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Co single atoms and nanoparticles dispersed on N-doped carbon nanotube as high-performance catalysts for Zn-air batteries

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Rare Metals 2022年第6期41卷 2055-2062页

作者： Jing-Jing Chen Shuai Gu Rui Hao Zhen-Yu Wang Mu-Qing li zhi-Qiang li Kun liu Ke-Meng liao zhi-Qiang Wang He Huang ying-zhi li Kai-li Zhang Zhou-Guang Lu Department of Materials Science and Engineering Guangdong Provincial Key Laboratory of Energy Materials for Electric PowerShenzhen Key Laboratory of Interfacial Science and Engineering of MaterialsSouthern University of Science and TechnologyShenzhen 518055China Department of Mechanical Engineering City University of Hong KongHong Kong 999077China

Diminishing the size of active sites in catalysts is promis-ing to improve the kinetics of oxygen reduction reaction(ORR)and reduce the cost of metal-air ***,the facile preparation of high-performance catalysts with nanoscale active sites still suffers from great ***,we report a facile template-free strategy to fabri-cate Co single atoms and nanoparticles dispersed on porous N-doped carbon nanotube(Co-NCNT)by the pyrolysis of the composites of metal-organic complexes and porous carbon *** from the conventional strategy,the precursor metal-organic complexes in this work were prepared under mild conditions and used without complex purification *** with the pristine carbon nanotube,N-doped carbon nanotube with abundant meso-pores contribute to the formation of nanoscale Co sites.

关键词： nanoparticles composites carbon

Analysis of Vitamin K_3 by a Fluorescent Spectroelectrochemistry Method

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Chemical Research in Chinese Universities 2010年第5期26卷 742-745页

作者： ZHAO Chang-zhi li ying DU Hong XU Hua-jun JIAO Kui Key Laboratory of Eeo-Chemical Engineering Ministry of Education College of Chemistry ＆ Molecular Engineering Qingdao University of Science ＆ Technology Qingdao 266042 P. R. China

A simple and sensitive spectroelectrochemistry method for the determination of vitamin K3 was developed by combining electrolysis and fluoremetry. This method was based on that vitamin K3 was reduced at a glassy carbon electrode, and its product with characteristic fluorescence at 420 nm was determined with excitation wavelength at 309 nm. Under optimized electrochemical reaction conditions and fluorescent experiment parameters, the fluorescence intensity was proportional to the concentration of vitamin K3 in a range from 3.50×10^-7 to 1.05×10^-5 mol/L with a correlation coefficient of 0.9991, and detection limit was estimated to be 7.50× 10^-8 mol/L at a signal/noise ra- tio of 3. The relative standard deviation was less than 4.3%（n=5） and the recovery was in a range of 97%-105% for the determination of vitamin K3 in pharmaceutical preparations. The result is satisfactory for the determination of vitamin K3 as comparison to that from HPLC method.

关键词： Spectroelectrochemistry Fluorescence Electro-reduced Vitamin K3

Influence of Edge Rolling Reduction on Plate-Edge Stress Distribution During Finish Rolling

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Journal of Iron and Steel Research International 2009年第1期16卷 22-26页

作者： YU Hai-liang liU Xiang-hua CHEN li-qing li Chang-sheng zhi ying li Xin-wen The State Key Laboratory of Roiling and Automation Northeastern University Shenyang 110004 Liaoning China

Dimensions of one kind of stainless steel plate before finish rolling were obtained through analysis of the rough rolling processes by finite element method and updated geometrical method. The FE models of finish rolling process with a front edge roll were built, and influences of the edge rolling reduction on the stress change in the plate edge during finish rolling were analyzed. The results show that when the edge rolling reduction is increased from 0 mm to 2 mm, the compressive stress in plate corner clearly increases in edge rolling process, and the zone of tensile stress during whole rolling decreases; when the edge rolling reduction is increased from 2 mm to 5 ram, the compressive stress in the plate corner seldom changes, and the compressive stress decreases after the horizontal rolling.

关键词： edge rolling reduction stress FEM finish rolling

Interleukin-18 Suppresses Angiogenesis and Lymphangiogenesis in Implanted Lewis Lung Cancer

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Chinese Journal of Cancer Research 2010年第4期22卷 303-309页

作者： Sheng Yang Xiang-qi Chen Hui-shan Lu zhi-ying li Ting-yan lin Department of Oncology the Union Hospital Fu Jian Medical University Fuzhou 350001 China Department of Respiratory the Union Hospital Fu Jian Medical University Fuzhou 350001 China

Objective： To investigate the effects of interleukin-18 （IL-18） on implanted Lewis lung cancer in suppressing angiogenesis and lymphangiogenesis. Methods： One week after hypodermic inoculation of Lewis cells, sixteen tumor-bearing syngeneic mice were randomly divided into two groups. The mice in the treatment group （group A） were intraperitoneally injected with the IL-18 and in the control group （group B） were intraperitoneally injected with normal saline for 7 days. The mice were killed on day 19. The morphology of the tumors was studied, the growth curve was described and the tumor inhibition rate was calculated. The numbers of metastasized pulmonary colonies were calculated using hematoxylin-eosin （HE） staining. The vascular endothelial growth factor A （VEGF-A）, vascular endothelial growth factor C （VEGF-C）, microvessel density （MVD） and lymphatic microvessel density （LMVD） in tumor mass were measured by immunohistochemistry staining （IHCS）. Results： In the group A, the tumor volume, tumor weigh, lung metastatic nodules, expression of VEGF-A and VEGF-C, MVD were all decreased significantly （P0.01 or P0.05）. The tumor inhibition rate was 75% and the inhibition rate of lung metastatic nodules was 61%. The LMVD in group A was also lower than group B, but without significant difference （P0.05）. Conclusion： IL-18 could suppress the tumor growth and metastasis of implanted Lewis lung cancer by way of down-regulating VEGF-A and VEGF-C expression, suppressing angiogenesis and lymphangiogenesis.

关键词： Interleukin-18 Lung cancer VEGF LMVD

Salidroside attenuates oxygen and glucose deprivation-induced neuronal injury by inhibiting ferroptosis

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Asian Pacific Journal of Tropical Biomedicine 2023年第2期13卷 70-79页

作者： ying-zhi li Ai-Ping Wu Dan-Dan Wang Pan-Pan Yang Bin Sheng Department of Rehabilitation Medicine Zhejiang HospitalHangzhou 310007ZhejiangChina Department of Emergency Medicine Zhejiang Provincial People’s HospitalHangzhou 310014ZhejiangChina

Objective: To evaluate the effect of salidroside on oxygen and glucose deprivation(OGD)-treated NT2 cells and its underlying mechanisms of ***: Retinoic acid was used to induce the differentiation of NT2 cells into neurons. The effects of salidroside on survival, apoptosis, inflammatory response, and oxidative stress of neurons undergoing OGD were evaluated. Using precursor cells as controls, the effect of salidroside on the differentiation progression of OGDtreated cells was evaluated. In addition, the effect of erastin, a ferroptosis inducer, on NT2 cells was examined to investigate the underlying mechanisms of neuroprotective action of ***: Salidroside alleviated the effects of OGD on neuronal survival, apoptosis, inflammation, and oxidative stress, and promoted NT2 cell differentiation. Moreover, salidroside prevented ferroptosis of OGD-treated cells, which was abolished following erastin treatment, indicating that ferroptosis mediated the regulatory pathway of ***: Salidroside attenuates OGD-induced neuronal injury by inhibiting ferroptosis and promotes neuronal differentiation.

关键词： Salidroside Rhodiola rosea Ferroptosis Oxygen and glucose deprivation Neuronal differentiation Ischemic stroke

Arthroscopic surgery for synovial chondroma of the subacromial bursa with non-traumatic shoulder subluxation complications:Two case reports

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World Journal of Clinical Cases 2022年第5期10卷 1645-1653页

作者： Xiong-Feng Tang Yan-Guo Qin Xian-Yue Shen Bo Chen ying-zhi li Orthpoeadic Medical Center Jilin University Second HospitalChangchun 130041Jilin ProvinceChina

BACKGROUND Synovial chondromatosis is a disease originating from the synovium and characterized by the presence of metaplastic cartilaginous nodules in synovial *** exact prevalence of synovial chondromatosis remains unknown,and the involvement of the shoulder joint is very *** chondromatosis accompanied by subluxation of the humeral head without a history of trauma is rarely encountered,and to our knowledge,no published reports describe this *** SUMMARY We present two cases of synovial chondromatosis in the shoulder joint,accompanied by subluxation of the humeral head,in two arthroscopically managed adult *** performed arthroscopic labrum fixation and removal of the loose body from the shoulder *** identify primary and secondary categories,pathological analysis was *** and radiographic evaluations at the 1-mo follow-up were *** The biomechanical function of the shoulder joint requires attention,especially following the detection of loose bodies,as observed with synovial chondroma occurring in rare *** management is successful in patients with synovial chondromatosis combined with shoulder subluxation.

关键词： Synovial chondromatosis Shoulder Subluxation Arthroscopic surgery Case report

Analysis of the lignin Contents and Related Enzymes Activities in Seed Coat Between Black-Seeded and Yellow-Seeded Rapes (Brassica napus L.)

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Agricultural Sciences in China 2005年第12期4卷 890-897页

作者： RAN Xiu-zhi liANG ying li Jia-na College of Agronomy and life Science Southwest Agricultural University Chongqing 400716 P.R.China

One pair of near isonegic yellow/black seeded rape （Brassica napus L） were used as experimental materials to study the changes of lignin contents and enzymes activities of 4-coumarate： CoA ligase （4CL）, Cinnamyl alcohol dehydrogenase （CAD） and ferulate 5-hydroxylase （F5H） in seedcoats during the stage of seed development. The variation analysis showed that the changes of lignin contents and enzyme activities of 4CL, CAD and F5H in seed coat had significant differences between black- and yellow-seeded rapes, and also between different development stages. The correlation analysis demonstrated that the lignin contents were positively correlative to the activities of all three enzymes investigated in the study, and the interactions between them in the seed coat of the two lines. For yellow-seeded rape, the correlation coefficient （0.7262018） of lignin content and the interaction between 4CL and F5H was significant, the lignin contents were highly positively correlative to the activities of CAD and F5H, the interaction between 4CL and CAD, and the interaction between CAD and F5H. For the black-seeded rape, only the lignin content was highly positively correlative to the activity of F5H （the correlation coefficient was 0.772949）, the other correlation coefficients, i. e. lignin contents to 4CL, CAD activities, the interactions between the three enzymes were not significant although all the correlation coefficients were above 0.5000. The results suggested that 4CL, CAD and F5H regulated the biosynthesis of lignin in seedcoat of rapes, leading to the lignin contents in the seedcoats of the yellow-seeded rape much lower than that of the black-seeded line, and affecting the thickness of the developing seedcoats in rapes. Therefore, it was likely to change the seedcoat ratio by overexpressing or suppressing the activities of one of the enzymes, both of them or all of them.

关键词： Brassica napus L.0 lignin contents0 4CL CAD F5H

Determination of Dopamine in the Presence of Ascorbic Acid on the IrO2-Ta2O5 Type DSA Electrode

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Chinese Chemical Letters 2005年第1期16卷 64-66页

作者： Yang liU, zhi ying li, Jing Hong li? State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 State Key Laboratory of Electroanalytical Chemistry Changchun Institute of Applied Chemistry Chinese Academy of Sciences Changchun 130022 China

IrO2/Ta2O5 (70%: 30%, molar ratio) electrodes (ITEs) were prepared by the thermal decomposition method. Typical “mud-cracked” surface and surface enrichment of Ta were observed. The determination of dopamine (DA) was carried out in the presence of ascorbic acid (AA). The detection limit of DA was 5×10-5 mol/L without the interference of AA.

关键词： Dopamine ascorbic acid determination DSA.

A Review of Process Modeling Language Paradigms

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Systems Science and Systems Engineering 2002年第4期11卷 439-454页

作者： MA Qin-hai, GUAN zhi-min, li ying, ZHAO Xi-nanSchool of Business Administration, Northeastern University, Shenyang 110004, China School of Business Administration Northeastern University Shenyang 110004 China

Process representation or modeling plays an important role in business process engineering. Process modeling languages can be evaluated by the extent to which they provide constructs useful for representing and reasoning about the aspects of a process, and subsequently are chosen for a certain purpose. This paper reviews process modeling language paradigms and points out their advantages and disadvantages.

关键词： business process reengineering process representation process modelling language