检索结果-南通市图书馆

Effects of deep alkaline and acidic fluids on reservoir developed in fault belt of saline lacustrine basin

Petroleum Science 2023年第2期20卷 776-786页

作者： Lei-Lei Yang Xin-wei Li Guo wei yi-Dan Liu Qin-Gong Zhuo zhi-Chao Yu zhi-Ye Gao State Key Laboratory of Petroleum Resource and Prospecting China University of Petroleum(Beijing)Beijing102249China The Unconventional Petroleum Research Institute China University of Petroleum(Beijing)Beijing102249China Jilin Oilfield Company Jilin130062China PetroChina Exploration and Development Research Institute Beijing100083China

Through the long development processes of reservoir sedimentation and diagenesis, acidic and alkaline fluids play key roles in controlling deep reservoir development. However, the ways in which deep fluids control and transform the reservoir under complex fault conditions remain unclear. In this study, a 2D model was established based on a typical sub-salt to intra-salt vertical profile in the Qaidam Basin, China. Based on measured data, multiphase flow reaction and solute transport simulation technology were used to analyze fluids flow and migration in the intra-salt and sub-salt reservoirs, determine the mineral dissolution, precipitation, and transformation in the reservoir caused by the deep fluids, and calculate the changes in reservoir porosity. Results show that deep fluid migrates preferentially along dominant channels and triggers a series of fluid–rock chemical reactions. In the first stage, a large amount of anhydrite precipitated in the fault as a result of upward migration of deep saline fluid, resulting in the formation of anhydrite veins and blockage at the base of the fault. In the second stage, organic acids caused minerals dissolution and a vertical channel was opened in previously blocked area, which promoted continuous upward migration of organic acids and the formation of secondary pores. This study clarifies the transformative effects of deep alkaline and acidic fluids on the reservoir. Moreover, the important fluid transport role of faults and their effect on reservoir development were determined.

关键词： Saline lacustrine basin Alkaline and acidic fluids Fault-belt reservoir Mineral transformation Physical conditions

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Regiocontrolled Rh(Ⅲ)-catalyzed C-C coupling/C-N cyclization mediated by distinctive 1,2-migratory insertion of gem-difluoromethylene allenes:Reaction development and mechanistic insight

引用

Chinese Chemical Letters 2023年第5期34卷 250-255页

作者： zhi Zhou Kaifeng Chen yi Wang Xiuhua Zhong Shuang Lin Hui Gao wei yi Guangzhou Municipal and Guangdong Provincial Key Laboratory of Molecular Target&Clinical Pharmacology NMPA and State Key Laboratory of Respiratory DiseaseSchool of Pharmaceutical Sciences and the Fifth Affiliated HospitalGuangzhou Medical UniversityGuangzhou 511436China

By developing gem-difluoromethylene allenes as viable partners,regiocontrolled Rh(Ⅲ)-catalyzed redoxneutral C-C coupling/C-N cyclization has been realized to build the pyridin-2(1H)-one motifs with the embedment of a Z-configured monofluoroalkene functionality,in which either(hetero)aromatic or vinylic amides were found to be *** experimental and computational mechanistic studies revealed that a tandem regioselective allene 1,2-insertion/β-H elimination/hydrogen transfer/oxidative addition/cyclization/cis-β-F elimination involving an unconventional Rh(Ⅲ)-Rh(I)-Rh(Ⅲ)catalytic cycle accounts for the established *** further FMO analysis and IGMH maps,a non-covalent weak interaction network between the gem-difluoromethylene part and the OPiv moiety was rationally defined for the unconventional and specific regioselectivity control.

关键词： Gem-difluoromethylene allenes C-H functionalization Regiocontrol Rhodium(Ⅲ)catalysis DFT calculations

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Enantioselective synthesis of indenopyrazolopyrazolones enabled by dual directing groups-assisted and rhodium(Ⅲ)-catalyzed tandem C-H alkenylation/[3+2] stepwise cycloaddition

引用

Chinese Chemical Letters 2022年第2期33卷 842-846页

作者： Min Wu Hui Gao Huiying Xu wei yi zhi Zhou Guangzhou Municipal and Guangdong Provincial Key Laboratory of Protein Modiﬁcation and Degradation&Molecular Target and Clinical Pharmacology State Key Laboratory of Respiratory DiseaseSchool of Pharmaceutical SciencesGuangzhou Medical UniversityGuangzhou 511436China

The Cp;Rh(Ⅲ)-catalyzed asymmetric cascade C-H coupling/intramolecular cyclization of azomethine imines with propargyl carbonates has been developed, affording a variety of chiral tetracyclic indenopyrazolopyrazolone frameworks with good substrate/functional group tolerance and enantioselectivity(up to 97:3 er). Combined experimental studies and DFT calculations revealed the Rh(Ⅲ)-catalyzed stepwise annulation process and clarified the synergy coordination mode of dual directing groups in tuning the selectivity.

关键词： Indenopyrazolopyrazolone Azomethine imine Enantioselective synthesis DFT calculations Rhodium(Ⅲ)catalysis

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Research on construction of operation architecture based on complex network

引用

Defence Technology（防务技术） 2020年第1期16卷 232-241页

作者： You Chen Xing Wang Yuan-zhi Yang Cheng-wei Ruan yi-peng Zhou Xidian University Xi'anShaanxiChina Aeronautics Engineering College Air Force Engineering UniversityXi'anShaanxiChina 95910 Army JiuquanGansuChina

Operation architecture plays a more important role in Network Centric Warfare(NGAV),which involves dynamic operation networks with complex ***,it is essential to investigate the operation architecture under the informatization condition within NCAW and find a proper network construction method to efficiently coordinate various functional modules on a particular situation,i.e.,the aerial combat.A new method integrating the physical level and functional level of NCW is proposed to establish the operation architecture,where the concept of network operation constraints unit and net constructing mechanisms are employed to avoid conflicts among different ***,we conduct simulations to assess the effectiveness and feasibility of the constructed operation architecture and analyze the influence of the network parameters.

关键词： Operation architecture Network centric warfare Topology Complex network

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Nanocrystallization-locked Network of Poly(styrene-6-isobutylene-6-styrene)-g-Polytetrahydrofuran Block Graft Copolymer

引用

Chinese Journal of Polymer Science 2021年第7期39卷 874-886页

作者： Hang-Tian Zhang zhi-Tao wei Fang Zhang Tian Yang yi-Xian Wu State Key Laboratory of Chemical Resource Engineering Beijing Advanced Innovation Center for Soft Matter Sciences and EngineeringBeijing Laboratory of Biomedical MaterialsBeijing University of Chemical TechnologyBeijing 100029China

Poly(styrene-6-isobutylene-6-styrene)triblock copolymer(SIBS),a kind of thermoplastic elastomer with biocompatibility and biostability containing fully saturated soft segments,could be synthesized via living cationic copolymerization.A novel poly[(styrene-co-methylstyrene)-b-isobutylene-b-(styrene-co-methylstyrene)]-g-polytetrahydrofuran(M-SIBS-g-PTHF)block graft copolymer was prepared to increase the polarity and service temperature of SIBS by grafting polar PTHF segments onto SIBS.A series of the above block graft copolymers with average grafting numbers from 2 to 6 and molecular weights of PTHF branches ranging from 200 g·mol^(-1)to 4200 g·mol^(-1)were successfully synthesized via living cationic ring-opening polymerization of tetrahydrofuran(THF)coinitiated by *** introduction of PTHF branches led to an obvious microphase separation due to thermodynamic incompatibility among the three kinds of segments of polyisobutylene(PIB),polystyrene(PS)and ***,the microphase separation promotes the rearrangement of PTHF branches to form the nanocrystallization-locked physically cross-linked network after storage at room temperature for 2 months,leading to insolubility of the copolymers even in good *** melting temperature and enthalpy of PTHF nanocrystallization locked in hard domains of M-SIBS-g5-PTHF-1.1k block graft copolymer increased remarkably up to 153℃and 117.0 J·g^(-1)by 23℃and 11.6 J·g^-1(respectively after storage for long *** modulus(G′)is higher than loss modulus(G″)of M-SIBS-g-PTHF block graft copolymer at temperatures ranging from 100℃to 180℃,which is much higher than those of the SIBS triblock *** the best of our knowledge,this is the first example of high performance M-SIBS-g-PTHF block graft copolymers containing segments of PIB,PS and PTHF with nanocrystallization-locked architecture.

关键词： Poly(styrene-b-isobutylene-b-styrene) Polytetrahydrofuran Living cationic polymerization Block graft copolymers Nanocrystallization-locked network

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Research on a TOPSIS energy efficiency evaluation system for crude oil gathering and transportation systems based on a GA-BP neural network

引用

Petroleum Science 2024年第1期21卷 621-640页

作者： Xue-Qiang Zhang Qing-Lin Cheng wei Sun yi Zhao zhi-Min Li Key Lab of Ministry of Education for Enhancing the Oil and Gas Recovery Ratio Northeast Petroleum UniversityDaqing163318HeilongjiangChina China Petroleum Pipeline Material and Equipment Co. LtdLangfang065000HebeiChina Research Institute of Petroleum Engineering and Technology Sinopec Northwest Oilfield CompanyUrumqi830011XinjiangChina

As the main link of ground engineering,crude oil gathering and transportation systems require huge energy consumption and complex *** is necessary to establish an energy efficiency evaluation system for crude oil gathering and transportation systems and identify the energy efficiency *** this paper,the energy efficiency evaluation system of the crude oil gathering and transportation system in an oilfield in western China is *** with the big data analysis method,the GA-BP neural network is used to establish the energy efficiency index prediction model for crude oil gathering and transportation *** comprehensive energy consumption,gas consumption,power consumption,energy utilization rate,heat utilization rate,and power utilization rate of crude oil gathering and transportation systems are *** the efficiency and unit consumption index of the crude oil gathering and transportation system,the energy efficiency evaluation system of the crude oil gathering and transportation system is established based on a game theory combined weighting method and TOPSIS evaluation method,and the subjective weight is determined by the triangular fuzzy analytic hierarchy *** entropy weight method determines the objective weight,and the combined weight of game theory combines subjectivity with objectivity to comprehensively evaluate the comprehensive energy efficiency of crude oil gathering and transportation systems and their ***,the weak links in energy utilization are identified,and energy conservation and consumption reduction are *** above research provides technical support for the green,efficient and intelligent development of crude oil gathering and transportation systems.

关键词： Crude oil gathering and transportation system GA-BP neural network Energy efficiency evaluation TOPSIS evaluation method Energy saving and consumption reduction

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Single-atom Ag-loaded carbon nitride photocatalysts for efficient degradation of acetaminophen:The role of Ag-atom and O_(2)

引用

Journal of Environmental Sciences 2024年第5期139卷 12-22页

作者： yi Yuan Wen-Long Wang zhi-wei Wang Jin Wang Qian-Yuan Wu Key Laboratory of Microorganism Application and Risk Control of Shenzhen Guangdong Provincial Engineering Research Center for Urban Water Recycling and Environmental SafetyInstitute of Environment and EcologyShenzhen International Graduate SchoolTsinghua UniversityShenzhen 518055China Shenzhen Environmental Science and New Energy Technology Engineering Laboratory Tsinghua-Berkeley Shenzhen InstituteShenzhen 518055China College of Materials Science and Engineering Shenzhen UniversityShenzhen 518071China

Carbon nitride has been extensively used as a visible-light photocatalyst,but it has the disadvantages of a low specific surface area,rapid electron-hole recombination,and relatively low light *** this study,single-atom Ag was successfully anchored on ultrathin carbon nitride(UTCN)via thermal polymerization,the catalyst obtained is called *** Ag hardly changed the carbon nitride's layered and porous physical *** exhibited efficient visible-light photocatalytic performances in the degradation of various recalcitrant pollutants,eliminations of 85% were achieved by visible-light irradiation for *** with Ag improved the photocatalytic performance of UTCN by narrowing the forbidden band gap from 2.49 to 2.36 e V and suppressing electron-hole pair *** addition,Ag doping facilitated O_(2) adsorption on UTCN by decreasing the adsorption energy from -0.2 to -2.22 e V and favored the formation of O_(2)^(·-).Electron spin resonance and radical-quenching experiments showed that O_(2)^(·-)was the major reactive species in the degradation of Acetaminophen(paracetamol,APAP).

关键词： Ag single atom Carbon nitride Photocatalysis Visible light Adsorption energy Reactive species

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Role of iron ore in enhancing gasification of iron coke:Structural evolution,influence mechanism and kinetic analysis

引用

International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 58-69页

作者： Jie Wang wei Wang Xuheng Chen Junfang Bao Qiuyue Hao Heng Zheng Runsheng Xu School of Chemistry and Materials Science Hubei Engineering UniversityXiaogan 432000China Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education Wuhan University of Science and TechnologyWuhan 430081China Institue of Ironmaking Technology Baosteel Central Research InstituteShanghai 201999China State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing 100083China

The utilization of iron coke provides a green pathway for low-carbon *** uncover the influence mechanism of iron ore on the behavior and kinetics of iron coke gasification,the effect of iron ore on the microstructure of iron coke was ***,a comparative study of the gasification reactions between iron coke and coke was conducted through non-isothermal thermogravimetric *** findings indicate that compared to coke,iron coke exhibits an augmentation in micropores and specific surface area,and the micropores further extend and *** provides more adsorption sites for CO_(2) molecules during the gasification process,resulting in a reduction in the initial gasification temperature of iron *** the heating rate in non-isothermal gasification can enhance the reactivity of iron *** metallic iron reduced from iron ore is embedded in the carbon matrix,reducing the orderliness of the carbon structure,which is primarily responsible for the heightened reactivity of the carbon *** kinetic study indicates that the random pore model can effectively represent the gasification process of iron coke due to its rich pore ***,as the proportion of iron ore increases,the activation energy for the carbon gasification gradually decreases,from 246.2 kJ/mol for coke to 192.5 kJ/mol for iron coke 15wt%.

关键词： low-carbon ironmaking iron coke gasification structural evolution kinetic model

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

A long way to go:impacts of urbanization on migrants’livelihoods and rural ecology in less industrialized regions

引用

Journal of Mountain Science 2023年第12期20卷 3450-3463页

作者： ZHANG zhi-qi LI Ming-jing LI Wen-jun wei yi-ran SHI yi-lu Department of Environmental Management Peking UniversityBeijing 100871China

Urbanization,often coupled with industrialization,is generally considered as a boost for improving livelihood as well as alleviating ecological pressures of the rural ***,this experience needs to be tested in less industrialized areas,particularly where the urbanization is driven by non-economic factors such as urban public services and relevant government policies rather than employment *** two villages on the Qinghai-Tibet Plateau as examples,through the field investigation by using semi-structured questionnaires and in-depth interviews,and statistical data analysis,we explored the impacts of urbanization on migrants’livelihoods and the ecological conditions of their original village *** found that the disposable income and savings of emigrant households were less than the stay households,which might be correlated to the limited employment due to the lagged industrialization in the local township,and the mismatch between their traditional labor skills and the demands of urban *** home-village rangeland overuse was not alleviated since the increasing grazing pressure caused by the stay households,though the emigrant households intended to decrease the number of livestock on their home *** concluded that the urbanization misaligned with local industrialization may fail to improve migrant livelihoods and local ecological conditions in less industrialized *** research supplements the previous urbanization theory by highlighting the non-industrialization driven urbanization,and is particularly pertinent for the transitional countries worldwide.

关键词： Urbanization Industrialization Livelihoods Ecological conditions Pastoral areas Qinghai-Tibet Plateau

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Regression Analysis of the Number of Association Rules

引用

International Journal of Automation and computing 2011年第1期8卷 78-82页

作者： wei-Guo yi Ming-Yu Lu zhi Liu Department of Information Science and Technology Dalian Maritime University Dalian 116026 PRC Department of Software Institute Dalian Jiaotong University Dalian 116052 PRC

The typical model, which involves the measures： support, confidence, and interest, is often adapted to mining association rules. In the model, the related parameters are usually chosen by experience; consequently, the number of useful rules is hard to estimate. If the number is too large, we cannot effectively extract the meaningful rules. This paper analyzes the meanings of the parameters and designs a variety of equations between the number of rules and the parameters by using regression method. Finally, we experimentally obtain a preferable regression equation. This paper uses multiple correlation coeficients to test the fitting efiects of the equations and uses significance test to verify whether the coeficients of parameters are significantly zero or not. The regression equation that has a larger multiple correlation coeficient will be chosen as the optimally fitted equation. With the selected optimal equation, we can predict the number of rules under the given parameters and further optimize the choice of the three parameters and determine their ranges of values.

关键词： Association rules regression analysis multiple correlation coeficients interest support confidence.

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：