatalysts in various types of electrolytes are also introduced, and future research priorities of different electrolytes are proposed to develop new and efficient ENRR systems.

关键词： Electrocatalytic nitrogen reduction Ammonia Electrolytes Production rate Faradaic efficiency

Efficacy and safety of Chinese herbal medicine as adjunctive therapy in sepsis patients with bloodstream infection:a propensity-matched analysis

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Journal of Traditional Chinese Medicine 2024年第1期44卷 197-204页

作者： ZHOU Xianshi zhong Minlin XI Xiaotu LI Jun TANG Guanghua the Second Clinical College of Guangzhou University of Chinese Medicine Guangzhou 510120China Emergency Department Guangdong Provincial Hospital of Chinese MedicineGuangzhou 510120China Guangdong Provincial Key Laboratory of Research on Emergency in TCM Guangzhou 510120China Guangzhou Key Laboratory of Traditional Chinese Medicine for Prevention and Treatment of Emerging Infectious Diseases Guangzhou 510120China Administration Department the First Hospital of Guangzhou University of Chinese MedicineGuangzhou 510405China

OBJECTIVE:To investigate the efficacy and safety of Chinese herbal medicine in treating sepsis patients with bloodstream ***:A 6-year retrospective study was carried out at a university hospital in *** sepsis patients with bloodstream infection were *** primary outcome was 28-day mortality after *** score method was used to adjust for possible confounding.28-day mortality was estimated by KaplanMeier analysis and compared using the log-rank *** regression analysis was carried out to identify factors impacting in-hospital mortality ***:Following the application of the propensity score method,a total of 176 patients were *** all-cause 28-day mortality in the control group and Chinese herbal medicine group was 21.6%and 14.8%,***-Meier survival analysis showed that Chinese herbal medicine was associated with a lower hazard ratio(HR)in all-cause 28-day death compared with the control group[HR=0.44,95%CI(0.22,0.90),P0.05).Blood-activating and stasis-eliminating herb administration was associated with reduced inhospital mortality among sepsis patients with bloodstream infection[HR=0.54,95%CI(0.34,0.94),Ping and stasis-eliminating herb,might have certain efficacy and safety in treating sepsis patients with bloodstream *** should prescribe blood-activating and stasis-eliminating herb in treating these two coalescent critical diseases as long as no contraindications ***,further studies are needed to validate our results.

关键词： bacteremia medicine Chinese traditional herbal medicine sepsis propensity-matched analysis

REEs recovery from molten salt electrolytic slag:Challenges and opportunities for environmentally friendly techniques

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Journal of Rare Earths 2024年第6期42卷 1009-1019,I0001页

作者： Ziyan Yang Faxin Xiao Shuchen Sun Heng zhong Ganfeng Tu School of Metallurgy Northeastern UniversityShenyang110819China Key Laboratory for Recycling of Nonferrous Metal Resources(Shenyang) Shenyang110819China

Due to the unique physical and chemical properties,rare earth elements(REEs)play a significant role in the high-tech *** the past few decades,the rare earth reserve in China has been gradually decreasing and more pressure has been exerted on the global rare earth supply for the increasing demand of REEs,which indicates that it is essential to recycle secondary resources to meet the rare earth *** for rare earth molten salt electrolytic slag(REMES),although its high rare earth content has potential huge economic value,its high fluorine content of approximately 10 wt%-20 wt%can pollute the *** methods are used to treat *** metallurgical and pyro-hydrometallurgical methods have gotten a big success for solving most of the hydrometallurgical problems,while some problems,like long route and waste water,need to be *** distillation is a new and promising method with a short process due to its harmlessness and high efficiency,but has shortcomings such as high energy consumption and material *** review presents these above three treatment methods,and the challenges and chances of using the recovery technique of REMES in an environmentally friendly way.

关键词： Rare earths Molten salt electrolytic slag Hydrometallurgy Pyro-hydrometallurgy Vacuum distillation Recovery

Effect of phase transition during roasting of Mountain Pass rare earth concentrate on leaching efficiency of rare earths

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Journal of Rare Earths 2024年第2期42卷 409-414,I0006页

作者： Yanyan Zhao Xu Sun Deliang Meng Xiangsheng Liu Qiang zhong Zongyu Feng National Engineering Research Center for Rare Earth Grirem Advanced Materials Co.Ltd.Beijing0088China Rare Earth Functional Materials(Xiong'an)Innovation Center Co. Ltd.Xiongan071700China General Research Institute for Nonferrous Metals Beijing100088China

To find a greener and more economical approach for treating the Mountain Pass rare earth concentrate(MPREC),a novel "Combination Method",including the processes of oxidizing roasting,HCI leaching and sulfuric acid roasting,is proposed in this *** this paper,the effect of phase transition behavior in hydrochloric acid leaching during oxidative roasting at 450-600℃ was *** roasting,the bastnasite in MPREC is decomposed into CeLa_(2)O_(3)F_(3) and(Ce_(0.33),La_(0.33),Ca_(0.33))O_(1.5).As the CeLa_(2)O_(3)F_(3) phase has the fluorine-fixation effect,the generated CeLa_(2)O_(3)F_(3) phase can not be dissolved by HCI after roasting at 500 and 550℃,but it can be decomposed by HCI after roasting at over 600℃,resulting in the improvement of the leaching rate of total F *** maximum leaching efficiency of rare earth elements(REEs) can reach 70.32 wt% at the roasting temperature of 550℃.After roasting at over 600℃,some F^-ions in the solution combined with RE^(3+) to form REF_(3) precipitate and enter the leaching residue,and the others are in the form of [CeF_(3)]^+ in the leaching solution during leaching,therefore,the leaching efficiency of non-ce rium REEs decreases while that of cerium element *** work provides basic research for optimizing the actual production process of MPREC.

关键词： Mountain pass rare earth mine Roasting Phase change Rare earths

A novel DPSS filter optimization scheme to reduce the intrinsic interference of FBMC-QAM systems

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High Technology Letters 2024年第1期30卷 68-74页

作者：董琪阳 MA Tianming JIN Jie WU zhong School of Electrical and Electronic Engineering Shanghai University of Engineering ScienceShanghai 201620P.R.China

In order to reduce the intrinsic interference of the filter bank multicarrier-quadrature amplitude modulation(FBMC-QAM)system,a novel filter optimization scheme based on discrete prolate spheroidal sequences(DPSS)is ***,a prototype filter function based on DPSS is designed,since the eigenvalue can be used as an indicator of the energy concentration of DPSS,so a threshold is set,and the sequence with the most concentrated energy is selected under the threshold,that is,the sequence with the eigenvalue higher than the threshold,and the prototype filter function is rewritten as a weighted sum function of multiple *** the energy constraints of the filter,the relationship between the eigenvectors and the intrinsic interference function is established,and the function problem is transformed into an optimization problem for the weighted *** the interior point method,the most suitable weight is found to obtain the minimum intrinsic interference *** analysis and simulation results show that compared with the prototype filters such as Type1 and CaseC,the DPSS filter applying the proposed optimization algorithm can effectively suppress the intrinsic interference of the system and obtain a better bit error rate(BER)performance.

关键词： filter bank multicarrier-quadrature amplitude modulation(FBMC-QAM) intrinsic interference discrete prolate spheroidal sequences(DPSS) interior point method

Regulating interfacial stability of SiO_(x) anode with fluoride-abundant solid–electrolyte interphase by fluorine-functionalized additive

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Rare Metals 2024年第2期43卷 671-681页

作者： Subin lee Taeeun Yim Advanced Batteries Laboratory Department of ChemistryIncheon National UniversityIncheon22012Republic of Korea Research Institute of Basic Sciences College of Natural ScienceIncheon National UniversityIncheon22012Republic of Korea

Silicon oxide(SiO_(x))has received remarkable attention as a next-generation battery material;however,the sudden decrease in the cycling retention constitutes a significant challenge in facilitating its ***(2,2,2-trifluoroethyl)phosphite(TTFP),which can control parasitic reactions such as the pulverization of SiO_(x)anode materials and electrolyte decomposition,has been proposed to improve the lifespan of the *** electrochemical reduction of TTFP results in solid-electrolyte interphase(SEI)layers that are mainly composed of LiF,which occur at a higher potential than the working potential of the SiO_(x)anode and carbonate-based *** electrolyte with TTFP exhibited a substantial improvement in cycling retention after 100 cycles,whereas the standard electrolyte showed acutely decreased *** thickness of the SiO_(x)anode with TTFP also changed only slightly without any considerable delamination spots,whereas the SiO_(x)anode without TTFP was prominently deformed by an enormous volume expansion with several internal *** cycled SiO_(x)anode with TTFP exhibited less increase in resistance after cycling than that in the absence of TTFP,in addition to fewer decomposition adducts in corresponding X-ray photoelectron spectroscopy(XPS)analyses between the cycled SiO_(x)*** results demonstrate that TTFP formed SEI layers at the SiO_(x)interface,which substantially reduced the pulverization of the SiO_(x)anode materials;in addition,electrolyte decomposition at the interface decreased,which led to improved cycling retention.

关键词： Lithium-ion batteries(LIBs) Silicon oxide anode Electrolyte Additive Solid-electrolyte interphases(SEI) Tris(2,2,2-trifluoroethyl)phosphite

Block Incremental Dense Tucker Decomposition with Application to Spatial and Temporal Analysis of Air Quality Data

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Computer Modeling in Engineering & Sciences 2024年第4期139卷 319-336页

作者： SangSeok lee HaeWon Moon lee Sael Department of Artificial Intelligence Ajou UniversitySuwon-si16499Korea Department of Software and Computer Engineering Ajou UniversitySuwon-si16499Korea

How can we efficiently store and mine dynamically generated dense tensors for modeling the behavior of multidimensional dynamic data?Much of the multidimensional dynamic data in the real world is generated in the form of time-growing *** example,air quality tensor data consists of multiple sensory values gathered from wide locations for a long *** data,accumulated over time,is redundant and consumes a lot ofmemory in its raw *** need a way to efficiently store dynamically generated tensor data that increase over time and to model their behavior on demand between arbitrary time *** this end,we propose a Block IncrementalDense Tucker Decomposition(BID-Tucker)method for efficient storage and on-demand modeling ofmultidimensional spatiotemporal *** that tensors come in unit blocks where only the time domain changes,our proposed BID-Tucker first slices the blocks into matrices and decomposes them via singular value decomposition(SVD).The SVDs of the time×space sliced matrices are stored instead of the raw tensor blocks to save *** modeling from data is required at particular time blocks,the SVDs of corresponding time blocks are retrieved and incremented to be used for Tucker *** factor matrices and core tensor of the decomposed results can then be used for further data *** compared our proposed BID-Tucker with D-Tucker,which our method extends,and vanilla Tucker *** show that our BID-Tucker is faster than both D-Tucker and vanilla Tucker decomposition and uses less memory for storage with a comparable reconstruction *** applied our proposed BID-Tucker to model the spatial and temporal trends of air quality data collected in South Korea from 2018 to *** were able to model the spatial and temporal air quality *** were also able to verify unusual events,such as chronic ozone alerts and large fire events.

关键词： Dynamic decomposition tucker tensor tensor factorization spatiotemporal data tensor analysis air quality

Lateral earth pressure of granular backfills on retaining walls with expanded polystyrene geofoam inclusions under limited surcharge loading

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第4期16卷 1388-1397页

作者： Kewei Fan Guangqing Yang Weilie Zou zhong Han Yang Shen Key Laboratory of Ministry of Education for Geomechanics and Embankment Engineering Hohai UniversityNanjing210098China School of Civil Engineering Wuhan UniversityWuhan430072China State Key Laboratory of Mechanical Behavior and System Safety of Traffic Engineering Structures Shijiazhuang Tiedao UniversityShijiazhuang050043China

Existing studies have focused on the behavior of the retaining wall equipped with expanded polystyrene(EPS)geofoam inclusions under semi-infinite surcharge loading rather than limited surcharge *** this paper,the failure mode and the earth pressure acting on the rigid retaining wall with EPS geofoam inclusions and granular backfills(henceforth referred to as EPS-wall),under limited surcharge loading are investigated through two-and three-dimensional model *** testing results show that different from the sliding of almost all the backfill in the EPS-wall under semi-infinite surcharge loading,only an approximately triangular backfill slides in the wall under limited surcharge *** distribution of the lateral earth pressure on the EPS-wall under limited surcharge loading is non-linear,and the distribution changes from the increase of the wall depth to the decrease with the increase of the limited surcharge *** approach based on the force equilibrium of a differential element is developed to predict the lateral earth pressure behind the EPS-wall subjected to limited surcharge loading,and its performance was fully validated by the three-dimensional model tests.

关键词： Retaining wall Expanded polystyrene(EPS)geofoam Limited surcharge loading Lateral earth pressure Model test Prediction