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Strong and tough chitin hydrogel constructed by dehydration and rehydration strategy

Nano Research 2024年第9期17卷 8192-8199页

作者： Rui-Rui liu Li-Bo Mao Shu-hong Yu Division of Nanomaterials and Chemistry Hefei National Research Center for Physical Sciences at the MicroscaleDepartment of ChemistryInstitute of Biomimetic Materials and ChemistryAnhui Engineering Laboratory of Biomimetic MaterialsUniversity of Science and Technology of ChinaHefei 230026China Institute of Innovative Materials Department of Materials Science and EngineeringDepartment of ChemistrySouthern University of Science and TechnologyShenzhen 518055China

As a renewable,biocompatible,biodegradable soft material,chitin hydrogels have better advantages in stability,antibacterial activity,antifouling,cost,immunogenicity,and so on than most polymer ***,compared with other widely used polymer hydrogels with high strength and toughness,the practical applications of chitin-based hydrogels have been limited by their weak mechanical properties,such as cartilage repair and meniscus ***,we present the design and fabrication of chitin hydrogels with excellent mechanical strength and toughness by a dehydration and rehydration *** sequential dehydration and rehydration processes,the crystalline domains in the chitin hydrogels can be properly *** optimized crystallinity,the elastic modulus of the chitin hydrogels exceeds all previously reported values,and the fracture toughness is even comparable to some synthetic polymer hydrogels,while maintaining a high-water-content of about 80 wt.%.At the same water content,the mechanical properties of the chitin hydrogels are positively correlated with the hydrogel crystallinity,which proves that the change of mechanical properties of hydrogels is not simply dependent on weight *** hydrogels can be further strengthened by incorporating other biopolymers that are intrinsically weak,which makes the hydrogels promising for applications in fields such as cartilage repair and meniscus ***,the hydrogels enable loading and release of water-soluble and poorly water-soluble *** highly extendable strengthening and toughening strategy of chitin and chitin-based biopolymer hydrogels paves the way for their widely applications.

关键词： chitin hydrogel crystallinity rehydration chemical transformation strong and tough

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A path planning algorithm for a crop monitoring fixed-wing unmanned aerial system

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Science China(Information Sciences) 2024年第8期67卷 5-23页

作者： Longhao QIAN Yi Lok LO Hugh hong-tao liu Institute of Aerospace Studies University of Toronto Department of Mechanical Engineering The University of Hong Kong

With the growing demand for automation in agriculture, industries increasingly rely on drones to perform crop monitoring and surveillance. In this regard, fixed-wing unmanned aerial systems(UASs)are viable platforms for scanning a large crop field, given their payload capacity and range. To achieve maximum coverage without landing for battery replacement, an algorithm for producing a minimal required energy survey path is essential. Hence, an energy-aware coverage path planning algorithm is proposed *** constraints for a fixed-wing UAS to fly at low altitudes while achieving full coverage of the crop field are first analyzed. Then, the full path is decomposed into straight-line and U-turn primitives. Finally, an algorithm to calculate a combination of straight-line segments and U-turns is proposed to obtain the path with minimum required energy consumption. The genetic algorithm is used to efficiently determine the order of the straight-line paths to traverse. Case studies show that the proposed algorithm can produce planning results for a convex-polygon-shaped crop field.

关键词： path planning genetic algorithm energy minimization fixed-wing UAS aerial survey

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Stratigraphic framework and sedimentary evolution during the Cryogenian-Ediacaran transition in northeastern Sichuan Basin,South China

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Petroleum Science 2024年第2期21卷 823-835页

作者： Yi Zhang hong-Wei Kuang Yong-Qing liu Qiang Shi Dong-Ge Wang Ke-Ning Qi Yu-Chong Wang Da-Wei Qiao Xiao-Shuai Chen Li-zhi Wu Meng Tian Long Chen Yi Wei Liao-Yuan Song Jian Li Zi-Gang Wu Yun-Qian liu Xuan-Chun liu An-Qing Chen zhi-Wei Liao Institute of Geology Chinese Academy of Geological SciencesBeijing100037China State Key Laboratory of Coal Mine Disaster Dynamics and Control School of Resources and Safety EngineeringChongqing UniversityChongqing400044China No.205 Geological Team Chongqing Bureau of Geology and Minerals ExplorationChongqing401121China Chongqing Institute of Geological Survey Chongqing401122China Key Laboratory of Deep-time Geography and Environment Reconstruction and Applications of Ministry of Natural Resources Chengdu University of TechnologyChengdu610059SichuanChina

The northeastern Sichuan area in the northern Yangtze margin has unique Ediacaran geological records,especially the Doushantuo Formation(DST),and become a hot research area in recent ***,the Cryogenian-Ediacaran(C-E)boundary has not been precisely identified,which restricts the in-depth study of geological information during this crucial transitional period and is unfavorable for a systematic and complete understanding of the Yangtze Block and even the global paleogeographic *** study conducted stratigraphy,sedimentology,and chronostratigraphy to establish the stratigraphic framework and sedimentary evolution of the C-E transition strata in northeastern *** results showed that the Ediacaran sediments,without the cap dolomite,unconformably overlaid the Cryogenian sediments in the studied *** Member II of the DST,characterized by 50-160 m of red-green sandstone(approximately equivalent to the original Chengkou“Guanyinya Formation”),directly overlaid the Cryogenian sediments and displayed a 623±2.3 Ma maximum depositional age from the detrital zircon U-Pb *** stratigraphic correlations indicate that the C-E transition strata in northeastern Sichuan had a consistent lithological association and sedimentary sequence characteristics but differed from the Three ***,the upper Nantuo massive glacial diamictites transition to the icebergs rafted lonestone-bearing mudstones at the top,then change upward to DST barrier coast *** proposed DST of the northeastern Sichuan Basin was divided into three lithostratigraphic members without the regional Member I cap dolomite:(i)Member II purple-red,gray-green sandstone strata,(ii)MemberⅢblack mudstone strata,and(iii)Member IV P-Mn bearing *** the C-E transition,the study area experienced(i)the global deglaciation stage in the terminal Marinoan glaciation and(ii)the filling-leveling up stage with clastic rocks in the early ***,the early Ediacaran

关键词： Marinoan glaciation Doushantuo formation Cap dolomite Deglacial and coastal deposits Detrital zircon U-Pb dating

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Depositional process of hyperpycnal flow deposits:A case study on Lower Cretaceous Sangyuan outcrop in the Luanping Basin,Northeast China

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China Geology 2024年第3期7卷 505-516页

作者： De-zhi Yan Ru-kai Zhu Hao Shou Zhao-hui Xu Wei-hong liu Si-cheng Zhu zhi-cheng Lei Jing-ya Zhang Chang liu Yi Cai Huai-min Xu Research Institute of Petroleum Exploration and Development PetroChinaBeijing 100083China National Energy Tight Oil and Gas R&D Center Beijing 100083China PetroChina Key Laboratory of Oil and Gas Reservoir Beijing 100083China State Key Laboratory of Petroleum Resources and Prospecting China University of Petroleum(Beijing)Beijing 102249China College of Geosciences China University of Petroleum(Beijing)Beijing 102249China Jiangxi Engineering Laboratory on Radioactive Geoscience and Big Data Technology Department of Information and EngineeringEast China University of TechnologyNanchang 330013China

Sedimentary process research is of great significance for understanding the distribution and characteristics of *** the detailed observation and measurement of the Sangyuan outcrop in Luanping Basin,this paper studies the depositional process of the hyperpycnal flow deposits,and divides their depositional process into three phases,namely,acceleration,erosion and *** the acceleration phase,hyperpycnal flow begins to enter the basin nearby,and then speeds up *** developed in the acceleration phase are *** addition,the original deposits become unstable and are taken away by hyperpycnal flows under the eroding *** a result,there are a lot of mixture of red mud pebbles outside the basin and gray mud pebbles within the *** the erosion phase,the reverse deposits are eroded and become thinner or even ***,no reverse grading characteristic is found in the proximal major channel that is closer to the source,but it is still preserved in the middle branch channel that is far from the *** entering the deceleration phase,normally grading deposits appear and cover previous *** final deposits in the basin are *** are reverse,and others are *** are superimposed with each other under the action of hyperpycnal *** analysis of the Sangyuan outcrop demonstrates the sedimentary process and distribution of hyperpycnites,and reasonably explain the sedimentary characteristics of *** is helpful to the prediction of oil and gas exploration targets in gravity flow deposits.

关键词： Hyperpycnal flow Sedimentary characteristics Depositional process Gravity flow deposit Hyperpycnite Red mud pebble Gray mud pebble Oil and gas exploration engineering Luanping Basin

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Preparing cyclic polymers at high concentrations via self-folding cyclization technique by adjusting the contents of hydrophilic units in linear precursors

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Chinese Chemical Letters 2024年第2期35卷 283-288页

作者： Hao Zha Zuowei Wang Chao liu Chunyan hong Department of Polymer Science and Engineering University of Science and Technology of ChinaHefei 230026China Hefei National Laboratory for Physical Sciences at the Microscale University of Science and Technology of ChinaHefei 230026China

Cyclic polymers are a class of polymers that feature endless topology,and the synthesis of cyclic polymers has attracted the attention of many ***,cyclic polymers were efficiently constructed by self-folding cyclization technique at high *** poly((oligo(ethylene glycol)acrylate)-co-(dodecyl acrylate))(P(OEGA-co-DDA))precursors with different ratios of hydrophilic and hydrophobic moieties were synthesized by reversible addition-fragmentation chain transfer(RAFT)polymerization using a bifunctional chain transfer agent with two anthryl end *** amphiphilic linear precursors underwent the self-folding process to generate polymeric nanoparticles in *** irradiating the aqueous solution of the nanoparticles with 365 nm UV light,cyclic polymers were synthesized successfully via coupling of anthryl *** effects of the ratios of hydrophilic and hydrophobic moieties in linear P(OEGA-co-DDA)copolymers and polymer concentration on the purity of the obtained cyclic polymers were explored in detail via ^(1)H nuclear magnetic resonance(^(1)H NMR),dynamic light scattering(DLS),UV‒visible(vis)analysis,three-detection size exclusion chromatography(TD-SEC)and transmission electron microscopy(TEM).It was found that by adjusting the content of the hydrophilic segments in linear precursors,single chain polymeric nanoparticles(SCPNs)can be generated at high polymer ***,cyclic polymers with high purity can be constructed *** method overcomes the limitation of traditional ring-closure method,which is typically conducted in highly dilute conditions,providing an efficient method for the scalable preparation of cyclic polymers.

关键词： Cyclic polymers Self-folding cyclization technique Single chain polymeric nanoparticles RAFT polymerization Direct visualization

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Boundary Regularity of Isometries Between Infinitely Flat Complex Domains

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Acta Mathematica Sinica,English Series 2024年第6期40卷 1375-1387页

作者： Jin Song liu Fei TAO hong Yu WANG Academy of Mathematics and Systems Science Chinese Academy of SciencesBeijing 100190P.R.China School of Mathematical Sciences University of Chinese Academy of SciencesBeijing 100049P.R.China Beijing International Center for Mathematical Research Peking UniversityBeijing 100871P.R.China School of Science Beijing University of Posts and TelecommunicationsBeijing 100876P.R.China Key Laboratory of Mathematics and Information Networks(Beijing University of Posts and Telecommunications) Ministry of EducationBeijing 100876P.R.China

In this paper we prove that isometries with respect to the Kobayashi metric between certain domains having boundary points at which the boundary is infinitely flat extend continuously to the *** strategy is to reestab... 详细信息

关键词： Boundary extension Kobayashi metric isometries

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Characteristics and geological significance of carbon and oxygen isotopes of the Permian Lucaogou Formation dolomite in the southern Junggar Basin, northwestern China

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Journal of Palaeogeography 2024年第4期13卷 862-882页

作者： Gang liu Guo-zhi Wang Na Li hong-Ling He Nan-Nan Lu Qing Lei Zi-Ang Wang College of Earth and Planetary Sciences Chengdu University of Technology National Key Laboratory of Oil and Gas Reservoir Geology and Exploitation Chengdu University of Technology Hebei Survey Institute of Coal Geology Sichuan Earthquake Agency

Anomalously positive δ13C values in ancient dolomites are very *** gray argillaceous rocks of the lacustrine sediments of the Permian Lucaogou Formation are important source rocks in the Junggar Basin,and dolomites of varying thicknesses from 10 cm to 150 cm are often interspersed in argillaceous *** on the study of petrographic sections,this paper systematically analyzes the carbon and oxygen isotopes of dolomite and discusses the causes of abnormally high carbon isotope values and their significance in reconstructing paleoenvironment and *** results show that carbon isotope values are abnormally high in the dolomite of Lucaogou Formation,and the δ13C value is between+3.2‰PDB and+19.6‰PDB,with an average of+9.7‰*** δ18O values range from-17.4‰PDB to-1.7‰PDB,with an average of-8.1‰*** the lower part to the upper part of the Lucaogou Formation,the carbon isotope value gradually increases and becomes increasingly positive,and the carbon isotope of the dolomite deposited near the shore is more positive than that of the dolomite deposited far from the *** anomalously positive δ13C of the dolomite is mainly caused by microbial methanogenesis,with some contribution from *** are mainly distributed at the redox *** controls the salinity and fluctuation of the redox interface in sedimentary *** positive deviation difference in carbon isotopes between nearshore and offshore sedimentary dolomites may be related to the location of the redox interface during ***,the petrographic features and carbon and oxygen isotope signatures of the sections reflect the gradual evolution of the paleolake from a hydrologically open environment to a hydrologically closed one and the possible transition of the paleoclimate from a relatively warm to an arid condition,which is possibly a geochemical response to global climate change in the Permian period.

关键词： Junggar Basin Lucaogou Formation Dolomite Positive carbon isotope anomaly Paleoenvironment

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Seed-Specific Overexpression of Bnrbc S from Oilseed Increases Seed Weight and Oil Content in Arabidopsis thaliana

Seed-Specific Overexpression of Bnrbc S from Oilseed Increas...

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2010全国植物生物学研讨会

作者： Xue-Long Wu zhi-hong liu Si-Wei Yuan Rui-zhi Huang Key Laboratory of Plant Metabolic Engineering of Zhejiang Province Institute of Virology and Biotechnology Zhejiang Academy of Agricultural Sciences

Ribulose-1,5-bisphosphate carboxylase/oxygenase(Rubisco),which catalyzes the first step of CO2fixation,is the key photosynthetic enzyme to convert atmospheric carbon to food and support life on the *** higher plants,R... 详细信息

关键词： BnrbcS Brassica napus gene seed weight oil content

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Multi-Scale Fusion Model Based on Gated Recurrent Unit for Enhancing Prediction Accuracy of State-of-Charge in Battery Energy Storage Systems

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Journal of Modern Power Systems and Clean Energy 2024年第2期12卷 405-414页

作者： Hao liu Fengwei Liang Tianyu Hu Jichao hong Huimin Ma School of Computer and Communication Engineering University of Science and Technology BeijingBeijingChina School of Mechanical Engineering University of Science and Technology BeijingBeijingChina IEEE

Accurate prediction of the state-of-charge(SOC)of battery energy storage system(BESS)is critical for its safety and lifespan in electric *** overcome the imbalance of existing methods between multi-scale feature fusion and global feature extraction,this paper introduces a novel multi-scale fusion(MSF)model based on gated recurrent unit(GRU),which is specifically designed for complex multi-step SOC prediction in practical *** correlation analysis is first employed to identify SOC-related *** parameters are then input into a multi-layer GRU for point-wise feature ***,the parameters undergo patching before entering a dual-stage multi-layer GRU,thus enabling the model to capture nuanced information across varying time ***,by means of adaptive weight fusion and a fully connected network,multi-step SOC predictions are *** extensive validation over multiple days,it is illustrated that the proposed model achieves an absolute error of less than 1.5%in real-time SOC prediction.

关键词： Electric vehicle battery energy storage system(BESS) state-of-charge(SOC)prediction gated recurrent unit(GRU) multi-scale fusion(MSF).

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Impact of Mo/Ni alloying on microstructural modulation and low-temperature toughness of high-strength low-alloy steel

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Journal of Iron and Steel Research International 2024年第7期31卷 1746-1762页

作者： Wei liu hong-li Zhao Bing-xing Wang Yong Tian State Key Laboratory of Rolling and Automation Northeastern UniversityShenyang 110819LiaoningChina

The high-strength low-alloy steel plates with varying Ni/Mo contents were manufactured using the thermos-mechanical control *** investigation was conducted to explore the effect of Ni/Mo microalloying on microstructure evolution and mechanical properties of the *** results revealed that the increase in Ni content from 1 to 2 wt.%reduced the transition temperature of ferrite and the growth range of ferritic grain was narrowed,which promoted grain *** optimized combination of grain size,high-angle grain boundaries(HAGBs),and martensite-austenite(M-A)islands parameter contributed to the excellent impact toughness of S1 steel at-100℃(impact absorbed energy of 218.2 J at-100℃).As the Mo increases from 0 to 2 wt.%,the matrix structure changes from multiphase structure to granular bainite,which increases the average effective grain size to~4.62 pm and reduces HAGBs proportion to~36.22%.With these changes,the low-temperature impact toughness of S3 steel is *** addition,based on the analysis of the characteristics of crack propagation path,it was found that M-A islands with low content(~2.21%)and small size(~1.76 pm)significantly retarded crack propagation,and the fracture model of M-A islands with different morphologies was further ***,correlation between behaviour of delamination and toughness was further analysed by observing delamination size and impact energy parameters.

关键词： High-strength low-alloy steel Microstructural regulation Ni addition Mo addition Crack propagation Low-temperature toughness

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