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Molecular-level proton acceptor boosts oxygen evolution catalysis to enable efficient industrial-scale water splitting

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Green Energy & Environment 2024年第2期9卷 344-355页

作者： Yaobin Wang Qian Lu Xinlei Ge Feng Li Le Chen zhihui zhang Zhengping Fu Yalin Lu Yang Song Yunfei Bu Jiangsu Collaborative Innovation Center of Atmospheric Environment and Equipment Technology(CICAEET) Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control(AEMPC)UNIST-NUIST Energy and Environment Jointed Lab(UNNU)School of Environmental Science and TechnologyNanjing University of Information Science and Technology(NUIST)219 NingliuNanjing210044China Laboratory of Advanced Materials Shanghai Key Laboratory of Molecular Catalysis and Innovative MaterialsFudan University220 HandanShanghai200433China Jiangsu Key Laboratory of Advanced Materials and Technology School of Petrochemical EngineeringChangzhou University1 GehuChangzhou213164China Anhui Laboratory of Advanced Photon Science and Technology University of Science and Technology of China(USTC)96 JinzhaiHefeiAnhui 230026China School of Chemistry and Chemical Engineering Nanjing University of Science and Technology200 Xiaolingwei210094China

Industrial water splitting has long been suppressed by the sluggish kinetics of the oxygen evolution reaction(OER),which requires a catalyst to be efficient.Herein,we propose a molecular-level proton acceptor strategy to produce an efficient OER catalyst that can boost industrial-scale water splitting.Molecular-level phosphate(-PO_(4))group is introduced to modify the surface of PrBa_(0.5)Ca_(0.5)Co_(2)O_(5)+δ(PBCC).The achieved catalyst(PO_(4)-PBCC)exhibits significantly enhanced catalytic performance in alkaline media.Based on the X-ray absorption spectroscopy results and density functional theory(DFT)calculations,the PO_(4)on the surface,which is regarded as the Lewis base,is the key factor to overcome the kinetic limitation of the proton transfer process during the OER.The use of the catalyst in a membrane electrode assembly(MEA)is further evaluated for industrial-scale water splitting,and it only needs a low voltage of 1.66 V to achieve a large current density of 1 A cm^(-2).This work provides a new molecular-level strategy to develop highly efficient OER electrocatalysts for industrial applications.

关键词： Oxygen evolution reaction Nanofiber Water splitting Proton acceptor Perovskite

Mechanism of acupuncture in attenuating cerebral ischaemia-reperfusion injury based on nuclear receptor coactivator 4 mediated ferritinophagy

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Journal of Traditional Chinese Medicine 2024年第2期44卷 345-352页

作者： zhang Xinchang HUANG Zheng HUANG Peiyan YANG Mengning zhang zhihui NI Guangxia College of Acupuncture-Moxibustion and Tuina Nanjing University of Chinese MedicineNanjing 210023China Key Laboratory of Acupuncture and Medicine Research of Ministry of Education Nanjing University of Chinese MedicineNanjing 210023China

OBJECTIVE:To explore the effect of acupuncture treatment on cerebral ischaemia-reperfusion injury(CIRI)and reveal the underlying mechanism of the effect based on nuclear receptor coactivator 4(NCOA4)mediated ferritinophagy.METHODS:Sprague-Dawley male rats were divided into four groups:the sham group,model group,acupuncture group,and sham acupuncture group.After 2 h of middle cerebral artery occlusion(MCAO),reperfusion was performed for 24 h to induce CIRI.The rats were treated with acupuncture at the Neiguan(PC6)and Shuigou(GV26)acupoints.Their neurological function was evaluated by taking their Bederson scores at 2 h after ischaemia and 24 h after reperfusion.Triphenyltetrazolium chloride staining was applied to assess the cerebral infarct volume at 24 h after reperfusion.The malondialdehyde(MDA)and ferrous iron(Fe^(2+))levels were observed after 24 h of reperfusion using an assay kit.Western blotting was performed to detect the expression of NCOA4 and ferritin heavy chain 1(FTH1)at 24 h after reperfusion.Moreover,the colocalization of ferritin with neurons,NCOA4 with microtubule-associated protein 1 light chain 3(LC3),and NCOA4 with ferritin was visualized using immunofluorescence staining.RESULTS:Acupuncture significantly improved neurological function and decreased cerebral infarct volume in the acupuncture group.Following CIRI,the expression of NCOA4,LC3 and FTH1 was increased,which enhanced ferritinophagy and induced an inappropriate accumulation of Fe^(2+)and MDA in the ischaemic brain.However,acupuncture dramatically downregulated the expression of NCOA4,LC3 and FTH1,inhibited the overactivation of ferritinophagy,and decreased the levels of MDA and Fe^(2+).CONCLUSIONS:Acupuncture can inhibit NCOA4-mediated ferritinophagy and protect neurons against CIRI in a rat model.

关键词： acupuncture ferritinophagy ferroptosis ferritin nuclear receptor coactivator 4 cerebral ischaemia-reperfusion injury

Dynamics of Rossby solitary waves with time-dependent mean flow via Euler eigenvalue model

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Applied Mathematics and Mechanics(English Edition) 2022年第10期43卷 1615-1630页

作者： zhihui zhang Liguo CHEN Ruigang zhang Liangui YANG Quansheng LIU School of Mathematical Sciences Inner Mongolia UniversityHohhot010021China School of Statistics and Mathematics Inner Mongolia University of Finance and EconomicsHohhot010070China

The investigation on the fluctuations of nonlinear Rossby waves is of great importance for the understanding of atmospheric or oceanic motions.The present paper mainly deals with the well-known atmospheric blocking phenomena through the nonlinear Rossby wave theories and the corresponding methods.Based on the equivalent barotropic potential vorticity model in theβ-plane approximation underlying a weak time-dependent mean flow,the multiscale technique and perturbation approximated methods are adopted to derive a new forced Korteweg-de Vries model equation with varied coefficients(vfKdV)for the Rossby wave amplitude.For a further analytical treatment of the obtained model problem,a special kind of basic flow is adopted.The evolution processes of atmospheric blocking are well discussed according to the given parameters according to the dipole blocking theory.The effects of some physical factors,especially the mean flow,on the propagation of atmospheric blocking are analyzed.

关键词： theory methods flow

Effect of TiAl3 Content on Thermal Shock Resistance of Bionic Self-healing Thermal Barrier Coatings

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Journal of Bionic Engineering 2022年第1期19卷 126-138页

作者： Panpan zhang Yujia Guo zhihui zhang Xiaofeng zhang Qunli zhang Jianhua Yao Institute of Laser Advanced Manufacturing Zhejiang University of TechnologyHangzhou310023China Collaborative Innovation Center of High-End Laser Manufacturing Equipment(National“2011 Plan”) Zhejiang University of TechnologyHangzhou310023China The Key Laboratory of Bionic Engineering(Ministry of Education China) Jilin UniversityChangchun130022China Institute of New Materials Guangdong Academy of SciencesGuangzhou510650China

Inspired by the self-healing function of biological organisms,Bionic Laser Alloying(BLA)process was adopted to fabricate the bionic self-healing Thermal Barrier Coatings(TBCs).The BLA with different fractions of TiAl3 self-healing agent and Ceria and Yttria-Stabilized Zirconia(CYSZ)on the plasma-sprayed 7YSZ TBCs was carried out by a pulsed Nd:YAG laser.The effect of TiAl3 content on the microstructure,phase composition,and thermal shock behaviors of the bionic self-healing TBCs were investigated.Results indicated that the bionic self-healing TBCs had better thermal shock resistance than that of the as-sprayed TBCs.The thermal shock resistance increased first and then decreased with increasing TiAl3 fraction.The thermal shock resistance of the bionic self-healing TBCs with 15%TiAl3 is triple that of the as-sprayed TBCs.On one hand,the columnar crystals and vertical cracks could improve strain compatibility of TBCs during the thermal shock process;on the other hand,the TiAl3 as a self-healing agent reacted with oxygen in air at high temperature to seal the microcracks,thereby delaying the crack connection.

关键词： Thermal barrier coating Laser Bionic self-healing Thermal shock resistance

Bionic Stepping Motors Driven by Piezoelectric Materials

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Journal of Bionic Engineering 2023年第3期20卷 858-872页

作者： Shupeng Wang Shihui Zhou Xiaolong zhang Pengyun Xu zhihui zhang Luquan Ren Key Laboratory of Bionic Engineering(Ministry of Education) Jilin UniversityChangchun130022China Department of Mechanical and Electrical Engineering Ocean University of ChinaQingdao266100China

By imitating the behavioral characteristics of some typical animals, researchers develop bionic stepping motors to extend the working range of piezoelectric materials and utilize their high accuracy advantage as well. A comprehensive review of the bionic stepping motors driven by piezoelectric materials is presented in this work. The main parts of stepping piezoelectric motors, including the feeding module, clamping module, and other critical components, are introduced elaborately. We classify the bionic stepping piezoelectric motors into inchworm motors, seal motors, and inertia motors depending on their main structure modules, and present the mutual transformation relationships among the three types. In terms of the relative position relationships among the main structure modules, each of the inchworm motors, seal motors, and inertia motors can further be divided into walker type, pusher type, and hybrid type. The configurations and working principles of all bionic stepping piezoelectric motors are reported, followed by a discussion of the advantages and disadvantages of the performance for each type. This work provides theoretical support and thoughtful insights for the understanding, analysis, design, and application of the bionic stepping piezoelectric motors.

关键词： Bionic stepping piezoelectric motor Inchworm motor Seal motor Inertia motor Walker type Pusher type Hybrid type

Modulating effects of RAMPs on signaling profiles of the glucagon receptor family

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Acta Pharmaceutica Sinica B 2022年第2期12卷 637-650页

作者： Lijun Shao Yan Chen Shikai zhang zhihui zhang Yongbing Cao Dehua Yang Ming-Wei Wang The National Center for Drug Screening and CAS Key Laboratory of Receptor Research Shanghai Institute of Materia MedicaChinese Academy of Sciences(CAS)Shanghai 201203China School of Life Science and Technology ShanghaiTech UniversityShanghai 201210China University of Chinese Academy of Sciences Beijing 100049China School of Pharmacy Fudan UniversityShanghai 201203China Shanghai TCM-Integrated Hospital Shanghai University of Traditional Chinese MedicineShanghai 200082China Department of Pharmacology School of Basic Medical SciencesFudan UniversityShanghai 200032China

Receptor activity-modulating proteins(RAMPs)are accessory molecules that form complexes with specific G protein-coupled receptors(GPCRs)and modulate their functions.It is established that RAMP interacts with the glucagon receptor family of GPCRs but the underlying mechanism is poorly understood.In this study,we used a bioluminescence resonance energy transfer(BRET)approach to comprehensively investigate such interactions.In conjunction with c AMP accumulation,Gaqactivation andβ-arrestin1/2 recruitment assays,we not only verified the GPCR-RAMP pairs previously reported,but also identified new patterns of GPCR-RAMP interaction.While RAMP1 was able to modify the three signaling events elicited by both glucagon receptor(GCGR)and glucagon-like peptide-1 receptor(GLP-1 R),and RAMP2 mainly affectedβ-arrestin1/2 recruitment by GCGR,GLP-1 R and glucagon-like peptide-2 receptor,RAMP3 showed a widespread negative impact on all the family members except for growth hormone-releasing hormone receptor covering the three pathways.Our results suggest that RAMP modulates both G protein dependent and independent signal transduction among the glucagon receptor family members in a receptor-specific manner.Mapping such interactions provides new insights into the role of RAMP in ligand recognition and receptor activation.

关键词： G protein-coupled receptor Glucagon receptor family Receptor activitymodulating protein Signaling Allosteric modulation GPCR-RAMP interaction Receptor pharmacology Ligand selectivity

3D printed aluminum matrix composites with well-defined ordered structures of shear-induced aligned carbon fibers

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Nano Materials Science 2022年第4期4卷 366-375页

作者： Yunhong Liang Han Wu Zhaohua Lin Qingping Liu zhihui zhang The Key Laboratory of Bionic Engineering Ministry of EducationJilin UniversityChangchun 130025China School of Mechanical and Aerospace Engineering Jilin UniversityChangchun 130025China

Carbon fiber reinforced aluminum composites with ordered architectures of shear-induced aligned carbon fibers were fabricated by 3D printing.The microstructures of the printed and sintered samples and mechanical properties of the composites were investigated.Carbon fibers and aluminum powder were bonded together with resin.The spatial arrangement of the carbon fibers was fixed in the aluminum matrix by shear-induced alignment in the3D printing process.As a result,the elongation of the composites with a parallel arrangement of aligned fibers and the impact toughness of the composites with an orthogonal arrangement were 0.82%and 0.41 J/cm^(2),respectively,about 0.4 and 0.8 times higher than that of the random arrangement.

关键词： 3D printing Shear-induced alignment Carbon fiber Aluminum matrix composites Powder metallurgy

Investigation on the Mechanical Properties and Shape Memory Effect of Landing Buffer Structure Based on Ni Ti Alloy Printing

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Chinese Journal of Mechanical Engineering 2023年第4期36卷 415-424页

作者： Zhenglei Yu Renlong Xin Zezhou Xu Yining Zhu Xiaolong zhang Shijie Hao zhihui zhang Ping Liang State Key Laboratory of Automotive Simulation and Control Jilin University Key Lab of Bionic Engineering Ministry of Education Jilin University Agriculture College Yanbian University State Key Laboratory of Heavy Oil Processing China University of Petroleum

With the deepening of human research on deep space exploration, our research on the soft landing methods of landers has gradually deepened. Adding a buffer and energy-absorbing structure to the leg structure of the lander has become an effective design solution. Based on the energy-absorbing structure of the leg of the interstellar lander, this paper studies the appearance characteristics of the predatory feet of the Odontodactylus scyllarus. The predatory feet of the Odontodactylus scyllarus can not only hit the prey highly when preying, but also can easily withstand the huge counter-impact force. The predatory feet structure of the Odontodactylus scyllarus, like a symmetrical cone, shows excellent rigidity and energy absorption capacity. Inspired by this discovery, we used SLM technology to design and manufacture two nickel-titanium samples, which respectively show high elasticity, shape memory, and get better energy absorption capacity. This research provides an effective way to design and manufacture highmechanical energy-absorbing buffer structures using bionic 3D printing technology and nickel-titanium alloys.

关键词： Bionic protective structure Odontodactylus scyllarus NiTi alloy 3D printing Numerical simulation Recoverability

Compression Behavior and Failure Mechanisms of Bionic Porous NiTi Structures Built via Selective Laser Melting

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Acta Metallurgica Sinica(English Letters) 2023年第6期36卷 926-936页

作者： Xiaolong zhang Yue Jiang Shupeng Wang Shuo Wang Ziqiang Wang Zhenglei Yu zhihui zhang Luquan Ren Key Laboratory of Bionic Engineering Ministry of EducationJilin UniversityChangchun 130022China Luoyang Ship Material Research Institute Luoyang 471023China

Inspired by the crystal microstructure of metals and the bamboo,the bionic porous NiTi structures with the porosities in the range of 75.8%–84.9%were built via selective laser melting(SLM).The compression behavior and the failure mechanisms of the porous NiTi structures were evaluated.It demonstrated an increase in the elastic modulus and ultimate strength when the porosity was decreased,from 3.06 to 7.66 GPa and from 34.1 to 147.6 MPa,respectively.The relationship between the elastic modulus and the porosity obtained by the finite element analysis exhibited similar tendency with the experiment,and agreed well with the Gibson-Ashby model’s prediction.Based on the theoretical model above and the observation of the deformation processing,the plastic deformation behavior and failure mechanisms of the SLMed porous NiTi structures were analyzed.

关键词： Selective laser melting NiTi shape memory alloys Additive manufacturing Porous structure Bionic design