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Stability of water yield in watersheds

Science China Earth Sciences 2024年第2期67卷 483-496页

作者： yu YAN zhiyong LIU Xiaohong CHEN Liyan HUANG Center for Water Resources and Environment School of Civil EngineeringSun Yat-Sen UniversityGuangzhou510275China Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai) Zhuhai519082China

The hydrological system of a watershed is intricately influenced by both underlying characteristics and climate conditions.Understanding the variability in water yield is essential for effective water resources management and water security in the context of changing environments.In this study,we adopted the Budyko framework and leveraged simulations from the CMIP6 model to investigate the compensation effects of climate and underlying characteristics on watershed water yield.Based on Taylor expansion and Budyko framework,we estimated the sensitivity of watershed water yield to climate and underlying characteristics(the first-and second-order partial derivatives).By combining external watershed characteristics(e.g.,water yield ratios and underlying characteristics)with internal sensitivity coefficients,this study further used vine copula and principal component analysis to quantify the stability of watershed water yield.Our findings show:(1)Water-yield changes related to underlying characteristics could be offset by climate-related water-yield changes across all climate zones,maintaining the water yield ratio steady(i.e.,the compensation effects).(2)However,global watersheds will turn more sensitive to underlying characteristics and less sensitive to climate variation in the future.Both climate-and underlying-related sensitivities increase in watersheds with arid climates.(3)The stability of watershed water yield will gradually diminish in the future.From 1901–1950to 2051–2100,the global stability of 280 watersheds drops from 0.054 to 0.021(i.e.,stability index identified by the joint probability).Particularly,the largest change in stability of water yield reaches-0.347±0.18 in arid regions.In semi-arid,semihumid,and humid regions,the changes are-0.039±0.010,-0.028±0.005,and-0.005±0.002,respectively.The findings provide a reference for the future sustainable water resources development under climate change,highlighting the vulnerability of the water resources in arid and semi-arid watersheds.

关键词： Hydrological system stability Compensation effects on water yield Sensitivities Budyko-Fu decomposition framework Global watersheds

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Impact of Polymer Matrix on Polymer Mechanochromism from Excited State Intramolecular Proton Transfer

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Chinese Journal of Chemistry 2024年第6期42卷 611-616页

作者： yu Wu Xin Cheng Huan Hu Shui Hu Zhimin Ma zhiyong Ma Beijing Advanced Innovation Center for Soft Matter Science and Engineering Beijing State Key Laboratory of Organic-Inorganic CompositesCollege of Chemical EngineeringBeijing University of Chemical TechnologyBeijing100029 China Center of Advanced Elastomer Materials College of Materials Science and EngineeringBeijing University of Chemical TechnologyBeijing100029 China College of Engineering Peking UniversityBeijing100871 China

Mechanochromic polymers based on non-covalent changes have attracted much attention recently.Herein,we report the impact of inter/intramolecular hydrogen bonds on polymer mechanochromism from the excited state intramolecular proton transfer (ESIPT) process.PhMz-NH2-OH and PhMz=2A are designed and obtained by simple and high-yield synthesis,and are connected into polyurethane and poly(methyl acrylate-co-2-ethylhexyl acrylate),respectively.In the initial state,the PhMz-NH2-OH@PU sample shows blue fluorescence from the excited enol form (E*) excitons,owing to intermolecular hydrogen bonds that interrupt the ESIPT reactions but the PhMz=2A@PMA-2-EA sample expresses cyan fluorescence belonging to the excited keto form (K*) emission,implying that the intramolecular hydrogen bonds matter.Furthermore,under stretching,external force can tune the emission of the PhMz=2A@PMA-2-EA sample from K* to E* state.Though external force can putatively still promote a bond rotation,ESIPT reactions remain equivalently interrupted in both the relaxed and stressed states in a hydrogen-bond donating environment.DFT calculation confirms the force-induced increase in dihedral angle for the transition of ESIPT-on/off.Thus,PhMz-NH2-OH@PU and PhMz=2A@PMA-2-EA showed disparate initial ESIPT states and further different responses/sensitivity to force.This study reports a novel and efficient strategy for enriching mechanochromic investigation and extending the applications of ESIPT reactions.

关键词： Polymer mechanochromism Excited state intramolecular proton transfer Hydrogen bonding Supramolecular chemistry Elastomers

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Influence of Irregular Coastlines on a Tornadic Mesovortex in the Pearl River Delta during the Monsoon Season. Part Ⅰ:Pre-storm Environment and Storm Evolution

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Advances in Atmospheric Sciences 2024年第6期41卷 1115-1131页

作者： Lanqiang BAI Dan YAO zhiyong MENG yu ZHANG Xianxiang HUANG Zhaoming LI Xiaoding yu Foshan Tornado Research Center and China Meteorological Administration Tornado Key LaboratoryGuangdong Meteorological Serviceand Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai)Guangdong 528000China Meteorological Observation Centre CMABeijing 100081China Department of Atmospheric and Oceanic Sciences and China Meteorological Administration Tornado Key LaboratorySchool of PhysicsPeking UniversityBeijing 100871China Guangzhou Meteorological Observatory CMAGuangdong 511430China Foshan Tornado Research Center and China Meteorological Administration Tornado Key LaboratoryCMAGuangdong 528000China China Meteorological Administration Training Center CMABeijing 528000China

The Pearl River Delta(PRD),a tornado hotspot,forms a distinct trumpet-shaped coastline that concaves toward the South China Sea.During the summer monsoon season,low-level southwesterlies over the PRD’s sea surface tend to be turned toward the west coast,constituting a convergent wind field along with the landward-side southwesterlies,which influences regional convective weather.This two-part study explores the roles of this unique land–sea contrast of the trumpet-shaped coastline in the formation of a tornadic mesovortex within monsoonal flows in this region.Part I primarily presents observational analyses of pre-storm environments and storm evolutions.The rotating storm developed in a lowshear environment(not ideal for a supercell)under the interactions of three air masses under the influence of the land–sea contrast,monsoon,and storm cold outflows.This intersection zone(or“triple point”)is typically characterized by local enhancements of ambient vertical vorticity and convergence.Based on a rapid-scan X-band phased-array radar,finger-like echoes were recognized shortly after the gust front intruded on the triple point.Developed over the triple point,they rapidly wrapped up with a well-defined low-level mesovortex.It is thus presumed that the triple point may have played roles in the mesovortex genesis,which will be demonstrated in Part II with multiple sensitivity numerical simulations.The findings also suggest that when storms pass over the boundary intersection zone in the PRD,the expected possibility of a rotating storm occurring is relatively high,even in a low-shear environment.Improved knowledge of such environments provides additional guidance to assess the regional tornado risk.

关键词： tornado mesovortex surface boundary land–sea contrast monsoon

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A novel electro-Fenton hybrid system for enhancing the interception of volatile organic compounds in membrane distillation desalination

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Journal of Environmental Sciences 2024年第4期138卷 189-199页

作者： Hongxin Liu Kuiling Li Kunpeng Wang zhiyong Wang Zimou Liu Sichao Zhu Dan Qu yu Zhang Jun Wang State Key Laboratory of Environmental Aquatic Chemistry Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China University of Chinese Academy of Sciences Beijing 100049China State Key Laboratory of Environment Simulation and Pollution Control School of Environment Tsinghua UniversityBeijing 100084China School of Chemical and Environmental Engineering Beijing CampusChina University of Mining and TechnologyBeijing 100083China Beijing Key Lab for Source Control Technology of Water Pollution College of Environmental Science and EngineeringBeijing Forestry UniversityBeijing 100083China

Membrane distillation(MD)is a promising alternative desalination technology,but the hydrophobic membrane cannot intercept volatile organic compounds(VOCs),resulting in aggravation in the quality of permeate.In term of this,electro-Fenton(EF)was coupled with sweeping gas membrane distillation(SGMD)in a more efficient way to construct an advanced oxidation barrier at the gas-liquid interface,so that the VOCs could be trapped in this layer to guarantee the water quality of the distillate.During the so-called EF-MD process,an interfacial interception barrier containing hydroxyl radical formed on the hydrophobic membrane surface.It contributed to the high phenol rejection of 90.2% with the permeate phenol concentration lower than 1.50 mg/L.Effective interceptions can be achieved in a wide temperature range,even though the permeate flux of phenol was also intensified.The EF-MD system was robust to high salinity and could electrochemically regenerate ferrous ions,which endowed the long-term stability of the system.This novel EF-MD configuration proposed a valuable strategy to intercept VOCs in MD and will broaden the application of MD in hypersaline wastewater treatment.

关键词： Membrane distillation VOC interception Interfacial oxidation Electro-Fenton Hypersaline wastewater

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Highly selective extraction of aromatics from aliphatics by using metal chloride-based ionic liquids

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Chinese Journal of Chemical Engineering 2024年第1期65卷 222-229页

作者： Hui yu Xiaojia Wu Chuanqi Geng Xinyu Li Chencan Du zhiyong Zhou Zhongqi Ren State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical TechnologyBeijing 100029China

The separation of aromatics from aliphatics is essential for achieving maximum exploitation of oil resources in the petrochemical industry.In this study,a series of metal chloride-based ionic liquids were prepared and their performances in the separation of 1,2,3,4-tetrahydronaphthalene(tetralin)/dodecane and tetralin/decalin systems were studied.Among these ionic liquids,1-ethyl-3-methylimidazolium tetrachloroferrate([EMIM][FeCl_(4)])with the highest selectivity was used as the extractant.Density functional theory calculations showed that[EMIM][FeCl_(4)]interacted more strongly with tetralin than with dodecane and decalin.Energy decomposition analysis of[EMIM][FeCl_(4)]-tetralin indicated that electrostatics and dispersion played essential roles,and induction cannot be neglected.The van der Waals forces was a main effect in[EMIM][FeCl_(4)]-tetralin by independent gradient model analysis.The tetralin distribution coefficient and selectivity were 0.8 and 110,respectively,with 10%(mol)tetralin in the initial tetralin/dodecane system,and 0.67 and 19.5,respectively,with 10%(mol)tetralin in the initial tetralin/decalin system.The selectivity increased with decreasing alkyl chain length of the extractant.The influence of the extraction temperature,extractant dosage,and initial concentrations of the system components on the separation performance were studied.Recycling experiments showed that the regenerated[EMIM][FeCl_(4)]could be used repeatedly.

关键词： Ionic liquid Aromatic hydrocarbon Aliphatic hydrocarbon Extraction

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Experimental study on ice monitoring method for 10 kV transmission line with tangent tower in alpine landform

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High Voltage 2024年第1期9卷 182-194页

作者： Lin Yang Zhiqiang Chen Yanpeng Hao Xinhao Lin Lei yu yue Li zhiyong yuan Licheng Li School of Electric Power South China University of TechnologyGuangzhouChina Electrical Power Research Institute China Southern Power GridGuangzhouChina Electric Power Research Institute of Guizhou Power Grid Co.Ltd. GuizhouChina

Ice monitoring methods were applied for 110 kV and above transmission lines with tangent towers.However,the change in the vertical span is not considered,and a significant difference lies in the tower-conductor structure of 10 kV transmission lines.For this reason,a proposal is made about the ice monitoring method for the 10 kV transmission line with tangent tower in alpine landform,which includes the ice monitoring system based on pressure measurement and corresponding equivalent ice thickness calculating methods.Different methods calculate the vertical span under different height difference coefficients.A finite element simulation model and a simulated ice load experiment system are established based on real conductors and insulators.Experiments and simulations under four simulated terrains are conducted within 2.5–20 mm ice thickness range.The comparison is made between this method and the method without considering the change in vertical span.The results show that the two methods are consistent and the relative errors are lower than�4%in simulation and�10%in experiment when the height difference coefficient is 0.When it is not 0,the relative errors of this method fall between t0.38%and t6.78%in simulation and−6.40%to t6.60%in experiment,while the relative errors of the method without considering the change in vertical span ranges between−11.13%and−20.23%in simulation and−11.65%to−23.20%in experiment.

关键词： methods tangent method

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Drug delivery systems for colorectal cancer chemotherapy

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Chinese Chemical Letters 2024年第2期35卷 163-175页

作者： Wen Chen Kun Shi Yan yu Peipei Yang Zhongwu Bei Dong Mo Liping yuan Meng Pan yu Chen zhiyong Qian Department of Biotherapy Cancer Center and State Key Laboratory of BiotherapyWest China HospitalSichuan UniversityChengdu 610041China

Colorectal cancer causes the third most common type of malignant tumors with high morbidity and mortality.Chemotherapy is currently one of the most effective and common treatments for colorectal cancer.However,the poor water solubility of some chemotherapeutics,untargeted drug delivery,and the undesirable systemic side effects of conventional treatment remain the major issues for colorectal cancer chemotherapy.Fortunately,drug delivery systems(DDS)based on biomaterials have been widely investigated and found to be capable of resolving those issues with good performance.Therefore,the main goal of this review is to summarize and discuss the progress and potential advantages of different DDS for colorectal cancer chemotherapy.We not only reviewed the nanocarriers used to improve the solubility of chemotherapeutics,including liposomes,micelles,and nanoparticles,but also discussed targeted DDS based on specific ligand-receptor recognition and tumor microenvironmental stimulus responses.Furthermore,locally administered systems based on hydrogels and microspheres,which have been shown to increase drug accumulation at the tumor site while decreasing systemic toxicity,were also emphasized.DDS provides a good option for improving the efficacy of chemotherapy in the treatment of colorectal cancer.

关键词： Colorectal cancer Chemotherapy Drug delivery systems Solubility Targeted Local administration

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Direct amplification of femtosecond optical vortices in a single-crystal fiber

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Photonics Research 2024年第1期12卷 27-32页

作者： CHANGSHENG ZHENG TIANYI DU LEI ZHU ZHANXIN WANG KANGZHEN TIAN YONGGUANG ZHAO zhiyong YANG HAOHAI yu VALENTIN PETROV Jiangsu Key Laboratory of Advanced Laser Materials and Devices School of Physics and Electronic EngineeringJiangsu Normal UniversityXuzhou 221116China State Key Laboratory of Crystal Materials and Institute of Crystal Materials Shandong UniversityJinan 250100China Max Born Institute for Nonlinear Optics and Short Pulse Spectroscopy 12489 BerlinGermany

Spatially twisted light with femtosecond temporal structure is of particular interest in strong-field physics and light–matter interactions.However,present femtosecond vortex sources exhibit limited power handling capabilities,and their amplification remains an ongoing challenge particularly for high-order orbital angular momentum(OAM)states due to several inherent technical difficulties.Here,we exploit a straightforward approach to directly amplify a femtosecond optical vortex(FOV,OAM=-8?)by using a two-stage single-crystal fiber(SCF)amplifier system without pulse stretching and compression in the time domain,delivering 23-W,163-fs pulses at a repetition rate of1 MHz.The spatial and temporal features are well-conserved during the amplification,as well as the high modal purity(>96%).The results indicate that the multi-stage SCF amplifier system is particularly suited for direct amplification of high-order FOVs.The generated high-power femtosecond OAM laser beams are expected to help reveal complex physical phenomena in light–matter interactions and pave the way for practical applications in attoscience,laser plasma acceleration,and high-dimension micromachining.

关键词： fiber amplifier crystal

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Identification of unknown disinfection byproducts in drinking water produced from Taihu Lake source water

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Journal of Environmental Sciences 2022年第3期34卷 1-11页

作者： Jiabao Li Haifeng Zhang Juan Wang zhiyong yu Hongyan Li Min Yang Key Laboratory of Drinking Water Science and Technology Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China State Key Laboratory of Environmental Aquatic Chemistry Research Center for Eco-Environmental SciencesUniversity of Chinese Academy of SciencesBeijing 100049China University of Chinese Academy of Sciences Beijing 100049China

Although disinfection byproducts(DBPs) in drinking water have been suggested as a cancer causing factor, the causative compounds have not yet been clarified. In this study, we used liquid chromatography quadrupole-time-of-flight spectrometry(LC-QTOF MS) to identify the unknown disinfection byproducts(DBPs) in drinking water produced from Taihu Lake source water, which is known as a convergence point for the anthropogenic pollutants discharged from intensive industrial activities in the surrounding regions. In total, 91 formulas of DBPs were discovered through LC-QTOF MS nontarget screen, 81 of which have not yet been reported. Among the 91 molecules, 56 only contain bromine, 15 only contain chlorine and 20 DBPs have both bromine and chlorine atoms. Finally, five DBPs including 2,4,6-tribromophenol, 2,6-dibromo-4-chlorophenol, 2,6-dichloro-4-bromophenol, 4-bromo-2,6-di-tert-butylphenol and 3,6-dibromocarbazole were confirmed using standards. The former three compounds mainly formed in the predisinfection step(maximum concentration, 0.2-2.6 μg/L), while the latter two formed in the disinfection step(maximum concentration, 18.2-33.6 ng/L). In addition, 19 possible precursors of the discovered DBPs were detected, with the aromatic compounds being a major group. 2,6-di-tert-butylphenol as the precursor of 4-bromo-2,6-di-tert-butylphenol was confirmed with standard, with a concentration of 20.3 μg/L in raw water. The results of this study show that brominated DBPs which are possibly formed from industrial pollutants are relevant DBP species in drinking water produced form Taihu source water, suggesting protection of Taihu Lake source water is important to control the DBP risks.

关键词： Source water Disinfection byproducts Brominated disinfection byproducts Nontarget analysis Precursors Source water pollution

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Faster structured illumination microscopy using complementary encoding-based compressive imaging

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Photonics Research 2024年第4期12卷 740-748页

作者： ZHENGQI HUANG yuNHUA YAO YILIN HE yu HE CHENGZHI JIN MENGDI GUO DALONG QI LIANZHONG DENG ZHENRONG SUN zhiyong WANG SHIAN ZHANG State Key Laboratory of Precision Spectroscopy School of Physics and Electronic ScienceEast China Normal UniversityShanghai 200241China School of Mathematical Sciences University of Electronic Science and Technology of ChinaChengdu 611731China Joint Research Center of Light Manipulation Science and Photonic Integrated Chip of East China Normal University and Shandong Normal University East China Normal UniversityShanghai 200241China Collaborative Innovation Center of Extreme Optics Shanxi UniversityTaiyuan 030006China

Structured illumination microscopy (SIM) has been widely applied to investigate intricate biological dynamics due to its outstanding super-resolution imaging speed. Incorporating compressive sensing into SIM brings the possibility to further improve the super-resolution imaging speed. Nevertheless, the recovery of the superresolution information from the compressed measurement remains challenging in experiments. Here, we report structured illumination microscopy with complementary encoding-based compressive imaging (CECI-SIM) to realize faster super-resolution imaging. Compared to the nine measurements to obtain a super-resolution image in a conventional SIM, CECI-SIM can achieve a super-resolution image by three measurements;therefore, a threefold improvement in the imaging speed can be achieved. This faster imaging ability in CECI-SIM is experimentally verified by observing tubulin and actin in mouse embryonic fibroblast cells. This work provides a feasible solution for high-speed super-resolution imaging, which would bring significant applications in biomedical research.

关键词： illumination complementary faster

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