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Enhanced photocatalytic water splitting with surface defective SrTiO_(3)nanocrystals

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Frontiers in Energy 2021年第3期15卷 700-709页

作者： Junying LIU zhidong wei Wenfeng SHANGGUAN Institute of Physical Chemistry University of HamburgGrindelallee 11720146 HamburgGermany Research Center for Combustion and Environment Technology Shanghai Jiao Tong UniversityShanghai 200240China

Surface reconstructed SrTiO_(3)nanocrystals were synthesized by a thermal treatment process in presence of NaBH_(4)and SrTiO_(3)*** surface reconstruction of SrTiO_(3)nanocrystals is attributed to the introduction of surface oxygen vacancies or Ti sites(such as Ti^(3+)and Ti^(2+))during the hydrogenation treatment *** light absorption and the charge transfer ability of SrTiO_(3)nanocrystals are simultaneously enhanced due to surface oxygen vacancies or Ti sites(such as Ti^(3+)and Ti^(2+)),which are beneficial to photocatalytic water ***,these defects also change the redox potential of the *** there existed a synergistic effect between the three,the ratio of hydrogen to oxygen production was also regulated.

关键词： SrTiO_(3) surface reconstruction oxygen vacancies photocatalytic water splitting

A review on photocatalysis in antibiotic wastewater:Pollutant degradation and hydrogen production

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Chinese Journal of Catalysis 2020年第10期41卷 1440-1450页

作者： zhidong wei Junying Liu Wenfeng Shangguan Research Center for Combustion and Environment Technology Shanghai Jiao Tong UniversityShanghai 200240China Center of Hydrogen Science Shanghai Jiao Tong UniversityShanghai 200240China

Surveys on antibiotics have become one of the most popular topics in the recent two decades. From 1998 to 2018, more than 5,000 articles concentrated on the research of antibiotic wastewater treatment have been published. Among them, photocatalysis has received much attention due to its green and environmental-friendly properties. In this mini-review, the recent progress of photocatalysis in antibiotic wastewater was summarized, including antibiotics degradation and hydrogen energy conversion. The photocatalysts commonly used were also discussed. It can be mainly classified as TiO2-based materials, sulfides and polymeric carbon nitride-based materials and bismuth-contained materials. Four major types of antibiotics, tetracycline, sulfonamide, β-lactam and quinolone, were involved. Furthermore, perspectives concentrated on future development and challenges, especially converting antibiotics into hydrogen energy, were also proposed.

关键词： Photocatalytic Antibiotics Degradation Hydrogen Energy Thermodynamic

Zinc-doped g-C_3N_4/BiVO_4 as a Z-scheme photocatalyst system for water splitting under visible light

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Chinese Journal of Catalysis 2018年第3期39卷 472-478页

作者： Zhen Qin Wenjian Fang Junying Liu zhidong wei Zhi Jiang Wenfeng Shangguan Research Center for Combustion and Environmental Technology School of Mechanical Engineering Shanghai Jiao Tong University Shanghai 200240China

A two‐step photocatalytic water splitting system,termed a“Z‐scheme system”,was achieved using Zn‐doped g‐C3N4for H2evolution and BiVO4for O2evolution with Fe2+/Fe3+as a shuttle redox mediator.H2and O2were evaluated simultaneously when the doping amount of zinc was10%.Moreover,Zn‐doped(10%)g‐C3N4synthesized by an impregnation method showed superior active ability to form the Z‐scheme with BiVO4than by in‐situ synthesis.X‐ray diffraction,UV‐Vis spectroscopy,scanning electron microscopy,and X‐ray photoelectron spectroscopy were used to characterize the *** was determined that more Zn?N bonds could be formed on the surface of g‐C3N4by impregnation,which could facilitate charge transfer.

关键词： g‐C3N4 BiVO4 Z‐scheme Shuttle redox mediator Water splitting

Simultaneous visible-light-induced hydrogen production enhancement and antibiotic wastewater degradation using MoS2@ZnxCd1-xS: Solid-solution-assisted photocatalysis

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Chinese Journal of Catalysis 2020年第1期41卷 103-113页

作者： zhidong wei Meiqi Xu Junying Liu weiqi Guo Zhi Jiang Wenfeng Shangguan Research Center for Combustion and Environment Technology Shanghai Jiao Tong UniversityShanghai 200240China Center of Hydrogen Science Shanghai Jiao Tong UniversityNO.800Dongchuan RoadShanghai 200240China

In this study,a ZnxCd1-xS solid solution was successfully synthesized using a hydrothermal ***2 serving as a co-catalyst for hydrogen evolution was also prepared through a one-pot hydrothermal *** structures,morphology,chemical states,and optical properties were characterized using powder X-ray diffraction,scanning electron microscopy,high-angle annular dark field-scanning transmission electron microscopy,elemental mapping,X-ray photoelectron spectroscopy,and UV-Vis diffuse reflection ***-light-driven photocatalytic experiments were conducted to simultaneously achieve hydrogen production and amoxicillin antibiotic wastewater *** results indicated 8%MoS2/ZnxCd1-xS achieves the best photocatalytic *** ZnxCd1-xS samples illustrated a superior performance to that of CdS,which can be attributed to a thermodynamic *** on the results of PL and TRPL analyses,the enhancement of the hydrogen production mechanisms can be ascribed to the prolonged separation process of the ***,the degradation results were analyzed using the HPLC method and the possible degradation pathways were determined through the HPLC-MS techniques.

关键词： Photocatalytic Hydrogen energy Antibiotic wastewater Degradation Simultaneous

Electromagnetic wave absorption and corrosion resistance performance of carbon nanoclusters/Ce-Mn codoped barium ferrite composite materials

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International Journal of Minerals,Metallurgy and Materials 2025年第3期32卷 699-709页

作者： Bo Li Lin Ma Sinan Li Jiewu Cui Xiaohui Liang wei Sun Pengjie Zhang Nan Huang Song Ma zhidong Zhang Shenyang National Laboratory for Materials Science Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China School of Materials Science and Engineering University of Science and Technology of ChinaShenyang 110016China School of Metallurgy Engineering Liaoning Institute of Science and TechnologyBenxi 117004China School of Materials Science and Engineering Hefei University of TechnologyHefei 230009China Institute of Microelectronics Hangzhou Dianzi UniversityHangzhou 310018China BGRIMM Magnetic Materials&Technology Co. Ltd.Beijing 100160China

To realize the application of electromagnetic wave absorption(EWA)devices in humid marine environments,bifunctional EWA materials with better EWA capacities and anticorrosion properties have great exploration significance and systematic research *** utilizing the low-cost and excellent magnetic and stable chemical characteristics of barium ferrite(BaFe_(12)O_(19))and using the high dielectric loss and excellent chemical inertia of nanocarbon clusters,a new type of nanocomposites with carbon nanoclusters en-capsulating BaFe_(12)O_(19)was designed and synthesized by combining an impregnation method and a high-temperature calcination ***,Ce-Mn ions were introduced into the BaFe_(12)O_(19)lattice to improve the dielectric and magnetic properties of BaFe_(12)O_(19)cores significantly,and the energy band structure of the doped lattice and the orders of Ce replacing Fe sites were *** from Ce-Mn ion doping and carbon nanocluster encapsulation,the composite material exhibited excellent dual functionality of corrosion resist-ance and *** BaCe_(0.2)Mn_(0.3)Fe_(11.5)O_(19)-C(BCM-C)was calcined at 600°C,the minimum reflection loss of-20.1 dB was achieved at 14.43 *** Ku band’s effective absorption bandwidth of 4.25 GHz was achieved at an absorber thickness of only 1.3 *** BCM-C/polydimethylsiloxane coating had excellent corrosion resistance in the simulated marine environment(3.5wt%NaCl solution).The|Z|0.01Hz value of BCM-C remained at 106Ω·cm^(2)after 12 soaking *** successful preparation of the BaFe_(12)O_(19)composite en-capsulated with carbon nanoclusters provides new insights into the preparation of multifunctional absorbent materials and the fabrication of absorbent devices applied in humid marine environments in the future.

关键词： electromagnetic wave absorption anticorrosion barium ferrite cerium and manganese doping carbon nanoclusters

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挠性航天器非约束模态动力学模型的降阶研究

应用力学学报 2022年第6期39卷 1030-1037页

作者：韦志东戈新生北京信息科技大学机电工程学院北京100192

针对中心刚体-挠性附件的挠性航天器,应用拉格朗日方程推导出动力学模型,再利用模态展开法得到非约束模态动力学方程,然后分别基于模态价值分析准则和内平衡降阶准则的相关理论探讨模型降阶。通过模态价值分析准则能够显示出各阶模态占... 详细信息

针对中心刚体-挠性附件的挠性航天器,应用拉格朗日方程推导出动力学模型,再利用模态展开法得到非约束模态动力学方程,然后分别基于模态价值分析准则和内平衡降阶准则的相关理论探讨模型降阶。通过模态价值分析准则能够显示出各阶模态占系统总价值的份额,保留贡献较多的模态组成降阶系统。内平衡降阶准则通过非奇异线性变换,将系统模型转换为内平衡系统,在内平衡系统内舍掉Gram矩阵对角线上较小的值所对应的模态以构成降阶系统。最后,利用数值仿真对中心刚体-单侧挠性梁航天器的非约束模态动力学模型进行模型降阶,通过两种准则对系统模型降阶数值计算,结果表明两种降阶准则均能够有效地对原系统进行模型降阶。

关键词：挠性航天器非约束模态模型降阶模态价值分析准则内平衡降阶准则

多面体SrTiO_(3)原位生长N缺陷PCN中的纳米叠层效应助力光催化完全分解水:内建电场调控的协同机制

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Chinese Journal of Catalysis 2023年第5期48卷 279-289页

作者：韦之栋严嘉玮郭伟琦上官文峰上海交通大学智慧能源创新学院上海200030 上海交通大学燃烧与环境技术中心上海200030 上海交通大学氢科学中心上海200030

光的钻穿效应使得纳米级光催化剂(粒径200nm以下催化剂和低维催化剂等)能带弯曲程度降低,无法有效利用“向阳背阴”的Dember效应,进而削弱光生载流子从体相到表面的驱动力,不利于完全分解水的实现.我们前期研究发现,催化剂微结构的极化... 详细信息

光的钻穿效应使得纳米级光催化剂(粒径200nm以下催化剂和低维催化剂等)能带弯曲程度降低,无法有效利用“向阳背阴”的Dember效应,进而削弱光生载流子从体相到表面的驱动力,不利于完全分解水的实现.我们前期研究发现,催化剂微结构的极化率影响其扭曲度,进而可以实现对催化剂内建电场的调控,促进纳米颗粒光催化完全分解水的过程.基于此,本文在粒径小于200 nm的多面体SrTiO_(3)催化剂表面.原位生长聚合物的氮化碳(PCN),形成了薄层PCN包覆的SrTiO_(3)纳米叠层催化剂,实现了完全分解水过程.并利用物相结构分析、形貌分析、表面分析、光谱分析、同步辐射分析和理论计算等方法深入解析了SrTiO_(3)-PCN复合催化剂的结构,揭示了由纳米尺度的叠层效应引发的内建电场协同调控机制.催化剂的物相结构分析结果表明,SrTiO_(3)和PCN是组成复合催化剂的主要单体,并没有新的物质生成,复合后各元素微结构极化率发生变化,表现为拉曼光谱峰强度的变化.片层状的PCN包覆在多面体SrTiO_(3)的表面,形成了独特的复合催化剂叠层结构.N 1s与Sr 3d的X射线光电子能谱结果表明,SrTiO_(3)与PCN的结合围绕着Sr和N两种元素进行.随着SrTiO_(3)含量的增加,-NH_(2)中的N与SrTiO_(3)中的元素结合,促进了-N-H基团的生成,而-N-H-基团受到化学环境改变的影响,倾向于向氰基转变,进而形成缺陷.利用同步辐射研究了Sr原子配位数的变化,揭示了N-Sr键的形成源自于Sr-Ti键中的Sr与-NH_(2)中的N结合,促进了N缺陷态的形成,显著提升了光吸收性能.催化剂热力学分析结果表明,体相氮缺陷引起价带位置上移,而表面氮缺陷对价带位置影响较小.当SrTiO_(3)/PCN的比为1:2时,复合催化剂可以实现完全分解水过程,氢氧比接近2:1.其原因在于SrTiO_(3)与PCN之间的费米能级不同,N-Sr键的形成增强了表面电势,促进了二者复合后内建电场的重构.随着SrTiO_(3)含量的增加,体相缺陷浓度增加,进而使得分解水性能显著降低.研究表明,由N-Sr形成使得催化剂在光吸收率、热力学性质及动力学性质的改变所引起的纳米尺度叠层效应,是引发内建电场协同调控进而实现光催化完全分解水的重要因素.综上,本文结果可以对调控内建电场实现完全分解水方面研究提供一定借鉴.

关键词：光催化水分解纳米叠层效应内建电场氮缺陷的聚合物氮化碳纳米多面体钛酸锶

基于ArcGIS+FME的基础性地理国情监测质检工具设计

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测绘与空间地理信息 2021年第9期44卷 106-109页

作者：魏智东广东省国土资源测绘院广东广州510500

针对基础性地理国情监测中耗时耗力的质量检查工作,以广东省2019年基础性地理国情监测为例,基于ArcGIS+FME设计了一套地理国情监测检查工具。通过ArcGIS+FME实现了地表覆盖图斑常规检查模型和地表覆盖图斑接边检查模型,提高了质量检查效... 详细信息

针对基础性地理国情监测中耗时耗力的质量检查工作,以广东省2019年基础性地理国情监测为例,基于ArcGIS+FME设计了一套地理国情监测检查工具。通过ArcGIS+FME实现了地表覆盖图斑常规检查模型和地表覆盖图斑接边检查模型,提高了质量检查效率,为基础性地理国情监测项目质量检查工作提供了参考。

关键词：基础性地理国情监测 ArcGIS FME 质量检查

Dynamic event-triggered data-driven iterative learning bipartite tracking control for nonlinear MASs with prescribed performance

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Science China(Information Sciences) 2025年第1期68卷 292-305页

作者： Tao SHI wei-wei CHE School of Mechatronic Engineering and Automation Shanghai University State Key Laboratory of Synthetical Automation for Process Industries Northeastern University College of Information Science and Engineering Northeastern University

This article proposes a distributed dynamic event-triggered data-driven iterative learning control(DET-DDILC)scheme under a predefined performance to tackle the bipartite tracking control problem for multiagent systems(MASs). An improved dynamic linearization technique is utilized to convert the nonlinear MASs into an iterative linear data model. First,a peer-to-peer mapping function is introduced to map the constrained distributed system output homeomorphism to an unconstrained one. In addition, a DET mechanism based on a time-iteration-varying function is devised to conserve network communication resources. Based on the unconstrained transformation and the designed DET mechanism, the DET-DDILC algorithm is devised to ensure that the bipartite tracking performance of MASs can be within the preset range. Finally, the effectiveness and feasibility of the designed control scheme are demonstrated via a simulation case by a comparison.

关键词： bipartite tracking control prescribed performance event-triggered iterative learning control multiagent systems