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Effect of polyethylene glycol on the crystallization,rheology and foamability of poly(lactic acid)containing in situ generated polyamide 6 nanofibrils

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Frontiers of Chemical Science and Engineering 2023年第12期17卷 2074-2087页

作者： Yuhui Qiao Qian Li Amirjalal Jalali Dongsheng Yu Xichan He Xiaofeng Wang Jing Jiang zhiyu min Department of Materials Science and Engineering Luoyang Institute of Science and TechnologyLuoyang 471023China Henan Province International Joint Laboratory of Materials for Solar Energy Conversion and Lithium Sodium Based Battery Luoyang Institute of Science and TechnologyLuoyang 471023China National Center for International Research of Micro-Nano Molding Technology Zhengzhou 450001China Microcellular Plastics Manufacturing Laboratory Department of Mechanical and Industrial EngineeringUniversity of TorontoToronto M5S 3G8Canada School of Mechanical and Power Engineering Zhengzhou UniversityZhengzhou 450001China

In this study,the rheological properties,crystallization and foaming behavior of poly(lactic acid)with polyamide 6 nanofibrils were examined with polyethylene glycol as a *** 6 particles were deformed into nanofibrils during *** the 10%polyamide 6 case,polyethylene glycol addition reduced the polyamide 6 fibril diameter from 365.53 to 254.63 nm,owing to the smaller polyamide 6 particle size and enhanced interface *** experiments revealed that the viscosity and storage modulus of the composites were increased,which was associated with the three-dimensional entangled network of polyamide 6 *** presence of higher aspect ratio polyamide 6 nanofibrils substantially enhanced the melt strength of the *** isothermal crystallization kinetics results suggested that the polyamide 6 nanofibrils and polyethylene glycol had a synergistic effect on accelerating poly(lactic acid)*** the polyethylene glycol,the crystallization half-time reduced from 103.6 to 62.2 *** foaming results indicated that owing to higher cell nucleation efficiency,the existence of polyamide 6 nanofibrils led to a higher cell density and lower expansion ***,the poly(lactic acid)/polyamide 6 foams exhibited a higher cell density and expansion ratio than that of the foams without polyethylene glycol.

关键词： poly(lactic acid) foaming microfibrillation rheological property crystallization

In situ formed cross-linked polymer networks as dual-functional layers for high-stable lithium metal batteries

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Journal of Energy Chemistry 2023年第4期79卷 253-262页

作者： Lei Shi Wanhui Wang Chunjuan Wang Yang Zhou Yuezhan Feng Tiekun Jia Fang Wang zhiyu min Ji Hu Zhigang Xue School of Materials Science and Engineering School of Environmental Engineering and ChemistryLuoyang Institute of Science and TechnologyLuoyang 471023HenanChina Key Laboratory for Material Chemistry of Energy Conversion and Storage Ministry of EducationSchool of Chemistry and Chemical EngineeringHuazhong University of Science and TechnologyWuhan 430074HubeiChina Key Laboratory of Advanced Materials Processing&Mold(ministry of Education) National Engineering Research Center for Advanced Polymer Processing TechnologyZhengzhou UniversityZhengzhou 450002HenanChina Henan Intelligent Manufacturing Engineering Technology Research Center for Building Profile Luoyang Institute of Science and TechnologyLuoyang 471023HenanChina Henan Province International Joint Laboratory of Materials for Solar Energy Conversion and Lithium Sodium based Battery Luoyang Institute of Science and TechnologyLuoyang 471023HenanChina

Lithium-metal anodes(LMAs)have been recognized as the ultimate anodes for next-generation batteries with high energy density,but stringent assembly-environment conditions derived from the poor moisture stability dramatically hinder the transformation of LMAs from laboratory to ***,an in situ formed cross-linked polymer layer on LMAs is designed and constructed by a facile thiol-acrylate click chemistry reaction between poly(ethylene glycol)diacrylate(PEGDA)and the crosslinker containing multi thiol groups under UV *** to the hydrophobic nature of the layer,the treated LMAs demonstrate remarkable humid stability for more than 3 h in ambient air(70%relative humidity).The coating humid-resistant protective layer also possesses a dual-functional characterization as solid polymer electrolytes by introducing lithium bis(trifluoromethanesulfonyl)imide in the system in *** intimate contact between the polymer layer and LMAs reduces interfacial resistance in the assembled Li/LiFePO_(4)or Li/LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)full cell effectively,and endows the cell with an outstanding cycle performance.

关键词： Lithium-metal anode Humid-resistant protective film Solid-state polymer electrolytes Cross-linked polymers

Enhanced electromagnetic wave absorption via optical fiber-like PMMA@Ti_(3)C_(2)T_(x)@SiO_(2) composites with improved impedance matching

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Nano Research 2024年第3期17卷 1676-1686页

作者： Huanhuan Niu Xuewen Jiang Wei Li zhiyu min Budi Riza Putra Wulan Tri Wahyuni Hailong Wang Rui Zhang Bingbing Fan School of Material Science and Engineering Zhengzhou UniversityZhengzhou 450001China School of Materials Science and Engineering Tongji UniversityShanghai 201804China Department of Materials and Earth Sciences Technical University of DarmstadtDarmstadt 64287Germany School of Material Science and Engineering Luoyang Institute of Science and TechnologyLuoyang 471023China Research Center for Metallurgy National Research and Innovation Agency(BRIN)PUSPIPTEK Gd.470South TangerangBanten 15315Indonesia Analytical Chemistry Division Department of ChemistryFaculty of Mathematics and Natural SciencesIPB UniversityWest Java 16680Indonesia

Ti_(3)C_(2)T_(x) nanosheets have attracted significant attention for their potential in electromagnetic wave absorption(EWA).However,their inherent self-stacking and exorbitant electrical conductivity inevitably lead to serious impedance mismatch,restricting their EWA ***,the optimization of impedance matching becomes *** this work,we developed polymethyl methacrylate(PMMA)@Ti_(3)C_(2)T_(x)@SiO_(2) composites with a sandwich-like core–shell structure by coating SiO_(2) on PMMA@Ti_(3)C_(2)T_(x).The results demonstrate that the superiority of the SiO_(2) layer in combination with PMMA@Ti_(3)C_(2)T_(x),outperforming other relative graded distribution structures and meeting the requirements of EWA *** resulting PMMA@Ti_(3)C_(2)T_(x)@SiO_(2) composites achieved a minimum reflection loss of-58.08 dB with a thickness of 1.9 mm,and an effective absorption bandwidth of 2.88 *** analysis revealed that the structural design of SiO_(2) layer not only optimized impedance matching,but also synergistically enhanced multiple loss mechanisms such as interfacial polarization and dipolar ***,this work provides valuable insights for the future preparation of high-performance electromagnetic wave absorbing Ti_(3)C_(2)T_(x)-based composites.

关键词： polymethyl methacrylate(PMMA)@Ti_(3)C_(2)T_(x)@SiO_(2)composites impedance match SiO_(2)layer optical fiber-like structure interfacial polarization and dipolar polarization

Sr(Cr_(0.2)Mn_(0.2)Fe_(0.2)C_(0.2)Ni_(0.2))O_(3):A novel high-entropy perovskite oxide with enhanced electromagnetic wave absorption properties

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Journal of Materiomics 2024年第6期10卷 1176-1185页

作者： Mengru Li Qing Zhi Jinlu Li Chengwen Wu Xuewen Jiang zhiyu min Rui Zhang Hailong Wang Haibin Wang Bingbing Fan School of Materials Science and Engineering Zhengzhou University Zhengzhou450001China School of Material Science and Engineering Luoyang Instiute pf Science and TechnologyLuoyang471023HenanChina Institute of Advanced Ceramics Henan Acaderry of SciencesZhengzhou450046China

Perovskite materials(ABO_(3))possess a wealth of elements selectable and exhibit a diverse range of octahedral *** emergence of high-entropy perovskite ceramics provides a fresh perspective for advancing the field of wave-absorbing *** this study,we concentrate on the wet chemical synthesis of a high-entropy perovskite oxide,Sr(Cr_(0.2)Mn_(0.2)Fe_(0.2)C_(0.2)Ni_(0.2))O_(3),and investigate its crystal structure,microstructure,chemical composition,magnetic properties,and microwave absorbing *** results indicate that when sintered at a temperature of 1,350℃,the sample achieves a minimum reflection loss of-54.0 dB at a frequency of 9.68 GHz,accompanied by a maximum effective absorption bandwidth(EAB)of 7.44 GHz at the thickness of 1.8 *** high-entropy design of the B-site induces distortions of oxygen vacancy and octahedral structure of the perovskite *** leads to the fine tuning of its dielectric and magnetic properties,thereby endowing perovskite with excellent electromagnetic wave absorption ***,perovskite emerges as a promising new electromagnetic wave absorption material with significant potential.

关键词： High-entropy ceramics Perovskite Microwave absorption Magnetism

Tailoring of thermal expansion and phase transition temperature of ZrW_(2)O_8 with phosphorus and enhancement of negative thermal expansion of ZrW_(1.5)P_(0.5)O_(7.75)

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Chinese Physics B 2023年第4期32卷 696-700页

作者：张晨骏何小可闵志宇李保忠 School of Agricultural Engineering Jiangsu UniversityZhenjiang 212013China Luoyang Institute of Science and Technology Luoyang 471023China North China University of Water Resources and Electric Power Zhengzhou 450045China Luoyang Smart Agricultural Equipment Institute Co. Ltd.Luoyang 471023China

ZrW_(2)O_(8)is a typical isotropic negative thermal expansion material with cubic ***,quenching preparation,pressure phase transition and metastable structure influence its practical *** P to part-substitute W for ZrW_(2-x)P_(x)O_(8-0.5x)has decreased the sintering temperature and avoided the quenching *** x=0.1,ZrW_(1.9)P_(0.1)O_(7.95)with a stable cubic structure can be obtained at 1150℃.The thermal expansion coefficient is tailored with the P content,and phase transition temperature is *** x=0.5,thermal expansion coefficient attains-13.6×10^(-6)℃^(-1),ZrW_(1.5)P_(0.5)O_(7.75)exhibits enhance negative thermal expansion *** difference of electronegativity leads to the decrease of phase transition temperature with the increase of P *** different radii of ions lead to new structure of materials when P substitutes *** results suggest that the P atom plays the stabilization role in the crystal structure of ZrW_(2-x)P_(x)O_(8-0.5x).

关键词： tailored thermal expansion phase transition negative thermal expansion stabilization role XRD

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双联圆柱直齿轮注塑模具设计

工程塑料应用 2010年第8期38卷 64-66页

作者：闵志宇方世杰沈俊芳洛阳理工学院机电工程系洛阳471023

针对聚甲醛(POM)塑料双联圆柱直齿轮的精度和外观质量要求,通过对塑料件结构和成型工艺特性分析,设计出了一套注塑模具。型腔、型芯采用组合式结构,设计了型芯安装定位杆以保证嵌件在型腔中的位置。模具采用点浇口浇注形式,推出机构采... 详细信息

针对聚甲醛(POM)塑料双联圆柱直齿轮的精度和外观质量要求,通过对塑料件结构和成型工艺特性分析,设计出了一套注塑模具。型腔、型芯采用组合式结构,设计了型芯安装定位杆以保证嵌件在型腔中的位置。模具采用点浇口浇注形式,推出机构采用推管推出。并对注射成型工艺参数进行优化,该模具可以实现自动化生产,提高产量。

关键词：双联圆柱齿轮注塑模具点浇口推管

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带嵌件结构的塑料钥匙注塑模设计

工程塑料应用 2014年第5期42卷 68-70页

作者：闵志宇康莉沈俊芳洛阳理工学院河南洛阳471023

分析了带金属嵌件结构塑料钥匙的工艺特点,介绍了带金属嵌件塑料钥匙注塑模具结构设计的要点和模具工作过程。模具型腔采用组合式结构,小型芯和推管成型塑料件上带凸台的工艺孔,利用弹簧和卡槽固定嵌件保证其在型腔中的位置,推出机构采... 详细信息

分析了带金属嵌件结构塑料钥匙的工艺特点,介绍了带金属嵌件塑料钥匙注塑模具结构设计的要点和模具工作过程。模具型腔采用组合式结构,小型芯和推管成型塑料件上带凸台的工艺孔,利用弹簧和卡槽固定嵌件保证其在型腔中的位置,推出机构采用推杆和推管组合结构。模具结构合理,运行可靠,可以实现自动化生产。

关键词：塑料钥匙嵌件 ABS 注塑模具

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基于齿轮齿条侧抽芯机构的注塑模设计

塑料科技 2017年第3期45卷 72-75页

作者：闵志宇李豪程玉飞洛阳理工学院材料科学与工程学院河南洛阳471023

分析了圆孔衬套支架塑件的结构特点和工艺性能,介绍了一种带齿轮齿条侧抽芯机构的注塑模具设计的要点和模具工作过程。设计了齿轮齿条侧抽芯螺纹机构成型塑件侧方的螺纹孔。为了优化模具结构,通过螺纹型芯与小圆螺母配合共同调节螺纹型... 详细信息

分析了圆孔衬套支架塑件的结构特点和工艺性能,介绍了一种带齿轮齿条侧抽芯机构的注塑模具设计的要点和模具工作过程。设计了齿轮齿条侧抽芯螺纹机构成型塑件侧方的螺纹孔。为了优化模具结构,通过螺纹型芯与小圆螺母配合共同调节螺纹型芯到主型芯的距离。模具为一模四腔结构,型腔和型芯分别采用整体式和嵌入式结构,模具结构合理,运动可靠,可以实现自动化生产。

关键词：工艺分析注塑模具设计侧抽芯齿轮齿条

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基于分子模型的支化聚合物流变性能模拟

高分子材料科学与工程 2017年第1期33卷 109-112,118页

作者：闵志宇沈俊芳申长雨曹伟刘春太洛阳理工学院材料科学与工程学院河南洛阳471023 郑州大学橡塑模具国家工程中心河南郑州450002

通过布朗(Brown)动力学方法模拟了有限伸展非线性弹性(FENE)珠-簧链支化聚合物分子模型在稳态和瞬态剪切流场中的运动,得到分子构象信息,同时对支化聚合物分子力场进行计算分析,模拟支化聚合物流变性质,研究支链长度、弹簧模型参数和剪... 详细信息

通过布朗(Brown)动力学方法模拟了有限伸展非线性弹性(FENE)珠-簧链支化聚合物分子模型在稳态和瞬态剪切流场中的运动,得到分子构象信息,同时对支化聚合物分子力场进行计算分析,模拟支化聚合物流变性质,研究支链长度、弹簧模型参数和剪切速率等对该模型定常与非定常流变性质的影响。结果表明,珠簧链模型能够较好地描述支化聚合物分子结构,随支链长度的增加,支化聚合物黏度升高,随剪切速率的升高,伴随有假塑性剪切变稀现象发生,并且弹簧拉伸常数不同,支化聚合物黏度稳态值也不同。

关键词： Brown动力学 FENE珠簧链流变性能分子模型支化聚合物