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Ultrastable graphene isolated Au Ag nanoalloy for SERS biosensing and photothermal therapy of bacterial infection

Chinese Chemical Letters 2024年第3期35卷 198-203页

作者： Shengkai li zhiyang li Qing Hao Shen Wang Yanxia Yang Jieqiong Xu Zhiwei Yin liang Zhang Zhuo Chen Molecular Science and Biomedicine Laboratory(MBL) State Key Laboratory of Chemo/Biosensing and ChemometricsCollege of Chemistry and Chemical EngineeringCollege of BiologyAptamer Engineering Center of Hunan ProvinceHunan UniversityChangsha 410082China School of Chemistry and Chemical Engineering/Guangzhou Key Laboratory for Clean Energy and Materials/Key Laboratory for Water Quality and Conservation of the Pearl River Delta Ministry of EducationGuangzhou UniversityGuangzhou 510006China

Plasmonic metal nanomaterials with intrinsic surface–enhanced Raman scattering(SERS)and photothermal properties,especially AuAg nanoalloys with both the outstanding merits of Au and Ag nanocrystals,show huge application prospects in bacterial ***,the direct exposure of AuAg nanoalloys in external conditions probably cause undesirable reactions and poisonous metal ion leakage during SERS detection and photothermal antibacterial therapy process,which severely hinder bacterial theranostics ***,we report an ultrastable graphene–isolated AuAg nanoalloy(GAA)with AuAg core confined in few–layer graphitic shell as a versatile platform for bacterial detection and *** encapsulation of graphene ensures the good stability of AuAg core,that its superior SERS and photothermal properties are therefore further *** is used for SERS detection of two vital bacterial biomarkers(including corrosive cyanide and pyocyanin),exhibiting good SERS quantitative and multiplexing *** is further used for photothermal antibacterial therapy application,and ultrahigh antibacterial efficacies for both Gram–negative Escherichia coli and Gram–positive Staphylococcus aureus are achieved under 808 nm laser *** work proposes a valuable method to develop robust bacterial theranostic platform.

关键词： Localized surface plasmon resonance Graphitic shell isolated AuAg nanoalloy(GAA) Surface–enhanced Raman scattering(SERS) Bacterial biomarker detection Photothermal antibacterial therapy

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Tuning interfacial charge transfer for efficient visible-light-driven photodegradation and simultaneous H_(2)evolution

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Journal of Materials Science & Technology 2024年第1期168卷 35-49页

作者： zhiyang li Yaogang Chen Yinghe Zhang Wei Ai Qian Lei Tingjun Yao Dan Zhong Wenjie liu Wenbiao Jin Lei Yang State Key Laboratory of Urban Water Resource and Environment Shenzhen Key Laboratory of Organic Pollution Prevention and ControlSchool of Civil and Environmental EngineeringHarbin Institute of Technology ShenzhenShenzhen 518055China Key Laboratory of Northwest Water Resources Environment and EcologyMinistry of EducationSchool of Environmental and Municipal EngineeringXi’an University of Architecture and TechnologyXi’an 710055China CNAS Accredited Test Center Guangdong Engineering Technology Research Center of Air PurificationHealthlead Co.Ltd.Shenzhen 518055China School of Science Harbin Institute of Technology ShenzhenShenzhen 518055China

The edge-graphitized carbon nitride(C_(3)N_(4)-C g)was prepared by secondary pyrolysis to construct ZnO/C_(3)N_(4)-C g(ZCN)type-Ⅱheterojunction photocatalyst via a facile sonication dispersion method,which achieved∼7.04-fold and∼18.3-fold enhanced visible-light-driven photocatalytic performance for refrac-tory micropollutant removal and simultaneous hydrogen(H_(2))evolution respectively compared to con-ventional ZnO/g-C_(3)N_(4)Step-scheme *** apparent quantum efficiency of the ZCN_(0.4)het-erojunction reaches 0.92%(λ=420 nm).Such excellent performance stems from that the edge-graphene moieties stitched onto the interface of heterojunction extend light absorption to the full visible spec-trum,meanwhile,the built-in electric field generated during Fermi level alignment accompanying fa-vorable band-bending structure provides an effective pathway for the rapid migration of photoinduced electrons via the edge graphene channel to improve interfacial charge separation ***,the midgap states introduced in ZCN heterojunction could temporarily retain photoexcited electrons to effectively inhibit the in situ carrier recombination for improved photocatalytic H_(2)***,ZCN/peroxymonosulfate system exhibited excellent anti-interference performance against complex water bodies under visible illumination due to the synergistic effect between the co-existing anions and organic ***,the eco-friendly nature of the ZCN/peroxymonosulfate system showed no biotoxicity of reaction filtrate on cell proliferation after treatment,which avoided secondary ***-ering the outstanding performance in photocatalysis,the ZCN system exhibits broad potential for practical applications in water pollution control and green energy production.

关键词： ZnO C_(3)N_(4)-C g Heterojunction Photodegradation Hydrogen evolution

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Rh(Ⅱ)catalyzed efficient sigmatropic rearrangement reaction of pyridotriazoles and sulfides

Green Synthesis and Catalysis

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Green Synthesis and Catalysis 2024年第2期5卷 77-79页

作者： Yuting Chen Guanghui Lv zhiyang li Meiling Ye Tianle Huang li Hai Yong Wu Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry and Sichuan Province Sichuan Engineering Laboratory for Plant-Sourced Drug and Sichuan Research Center for Drug Precision Industrial TechnologyWest China School of PharmacySichuan UniversityChengdu610041China Department of Pharmacy Taihe HospitalHubei University of MedicineShiyan442000China

The[2,3]-and[1,2]-sigmatropic rearrangement reactions between pyridotriazoles and sulfides catalyzed by rhodium(II)were *** utilization of pyridotriazoles as the carbene precursors in this kind of reaction efficiently... 详细信息

关键词： Pyridotriazole Sulfide -Sigmatropic rearrangement -Sigmatropic rearrangement Rhodium catalysis

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磁性核壳胶囊局域中和胃酸用于活性益生菌的高效递送

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物理化学学报 2024年第7期40卷 61-68页

作者：李芷阳邓晖蔡芯琪陈卓湖南大学化学化工学院化学生物传感与计量学国家重点实验室分子科学与生物医学实验室长沙410082

近年来基于益生菌的幽门螺旋杆菌感染治疗策略受到了越来越多的关注,然而益生菌在胃部中直接递送会受到胃酸环境的干扰,难以存活,无法有效抑制幽门螺旋杆菌。为了实现益生菌在胃部的高效递送,我们制备了具有核壳结构的益生菌胶囊。胶囊... 详细信息

近年来基于益生菌的幽门螺旋杆菌感染治疗策略受到了越来越多的关注,然而益生菌在胃部中直接递送会受到胃酸环境的干扰,难以存活,无法有效抑制幽门螺旋杆菌。为了实现益生菌在胃部的高效递送,我们制备了具有核壳结构的益生菌胶囊。胶囊外壳由海藻酸钙(Alg)、碳酸钙(CaCO_(3))以及铁钴磁性石墨纳米囊FeCo@G组成,胶囊内核为益生菌(约氏乳杆菌,Laj)菌液。其中,CaCO_(3)用于局域中和胃酸以保护内核益生菌,而FeCo@G则赋予了胶囊良好的磁驱动性能。我们利用扫描电子显微镜以及细胞显微成像系统等手段考察了益生菌胶囊的形貌和包裹稳定性,结果显示,胶囊能稳定包裹益生菌并抵御模拟胃液(SGF)中盐酸的侵蚀,维持了益生菌活性,并对幽门螺旋杆菌(H.p)具有明显抑制作用。此外,我们进一步探究了Alg/CaCO_(3)/FeCo@G-Laj(ACFL)胶囊在模拟胃部环境内的磁导航运动性能,结果表明,在磁场条件下,ACFL胶囊在不同粘度的介质中均可以实现高效的磁驱动效应,证实了ACFL胶囊的益生菌靶向递送能力。综上,ACFL胶囊为幽门螺旋杆菌的治疗提供新的方法,同时也为胃酸不稳定药物的高效保护以及精准投递提供了新平台。

关键词：益生菌幽门螺旋杆菌胃部药物投递磁性石墨纳米囊酸稳定性

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Research progress of severe acute respiratory syndrome coronavirus 2 on aerosol collection and detection

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Chinese Chemical Letters 2024年第1期35卷 108-115页

作者： Xinyu Zhang Yuting Chen Yueying Pan Xinye Ma Gui Hu Song li Yan Deng Zhu Chen Hui Chen Yanqi Wu Zhihong Jiang zhiyang li Hunan Key Laboratory of Biomedical Nanomaterials and Devices Hunan University of TechnologyZhuzhou 412007China State Key Laboratory of Quality Research in Chinese Medicine Macao University of Science and TechnologyMacao 999078China Shenzhen Lemniscare Med Technol Co.Ltd. Shenzhen 518000China Department of Clinical Laboratory the Affiliated Drum Tower Hospital of Nanjing University Medical SchoolNanjing 210008China

The outbreak of severe acute respiratory syndrome coronavirus 2(SARS-CoV-2)in late 2019 has negatively affected people's lives and *** the mode of transmission of SARS-CoV-2 is of great concern,this review discusses the sources of virus aerosols and possible transmission ***,we discuss virus aerosol collection methods,including natural sedimentation,solid impact,liquid impact,centrifugal,cyclone and electrostatic adsorption ***,we review common virus aerosol detection methods,including virus culture,metabolic detection,nucleic acid-based detection and immunology-based detection ***,possible solutions for the detection of SARS-CoV-2 aerosols are ***-of-care testing has long been a focus of *** the near future,the development of an instrument that integrates sampling and output results will enable the real-time,automatic monitoring of patients.

关键词： Virus aerosol Aerosol transmission Aerosol collection Aerosol detection Protective measure

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多孔介质微观结构对柴油机颗粒捕集器性能影响的模拟探究

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哈尔滨工程大学学报 2024年第5期45卷 886-893页

作者：李志军李智洋李振国王妍杨绵松天津大学内燃机燃烧学国家重点实验室天津300072 中国汽车技术研究中心有限公司天津300300

为了优化柴油机颗粒捕集器的捕集、压降性能,本文基于孔径概率密度函数和孔隙率分布函数建立了二维柴油机颗粒捕集器孔道微观结构模型,考虑了拦截机理和扩散机理用以计算颗粒在过滤器中的沉积分布情况和捕集效率。计算结果表明:多孔介... 详细信息

为了优化柴油机颗粒捕集器的捕集、压降性能,本文基于孔径概率密度函数和孔隙率分布函数建立了二维柴油机颗粒捕集器孔道微观结构模型,考虑了拦截机理和扩散机理用以计算颗粒在过滤器中的沉积分布情况和捕集效率。计算结果表明:多孔介质微观结构和入口速度对颗粒捕集效率的影响与粒径有关,100 nm粒径颗粒随流速增大初始捕集效率降低最为明显,1000 nm粒径颗粒在不同均匀性的过滤壁下的捕集效率差超过了30%;孔径分布函数方差越大,颗粒就会更多地分布在过滤壁前端,捕集效率也越高,但较大的孔径方差会导致捕集器的初始压降增大和捕集过程结束时的性能出现恶化。

关键词：颗粒捕集器数值模拟微观结构概率密度函数压降捕集效率

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基于EMD和CatBoost算法的改进时间序列模型——以大连市PM_(2.5)预测为例

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南京林业大学学报（自然科学版） 2024年第3期48卷 268-274页

作者：赵凌霄李智扬屈磊磊大连海洋大学海洋与土木工程学院辽宁大连116023 复旦大学大气与海洋科学系上海200438 重庆大学土木工程学院重庆400044 大连海洋大学信息工程学院辽宁大连116023

【目的】解决传统大气PM_(2.5)浓度时序预测时精度较低问题,减少PM_(2.5)时间序列的非线性、高噪声、不平稳与波动性对预测的影响,从而更精确地预测PM_(2.5)浓度。【方法】以2014年1月1日至2022年1月31日大连市雾霾天气时PM_(2.5)数据为... 详细信息

【目的】解决传统大气PM_(2.5)浓度时序预测时精度较低问题,减少PM_(2.5)时间序列的非线性、高噪声、不平稳与波动性对预测的影响,从而更精确地预测PM_(2.5)浓度。【方法】以2014年1月1日至2022年1月31日大连市雾霾天气时PM_(2.5)数据为例,提出了经验模态分解(EMD)、分类提升(CatBoost)、自回归综合移动平均模型(ARIMA)组合的混合机器学习时间序列模型,并与传统自回归模型(AR)、ARIMA,以及只加入EMD方法后的混合模型进行比较。【结果】混合模型EMD-CatBoost-ARIMA较原始序列均方根误差(RMSE)改进20.76%,平均绝对值误差(MAE)改进17.40%,希尔不等系数(TIC)改进29.17%。【结论】对于高熵值的重构序列,EMD分解方法和CatBoost算法能够显著提升PM_(2.5)时间序列模型的预测性能。相比较传统时间序列模型,EMD-CatBoost-ARIMA模型对大气PM2.5浓度预测性能较高。

关键词： PM_(2.5)浓度经验模态分解(EMD) 时间序列模型混合模型 CatBoost算法机器学习大连市

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测压管长度对单测点信号的影响及修正效果验证

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土木与环境工程学报（中英文） 2024年第3期46卷 124-133页

作者：张亮亮陈傲李少鹏李智扬重庆大学土木工程学院重庆400045 重庆建筑科技职业学院重庆401331

测压试验中,测压管的存在会导致风压信号产生畸变,影响后续数据分析的精度。通过实际测定测压管路频响函数,获得测压管对信号的影响规律,并揭示了“B-T理论”的不足。在实际紊流作用下研究测压管长度对单测点压力数据和模型整体力的影响... 详细信息

测压试验中,测压管的存在会导致风压信号产生畸变,影响后续数据分析的精度。通过实际测定测压管路频响函数,获得测压管对信号的影响规律,并揭示了“B-T理论”的不足。在实际紊流作用下研究测压管长度对单测点压力数据和模型整体力的影响,并验证“B-T理论”的修正效果。结果表明:对于单测点压力数据,测压管将不会影响数据均值和变异系数,标准差随管长增加先增后减,信号时域随管长增加而整体向均值靠近,相位则不断滞后,信号频域值随管长和频率的增加逐渐偏离真实值;对于整体力,整体阻力、各力的相关性、相干性均可认为不受测压管影响,力谱的变化规律与单测点频域值相同;“B-T理论”在信号时域上修正效果较差,在频域修正方面表现良好。

关键词：测压试验测压管频响函数信号修正紊流

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矩形断面迎风面脉动压力特性试验研究

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土木与环境工程学报（中英文） 2024年第4期46卷 143-150页

作者：黄晖李少鹏张亮亮李智扬重庆大学土木工程学院重庆400045 重庆建筑科技职业学院重庆401331

当紊流流经矩形钝体时,由于漩涡的拉伸和旋转运动,其顺流向脉动压力具有明显的非定常性和空间三维性,且主要依赖于紊流积分尺度与结构特征尺寸之比。为了深入研究紊流尺度效应作用机理,以4:1矩形断面为研究对象,基于三维谱张量理论和刚... 详细信息

当紊流流经矩形钝体时,由于漩涡的拉伸和旋转运动,其顺流向脉动压力具有明显的非定常性和空间三维性,且主要依赖于紊流积分尺度与结构特征尺寸之比。为了深入研究紊流尺度效应作用机理,以4:1矩形断面为研究对象,基于三维谱张量理论和刚性节段模型测压试验,系统研究矩形断面顺流向脉动压力的非定常气动力特性。结果表明:在紊流从矩形断面驻点至分离点运动过程中,脉动压力的谱能量从低频向高频转移,且该现象随着L_(u)/D(L_(u)为脉动风的纵向积分尺度,D为迎风面高度)的减小更明显。与之相比,紊流三维效应和畸变效应随L_(u)/D的增大而减弱,在此过程中脉动压力的能量由于阻塞效应只在低频发生了明显的衰减,在高频无明显变化。并通过引入三维压力导纳来揭示紊流作用下矩形断面迎风侧脉动压力的非定常效应机理,对于驻点压力,L_(u)/D越大,压力导纳越接近准定常理论;对于非驻点压力,其距驻点位置越远,阻塞效应对于低频能量的减弱作用越明显,紊流三维效应越弱,而高频的畸变效应则只由L_(u)/D控制。

关键词：紊流迎风面风压非定常效应风洞试验压力导纳

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Consensus statement on research and application of Chinese herbal medicine derived extracellular vesicles-like particles(2023 edition)

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Chinese Herbal Medicines 2024年第1期16卷 3-12页

作者： Qing Zhao Tong Wang Hongbin Wang Peng Cao Chengyu Jiang Hongzhi Qiao lihua Peng Xingdong lin Yunyao Jiang Honglei Jin Huantian Zhang Shengpeng Wang Yang Wang Ying Wang Xi Chen Junbing Fan Bo li Geng li Bifeng liu zhiyang li Suhua Qi Mingzhen Zhang Jianjian Zheng Jiuyao Zhou Lei Zheng Kewei Zhao Guangdong Engineering Research Center of Chinese Herbal Vesicles The Third Affiliated Hospital of Guangzhou University of Chinese MedicineGuangzhou 510378China Guangzhou Key Laboratory of Chinese Medicine Research on Prevention and Treatment of Osteoporosis The Third Affiliated Hospital of Guangzhou University of Chinese MedicineGuangzhou 510378China Institute of life and Health Engineering the First Affiliated HospitalJinan UniversityGuangzhou 510630China School of Pharmaceutical Sciences Guangzhou University of Chinese MedicineGuangzhou 510006China College of Pharmacy Nanjing University of Chinese MedicineNanjing 210046China Institute of Basic Medicine Chinese Academy of Medical SciencesBeijing 100005China College of Pharmaceutical Sciences Zhejiang UniversityHangzhou 310030China School of Pharmaceutical Sciences Tsinghua UniversityBeijing 100084China Department of Bone and Joint Surgery The First Affiliated Hospital of Jinan UniversityGuangzhou 510630China State Key Laboratory of Quality Research in Chinese Medicine Institute of Chinese Medical SciencesUniversity of MacaoAomen 999078China Shanghai Jiao Tong University Affiliated Sixth People’s Hospital Shanghai 200233China School of Basic Medical Sciences Southern Medical UniversityGuangzhou 510515China School of life Sciences Nanjing UniversityNanjing 210008China Nanfang Hospital Southern Medical UniversityGuangzhou 510515China Laboratory Animal Center Guangzhou University of Chinese MedicineGuangzhou 510405China College of life Science and Technology Huazhong University of Science and TechnologyWuhan 430074China Nanjing University Medical School Affiliated Nanjing Drum Tower Hospital Nanjing 210008China School of Medical and Technology Xuzhou Medical UniversityXuzhou 221004China School of Basic Medical Sciences Xi’an Jiaotong UniversityXi’an 710065China The First Affiliated Hospital of Wenzhou Medical University WenZhou 325035China

To promote the development of extracellular vesicles of herbal medicine especially the establishment of standardization,led by the National Expert Committee on Research and Application of Chinese Herbal Vesicles,research experts in the field of herbal medicine and extracellular vesicles were invited nationwide with the support of the Expert Committee on Research and Application of Chinese Herbal Vesicles,Professional Committee on Extracellular Vesicle Research and Application,Chinese Society of Research Hospitals and the Guangdong Engineering Research Center of Chinese Herbal *** on the collation of relevant literature,we have adopted the Delphi method,the consensus meeting method combined with the nominal group method to form a discussion draft of“Consensus statement on research and application of Chinese herbal medicine derived extracellular vesicles-like particles(2023)”.The first draft was discussed in online and offline meetings on October 12,14,November 2,2022 and April and May 2023 on the current status of research,nomenclature,isolation methods,quality standards and research applications of extracellular vesicles of Chinese herbal medicines,and 13 consensus opinions were finally *** the Third Academic Conference on Research and Application of Chinese Herbal Vesicles,held on May 26,2023,Kewei Zhao,convenor of the consensus,presented and read the consensus to the experts of the Expert Committee on Research and Application of Chinese Herbal *** consensus highlights the characteristics and advantages of Chinese medicine,inherits the essence,and keeps the righteousness and innovation,aiming to provide a reference for colleagues engaged in research and application of Chinese herbal vesicles at home and abroad,decode the mystery behind Chinese herbal vesicles together,establish a safe,effective and controllable accurate Chinese herbal vesicle prevention and treatment system,and build a bridge for Chinese medicine to the world.

关键词： Chinese herbal medicine extracellular vesicles research application consensus

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